• Title/Summary/Keyword: High-Oxygen Concentration

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Effect of Aeration Rates on Emissions of Oxygen and Sulfur compound gases during Composting of Dairy Manure (우분(牛糞) 퇴비화시(堆肥花時) 공기주입률(空氣注入率)이 산소 및 황화합물 가스 배출(排出)에 미치는 영향(影響))

  • Kang, Hang-Won;Zhang, Ruihong;Rhee, In-Koo
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.472-481
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    • 2000
  • This experiment used the enclosed bench-scale reactors was conducted to find out optimal aeration rate for reducing the emission of odors and producing the good-quality compost with the mixture of dairy manure and rice straw. The reactors with gas sampler were aerated at four different rates of 0.09, 0.18, 0.90 and $1.79l\;min^{-1}kg^{-1}$dry solids for 574 hours. The oxygen content within composting pile instantly decreased after aeration. Oxygen limitation(below 15%) in the treatments of $0.90l\;min^{-1}kg^{-1}$ and less was exponentially negative relationship with aeration rates and in the range of 35 to 300 hours after aeration. However, the treatment of $1.79l\;min^{-1}kg^{-1}$ didn't show the oxygen limitation. The oxygen consumption rate and the cumulative amount of oxygen consumed by different aeration rates was ranged in $0.80{\sim}1.57O_2g\;h^{-1}\;kg^{-1}VS^{-1}$, $460{\sim}900O_2g\;kg^{-1}VS^{-1}$, respectively, and they were high in the order of 0.90, 1.79, 0.18, $0.09l\;min^{-1}kg^{-1}$. The maximum oxygen consumption rate was estimated in the range of $1.2{\sim}1.3lmin^{-1}kg^{-1}$. The emission concentrations of sulfur compounds such as hydrogen sulfide, sulfur dioxide and methylmercaptan were remarkably high in the initial composting time. Then they were rapidly decreased with the passing of composting time and clearly with increasing aeration rates. Their average concentrations were in the range of 0.03~2.18, 0~0.50, $0.07{\sim}3.38mg\;kg^{-1}$, respectively and high in the order of methylmercaptan, hydrogen sulfide, and sulfur dioxide. Concentrations of sulfur compounds emitted from composting showed exponentially negative relationship at 1% statistically with the oxygen concentration. It was estimated that hydrogen sulfide and methylmercaptan suddenly increased in the level of 5% oxygen concentration and below, that they were little emitted in 15% and over but sulfur dioxide was emitted in the level of 20% oxygen.

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Characteristics of SiO2 Gas Barrier Films as a Function of Process Conditions in Facing Target Sputtering (FTS) System (대향타겟식 스퍼터링 장치의 공정 조건에 따른 SiO2 가스 차단막의 특성)

  • Bae, Kang;Wang, Tae-Hyun;Sohn, Sun-Young;Kim, Hwa-Min;Hong, Jae-Suk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.7
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    • pp.595-601
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    • 2009
  • For the silicon oxide $(SiO_x)$ films prepared by using the facing target sputtering (FTS) apparatus that was manufactured to enhance the preciseness of the fabricated thin-film and sputtering yield rate by forming a higher-density plasma in the electrical discharge space for using it as a thin-film passivation system for flexible organic light emitting devices (FOLEDs). The deposition characteristics were investigated under various process conditions, such as array of the cathode magnets, oxygen concentration$(O_2/Ar+O_2)$ introduced during deposition, and variations of distance between two targets and working pressure. We report that the optimum conditions for our FTS apparatus for the deposition of the $SiO_x$ films are as follows: $d_{TS}\;and\;d_{TT}$ are 90mm and 120mm, respectively and the maximum deposition rate is obtained under a gas pressure of 2 mTorr with an oxygen concentration of 3.3%. Under this optimum conditions, it was found that the $SiO_x$ film was grown with a very high deposition rate of $250{\AA}$/min by rf-power of $4.4W/cm^2$, which was significantly enhanced as compared with a deposition rate (${\sim}55{\AA})$/min) of the conventional sputtering system. We also reported that the FTS system is a suitable method for the high speed and the low temperature deposition, the plasma free deposition, and the mass-production.

Change of Survival, Growthand Oxygen Consumption Rate in the Juvenile Olive Flounder,Paralichthys olivaceus Exposed to Lead (Pb의 노출에 따른 넙치, paralichthys olivaceus, 치어의 생존, 성장 및 산소소비율의 변화)

  • Kim, Seong-Gil;Kim, Jae-Won;Jang, Seok-U;Kim, Sang-Gyu;Gang, Ju-Chan
    • Journal of fish pathology
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    • v.15 no.3
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    • pp.99-104
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    • 2002
  • Experiments were carried out to investigate the effects of lead exposure on survival, growth and oxygen consumption of juvenile oliver flounder, Paralichthys olivaceus for 6 weeks. Survival rate of the oliver flounder was significantly affected above 150 $\mu{g/L}$. Growth rate of the olive flounder exposed to ≥ 150 $\mu{g/L}$ of lead concentration were significantly decreased than that exposed to normal condition. Metabolic rate in the lead concentration ≥ 80 $\mu{g/L}$ was significantly reduced with increasing lead concentration then that in normal condition. This study revealed that high lead concentration (≥ 80 $\mu{g/L}$) reduced growth and metabolic rate of the juvenile olive flounder suggesting potential influence on the natural mortality of olive flounder in the coastal areas.

Changes in Hemolymph Protein Concentration and Oxygen Consumption during the Metamorphosis in pieris rapae L. (배추흰나비의 變態에 따른 血蛋白質과 酸素消費量의 變化)

  • Kim, Chang-Whan;Lee, Kyung-Ro;Kim, Hak-Ryul
    • The Korean Journal of Zoology
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    • v.12 no.2
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    • pp.60-66
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    • 1969
  • Changes in the protein concentration in the hemolymph and the oxidation of respiratory substrates at various developmental stages in cabbage worm, Pieris rapae Linne were measured using Biuret method and Warburg manometric method, respectively. The results are summarized as follows: 1. The hemolymph protein contentration decreased gradually until the six-day pupa and increased thereafter. In the fifth larval instar the concentration reached a maximum and was about two times the value for the six-day pupa. 2. Endogenous respiration was very high at the prepupal stage, decreasing at two-day pupa, followed by an increase at the late pupal stage. 3. Glucose showed the marked activity throughout the whole stages, and had the striking influence on both the prepupal and adult stages. 4. The changes in protein concentration and the rate of oxygen consumption exhibited a general pattern of U-shaped curve through the process of life cycle according to histogenesis of the adult organ and histolysis of the larval organ.

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Oxygen Transfer in Animal Cell Culture by Using a Silicone Tube as an Oxygenator (실리콘 튜브를 이용한 동물세포 배양장치의 산소전달)

  • 정흥채;김정회
    • Microbiology and Biotechnology Letters
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    • v.20 no.4
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    • pp.445-450
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    • 1992
  • An enhancement of the oxygen transfer rate in a 1$\ell$ bioreactor for mammalian cell culture by using a silicone rubber tubing as an oxygenator was investigated. When the silicone membrane was used to supply oxygen to the culture broth, the oxygen transfer coefficients ($k_{\iota}a$) measured in deionized-distilled water were markedly increased. Effect of surface aeration without the tubing aeration was very low under $1.0hr^{-1}$ of $k_{\iota}a$. The enhancing effects of agitation rates on $k_{\iota}a$ were much more effective than those of aeration rates. The increase of $k_{\iota}a$ with increasing tube length was observed as a result of the large surface area for oxygen supply. However, 2 m of the tube length was adequate for a 1$\ell$ vessel. The larger blade type of impeller was effective to enhance the kLa values because of its high mixing intensity. In culture medium supplemented with 5% serum, kLa values were reduced to approximately 40% probably due to the viscosity. We also obtained the normal cell concentration of $5{\times}10^6$ cells/m$\ell$ of HepG2 on microcarriers, which could be achieved in a typical bioreactor for animal cell culture.

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Theoretical Study on Polymerization of Oxepane High Explosives

  • Kim, Joon-Tae
    • Journal of Integrative Natural Science
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    • v.5 no.3
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    • pp.175-181
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    • 2012
  • Oxepane high explosives substituted to explosive group such as azido, nitrato and hydrazino are investigated theoretically the acid catalyzed reaction using the semiempirical MINDO/3, MNDO and AM1 methods to use as the guidelines of high explosives. The nucleophilicity and basicity of oxepane high explosives can be explained by the value of negative charge on oxygen atom of oxepane and the reactivity in propagation step can be represented by the value of positive charge on carbon atom and low electrophile LUMO energy. It was known that carbenium ion was favorable due to the stable energy (19.507~32.101 Kcal/mol) between oxonium ion and carbenium ion in the process of cyclic oxonium ion of oxepane high explosives being converted to open carbenium ion in oxepane high explosives. The value of concentration of cyclic oxonium ion and open carbenium ion in equilibrium status was found to be a major determinant of mechanism, it was expected to react faster in the prepolymer propagation step in SN1 mechanism than in that of $S_N2$.

Effects of pH, Temperature, and Dissolved Oxygen on Phosphorus Release from Marine Sediment to Seawater (해양퇴적물 인 용출에 미치는 pH, 온도, 용존 산소 농도의 영향)

  • Cheon, Hyo-Chang;Nam, Se-Yong;Kim, Sang-Hyoun
    • Journal of Navigation and Port Research
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    • v.36 no.6
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    • pp.513-519
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    • 2012
  • Understanding the behavior of pollutants in the marine environment is essential for coping with the marine pollution problems such as eutrophication. In this study, the effects of environmental parameters on phosphorus release from marine sediment to sea water were investigated. The environmental parameters such as pH in the range of 7 to 9, temperature from 10 to 20C and dissolved oxygen levels (DO) renging 0.7 to 7.0mg/L were examined. Phosphorus release data were taken from batch tests excluding biotic effects, and analyzed using a first-order kinetic model. The effects of environmental parameters were quantified using a statistical methodology. High pH, high temperature, and low DO increased phosphorus release from the sediment to sea water. pH from 7 to 9, temperature from 10 to $20^{\circ}C$, or DO from 7.0 to 0.7 mg/L magnified the equilibrium phosphorus concentration up to 2~3 times.

A Study on Synthesis of Lignin Peroxidase and Degradation of Pentachlorophenol(PCP) by Phanerochaete chrysosporium (Phanerochaete chrysosporium에 의한 Lignin Peroxidase의 생성과 Pentachlorophenol(PCP)의 분해)

  • Choi, Sue-Hyung;Song, Eun;Gu, Man-Bock;Moon, Seung-Hyeon
    • KSBB Journal
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    • v.13 no.3
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    • pp.223-230
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    • 1998
  • Experiments for lignin peroxidase production have been conducted by aerobic fermentation of Phanerochaete chrysosporium under low shear rate and enriched oxygen environment. The result of flask cultures of white rot fungus indicated that high oxygen concentration and low shear force were essential for enhancement of lignin peroxidase production. Pentachlorophenol was readily degraded by lignin peroxidase produced in nutrient limited flask cultures. Polyurethane foam was fond to be an effective immobilization matrix of P. chrysosporium.

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Observation of Water Consumption in Zn-air Secondary Batteries

  • Yang, Soyoung;Kim, Ketack
    • Journal of Electrochemical Science and Technology
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    • v.10 no.4
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    • pp.381-386
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    • 2019
  • Zn-air battery uses oxygen from the air, and hence, air holes in it are kept open for cell operation. Therefore, loss of water by evaporation through the holes is inevitable. When the water is depleted, the battery ceases to operate. There are two water consumption routes in Zn-air batteries, namely, active path (electrolysis) and passive path (evaporation and corrosion). Water loss by the active path (electrolysis) is much faster than that by the passive path during the early stage of the cycles. The mass change by the active path slows after 10 h. In contrast, the passive path is largely constant, becoming the main mass loss path after 10 h. The active path contributes to two-thirds of the electrolyte consumption in 24 h of cell operation in 4.0 M KOH. Although water is an important component for the cell, water vapor does not influence the cell operation unless the water is nearly depleted. However, high oxygen concentration favors the discharge reaction at the cathode.

A Study on the Combustability of Formed Polyethylene (성형 Polyethylene의 연소성에 관한 연구)

  • 정국삼;류영순
    • Journal of the Korean Society of Safety
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    • v.9 no.3
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    • pp.60-66
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    • 1994
  • The purpose of this study is to compare the combustability of the formed high density polyethylene (HDPE) with the low density polyethlyene(LDPE). That is, the easiness of ignition is examined by using the methods with Oxygen Index(OI) Tester and ventilation parameter, and the combustion velocity of these polyethylenes is measured by changing the size and shape of opening area. As the result of it, the oxygen index of HDPE, in a ignition, is required more than LDPE. Then, the concentration distribution of CO by combustion is increased when the opening area is small, but, in the same opening area, LDPE tends to increase more than HDPE. In addition, as the ratio of height to width of opening area is increased, combustion velocity becomes faster relatively. In consequence, when it is generally considered, the combustability of LDPE is better than HDPE.

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