• Fibers and Polymers
• /
• v.3 no.1
• /
• pp.18-23
• /
• 2002

The structure development and dynamic properties of fibers produced by high-speed spinning of P(EN-ET) random copolymers were investigated. The as-spun fibers were found to remain amorphous up to the spinning speed of 1500 m/min, and subsequent increases in speed resulted in the crystalline domains containing primarily $\alpha$ crystalline modification of PEN. The f modification was not found up to spinning speeds of 4500 m/min. On the other hand, annealing of constrained fibers spun at the 2100 m/min at 180,200, and 240^{\circ}C$ exhibited $\beta$-form crystalline structure, while the annealed fibers spun in 600-1500 m/min range exhibited dominantly $\alpha$-form. However $\beta$-form crystals disappeared above the spinning speed of 3000 m/min. With increasing spinning speeds from 600 to 4500 m/min, the storage modulus of as-spun fibers increased continuously and reached a value of about 10.4 spa at room temperature. The tan $\delta$curves showed the $\alpha$-relaxation peak at about 155-165^{\circ}C$, which is considered to correspond to the glass transition. The $\alpha$-relaxation peaks became smaller and broader, and shift to higher temperatures as the spinning speed increases, meaning that molecular mobility in the amorphous region is restricted by increased crystalline domain.

• Textile Coloration and Finishing
• /
• v.6 no.4
• /
• pp.34-39
• /
• 1994

For the purpose of obtaining high modulus PET tire cord fiber by high spinning speed, the change of initial modulus and taut tie molecules (T.T.M) fraction with the PET tire cord fibers by different spinning speed is investigated. Initial modulus decreased with increasing spinning speed but increased above spinning speed of 1500m/min. Therefore, high modulus PET tire cord fiber may be obtained above spinning speed of 3500m/min. It was found that the initial modulus of fibers depends on fraction of T.T.M.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.11
• /
• pp.3252-3258
• /
• 2010

In this study, the effects of the various parameters of spinning and drawing processes on the properties of polyester full drawn yarn (FDY) prepared by steam processing during high-speed spinning were investigated using several techniques. The wet shrinkage ratio of the FDY was able to be manipulated by controlling the temperature and draw ratio. The FDY made using the steam high speed spinning technique exhibited identical properties (such as tenacity, elongation, and wet shrinkage ratio) to that of regular FDY, made using the spin-draw process. FDY prepared using the steam process during high-speed spinning showed excellent dyeability. The dye pick-up of the polyester yarn spun at high-speed spinning was found to be improved when dyed under an atmospheric pressure of $100^{\circ}C$. This result was the same as regular FDY dyed under a high pressure of $130^{\circ}C$.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.30 no.4 s.152
• /
• pp.607-614
• /
• 2006

This study was carried out to suggest the optimal spinning process condition which provides a proper range of tenacity and biodegradability as textile fibers. The effects of the melt spinning speed and heat treatment on the mechanical property and biodegradability of polylactic acid fiber were investigated. Polylactic acid(PLA) was spun in a high spinning speed of $2000{\sim}4000m/min$. Each specimen was heat-treated at $100^{\circ}C$ during 30min. Mechanical properties such as breaking stress and the degree of crystallinity were evaluated using WAXS. Biodegradability was estimated from the decrease of breaking stress, weight loss, and the degree of crystallinity after soil burial. Experimental results revealed that heat treated specimens showed higher breaking stress than untreated specimens, but the increase was not so high as was expected from the remarkable change of crystallinity by heat treatment. It was concluded that breaking stress was more influenced by spinning speed than heat treatment. In the soil burial test, however biodegradability calculated from weight loss was more influenced by heat treatment than spinning speed.

• Transactions of the Korean Society of Machine Tool Engineers
• /
• v.14 no.4
• /
• pp.89-95
• /
• 2005

This paper intends to identify experimentally the relationship between transverse vibration behavior of a spinning disk and high-frequency fluctuation in the driving torque. A testrig has been developed using a CD-ROM disk, a driving motor with torque-varying capability and a power transmission belt and a laser vibrometer was employed to measure the transverse vibration displacements of the disk for a certain range of the spinning speed. The results show that the spinning speed and the magnitude and frequency of the torque fluctuation affect the stability of the disk. In other word, the torque fluctuation causes the instability of the disk at several ranges of the spinning speed below the critical speed and its effects become larger as the disk spins faster or the magnitude of torque fluctuation becomes bigger. The experimental results are found to be in good agreement with analytical estimation.

• Textile Coloration and Finishing
• /
• v.14 no.4
• /
• pp.197-207
• /
• 2002

The physical properties and dyeability of the nylon 6 fibers prepared by high speed spinning at take-up speed of 4,100~5,600m/min were investigated. The strain decreased as the take-up speed was raised from 4,100m/min to 4,400m/min, but further increase of take-up speed could not decrease the strain. The stresses of the fibers spinned at various take-up speed did not make any noticeable differences. Birefringences, densities and crystallinities of the fibers increased with the take-up speed and then reached to a nearly maximum value at 5,300m/min. In DSC diagrams, the $\gamma$ form of crystal became dominant at higher take-up speed. The dye uptakes of C. I. Acid Blue 113 on the fibers decreased a little with the increase of take-up speed.

• Textile Coloration and Finishing
• /
• v.8 no.6
• /
• pp.33-39
• /
• 1996

The purpose of this study was to investigate the structural characteristics, mechanical properties, and stress-relaxation behavior of PET filament, which were prepared at various spinning speeds(1650, 3300, 4500, 5000, 5500, and 6000 m/min) and anneal(12$0^{\circ}C$, 20 min & 15$0^{\circ}C$, 40 min). In 4500 m/min of spinning speed the crystallinity, crystallite size, and degree of orientation of PET filament rapidly increased. By increasing spinning speed, the temperature dependence of stress-relaxation sharply decreased. Same results were obtained from heat-treated samples. As a result, activation energy for stress-relaxation increased with the crystallinity and spinning speed.

• Textile Coloration and Finishing
• /
• v.35 no.4
• /
• pp.239-245
• /
• 2023

Cellulose is an abundant biodegradable material in nature with excellent properties, but due to its poor processability, it has been widely studied for processing through modification. Cellulose acetate propionate (CAP) is a cellulose derivative in which the hydroxyl group of cellulose is replaced by acetyl and propionyl groups. CAP has several advantages, such as excellent solubility, structural stability, light and weather resistance, and good transparency. Porous nanofibers with excellent specific surface area, which can be applied in various fields, can be easily formed by the phase separation method using highly volatile solvents. High speed centrifugal spinning is a nano/micro fiber preparation method with advantages such as fast spinning and easy alignment control. In this study, a CAP/polybutylene succinate (PBS) spinning solution with chloroform as solvent was prepared to prepare porous microfibers and the fiber morphology was examined as a function of the disk rotation speed in an high speed centrifugal spinning device.

• Textile Coloration and Finishing
• /
• v.34 no.3
• /
• pp.197-206
• /
• 2022

The purpose of this study was to confirm the optimal spinning conditions for PLA (Polylactic acid) as a fiber forming polymer. According to the melt spinning test results of PLA, the optimal spinning temperature was 258℃. However, it needs to note that relatively high pack pressure was required for spinning at 258℃. At an elevated temperature, 262℃, mono filament was broken easily due to hydrolysis of PLA at a higher temperature. In case of fiber strength, it was confirmed that the draw ratios of 2.7 to 3.3 were optimal for maximum strength of melt spun PLA. Above the draw ratio, 3.3, the strength of the PLA fibers was lowered. It was presumed that cleavage of the PLA polymer chain over maximum elongation. The heat setting temperature of GR (Godet roller) showed that the maximum strength of the PLA fibers was revealed around 100℃. The degree of crystallinity and the strength of the PLA fibers were decreased above 100℃. The optimal take-up speed (Spinning speed) was around 4,000m/min. Thermal analysis of PLA showed 170℃ and 57℃ as Tm (melting temperature) and Tg (glass transition temperature), respectively.

• Textile Coloration and Finishing
• /
• v.14 no.6
• /
• pp.335-341
• /
• 2002

The physical properties and the dyeability of the nylon S fibers Prepared by high speed spinning according to godet roller draw ratio form 1.1 to 1.6 were investigated. The strains of nylon 6 fibers were decreased against the increase of the godet roller draw ratio. The stresses of nylon 6 fibers were increased with the increase of the godet roller draw ratio. Birefringences, densities and crystallinities of the nylon 6 fibers were increased with the increase of godet roller draw ratio In DSC diagrams, the $\gamma$ form of crystal became dominant at higher godet roller draw ratio. The dye uptakes of C. 1. Acid Blue 113 on the fibers were decreased against the increase of godet roller draw ratio.