• Nuclear Engineering and Technology
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• v.54 no.12
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• pp.4474-4480
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• 2022

Deep geological disposal using a multibarrier system is a promising solution for treating high-level radioactive (HLRW) waste. The HLRW canister represents the first barrier for the migration of radionuclides into the biosphere, therefore, the corrosion behavior of canister materials is of significance. In this study, the electrochemical behaviors of SS316L, Ti-Gr.2, Alloy 22, and Cu in naturally aerated KAERI underground research tunnel (KURT) groundwater solutions were examined. The corrosion potential, current, and impedance spectra of the test materials were recorded using electrochemical methods. According to polarization and impedance measurements, Cu exhibits relatively higher corrosion rates and a lower corrosion resistance ability than those exhibited by the other materials in the given groundwater condition. In the anodic dissolution tests, SS316L exposed to the groundwater solution exhibited the most uniform corrosion, as indicated by its surface roughness. This phenomenon could be attributed to the extremely low concentration of chloride ions in KURT groundwater.

• Nuclear Engineering and Technology
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• v.55 no.11
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• pp.4120-4124
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• 2023

High-level radioactive waste produced by nuclear power plants are disposed subterraneously utilizing an engineered barrier system (EBS). A gap inevitably exists between the disposal canisters and buffer materials, which may have a negative effect on the thermal transfer and water-blocking efficiency of the system. As few previous experimental works have quantified this effect, this study aimed to create an experimental model for investigating differences in the temperature changes of bentonite buffer in the presence and absence of air gaps between it and a surrounding stainless steel cell. Three test scenarios comprised an empty cell and cells partially or completely filled with bentonite. The temperature was measured inside the buffers and on the inner surface of their surrounding cells, which were artificially heated. The time required for the entire system to reach 100℃ was approximately 40% faster with no gap between the inner cell surface and the bentonite. This suggests that rock-buffer spaces should be filled in practice to ensure the rapid dissipation of heat from the buffer materials to their surroundings. However, it can be advantageous to retain buffer-canister gaps to lower the peak buffer temperature.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.6
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• pp.603-612
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• 2016

The objective of this study was to estimate the emission characteristics for PM, $PM_{10}$, and $PM_{2.5}$ in the various stationary sources. The particulate matters collected in the various stationary sources such as power plants (Coal and B-C oil), incinerators(municipal and industrial waste), and glass furnaces. The PM and $PM_{10}$, PM and $PM_{2.5}$, $PM_{10}$ and $PM_{2.5}$ samples were collected using the cyclone type $PM_{10}$, $PM_{2.5}$ samplers and 30 species(19 inorganic species, 9 ionic species, OC and EC) were analyzed by ICP, IC, and TOR/IMPROVE methods. The mass concentrations of PM, $PM_{10}$, $PM_{2.5}$ from nine stationary sources ranged $0.63{\sim}9.58mg/Sm^3$, $0.26{\sim}7.47mg/Sm^3$ and $0.13{\sim}6.34mg/Sm^3$, respectively. The level of $PM_{10}$, $PM_{2.5}$ portion in PM calculated 0.63~0.99, 0.38~0.94, respectively. In the case of emission trend for species, power plant showed high concentrations for Al, Mg, Na, Si, V and $SO_4{^{2-}}$, respectively. Also, Ca, Fe, K, Si, $Cl^-$, and $K^+$ showed high in incinerator. In the case of glass furnace, Na, Pb, K, Si, $Na^+$ and $SO_4{^{2-}}$ represented high concentrations. Power plant showed higher EC/OC concentrations than other sampling sites. These results suggest the possible role for complement establishment process of emission inventory and emission management for PM.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.13 no.1
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• pp.55-61
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• 2015

When a radiation detector is applied to the measurement of the radioactivity of high-level of radioactive materials or the rapid response to the nuclear accident, several collimators with the different inner radii should be prepared according to the level of dose rate. This makes the in-situ measurement impractical, because of the heavy weight of the collimator. In this study, an IRIS collimator was developed so as to have a function of controlling the inner radius, with the same method used in optical camera, to vary the attenuation ratio of radiation. The shutter was made to have the double tungsten layers with different phase angles to prevent the radiation from penetrating owing to the mechanical tolerance. The performance evaluation through the MCNP code was conducted by calculating the attenuation ratio according to the inner radius of the collimator. The attenuation ratio was marked on the outer scale ring of the collimator. It is expected that when a radiation detector with the IRIS collimator is used for the in-situ measurement, it can change the attenuation ratio of the incident photon to the detector without replacing the collimator.

• Journal of the Korea Organic Resources Recycling Association
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• v.20 no.2
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• pp.44-52
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• 2012

As an alternative strategy in the era of high level petroleum cost, the study focused to suggest the way on the revitalization of renewable energy through the impact on introduction effect of renewable energy in green village. Total feasible solar energy production is 6.73 GWh/yr along with the biomass energy producing electric power energy is 134.06 GWh/yr, the two category's total electric power energy is 233.19 GWh/yr, which is possible to achieve the selfsufficiency of energy by 33% for total energy consumption of 705.80 GWh/yr in the region. The calculated feasibility on the carbon dioxide reduction, carbon dioxide reduction level is 1,891 ton_$CO_2$ by agricultural byproducts, 43,635 ton_$CO_2$ by livestock waste, 395 ton_$CO_2$ by municipal waste, 50,324 ton_$CO_2$ by forest byproducts, the total biomass shows 96,245 ton_$CO_2$, while the carbon dioxide reduction of solar light energy is 2,251 ton_$CO_2$, 1,383.3 ton_$CO_2$ by solar heat energy, the total solar energy shows 3,634 ton_$CO_2$. So total carbon dioxide reduction effect shows 99,879 ton_$CO_2$.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.1
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• pp.85-93
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• 2017

This paper presents mechanical properties and carbonation behavior of the recycled aggregate concretes(RAC) in which natural aggregate was replaced by recycled coarse aggregate and fine aggregate by specified concrete strength levels(21, 35, 50MPa). A total of 18 RAC were produced and classified into six series, each of which included three mixes designed with three specified concrete strength levels of 21MPa, 35MPa and 50MPa and three recycled aggregate replacement ratios of 0, 50 and 100%. Physical and mechanical properties of RAC were tested for slump test, compressive strength, and carbonation depth. The test results indicated that the slump of RAC could be improved or same by recycled coarse aggregate replacement ratios, when compared with natural aggregate. But slump of RAC was decreased as the recycled fine aggregate replacement ratios increase. Also, the test results showed that the compressive strength was decreased as the recycled aggregate replacement ratios increased and it had a conspicuous tendency to decrease when the content of the recycled aggregate exceeded 50%. Furthermore, the result indicated that the measured carbonation depth increases by 40% with the increase of the recycled aggregate replacement. In the case of the concrete having low level compressive strength, the increase of carbonation depth tends to be higher when using the RCA. However, the trend of carbonation resistivity in high level compressive strength concrete is similar to that obtained in natural aggregate concrete. Therefore, an advance on the admixture application and mix ratio control are required to improve the carbonation resistivity when using the recycled aggregate in large scale.

• Journal of Microbiology and Biotechnology
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• v.21 no.6
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• pp.627-636
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• 2011

A commercially important alkaline protease, produced by Bacillus sp. RRM1 isolated from the red seaweed Kappaphycus alvarezii (Doty) Doty ex Silva, was first recognized and characterized in the present study. Identification of the isolated bacterium was done using both biochemical characterization as well as 16S rRNA gene sequencing. The bacterial strain, Bacillus sp. RRM1, produced a high level of protease using easily available, inexpensive agricultural residues solid-state fermentation (SSF). Among them, wheat bran was found to be the best substrate. Influences of process parameters such as moistening agents, moisture level, temperature, inoculum concentration, and co-carbon and co-nitrogen sources on the fermentation were also evaluated. Under optimized conditions, maximum protease production (i.e., 2081 U/g) was obtained from wheat bran, which is about 2-fold greater than the initial conditions. The protease enzyme was stable over a temperature range of 30-$60^{\circ}C$ and pH 6-12, with maximum activity at $50^{\circ}C$ and pH 9.0. Whereas the metal ions $Na^+$, $Ca^{2+}$, and $K^+$ enhanced the activity of the enzyme, others such as $Hg^{2+}$, $Cu^{2+}$, $Fe^{2+}$, $Co^{2+}$, and $Zn^{2+}$ had rendered negative effects. The activity of the enzyme was inhibited by EDTA and enhanced by $Cu^{2+}$ ions, thus indicating the nature of the enzyme as a metalloprotease. The enzyme showed extreme stability and activity even in the presence of detergents, surfactants, and organic solvents. Moreover, the present findings opened new vistas in the utilization of wheat bran, a cheap, abundantly available, and effective waste as a substrate for SSF.

• Journal of Korean Society of Water and Wastewater
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• v.31 no.6
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• pp.539-549
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• 2017

In water treatment process using microfiltration membranes, manganese is a substance that causes inorganic membrane fouling. As a result of analysis on the operation data taken from I WTP(Water Treatment Plant), it was confirmed that the increase of TMP was very severe during the period of manganese inflow. The membrane fouling fastened the increase of TMP and shortened the service time of filtration or the cleaning cycle. The TMP of the membrane increased to the maximum of $2.13kgf/cm^2$, but it was recovered to the initial level ($0.17kgf/cm^2$) by the 1st acid cleaning step. It was obvious that the main membrane fouling contaminants are due to inorganic substances. As a result of the analysis on the chemical waste, the concentrations of aluminum(146-164 mg/L) and manganese(110-126 mg/L) were very high. It is considered that aluminum was due to the residual unreacted during coagulation step as a pretreatment process. And manganese is thought to be due to the adsorption on the membrane surface as an adsorbate in feed water component during filtration step. For the efficient maintenance of the membrane filtration facilities, optimization of chemical concentration and CIP conditions is very important when finding the abnormal level of influent including foulants such as manganese.

• Asian Pacific Journal of Cancer Prevention
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• v.14 no.3
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• pp.1851-1863
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• 2013

Diurnal variation of particulate polycyclic aromatic hydrocarbons (PAHs) was investigated by collecting PM10 at three different sampling altitudes using high buildings in the city center of Chiang-Mai, Thailand, during the relatively cold period in late February 2008. At site-1 (12 m above ground level), B[a]P concentrations ranged from 30.3-1,673 pg $m^{-3}$ with an average of $506{\pm}477\;pg\;m^{-3}$ contributing on average, $8.09{\pm}8.69%$ to ${\Sigma}PAHs$. Ind and B[b]F concentrations varied from 54.6 to 4,579 pg $m^{-3}$ and from 80.7 to 2,292 pg $m^{-3}$ with the highest average of $1,187{\pm}1,058\;pg\;m^{-3}$ and $963{\pm}656\;pg\;m^{-3}$, contributing on average, $19.0{\pm}19.3%$ and $15.4{\pm}12.0%$ to ${\Sigma}PAHs$, respectively. Morning maxima were predominantly detected in all observatory sites, which can be described by typical diurnal variations of traffic flow in Chiang-Mai City, showing a morning peak between 6 AM. and 9 AM. Despite the fact that most monitoring sites might be subjected to specific-site impacts, it could be seen that PAH profiles in Site-1 and Site-2 were astonishingly homogeneous. The lack of differences suggests that the source signatures of several PAHs become less distinct possibly due to the impacts of traffic and cooking emissions from ground level.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.198-198
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• 2011

Organocatalysis is a relatively new and popular area within the field of chiral molecule synthesis. It is one of the main branches of enantioselective synthesis with enzymatic and organometallic catalysis. In recent years, immense high quality studies on catalysis by chiral secondary amines were reported. These progresses instantly led to different organocatalytic activation concepts, so thousands of researchers from academia and the chemical industry are currently involved in this field and new ideas, new approaches, and creative thinking have been rapidly emerged. Organocatalysts, some of which are natural products, appear to solve the problems of metal catalysts. Compared to metal-based catalysis, they have many advantages including savings in cost, time, and energy, easier experimental procedure, and reduction of chemical waste. These benefits originate from the following factors. First, organocatalysts are generally stable in oxygen and water in the atmosphere, there is no need for special equipments or experimental techniques to operate under anhydrous or anaerobic conditions. Second, organic reagents are naturally available from biological materials as single enantiomers that they are easy and cheap to prepare which makes them suitable for small-scale to industrial-scale reactions. Third, in terms of safety related catalysis, small organic molecules are non-toxic and environmentally friendly. Therefore, the purpose of this research is to develop novel synthetic methods and design for various organocatalyst. Furthermore, it is expected that these organocatalysts can be applied to a variety of asymmetric reactions and study the transition state of these reactions using a metal sulface. Here, we report the synthesis of unprecedented organocatalysts, proline and pyrrolidine derivatives with quaternary carbon center.