• 제목/요약/키워드: High-Tc Superconductors

검색결과 55건 처리시간 0.025초

산화물계 초전도체의 고변이 송도부근의 곡출과 이의 성분 분석에 관한 연구 (Isolation and Analysis of Micro-Regions Having Possibly Higher Tc in Oxide Superconductors)

  • 이규용
    • 수산해양기술연구
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    • 제25권3호
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    • pp.143-153
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    • 1989
  • 산화물 초전도체에 있어서 고천이 임계온도를 갖는 미소영역을 추출하여 이를 분석하기 위하여 La-Ba-Cu-O 계, Y-Ba-Cu-O 계 및 Bi-Pb-Sr-Ca-Cu-O 계의 초전도체를 고상법 및 nitrate solution method로 제조하였다. 제조된 시료들에 대해서 x선회절분석과 저항을 측정하였다. 이들 시료 중에서 고천이온도를 나타내는 미소부분을 Meissner효과를 이용한 추출법으로 분리 해내고 EDAX로 이를 분석하였으며, 이들 결과를 요약하면 다음과 같다. nitrate solution method를 적용하면 YBCO계에 있어서 비교적 단시간에 치밀한 미세조직을 갖는 천이 온도 90K의 초전도체를 제조할 수 있다. Meissner효과를 이용하여 고천이온도에서 추출해낸 미소영역의 EDAX분석 결과는 고상법을 사용한 YBCO-23S와 nitrate solution method으로 제조한 YBCO-23N 및 YBCO-36N 에서는 초기의 조성과 거의 같았으며, 고천이 온도에서 추출된 미소영역은 조성보다는 산소 결함의 차이에 기인한 것으로 생각된다. 공침법으로 제조한 YBCO-23NA 에서는 과도한 Ba의 조성을 보였으며, 천이온도 100K 인 Bi계에서는 약한 반자성효과 때문에 추출이 불가능하였다.

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SOME CHARACTERISTICS OF THE CERAMIC SUPERCONDUCTORS PHYSICS PROERTIES AND CHEMICAL ASPECTS

  • Escudero, Roberto
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 1992년도 추계학술발표강연 및 논문개요집
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    • pp.17-17
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    • 1992
  • The ceramic high transition temperature superconducting materials present many interesting characteristics that will be analysed from two points of view: physical behavior, and chemical aspects. From the first point of view, these materials display an enormous variety of different physical properties. At low doping levels the normal state shows antiferromagnetism and insulating behavior. At intermediate doping levels, an anomalous metallic state appears and, the optimum Tc in the superconducting state is generated. With increasing doping a normal metallic state develops and superconductivity starts to disappear. Many of the physical phenomena that describe the overall behavior when doping levels are changed will be discussed. From the poing of view of the chemical aspects. we well discuss some of the problems involved in the methods of preparation with particular emphasis on defects, crystal structures, critical currrents, and applications in technology.

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전자가 도핑된 $Sr_{0.9}$$La_{0.1}$Cu$O_2$초전도체의 홀 효과

  • Kim, Hyun-Jung;W. N. Kang;Kim, Kijoon H. P.;Lee, Sung-Ik;S. Karimoto
    • Progress in Superconductivity
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    • 제4권1호
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    • pp.32-36
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    • 2002
  • We have measured the Hall effect in infinite-layer Sr/sub 0.9/La/sub 0.1/$CuO_2$ thin films grown by molecular beam epitaxy. We do not observe $T^{2}$ dependence of the cotangent of Hall angle, which is commonly observed in other cuprate High-Tc superconductors. Therefore, this result cannot be interpreted within two different scattering mechanism based on charge-spin separation theory. The mixed-state Hall effect shows no sign anomaly, implying that tile hydrodynamic contribution of vortex core is negligibly small.

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벌크형 고온 초전도 합성 (Fabrication of Bulk High-Tc Superconductor)

  • 이상헌
    • 한국전기전자재료학회논문지
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    • 제34권5호
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    • pp.333-336
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    • 2021
  • Oxide YBCO bulk superconductors are manufactured using the melt process. Because seed crystal growth method utilizes a slow-spreading layer-by-layer reaction, a long-term heat treatment is required to manufacture a single-crystal specimen of several cm. In this study, the melt process method was applied to compensate for the shortcomings of the seed crystal growth method. The thickness of the upper and lower pellets of the YBCO bulk was molded to 40 mm, and YBCO superconductor was produced by heat treatment. The measurement results of capture magnetism was in line with the literature. This results in a relationship that the higher the growth of Y211 particle in the YBCO, the higher the superconducting properties. We analyzed the YBCO superconductor, focusing on the Y2BaCuO5 particle distribution.

발화합성법으로 제조한 YBa2Cu3-yAgyO7-x의 초전도 특성 (Superconductivity of YBa2Cu3-yAgyO7-x Manufactured by Pyrophoric Synthetic Method)

  • 김영순;양석우;박정식;신형식
    • 공업화학
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    • 제7권4호
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    • pp.639-644
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    • 1996
  • 원료물질인 $Y_2O_3$, $BaCO_3$, CuO 및 $AgNO_3$ 분말로부터 Y계 고온초전도체를 발화합성법으로 제조하였다 $YBa_2Cu_3O_{7-x}$와 Cu를 Ag로 부분 치환한 $YBa_2Cu_{3-y}Ag_yO_{7-x}$의 특성을 X-ray diffractometer, resistivity measuring equipment, SEM, and Vickers Hardness 등으로 분석하였다. $YBa_2Cu_3O_{7-x}$의 Tc,zero는 91K였고, 밀도는 $5.2g/cm^3$, 경도는 $590kg/mm^2$였다. Cu를 Ag로 0.15몰 이하 부분 치환한 $YBa_2Cu_{3-y}Ag_yO_{7-x}$의 경우 임계온도(Tc)는 거의 변하지 않으면서 미세구조, 밀도 및 경도가 향상되었다.

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Ag와 Au가 혼합된 $Bi_{1.84}\;Pb_{0.34}\;Sr_{1.91}\;Ca_{2.03}\;Cu_{3.06}\;O_{10+\delta}$ 산화물 고온초전도체의 초전도특성 (Composite Effect of Ag and Au in the $Bi_{1.84}\;Pb_{0.34}\;Sr_{1.91}\;Ca_{2.03}\;Cu_{3.06}\;O_{10+\delta}$(110K Phase) High-Tc Superconductor)

  • 이민수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제52권6호
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    • pp.241-248
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    • 2003
  • $Bi_{1.84}Pb_{0.34}Sr_{1.91}Ca_{2.03}Cu_{3.06}O_{10+\delta}$ high $T_{c}$ superconductors containing Ag as an additive were fabricated by a solid-state reaction method. The superconducting properties, such as the structural characteristics, the critical temperatures, the grain size and the image of mapping on the surface were investigated. Samples with Ag and Au of 50 wt% each were sintered at various temperature(820~$850^{\circ}C$). The structural characteristics, the microstructure of surface and the critical temperature with respect to the each samples were analyzed by XRD and SEM, EDS and four-prove methode respectively. The critical temperature showed the result which the Ag additive samples are higher than Au additive samples. The microstructure of the surface showed the tendency which the Ag additive samples become more minuteness than Au additive samples.

고온초전도 한류기의 전력계통 적용에 관한 연구 (A Study on the Power System Application of High-Tc Superconducting Fault Current Limiter)

  • 배형택;유인근
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 A
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    • pp.115-116
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    • 2006
  • Since the discovery of the high-temperature superconductors, many researches have been performed for the practical applications of superconductivity technologies in various fields. As results, significant progress has been achieved. Especially, Superconducting Fault Current Limiter (SFCL) offers an attractive means to limit fault current in power systems. The SFCLS, in contrast to current limiting reactors or high impedance transformers, are capable of limiting short circuit currents without adding considerable voltage drop and energy loss to power systems during normal operation. Under fault conditions, a resistance is automatically inserted into the power grid to limit the peak short-circuit current by transition from the superconducting state to the normal state, the quench. The advantages, like fail safe operation and quick recovery, make SFCL very attractive, especially for rapidly growing power systems with higher short-circuit capacities. In order to verify the effectiveness of the SFCL, in this paper, the analysis of fault current and voltage stability assessment in a sample distribution system and a transmission system are performed by the PSCAD/EMTDC based simulation method. Through the simulation, the advantage of SFCL application is shown, and the effective parameters of the SFCL are also recommended for both distribution and transmission systems. A resistive type component of SFCL is adopted in the analysis. The simulation results demonstrate not only the effectiveness of the proposed simulation scheme but also SFCL parameter assessment technique.

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고온초전도 접합도체들의 I-V 특성에 관한 연구 (I-V Characteristics of HTS Conductors with Joints)

  • 손명환;민치현;이언용;심기덕;김석호;성기철
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 B
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    • pp.679-680
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    • 2006
  • Various different types of joining between High Tc superconducting(HTS) tapes were prepared and current-voltage(I-V) characteristic curves were investigated at 77 K, liquid nitrogen temperature. Two typos of HTS tapes wore used, one is no laminated tape(Sumitomo high strength type tape) and the other stainless steel laminated tape(AMSC(American Superconductors Inc.) 3ply tapes) Sample joints were lap-jointed with indium or solder. Joint resistances between Sumitomo tapes with 4-10 mm in length were estimated from I-V curves and in the range of $4-8n{\Omega}$ at 77 K. Joint resistances of AMSC tapes were in the range of $140-170n{\Omega}$, much higher than them of Sumitomo samples. The n-values of jointed HTS tapes were 50% of them with no joint. In AMSC tapes, indium is better than solder as the jointing material.

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Thickness dependence of grain growth orientation in MgB2 films fabricated by hybrid physical-chemical vapor deposition

  • Ranot, Mahipal;Kang, W.N.
    • 한국초전도ㆍ저온공학회논문지
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    • 제15권2호
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    • pp.9-11
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    • 2013
  • We have investigated the effect of thickness of the MgB2 film on the grain growth direction as well as on their superconducting properties. $MgB_2$ films of various thicknesses were fabricated on c-cut $Al_2O_3$ substrates at a temperature of $540^{\circ}C$ by using hybrid physical-chemical vapor deposition (HPCVD) technique. The superconducting transition temperature ($T_c$) was found to increase with increase in the thickness of the $MgB_2$ film. X-ray diffraction analysis revealed that the orientation of grains changed from c-axis to a-axis upon increasing the thickness of the $MgB_2$ film from 0.6 to 2.0 ${\mu}m$. $MgB_2$ grains of various orientations were observed in the microstructures of the films examined by scanning electron microscopy. It is observed that at high magnetic fields the 2.0-${\mu}m$-thick film exhibit considerably larger critical current density ($J_c$) as compared to 0.6-${\mu}m$-thick film. The results are discussed in terms of an intrinsic-pinning in $MgB_2$ similarly as intrinsic-pinning occurring in high-Tc cuprate superconductors with layered structure.

Critical Current Degradation Analysis in HTS Pancake Coil due to Self Field Effects

  • Nah, Wan-Soo;Joo, Jin-Ho;Yoo, Jai-Moo
    • Progress in Superconductivity
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    • 제1권1호
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    • pp.68-72
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    • 1999
  • Since the discovery of high Tc superconductors, great efforts have been focused to develop high performance HTS magnets for the ultimate applications to power system devices. Magnet designers, however, have had difficulties in the estimation of the maximum operating current of the designed magnet from the tested short sample data, due to the degradation of the critical current density in the magnet. Similar story applies to the HTS electrical bus bar. It has been found that the critical current of Bi-2223 stacked tapes is much less than the total summation of critical currents of each tape, which is mainly attributed to the self magnetic fields. Furthermore, since the critical current degradation of Bi-2223 tape is greater in the normal magnetic field (to the tape surface) than in the parallel one, detailed magnetic field configurations are required to reduce the self field effects. In this paper, we calculate the self field effects of a stacked conductor, defining self field factors of normal and parallel magnetic fields to the tape surface. Finally, the critical current degradations in the HTS magnet are explained by the introduced self field factors of the stacked conductor.

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