• Title/Summary/Keyword: High-spin

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Light-emitting Diodes based on a Densely Packed QD Film Deposited by the Langmuir-Blodgett Technique (랭뮤어-블롯젯을 통해 형성된 고밀도 양자점 박막과 이를 기반으로 한 발광다이오드)

  • Rhee, Seunghyun;Jeong, Byeong Guk;Roh, Jeongkyun
    • Journal of Sensor Science and Technology
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    • v.31 no.4
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    • pp.249-254
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    • 2022
  • To achieve high-performance colloidal quantum dot light-emitting diodes (QD-LEDs), the use of a densely packed QD film is crucial to prevent the formation of leakage current pathways and increase in interface resistance. Spin coating is the most common method to deposit QDs; however, this method often produces pinholes that can act as short-circuit paths within devices. Since state-of-the-art QD-LEDs typically employ mono- or bi-layer QDs as an emissive layer because of their low conductivities, the use of a densely packed and pinhole-free QD film is essential. Herein, we introduce the Langmuir-Blodgett (LB) technique as a deposition method for the fabricate densely packed QD films in QD-LEDs. The LB technique successfully transfers a highly dense monolayer of QDs onto the substrate, and multilayer deposition is performed by repeating the transfer process. To validate the comparability of the LB technique with the standard QD-LED fabrication process, we fabricate and compare the performance of LB-based QD-LEDs to that of the spin-coating-based device. Owing to the non-destructiveness of the LB technique, the electroluminescence efficiency of the LB-based QD-LEDs is similar to that of the standard spin coating-based device. Thus, the LB technique is promising for use in optoelectronic applications.

Model order reduction for Campbell diagram analysis of shaft-disc-blade system in 3D finite elements

  • Phuor, Ty;Yoon, GilHo
    • Structural Engineering and Mechanics
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    • v.81 no.4
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    • pp.411-428
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    • 2022
  • This paper presents the Campbell diagram analysis of the rotordynamic system using the full order model (FOM) and the reduced order model (ROM) techniques to determine the critical speeds, identify the stability and reduce the computational time. Due to the spin-speed-dependent matrices (e.g., centrifugal stiffening matrix), several model order reduction (MOR) techniques may be considered, such as the modal superposition (MS) method and the Krylov subspace-based MOR techniques (e.g., Ritz vector (RV), quasi-static Ritz vector (QSRV), multifrequency quasi-static Ritz vector (MQSRV), multifrequency/ multi-spin-speed quasi-static Ritz vector (MMQSRV) and the combined Ritz vector & modal superposition (RV+MS) methods). The proposed MMQSRV method in this study is extended from the MQSRV method by incorporating the rotational-speed-dependent stiffness matrices into the Krylov subspace during the MOR process. Thus, the objective of this note is to respond to the question of whether to use the MS method or the Krylov subspace-based MOR technique in establishing the Campbell diagram of the shaft-disc-blade assembly systems in three-dimensional (3D) finite element analysis (FEA). The Campbell diagrams produced by the FOM and various MOR methods are presented and discussed thoroughly by computing the norm of relative errors (ER). It is found that the RV and the MS methods are dominant at low and high rotating speeds, respectively. More precisely, as the spinning velocity becomes large, the calculated ER produced by the RV method is significantly increased; in contrast, the ER produced by the MS method is smaller and more consistent. From a computational point of view, the MORs have substantially reduced the time computing considerably compared to the FOM. Additionally, the verification of the 3D FE rotordynamic model is also provided and found to be in close agreement with the existing solutions.

Exotic superconducting state under high magnetic fields: Insights from iron-based superconductor

  • Min Jae Kim;Jong Mok Ok
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.2
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    • pp.1-4
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    • 2023
  • Over the past decade, the exploration of high-temperature superconductivity and the discovery of a wide range of exotic superconducting states in Fe-based materials have propelled condensed matter physics research to new frontiers. These materials exhibit intriguing phenomena arising from their multiband electronic structure, strongly orbital-dependent effects, extremely small Fermi energy, electronic nematicity, and topological aspects. Among the various factors influencing their superconducting properties, high magnetic fields play a crucial role as a control knob capable of disrupting the subtle balance between the spin, charge, lattice, and orbital degrees of freedom, leading to the emergence of various exotic superconducting states. In this review, we provide an overview of the current understanding of the exotic superconducting states observed in Fe-based superconductors, with a particular focus on FeSe and Sr2VO3FeAs, under the influence of high magnetic fields.

Sizes and Structures of Micelles of Cationic Octadecyl Trimethyl Ammonium Chloride and Anionic Ammonium Dodecyl Sulfate Surfactants in Aqueous Solutions

  • Kim, Hong-Un;Lim, Kyung-Hee
    • Bulletin of the Korean Chemical Society
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    • v.25 no.3
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    • pp.382-388
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    • 2004
  • The sizes and structures of micelles formed in aqueous solutions of cationic octadecyl trimethyl ammonium chloride (OTAC) and anionic ammonium dodecyl sulfate (ADS) surfactants were investigated using smallangle neutron scattering (SANS), self-diffusion coefficients by pulsed-gradient spin-echo (PGSE) NMR, and dynamic light scattering (DLS) methods. SANS and DLS data indicate that their structures are spherical at concentrations as high as 300 mM. As the total surfactant concentration increases, the peaks of SANS spectra shift to higher scattering vector and become sharper, indicating that the intermicellar distance decreases and its distribution becomes narrower. This is due to more compact packing of surfactant molecules at high concentrations. The intermicellar distance of around 100 ${\AA}$ above 200 mM corresponds approximately to the diameter of one micelle. The sizes of spherical micelles are 61 ${\AA}$ and 41 ${\AA}$ for 9 mM OTAC and 10 mM ADS, respectively. Also the self-diffusion coefficients by PGSE-NMR yield the apparent sizes 96 ${\AA}$ and 31 ${\AA}$ for micelles of 1 mM OTAC and 10 mM ADS, respectively. For ADS solutions of high concentrations (100-300 mM), DLS data show that the micelle size remains constant at $25{\pm}2{\AA}$. This indicates that the transition in micellar shape does not take place up to 300 mM, which is consistent with the SANS results.

Solution-processed Dielectric and Quantum Dot Thin Films for Electronic and Photonic Applications

  • Jeong, Hyeon-Dam
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.37-37
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    • 2010
  • Silicate-silsesquioxane or siloxane-silsesquioxane hybrid thin films are strong candidates as matrix materials for ultra low dielectric constant (low-k) thin films. We synthesized the silicate-silsesquioxane hybrid resins from tetraethoxyorthosilicate (TEOS) and methyltrimethoxysilane (MTMS) through hydrolysis and condensation polymerization by changing their molar ratios ([TEOS]:[MTMS] = 7:3, 5:5, and 3:7), spin-coating on Si(100) wafers. In the case of [TEOS]:[MTMS] 7:3, the dielectric permittivity value of the resultant thin film was measured at 4.30, exceeding that of the thermal oxide (3.9). This high value was thought to be due to Si-OH groups inside the film and more extensive studies were performed in terms of electronic, ionic, and orientational polarizations using Debye equation. The relationship between the mechanical properties and the synthetic conditions of the silicate-silsesquioxane precursors was also investigated. The synthetic conditions of the low-k films have to be chosen to meet both the low orientational polarization and high mechanical properties requirements. In addition, we have investigated a new solution-based approach to the synthesis of semiconducting chalcogenide films for use in thin-film transistor (TFT) devices, in an attempt to develop a simple and robust solution process for the synthesis of inorganic semiconductors. Our material design strategy is to use a sol-gel reaction to carry out the deposition of a spin-coated CdS film, which can then be converted to a xerogel material. These devices were found to exhibit n-channel TFT characteristics with an excellent field-effect mobility (a saturation mobility of ${\sim}\;48\;cm^2V^{-1}s^{-1}$) and low voltage operation (< 5 V). These results show that these semiconducting thin film materials can be used in low-cost and high-performance printable electronics.

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Patent Analysis of MRAM Technology (차세대 자기저항메모리 MRAM 기술의 특허동향 분석)

  • Noh, S.J.;Lee, J.S.;Cho, J.U.;Kim, D.K.;Kim, Y.K.;Yoo, Y.M.;Ha, M.Y.;Seo, J.W.
    • Journal of the Korean Magnetics Society
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    • v.19 no.1
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    • pp.35-42
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    • 2009
  • Among the next generation memory, MRAM (Magnetic Random Access Memory) is worthy of notice for substituting the preexisting memory thanks to its non-volatile property and other advantages. Recently perpendicular MRAM and spin transfer torque MRAM techniques are under active investigation to realize a high density and low power consumption. As a result, there are increasing of patents applications for high density, low current density for magnetization switching and high thermal stability. In this paper, we analyze the trend of patent applications and registrations about MRAM and propose a direction of future investigation.

Analysis Of The Thermal Behavior and Jacket Cooling Characteristics of Motor Integrated Spindle for High Speed Machine Tool (고속공작기계용 모터내장형 주축의 열거동 및 자켓냉각특성 해석)

  • Park, D.B.;Kang, J.P.;Song, J.B.
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.2
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    • pp.33-40
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    • 1997
  • Recently, there are an increasing needs for high speed rotating spindle which is an important mechanical ele- ment for a high efficiency machine tool in order to shorten machining time and cut production costs. The heat gen- eration is the most important problem in the motor integrated spindle. In this study, the effects of temperature distribution and thermal behavior according to the oil-air lubrication and cooling conditions are investigate theo- retically and experimentally on the motor-integrated spindle under unloading condition. The experimental spin- dle system is composed with the angular contact steel ball bearings, oil-air lubrication, air or oil jacket cooling system. To analyze the thermal behavior and cooling characteristics for the motor integrated spindle, the analysis using the finite element method is carried out. The analytical results are compared with the experimental results.

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Formation of Charged Exciton in GaAs-AlGaAs Double-Quantum-Well Structure at High Magnetic Field (GaAs 이중 양자우물구조에서 고자기장에 유도된 대전된 엑시톤의 발생)

  • Kim, Yong Min
    • Journal of Integrative Natural Science
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    • v.2 no.4
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    • pp.265-269
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    • 2009
  • The photoluminescence was measured in GaAs-AlGaAs double-quantum-well structure at high magnetic field. Although the phototransition characteristics displayed a free-particle transition at low magnetic field, the change of free-particle transition into bound-exciton transition was observed at high magnetic field (above 10 T). A charged exciton formation due to charge-unbalanced electron-hole was identified by using a spin-polarized photoluminescence method. An increase of exciton formation due to the localization of free-particle at magnetic field was observed according to the increase of magnetic field.

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Fabrication and Electrical Properties of Cyano Acrylate Terpolymer Thin Film (Cyano acrylate terpolymer 박막의 제작과 전기적 특성)

  • Seo, J.Y.;Kim, J.U.;Lee, B.J.;Kwon, Y.S.
    • Proceedings of the KIEE Conference
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    • 2001.11a
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    • pp.124-127
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    • 2001
  • In this study, the electrical properties of polymer thin film layered by spin-coating method was investigated, and this polymer is one of the polymer applied to insulation layer for display, this polymer has relatively high dielectric constant, hygroscopic property and easy to make thin film by spin-coating. That is, in this study use the polymer that is cyano acrylate terpolymer, and the MIM(Metal/Insulator/Metal) structures were fabricated to measure the electrical properties such as Voltage-Current characteristics and dielectric characteristics. Also the conductivity and dielectric constant has been calculated. As a result, the conductivity in room temperature was $0.85{\times}10^{-14}{\sim}1.35{\times}10^{-14}$[S/cm]. The fact that this polymer be acted as insulator can be supported by this result. The dielectric constant was calculated as $10.39{\sim}12.05$ higher than Dopont Inc., this make it possible to accumulate more charges in insulation layer under same condition.

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Low-Temperature Electron Transport Properties of La2/3+xTiO3-δ (x = 0, 0.13) (저온에서 La2/3+xTiO3-δ (x = 0, 0.13)세라믹스의 전자전도특성)

  • Jung, Woo-Hwan
    • Korean Journal of Materials Research
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    • v.24 no.11
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    • pp.604-609
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    • 2014
  • The thermoelectric power and dc conductivity of $La_{2/3+x}TiO_{3-{\delta}}$ (x = 0, 0.13) were investigated. The thermoelectric power was negative between 80K and 300K. The measured thermoelectric power of x = 0.13 increased linearly with increased temperatures and was represented by $S_0+BT$. The x = 0 sample exhibited insulating behavior, while the x = 0.13 sample showed metallic behavior. The electric resistivity of x = 0.13 had a linear temperature dependence at high temperatures and a T3/2 dependence below about 100K. On the other hand, the electric resistivity of x = 0 has a linear relation between $ln{\rho}/T$ and 1/T in the range of 200 to 300K, and the activation energy for small polaron hopping was 0.23 eV. The temperature dependence of thermoelectric power and the resistivity of x = 0 suggests that the charge carriers responsible for conduction are strongly localized. This temperature dependence indicates that the charge carrier (x = 0) is an adiabatic small polaron. These experimental results are interpreted in terms of spin (x = 0.13) and small polaron (x = 0) hopping of almost localized Ti 3d electrons.