• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.2
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• pp.231-241
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• 2022

Several countries, including Korea, are considering the direct disposal of spent nuclear fuels. The radiological safety assessment results published after a geological repository closure indicate that the instant release is the main radiation source rather than the congruent release. Three Safety Case reports recently published were reviewed and the IRF values of seven long-lived radionuclides, including relevant experimental results, were compared. According to the literature review, the IRF values of both the CANDU and low burnup PWR spent fuel have been experimentally measured and used reasonably. In particular, the IRF values of volatile long-lived nuclides, such as ¹²⁹I and ¹³⁵Cs, were estimated from the FGR value. Because experimental leaching data regarding high burnup spent nuclear fuels are extremely scarce, a mathematical modelling approach proposed by Johnson and McGinnes was successfully applied to the domestic high burnup PWR spent nuclear fuel to derive the IRF values of iodine and cesium. The best estimate of the IRF was 5.5% at a discharge burnup of 55 GWd tHM^-1.

• Journal of the Korean institute of surface engineering
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• v.56 no.1
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• pp.84-93
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• 2023

The spent nuclear fuel is burned during the planned cycle in the plant and then generates elements such as actinide series, fission products, and plutonium with a long half-life. An 'interim storage' step is needed to manage the high radioactivity and heat emitted by nuclides until permanent-disposal. In the case of Korea, there is no space to dispose of high-level radioactive waste after use, so there is a need for a period of time using interim storage. Therefore, the intensity of neutrons and gamma-ray must be determined to ensure the integrity of spent nuclear fuel during interim storage. In particular, the most important thing in spent nuclear fuel is burnup evaluation, estimation of the source term of neutrons and gamma-ray is regarded as a reference measurement of the burnup evaluation. In this study, an analysis of spent nuclear fuel was conducted by setting up a virtual fuel burnup case based on CE16×16 fuel to check the total amount and spectrum of neutron, gamma radiation produced. The correlation between BU (burnup), IE (enrichment), and CT (cooling time) will be identified through spent nuclear fuel burnup calculation. In addition, the composition of nuclide inventory, actinide and fission products can be identified.

• Nuclear Engineering and Technology
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• v.42 no.1
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• pp.79-88
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• 2010

Spent $UO_2$ nuclear fuel discharged from a nuclear power plant (NPP) contains fission products, U, Pu, and other actinides. Due to neutron capture by $^{238}U$ in the rim region and a temperature gradient between the center and the rim of a fuel pellet, a considerable increase in the concentration of fission products, Pu, and other actinides are expected in the pellet periphery of high burnup fuel. The characterization of the radial profiles of the various isotopic concentrations is our main concern. For an analysis, spent nuclear fuels originating from the Yeonggwang-2 pressurized water reactor (PWR) were chosen as the test specimens. In this work, the distributions of some actinide isotopes were measured from center to rim of the spent fuel specimens by a radiation shielded laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) system. Sampling was performed along the diameter of the specimen by reducing the sampling intervals from 500 ${\mu}m$ in the center to 100 ${\mu}m$ in the pellet periphery region. It was observed that the isotopic concentration ratios for minor actinides in the center of the specimen remain almost constant and increase near the pellet periphery due to the rim effect apart from the $^{236}U$ to $^{235}U$ ratio, which remains approximately constant. In addition, the distributions of local burnup were derived from the measured isotope ratios by applying the relationship between burnup and isotopic ratio for plutonium and minor actinides calculated by the ORIGEN2 code.

• Nuclear Engineering and Technology
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• v.39 no.5
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• pp.673-682
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• 2007

The contents of transuranic elements in high-burnup spent fuel samples were determined. The activity amounts of $^{238}Pu,\;^{239}Pu,\;^{240}Pu,\;^{241}Am,\;^{244}Cm\;and\;^{242}Cm$ were measured by alpha spectrometry using $^{242}Pu\;and\;^{243}Am$ as tracers, respectively. A spike addition method for $^{237}Np$ was established by an alpha and gamma spectrometry using $^{239}Np$ as a spike after the optimum conditions for the measurements of $^{237}Np\;and\;^{239}Np$, respectively, were obtained. A separation system using anion exchange chromatography and diethylhexylphosphoric acid extraction chromatography was applied for the separation of these elements. This method was applied to high-burnup spent nuclear fuel samples $(40{\sim}60GWD/MTU)$. The contents of the transuranic elements were compared with those by ORIGEN-2 code. Measurements and the calculations of the contents of the plutonium isotopes $^{238}Pu,\;^{239}Pu\;and\;^{240}Pu$ agreed to within 10% on average. The contents of $^{237}Np$ agreed to within approximately 5% except for one instance of a calculation, while those of $^{241}Am,\;^{244}Cm\;and\;^{242}Cm$ showed higher values by approximately 19%, 35% and 14% on average, respectively, compared to the calculations according to the burnup.

• Nuclear Engineering and Technology
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• v.41 no.1
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• pp.99-106
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• 2009

The contents of transuranic elements ($^{237}Np$, $^{238}Pu$, $^{239}Pu$, $^{240}Pu$, $^{241}Am$, $^{244}Cm$, and $^{242}Cm$) in high-burnup spent fuel samples ($35.6{\sim}53.9\;GWd/MtU$) were determined by alpha spectrometry. Anion exchange chromatography and diethylhexyl phosphoric acid extraction chromatography were applied for the separation of these elements from the uranium matrix. The measured values of the nuclides were compared with ORIGEN-2 calculations. For plutonium, the measurements were higher than the calculations by about $2.6{\sim}32.7%$ on average according to each isotope, and those for americium and curium were also higher by about $35.9{\sim}63.1%$. However, for $^{237}Np$, the measurements were lower by about 52% on average for the samples.

• Nuclear Engineering and Technology
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• v.52 no.4
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• pp.689-699
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• 2020

In this work, new multi-recycling options of TRU nuclides using PWR fuel assemblies comprised of MOX and FCM (Fully Ceramic Micro Encapsulated) fuels are suggested and neutronically analyzed. These options do not use a fully recycling of TRU but a partial recycling where TRUs from MOX fuels are recycled while the ones from FCM fuels are not recycled due to their high consumption rate resulted from high burnup. In particular, additional external TRU feed in MOX fuels for each cycle was considered to significantly increase the TRU consumption rate and the finally selected option is to use external TRU and enriched uranium feed as a makeup for the heavy metal consumption in MOX fuels. This hybrid external feeding of TRU and enriched uranium in MOX fuel was shown to be very effective in significantly increasing TRU consumption rate, maintaining long cycle length, and achieving negative void reactivity worth during recycling.

• Nuclear Engineering and Technology
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• v.37 no.4
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• pp.327-362
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• 2005

The design, construction, and operation of a light water reactor (LWR) are subject to compliance with safety criteria specified for accident situations, such as loss-of-coolant accident (LOCA) and reactivity-initiated accident (RIA). Because reactor fuel is the primary source of radioactivity and heat generation, such a criterion is established on the basis of the characteristics and performance of fuel under the specific accident condition. As such, fuel behavior under accident situations impact many aspects of fuel design and power generation, and in an indirect manner, even spent fuel storage and management. This paper provides a comprehensive review of: the history of the current LOCA criteria, results of LOCA-related investigations on conventional and new classes of fuel, and status of on-going studies on high-burnup fuel under LOCA situations. The objective of the paper is to provide a better understanding of important issues and an insight helpful to establish new LOCA criteria for modem LWR fuels.

• Nuclear Engineering and Technology
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• v.53 no.7
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• pp.2095-2103
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• 2021

A small power ADS design using thorium oxide and diluent matrix reprocessed fuel is proposed for a high transmutation rate, small reactivity swing, and strong safety features. Two fuel matrices (CERCER and CERMET) and different recycled fuel compositions recovered from UO₂ spent fuels with 45 GWd/tU and 60 GWd/tU burnup were investigated to determine the suitable fuel for the ADS. It was found that the transmutation of each isotope depends on TRU initial loading amount. After examining the cores, the results show that CERCER fueled ADS has a negative coolant void reactivity (CVR) and a smaller radiotoxicity at discharge compared to that of CERMET core. It implies that CERCER fuel has enhanced safety features and more flavor in terms of radiotoxicity management. To increase fuel utilization and core operation efficiency, a simple assembly shuffling pattern for the CERCER fueled ADS is also proposed. Eigenvalue and burnup calculations were conducted using Serpent 2 with ENDF/B-VII.0 library in both kcode and external source modes, and it indicates that the results of transmutation analyses obtained by kcode only is reliable to discuss the transmutation potential of ADS. Burnup calculation with the fixed-source mode is essential to be used for more practical results of the transmutation by ADS.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.261-267
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• 2004

Inventories, projections, and characteristics of spent nuclear fuel(SNF) generated from domestic nuclear power plants were updated to support high-level waste disposal system design. The historical and projected inventory by the end 2055 is expected to be 20,500 and 14,800MTU for PWR and CANDU spent nuclear fuel, respectively The ratio of quantity for TEX>$17{\times}17$ SNF was shown to be 0.6 as of 2003. The amount of TEX>$17{\times}17$ SNF, however, will be less than that of TEX>$16{\times}16$ KSFA after 2012, while the quantity of TEX>$16{\times}16$ KSFA will reach to 70% of the total spent fuels in the 2055. Average turnup of SNF revealed ~36GWD/MTU and ~40GWD/MTU for the period of 1994-1999 and 2000-2003, respectively. It is expected that the average burnup of SNF will exceed 45GWD/MTU at the end of 2000's. Therefore, it seems reasonable to use the TEX>$17{\times}17$ 4.5w/o, 45GWD/MTU as the Reference SNF at present state. The TEX>$16{\times}16$ KSFA 4.5w/o, 55GWD/MTU, however, should be Reference SNF after ~2010.

• Nuclear Engineering and Technology
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• v.55 no.6
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• pp.2288-2297
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• 2023

Current designs of both large reactor units and small modular reactors utilize a nuclear fuel with increasing enrichment. This increasing demand for better nuclear fuel utilization is a challenge for nuclear fuel handling facilities. The operation with higher enriched fuels leads to reduced reserves to legislative and safety criticality limits of spent fuel transport, storage and final disposal facilities. Design changes in these facilities are restricted due to a boron content in steel and aluminum alloys that are limited by rolling, extrusion, welding and other manufacturing processes. One possible solution for spent fuel pools and casks is the burnup credit method that allows decreasing very high safety margins associated with the fresh fuel assumption in spent fuel facilities. This solution can be supplemented or replaced by an alternative solution based on placing the neutron absorber material directly into the fuel assembly, where its efficiency is higher than between fuel assemblies. A neutron absorber permanently fixed in guide tubes decreases system reactivity more efficiently than absorber sheets between the fuel assemblies. The paper summarizes possibilities of fixed neutron absorbers for various nuclear fuel and fuel handling facilities. Moreover, an absorber material was optimized to propose alternative options to boron. Multiple effective absorbers that do not require steel or aluminum alloy compatibility are discussed because fixed absorbers are placed inside zirconium or steel cladding.