• Title/Summary/Keyword: High-Tc Superconductors

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Ceramics superconducting Energy Materials (세라믹 에너지 재료)

  • Lee, Sang-Heon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1238-1239
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    • 2008
  • The high Tc supeconductor of ceramic oxides type was studied for finding its application field. The results reportaed in this paper on the stability of the ceramic superconductors and the resistance to ripening in the BCO liquid phase at elevated temperature opens a processing window for engineering the microstructure of large superconductor at the nanoscale level. The results suggest further that the introduction of highly efficient artifical pinning center to bulk ceramics superconductor.

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Microstructure and Electrical Properties of (YNdSm)-Ba-Cu-O High Tc Composite Superconductors by Zone Melting Process (존멜팅법으로 제조한 (YNdSm)-Ba-Cu-O계 고온복합초전도체의 미세구조 및 전기적 특성)

  • Kim, So-Jung;Lee, Sang-Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.2
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    • pp.110-113
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    • 2016
  • (YNdSm)-Ba-Cu-O system high Tc composite superconductors were directionally grown by zone melting process, having large temperature gradient, in air atmosphere. Cylindrical green rods of $(YNdSm)_{1.8}Ba_{2.4}Cu_{3.4}O_x$ [(YNS)1.8]composite oxides by CIP (cold isostatic pressing) method using rubber mold were fabricated. The microstructure and superconducting properties were investigated by XRD, TEM and SQUID magnetometer. The size of nonsuperconducting $(YNdSm)_2BaCuO_5$ inclusions of the melt-textured (YNS)1.8 sample with $CeO_2$ additive were remarkably reduced and uniformly distributed within the superconducting (YNS)1.8 matrix. (YNS)1.8 samples, with / without $CeO_2$ additive, showed an onset $T_c{\geq}90K$ and sharp superconducting transition. The critical current density $J_c$ value of the (YNdSm)1.8 superconductor with $CeO_2$ additive were 840 A, $1.2{\times}104A/cm^2$ in 77 K, 0 Tesla by direct current transport method.

Fabrication arid Performance Tests of Flywheel Energy Storage System using High Tc Superconducting Bearing (고온초전도체 베어링을 사용하는 에너지 저장용 플라이휠 장치의 제작 및 성능 평가)

  • Lee, Ho-Jin;Kim, Ki-Baik;Koh, Chang-Seop;Lee, Soo-Hoon;Hong, Gye-Won
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.310-314
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    • 1999
  • A prototype of Flywheel Energy Storage System with high Tc superconducting bearings was fabricated and tested to verify its applicability for the energy industry. The moment of inertia of assembled wheel with rotor magnets is about 1.072${\times}$10$^{-1}$ Kg-m$^2$. The wheel was designed to withstand its integrity up to the rotation speed of 20,000 rpm. YBCO bulk superconductors prepared by seed growth method were used as bearing to levitate and stabilize the rotating wheel. High speed rotation of the flywheel without mechanical contact was achieved by using specially designed Halbach type motor. The flywheel system showed very high stability during test operation performed up to the speed of about 10,000rpm. The energy loss measured by free decay test performed between 9,300 rpm and 7,000 rpm was calculated as about 45 W.

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A Study on the Magnetic Properties of Ceramics Superconductors for Simpllified Testing System (간소화 시스템적용을 위한 자기특성)

  • Lee, Sang-Heon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.2
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    • pp.339-341
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    • 2012
  • The high Tc superconductor of YBCO system with the nominal composition of precursor was prepared from mixed powders of $Y_2O_3$, $BaCO_3$, CuO and $TiO_2$ by the thermal pyrolysis method. The effect of $TiO_2$ doping to Y based ceramics superconductors fabricated by the thermal pyrolysis reaction, to investigate the effect of the dopant on the superconductivity. The voltage appearing across the field-cooled HTS sample increased with external magnetic field. The improvement of critical current property as well as the mechanical property is important for the application. The improvement of the critical current can be achieved by forming the nano size defect working as a flux pining center inside the superconductor. We simply added $TiO_2$ to starting materials to dope $TiO_2$ and observed an increase in the trapped field and the critical current density up to at least 5 wt % $TiO_2$. The $TiO_2$ was converted to fine $BaTiO_3$ particles which were trapped in YBCO matrix during the sintering process. We observed a peak effect of Jc that can be attributed to $TiO_2$ doping and results suggest that introducing a proper amount of pinning centers can significantly enhance current density.

Electromagnetic Properties of Bulk High-Tc Superconductor (벌크형 초전도체의 전기자기적 특성)

  • Lee, Sang-Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.2
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    • pp.111-114
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    • 2017
  • In this research, the development of fabrication technique of bulk YBaCuO superconductors for application was studied. In fluence of $BaZrO_3$ addition on magnetization characteristics of thermal pyrolysis textured YBaCuO superconductor was investigated. Fine $BaZrO_3$ particle were dispersed within the textured YBaCuO matrix by means of the thermal pyrolysis processing. Magnetic levitation force for YBaCuO superconductors were obtained using Nd-B-Fe permanent magnet, at 77 K and at the magnetic field from 0 to 5.3 K gauss. In the unadded superconductor and 5 wt% $BaZrO_3$ addition, anomalous magnetization behavior, which is characterized by the intermediate magnetic field, was observed at 77 K. Critical current density was about few hundreds $A/cm^2$ and the magnetic characteristics increased slightly by addition of $BaZrO_3$ powder. Maximum magnetic force was obtained in the YBaCuO superconducting bulk with 3 wt.% $BaZrO_3$ addition.

Microstructure and Superconducting Properties of Ag-$Bi_{1.84}Pb_{0.34}Sr_{1.91}Ca_{2.03}Cu_{3.06}O_{10+{\delta}}$ Composites (Ag-$Bi_{1.84}Pb_{0.34}Sr_{1.91}Ca_{2.03}Cu_{3.06}O_{10+{\delta}}$ 복합체의 미세구조와 초전도특성)

  • 이민수
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.6
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    • pp.249-256
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    • 2003
  • Samples with the nominal composition, Ag-$Bi_{1.84}Pb_{0.34}Sr_{1.91}Ca_{2.03}Cu_{3.06}O_{10+{\delta}}$ high $T_{c}$ superconductors containing Ag as an additive were fabricated by a solid-state reaction method. Samples with Ag of 10 wt%, 30 wt%, and 50 wt% each were sintered at $860^{\circ}C$~$870^{\circ}C$ for 24 hours. The structural characteristics, the microstructures and the critical temperature with respect to the each samples were investigated by XRD, four-prove methode, SEM and EDS respectively. The $T_{c}\;^{zero}$ of the sample with the 50 wt% Ag additive at the surface showed 94 K.

Miniaturized Development of Microwave Power Divider Using High-Tc Superconductors (고온초전도체를 이용한 마이크로파 전력분배기의 소형화 개발)

  • Chung, Dong-Chul;Yoo, Byung-Hwa;Kwak, Min-Hwan;Kang, Gwang-Yong;Han, Byoung-Sung
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.3
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    • pp.334-338
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    • 2009
  • In this paper, We report the miniaturization of superconducting microwave power dividers based on lumped element equivalent circuits. To do this, we analyzed a conventional branch-type power divider by using an ABCD matrix under even and odd mode excitation. Then, we calculated each lumped element impedance throughout this analysis of a transmission line matrix. Also we simulated our equivalent circuits made of lumped elements by using a full wave analysis, em Sonnet. Our deign of microwave power divider based on simulated results was fabricated on high-$T_c$ superconducting thin films deposited on MgO substrate. Experimental results were reported in terms of bandwidth, center frequency, and phase difference between $S_{21}$ and $S_{31}$. We confirm that our design will be useful in the future microwave power systum.

Microstructure and Properties of High Tc Superconductor fabricated by Hot Isostatic Pressing (열간정수압소결(HIP) 시킨 고온초전도체의 조직과 특성)

  • Song, Jin-Tae;Akihama, Ryozo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.05a
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    • pp.17-19
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    • 1988
  • $YBa_2Cu_3O_{7-x}$ oxide superconductors were fabricated by the hot isostatic pressing (HIP). It was shown that their structures were orthorombic and constited of a single (123) phase. While as-sintered compacts had many pores, they were remarkably reduced by Hiping. The on-set and off set temperature of (123) compound sintered at $950^{\circ}C$ in oxygen and hiping at $880^{\circ}C$ were the highest and it showed 0 resistance at $90^{\circ}K$. The critical current density ($J_c$) of the above superconductor was $27A/cm^2$ and it also showed a number of twin structures, which are typical of high $T_c$ superconductor. It seemed that the low current density may be due to the many pores of starting-sintered compacts.

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Substitution Effect of Fluorine on $HoBa_2Cu_3O_{7-x}F_y(0.0{\leq}y{\leq}0.5)$ Superconductors

  • Park, Jong Sik;Kim Seong Han;Kim, Hong Seok;Cho Seung Koo;Kim Keu Hong
    • Bulletin of the Korean Chemical Society
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    • v.13 no.2
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    • pp.131-135
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    • 1992
  • High-Tc superconducting materials, $HoBa_2Cu_3O_{7-x}F_y$ with $0.0{\leq}y{\leq}0.5$, were synthesized by ceramic method and studied by X-ray diffraction, thermogravimetric analysis, differential thermal analysis, scanning electron microscopy and resistivity measurement. From the X-ray diffraction data, it was found that the samples had only single phase of which lattice volumes were decreased in proportional to the amount of fluorine, which indicated that the relatively small fluorine atoms are effectively substituted for the oxygen sites. Also, an anomalous phenomenon appeared that the peak intensities of (001) planes were greatly increased as fluorine contents increased. SEM photographs revealed that the grain sizes were enlarged progressively with fluorine contents. This fact could be explained along with DTA & TGA data that the incorporation of fluorine gave rise to lowering the melting point. Tc decreased as the incorporation of fluorine content increased. This implies that the superconducting electrons are perturbed due to the substitution of electronegative fluorine atom.