• Title/Summary/Keyword: High solid coating

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The Lubricant Effect of Oxidation and Wear Products of HVOF Co-alloy T800 Powder Coating

  • Cho, Tong Yul;Yoon, Jae Hong;Kim, Kil Su;Song, Ki Oh;Youn, Suk Jo;Chun, Hui Gon;Hwang, Soon Young
    • Corrosion Science and Technology
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    • v.6 no.4
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    • pp.159-163
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    • 2007
  • Micron size Co-alloy 800 (T800) powder is coated on the high temperature, oxidation and corrosion resistant super alloy Inconel 718 substrate by the optimal high velocity oxy-fuel (HVOF) thermal spray coating process developed by this laboratory. For the study of durability improvement of high speed spindle operating without lubricants, friction and sliding wear behaviors of the coatings are investigated both at room and at an elevated temperature of $1000^{\circ}F(538^{\circ}C)$. Friction coefficients, wear traces and wear debris of coatings are drastically reduced compared to those of non-coated surface of Inconel 718 substrate both at room temperature and at $538^{\circ}C$. Friction coefficients and wear traces of both coated and non-coated surfaces are drastically reduced at higher temperature of $538^{\circ}C$ compared with those at room temperature. At high temperature, the brittle oxides such as CoO, $Co_{3}O_{4}$, $MoO_2$ and $MoO_3$ are formed rapidly on the sliding surfaces, and the brittle oxide phases are easily attrited by reciprocating slides at high temperature through oxidation and abrasive wear mechanisms. The brittle solid oxide particles, softens, melts and partial-melts play roles as solid and liquid lubricants reducing friction coefficient and wear. These show that the coating is highly recommendable for the durability improvement coating on the machine component surfaces vulnerable to frictional heat and wear.

Li3PO4 Coated Li[Ni0.75Co0.1Mn0.15]O2 Cathode for All-Solid-State Batteries Based on Sulfide Electrolyte

  • Lee, Joo Young;Park, Yong Joon
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.407-415
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    • 2022
  • Surface coating of cathodes is an essential process for all-solid-state batteries (ASSBs) based on sulfide electrolytes as it efficiently suppresses interfacial reactions between oxide cathodes and sulfide electrolytes. Based on computational calculations, Li3PO4 has been suggested as a promising coating material because of its higher stability with sulfides and its optimal ionic conductivity. However, it has hardly been applied to the coating of ASSBs due to the absence of a suitable coating process, including the selection of source material that is compatible with ASSBs. In this study, polyphosphoric acid (PPA) and (NH4)2HPO4 were used as source materials for preparing a Li3PO4 coating for ASSBs, and the properties of the coating layer and coated cathodes were compared. The Li3PO4 layer fabricated using the (NH4)2HPO4 source was rough and inhomogeneous, which is not suitable for the protection of the cathodes. Moreover, the water-based coating solution with the (NH4)2HPO4 source can deteriorate the electrochemical performance of high-Ni cathodes that are vulnerable to water. In contrast, when an alcohol-based solvent was used, the PPA source enabled the formation of a thin and homogeneous coating layer on the cathode surface. As a consequence, the ASSBs containing the Li3PO4-coated cathode prepared by the PPA source exhibited significantly enhanced discharge and rate capabilities compared to ASSBs containing a pristine cathode or Li3PO4-coated cathode prepared by the (NH4)2HPO4 source.

Studies on Rheological Properties of High Solid Coating Colors(Part 2) - Effect of Rheology Modifiers on High-Shear Viscosity and Dynamic Penetration Behavior - (고농도 도공액의 유동특성에 관한 연구(제2보) - 유동성 조절제가 고전단 점도 및 동적 침투특성에 미치는 영향 -)

  • Yoo, Sung-Jong;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.121-127
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    • 2011
  • This study used two types of rheology modifiers including an alkali-swellable emulsion (ASE) and an surface-adhesion emulsion (SAE) to elucidate their effects on high shear viscosity and dynamic penetration behavior among the flow properties of high solids coating. Since rheology under high shear and dynamic penetration behavior significantly affect the quality of coated paper in case of high solids coating, it is very important to examine the variations in rheology of high solids coating color by rheology modifier. It was found that the high solids coating color prepared with the SAE type showed superior dynamic penetration behavior and high shear viscosity than that with the ASE type rheology modifier.

Characteristic ependences of High Power Semiconductor Laser on AR Coating (AR Coating에 따른 고출력 반도체 레이저의 특성변화)

  • 오윤경;곽계달
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.11
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    • pp.29-34
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    • 1995
  • Mirror coating is applied to laser facets to improve properties of edge emitting laser diodes. In this experiment, InGaAsP/GaAs high power laser diodes were studied with respect to different degrees of anti-reflective coating. Sputterred $Al_{2}$O$_{3}$ was used as the coating material and the HR coating was kept constant at 90%. Threshold current density, differential quantum efficiency, emission wavelength and the operating current at 500mW were measured for a range of AR coating and compared with theoretically calculated values; that showed good agreements. Precise wavelength control is important for laser diodes for solid state pumping because of small absorption bandwidth. In addition, since these lasers operate under CW condition, a lowest possible operating current for a given power is desired in order to minimize the heat produced. From the results of this experiment, we were able to obtain a optimum range of AR coatings for minimum operating current. The wavelength can be varied up to 4nm within this range.

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Wear behaviors of HVOF spray coating of Co-alloy T800

  • Cho, Tong-Yul;Yoon, Jae-Hong;Kim, Kil-Su;Park, Bong-Kyu;Youn, Suk-Jo;Back, Nam-Ki;Chun, Hui-Gon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.3
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    • pp.121-126
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    • 2006
  • HVOF thermal spray coating of Co-alloy T800 is progressively replacing the classical hard coatings such as chrome plating because of the very toxic $Cr^{6+}$ ion known as carcinogen causing lung cancer. For the study of the possibility of replacing of chrome plating, the wear properties of HVOF Co-alloy T800 coatings are investigated using the reciprocating sliding tester both at room and at an elevated temperature of $1000^{\circ}F\;(538^{\circ}C)$. The possibility as durability improvement coating is studied for the application to the high speed spindles vulnerable to frictional heat and wear. Wear mechanisms at the reciprocating sliding wear test are studied for the application to the systems similar to the sliding test such as high speed spindles. Wear debris and frictional coefficients of T800 coatings both at room and at an elevated temperature of $1000^{\circ}F\;(538^{\circ}C)$ are drastically reduced compared to those of non-coated surface of parent substrate Inconel 718. This study shows that the coating is recommendable for the durability improvement coatings on the surfaces vulnerable to frictional heat. The sliding surfaces are weared by the mixed mechanisms such as oxidative wear, abrasion by the sliding ball slurry erosion by the mixture of solid particles and small drops of the melts and semi-melts of the attrited particles cavitation by the relative motions among the coating, sliding ball, the melts and semi-melts. and corrosive wear. The oxide particles and the melts and semi-melts play roles as solid and liquid lubricant reducing the wear and friction coefficient.

Enhancement of Wear Resistance of CoCrNiAlTi Plasma Sprayed Coatings Using Titanium Carbide

  • De-Yong Li;Chul-Hee Lee
    • Tribology and Lubricants
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    • v.39 no.1
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    • pp.13-20
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    • 2023
  • Large drill bits may face high hardness ore and high working pressure when working. To optimize the use effect of large drill bits and prolong the use time, it is necessary to add a layer of pressure-resistant, wear-resistant, and low-friction coating on the surface of the drill bit. In this study, CoCrNiAlTi high-entropy alloy coatings and CoCrNiAlTi (70 wt%)-TiC (30 wt%) composite coatings are successfully prepared on Q235 steel by plasma spraying. The CoCrNiAlTi (70 wt%)-TiC (30 wt%) coating consists of FCC solid solution and a small amount of TiC phase. The effect of TiC on the composition phase, microhardness, and elastic modulus of HEA coating is studied by X-ray diffractometer (XRD) and microhardness tester. The effect of TiC on the friction and wear properties of HEA coatings is investigated using a wear tester. By improving the process parameters, the metallurgical bonding between the coating and the substrate is well combined, and a coating without pores and cracks is obtained. The experimental results confirm that the microhardness, elastic modulus, and wear resistance of CoCrNiAlTi-TiC composite coating are better, and the friction coefficient is lower.

A Study on Coating Performance Design for Ice Belt Zone of the Arctic Vessels (극지 운항 선박 Ice Belt Zone의 도장 사양 설계 연구)

  • Baek, Yun-Ho;Park, Chung-Seo;So, Yong-Shin
    • Special Issue of the Society of Naval Architects of Korea
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    • 2013.12a
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    • pp.66-72
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    • 2013
  • The demand for an ice class ship is rising expected to rise according to the increase of energy consumption and the opening of arctic sea routes. Ice class ship should be designed to cope with the severe environmental conditions of arctic sea such as a high mechanical impact and abrasion damage, caused by pack ice, ice bergs and low temperature. The ice class ship hulls are coated with an anti-abrasion and low friction coating such as a solvent free epoxy or high solid-volume epoxy. These coatings require two-component heating pump and a high grade surface preparation. In this study, the coating performances for the arctic vessels, such as puncture absorbed energy, abrasive wear loss, friction coefficients and impact absorbed energy were evaluated. Based on this study, a proper coating performance specification for the arctic vessels was proposed and coating selection guideline in terms of coating performance and workability was also established.

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The Preparation and Characteristics of High Solids Acrylic/Polyisocyanate Coatings (하이솔리드 아크릴/폴리이소시아네이트 도료의 제조와 도막 특성)

  • 김대원;황규현;정충호;우종표;박홍수
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.520-528
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    • 2000
  • New high solid acrylic resins (BMHA) containing 70% of solids content have been synthesized. The environmental friendly high solid coatings (BNHS) were prepared by using these acrylic resins and polyisocyanates. The BMHA was obtained by introducing a new functional group, acetoacetoxyethyl methacrylate (AAEM), in the copolymerization of n-butyl acrylate, methyl methacrylate, and 2-hydroxyethyl acrylate. Lowering T$_{g}$ and increasing the AAEM amount in the BMHA resulted in a high value of conversion. There was no difference in conversion with the variations of OH values. In the next step, high solid BNHS coatings were prepared by the curing reaction between BMHA and polyisocyanate at room temperature. The properties of these coatings were evaluated especially for the application of automotive top-coating materials. The introduction of AAEM in the BNHS enhanced the abrasion resistance and solvent resistance of the coatings, which indicated the possible use of BNHS coatings for top-coating materials of automobile..

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Preparation of Al-Sn Coating Bearings by RF Sputtering Method and Evaluation of Their Properties (RF 스퍼터링법에 의한 Al-Sn계 코팅베어링의 제작과 특성 평가)

  • 이찬식;이명훈
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.6
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    • pp.139-146
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    • 2000
  • The development of high performance materials is very important subject in order to enhance the properties of bearings whose role is to transfer energy harmoniously by reducing the problem of friction and wear down, etc. between the interacting solid surfaces in relative motion under high loads in comply with mechanical operating mechanism of engines. In this study, several (100-x)Al-xSn coating films (where x=85, 75, 65 atomic % at Al) on substrates which are abt. 2mm thickenss of Kelmet layer sintered back steel were prepared by using RF sputtering system. These coating films were observed the morphology by SEM(Scanning Electron Microscope) and investigated the crystal structure by XRD(X-ray Diffractor) for their properties. And friction coefficient of these films was measured by ball-on-disc tester for their tribological properties. From the experimental results, it was shown that high performance properties of bearing can be improved greatly by controlling the composition and morphology of material surface with effective use of the plasma-assisted sputtering process.

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A Study on the Lubricational Characteristics of Automotive Piston Motions With $MoS_{2}$ and PTFE Coating Materials ($MoS_{2}$와 PTFE 코팅재료에 의한 자동차 피스톤 운동의 윤활특성 연구)

  • Oh, Seong-Mo;Mun, Sang-Don
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.2
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    • pp.57-62
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    • 2007
  • The lubricational characteristics about friction wear has an effect on the material quality of surface. In this paper, we studied the lubricational characteristics through the surface modification experiment by spray coating the surface with $MoS_{2}$ and PTFE solid lubricants. In the case of $MoS_{2}$ and PTFE coating, the friction coefficient of Journal is lower than that for noncoating so the friction characteristics is excellent. In particular, the beginning characteristics of $MoS_{2}$ coating is excellent, and in the case of PTFE coating, seizure dose not appear seizure. $MoS_{2}$ and PTFE coating are excellent in the extreme pressure at high load. The wear characteristics is excellent in the following order; PTFE < $MoS_{2}$ < Non Coating. For Non coating, seizure appears at the beginning due to the heat, but in the case of $MoS_{2}$ and PTFE coating, it will have the excellent heat stability even at high temperature.