• 한국세라믹학회지
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• 제53권5호
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• pp.506-510
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• 2016

The eutectic melt of BaO-CuO flux is known to be a potential sintering aid for $Ba(Zr,Y)O_3$ (BZY) electrolyte for proton-conducting ceramic fuel cells (PCFCs). A density of BZY higher than 97% of theoretical density can be achieved via sintering at $1300^{\circ}C$ for 2 h using a flux composed of 28 mol% BaO and 72 mol% CuO. In the present study, chemical and structural evolution of BaO-CuO flux throughout the sintering process was investigated. An intermediate holding step at $1100^{\circ}C$ leads to formation of various impurity compounds such as $BaCuO_{1.977}$, $Ba_{0.92}Cu_{1.06}O_{2.28}$ and $Cu_{16}O_{14.15}$, which exhibit significantly larger unit cell volumes than the matrix. The presence of such secondary compounds with large lattice mismatch can potentially lead to mechanical failure. On the other hand, direct heating to the final sintering temperature produced CuO and $Cu_2O$ as secondary phases, whose unit cell volumes are close to that of the matrix. Therefore, the final composition of the flux is strongly affected by the thermal history, and a proper sintering schedule should be used to obtain the desired properties of the final product.

• 한국재료학회지
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• 제23권10호
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• pp.568-573
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• 2013

The deformation properties of a TiC-Mo eutectic composite were investigated in a compression test at temperatures ranging from room temperature to 2053 K and at strain rates ranging from $3.9{\times}10^{-5}s^{-1}$ to $4.9{\times}10^{-3}s^{-1}$. It was found that this material shows excellent high-temperature strength as well as appreciable room-temperature toughness, suggesting that the material is a good candidate for high-temperature application as a structure material. At a low-temperature, high strength is observed. The deformation behavior is different among the three temperature ranges tested here, i.e., low, intermediate and high. At an intermediate temperature, no yield drop occurs, and from the beginning the work hardening level is high. At a high temperature, a yield drop occurs again, after which deformation proceeds with nearly constant stress. The temperature- and yield-stress-dependence of the strain is the strongest in this case among the three temperature ranges. The observed high-temperature deformation behavior suggests that the excellent high-temperature strength is due to the constraining of the deformation in the Mo phase by the thin TiC components, which is considerably stronger than bulk TiC. It is also concluded that the appreciable room-temperature toughness is ascribed to the frequent branching of crack paths as well as to the plastic deformation of the Mo phase.

• Nuclear Engineering and Technology
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• 제49권3호
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• pp.569-575
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• 2017

One of the important requirements for the application of reduced-activation ferritic/martensitic (RAFM) steel is to retain proper mechanical properties under irradiation and high-temperature conditions. To simulate the yield strength and stress-strain curve of steels during high-temperature and irradiation conditions, a multiscale simulation method consisting of both microstructure and strengthening simulations was established. The simulation results of microstructure parameters were added to a superposition strengthening model, which consisted of constitutive models of different strengthening methods. Based on the simulation results, the strength contribution for different strengthening methods at both room temperature and high-temperature conditions was analyzed. The simulation results of the yield strength in irradiation and high-temperature conditions were mainly consistent with the experimental results. The optimal application field of this multiscale model was 9Cr series (7-9 wt.%Cr) RAFM steels in a condition characterized by 0.1-5 dpa (or 0 dpa) and a temperature range of $25-500^{\circ}C$.

• Corrosion Science and Technology
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• 제15권3호
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• pp.129-134
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• 2016

The effects of Ti on the high temperature oxidation of Ni-based superalloys were investigated by cyclic oxidation at $850^{\circ}C$ and $1000^{\circ}C$. The oxide scale formed at $850^{\circ}C$ consists of $Cr_2O_3$, $Al_2O_3$, and $NiCr_2O_4$ layers, while a continuous $Al_2O_3$ layer was formed at $1000^{\circ}C$. The oxidation rate of the alloy with higher Ti content was higher than the alloy with less Ti content at $850^{\circ}C$, possibly due to the increase in the metal vacancy concentration in the $Cr_2O_3$ layer involved by incorporation of $Ti^{4+}$. However, Ti improved the oxidation resistance of the superalloy at $1000^{\circ}C$ by reducing oxygen vacancy concentration in $Al_2O_3$ layer.

• 한국재료학회지
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• 제17권5호
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• pp.268-272
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• 2007

Inconel 617 is a candidate tube material for high temperature gas-cooled reactors(HTGR). The microstructure and mechanical properties of Inconel 617 were studied after exposure at high temperature($1050^{\circ}C$). The dominant oxide layer was Cr-oxide. The internal oxide and Cr-depleted region were observed below the Cr-oxide layer. The depth of Cr-depleted zone and internal oxide increased with exposure time. The major phases of carbides are $M_{23}C_6\;and\;M_6C$. The composition of $M_{23}C_6\;and\;M_6C$ were determined to be Cr-rich and Mo-rich, respectively. $M_6C$ carbide is more stable than $M_{23}C_6$ at high temperature. From the results of high temperature compression test, there were no significant changes in hardness and yield strength upon increasing exposure time.

• 한국세라믹학회지
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• 제51권4호
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• pp.271-277
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• 2014

To overcome the limitations of the solid oxide fuel cells (SOFCs) due to the high temperature operation, there has been increasing interest in proton conducting fuel cells (PCFCs) for reduction of the operating temperature to the intermediate temperature range. In present work, the perovskite $BaCe_{0.85-x}Zr_xY_{0.15}O_{3-\delta}$ (BCZY, x = 0.1, 0.3, 0.5, and 0.7) were synthesized via solid state reaction (SSR) and adopted as an electrolyte materials for PCFCs. Powder characteristics were examined using X-ray diffraction (XRD), thermogravimetric analysis (TGA) and Brunauer, Emmett and Teller (BET) surface area analysis. Single phase BCZY were obtained in all compositions, and chemical stability was improved with increasing Zr content. Anode-supported cell with $Ni-BaCe_{0.55}Z_{0.3}Y_{0.15}O_{3-\delta}$ (BCZY3) anode, BCZY3 electrolyte and BCZY3-$Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-\delta}$ (BSCF) composite cathode was fabricated and electrochemically characterized. Open-circuit voltage (OCV) was 1.05 V, and peak power density of 370 ($mW/cm^2$) was achieved at $650^{\circ}C$.

• 대한금속재료학회지
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• 제50권9호
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• pp.659-667
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• 2012

Alloy 617 is a Ni-base superalloy and a candidate material for the intermediate heat exchanger (IHX) of a very high temperature gas reactor (VHTR) which is one of the next generation nuclear reactors under development. The high operating temperature of VHTR enables various applications such as mass production of hydrogen with high energy efficiency. Alloy 617 has good creep resistance and phase stability at high temperatures in an air environment. However, it was reported that the mechanical properties decreased at a high temperature in an impure helium environment. In this study, high-temperature corrosion tests were carried out at $850^{\circ}C-950^{\circ}C$ in a helium environment containing the impurity gases $H_2$, CO, and $CH_4$, in order to examine the corrosion behavior of Alloy 617. Until 250 h, Alloy 617 specimens showed a parabolic oxidation behavior at all temperatures. The activation energy for oxidation in helium environment was 154 kJ/mol. The SEM and EDS results elucidated a Cr-rich surface oxide layer, Al-rich internal oxides and depletion of grain boundary carbides. The thickness and depths of degraded layers also showed a parabolic relationship with time. A normal grain growth was observed in the Cr-rich surface oxide layer. When corrosion tests were conducted in a pure helium environment, the oxidation was suppressed drastically. It was elucidated that minor impurity gases in the helium would have detrimental effects on the high-temperature corrosion behavior of Alloy 617 for the VHTR application.

• 대한금속재료학회지
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• 제50권7호
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• pp.495-502
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• 2012

The aim of this study was to analyze high temperature deformation stability and properties of duplex stainless steels(DSS) according to annealing temperature. In order to analyze high temperature deformation stability, a number of compression tests were carried out with a stain rate of $10^{-2}s^{-1}{\sim}10s^{-1}$ up to a compression ratio of 50% in a temperature range of $950^{\circ}C-1300^{\circ}C$. The analysis of high temperature deformation stability of DSS was performed based on the Ziegler model. In order to analyze the high temperature properties of DSS, annealing treatments were conducted by isothermal holding for 1 hr at $950^{\circ}C$ to $1300^{\circ}C$ with $50^{\circ}C$ intervals followed by water cooling. The hardness and tensile tests were performed on specimens with different volume fractions of constituent phases, such as austenite, ferrite and sigma. The hardness and tensile strength of 2507 according to the annealing temperature are better than those of 2205. The strain rate sensitivity and Ziegler parameter are higher in 2205 than in 2507 as a whole, which implies that 2205 is better than 2507 in terms of forgeability at high temperature.

• Applied Microscopy
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• 제45권2호
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• pp.89-94
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• 2015

This article briefly reviews the results of recently reported research on high-temperature Pb-free solder alloys and the research trend for characterization of the interfacial reaction layer. To improve the product reliability of high-temperature Pb-free solder alloys, thorough research is necessary not only to enhance the alloy properties but also to characterize and understand the interfacial reaction occurring during and after the bonding process. Transmission electron microscopy analysis is expected to play an important role in the development of high-temperature solders by providing accurate and reliable data with a high spatial resolution and facilitating understanding of the interfacial reaction at the solder joint.

• 소성∙가공
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• 제13권5호
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• pp.435-440
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• 2004

The temperature in hot forming of metallic materials, such as hot extrusion and hot forging, ranges from $300^{\circ}C$ to $900^{\circ}C$. Correspondingly, the die also exhibits high temperatures close to that of a work piece and its life is limited generally by high temperature fatigue. Thus, the analysis of high temperature fatigue would need the mechanical properties over the wide ranges of temperature. However, very few studies on the high temperature fatigue of brittle materials have been reported. Especially, the study on the fatigue behavior over such transition temperature regime is very rare. In this paper, the stress-strain curves and stress-life curves of a die steel such as STD61 are experimentally obtained. The wide ranges of temperature from $300^{\circ}C$ to $900^{\circ}C$ are considered in experiments and the transition temperature zone is carefully examined.