• Title/Summary/Keyword: High refractive index

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Fabrication of Hydrophobic Anti-Reflection Coating Film by Using Sol-gel Method (Sol-gel 법을 이용한 내오염 반사방지 코팅막 제조)

  • Kim, Jung-Yup;Lee, Ji-Sun;Hwang, Jonghee;Lim, Tae-Young;Lee, Mi-Jai;Hyun, Soong-Keun;Kim, Jin-Ho
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.689-693
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    • 2014
  • Anti-reflection coating films have used to increase the transmittance of displays and enhance the efficiency of solar cells. Hydrophobic anti-reflection coating films were fabricated on a glass substrate by sol-gel method. To fabricate an anti-reflection film with a high transmittance, poly ethylene glycol (PEG) was added to tetraethyl orthosilicate (TEOS) solution. The content of PEG was changed from 1 to 4 wt% in order to control the morphology, thickness, and refractive index of the $SiO_2$ thin films. The reflectance and transmittance of both sides of the coated thin film fabricated with PEG 4 wt% solution were 0.3% and 99.4% at 500 nm wavelength. The refractive index and thickness of the thin film were n = 1.29 and d = 105 nm. Fluoro alkyl silane (FAS) was used for hydrophobic treatment on the surface of the anti-reflection thin film. The contact angle was increased from $13.2^{\circ}$ to $113.7^{\circ}$ after hydrophobic treatment.

$SiN_x$ Film Deposited by Hot Wire Chemical Vapor Deposition Method for Crystalline Silicon Solar Cells (결정질 실리콘 태양전지 적용을 위한 HWCVD $SiN_x$ 막 연구)

  • Kim, Ha-Young;Park, Min-Kyeong;Kim, Min-Young;Choi, Jeong-Ho;Roh, Si-Cheol;Seo, Hwa-Il
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.3
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    • pp.27-33
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    • 2014
  • To develop high efficiency crystalline solar cells, the $SiN_x$ film for surface passivation and anti-reflection coating is very important and it is generally deposited by PECVD. In this paper, the $SiN_x$ film deposited by Hot-Wire chemical vapor deposition(HWCVD) that has no plasma damage was studied. First, to optimize the $SiN_x$ film deposition process, $SiH_4$ gas rate and substrate temperature were varied and then refractive index and thickness were measured. When $SiH_4$ gas rate was 22sccm and substrate temperature was $100^{\circ}C$, refractive index was 1.94 and higher than that of other process conditions. Second, the lifetime was measured by varying the annealing temperature and time. The annealing process was made from 5 to 30 minutes at $300{\sim}500^{\circ}C$. When the annealing temperature was $100^{\circ}C$ and time was 10minute, the lifetime was the highest. The lifetime of annealed samples was also measured after the firing process at $975^{\circ}C$. Although the lifetime of all samples was decreased by firing process, the lifetime of annealed samples before the firing process was higher than that of fired samples only. Finally, the characteristics of solar cells with HWCVD $SiN_x$ film were measured.

Design of Miniaturized Wilkinson Power Divider Using Substrate Integrated Artificial Dielectric (기판적층형 가유전체를 이용한 소형화된 윌킨슨 전력분배기 설계)

  • Koo, Ja-Kyung;Lim, Jong-Sik;Ahn, Dal
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.7
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    • pp.1542-1548
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    • 2009
  • This paper describes a size-reduced Wilkinson power divider using substrate integrated artificial dielectric(SIAD). SIAD transmission lines have increased effective refractive index, so the line width and length are reduced from those of standard transmission lines. Therefore the "size-reduction effect" is achieved if SIAD lines are applied to high frequency circuits. An efficient simulation method is proposed for SIAD lines which have an enormous number of via-holes. A 2GHz Wilkinson power divider is designed and measured using SIAD transmission line as an example of application. The size of the fabricated divider is reduced by 32% due to the increased effective refractive index of SIAD, while the performances are maintained similarly.

Preparation of Hard Coating Films with High Refractive Index using Organic-Inorganic Hybrid Coating Solutions (유-무기 하이브리드 코팅 용액을 이용한 고굴절 하드코팅 막의 제조)

  • Choi, Jin Joo;Kim, Nam Uoo;Ahn, Chi Yong;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.388-394
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    • 2014
  • Inorganic-organic hybrid coating solutions were synthesized using titania sol from titanium isopropoxide (TTIP) as an inorganic component and mixture of two or three types of silane coupling agents, such as methacryloxypropyl trimethoxysilane (MPTMS), aminopropyl triethoxysilane (APS), glycidoxypropyl trimethoxysilane (GPTMS) and vinyltriethoxysilane (VTES) as an organic component. The hard coating films were obtained by spin-coating on the polycarbonate sheets and curing the inorganic-organic hybrid coating solutions. The coating films made from the mixture of two types of silane coupling agents showed poor pencil hardness and adhesion, while those from the mixture of three types of silane coupling agents exhibited an improved pencil hardness of 2H~4H and adhesion of 5B. The refractive indexes of coating films were increased from 1.56 to 1.63 at 550 nm by increasing the content of titania sols from 20 to 30 g.

The optical and thermal properties of Li2O-BaO-Ga2O3-TeO2-TiO2-GeO2 mid-infrared transmission glass (Li2O-BaO-Ga2O3-TeO2-TiO2-GeO2 계 중적외선 투과 유리의 조성에 따른 광학적, 열적 특성)

  • Minsung Hwang;Jaeyeop Chung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.6
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    • pp.250-254
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    • 2023
  • In this study, Li2O-BaO-Ga2O3-TeO2-TiO2-GeO2 glasses with high transmittance in mid-infrared region and high refractive indices were successfully synthesized. The relationship between glass properties and glass composition was analyzed. In Li2O-BaO-Ga2O3-TeO2-TiO2-GeO2 glass system, as increasing TeO2 concentration, the refractive index increases and the glass transition temperature decreases. In addition, as increasing BaO concentration, the refractive index increases without decrease of Abbe number. The IR-cut off wavelength shifted to the longer wavelength with increasing TeO2 and BaO contents due to their large molecular weight. The glass transition temperature significantly decreases when BaO was replaced with Li2O.

Fiber-Optic Temperature Sensor Based on Single Mode Fused Fiber Coupler

  • Kim, Kwang-Taek;Park, Kiu-Ha
    • Journal of the Optical Society of Korea
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    • v.12 no.3
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    • pp.152-156
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    • 2008
  • This paper reports a fiber-optic temperature sensor using a single mode fused fiber coupler incorporating a thermo-optic external medium. The spectral transmission was altered by changing the refractive index of the external thermo-optic medium. A theoretical and experimental investigation was carried out with the aim of achieving high sensitivity. The measured sensitivity for the environmental temperature was as high as -1.5 $nm/^{\circ}C$.

Effect of RTA Temperature on the Structural and Optical Properties of HfO2 Thin Films (급속 열처리 온도가 HfO2 박막의 구조적 및 광학적 특성에 미치는 효과)

  • Chung, Yeun-Gun;Joung, Yang-Hee;Kang, Seong-Jun
    • The Journal of the Korea institute of electronic communication sciences
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    • v.14 no.3
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    • pp.497-504
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    • 2019
  • We fabricated $HfO_2$ thin films using RF magnetron sputtering method, and investigated structural and optical properties of $HfO_2$ thin films with RTA temperatures in $N_2$ ambient. $HfO_2$ thin films exhibited polycrystalline structure regardless of annealing process, FWHM of M (-111) showed reduction trend. The surface roughness showed the smallest of 3.454 nm at a annealing temperature of $600^{\circ}C$ in result of AFM. All $HfO_2$ thin films showed the transmittance of about 80% in visible light range. By fitting the refractive index from the transmittance and reflectance to the Sellmeir dispersion relation, we can predict the refractive index of the $HfO_2$ thin film according to the wavelength. The $HfO_2$ thin film annealed at $600^{\circ}C$ exhibited a high refractive index of 2.0223 (${\lambda}=632nm$) and an excellent packing factor of 0.963.

Design Optimization for High Efficiency Distributed Bragg Reflectors through Simulation Methodology (시뮬레이션을 이용한 고효율 분산 브래그 반사경 최적화 설계 및 특성)

  • Kim, Kwan-Do
    • Journal of IKEEE
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    • v.22 no.1
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    • pp.189-192
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    • 2018
  • This study focused on the development of simulation methodology and design optimization for the DBR(Distributed Bragg Reflectors) structures, which are commonly used in manufacturing optical films and the key components of LED chip and LCD inspection equipments. From the multi-layer simulation, the following results are obtained. First, the wavelength(nm) vs. reflectance(%) can be calculated in the DBR structures that $TiO_2$ and $SiO_2$ thin films are stacked alternately. As a results, it is suggested that highly efficient DBR structures can be designed and manufactured using simulation methodology.

Fabrication of La2O3-TiO2-SiO2 System Glass Derived from a Sol-Gel Process

  • Iwasaki, Mitsunobu;Masaki, Hitoshi;Ito, Seishiro;Park, Won-Kyu
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.137-141
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    • 2007
  • $La_{2}O_{3}-TiO_{2}-SiO_{2}$ glass, a type that could not obtained so far by the conventional melting method, was prepared successfully using a sol gel process. Glass derived with the sol-gel process has compositions of $5La_{2}O_{3}-5TiO_{2}-90SiO_{2},\;5La_{2}O_{3}-10TiO_{2}-85SiO_{2}$, and $5La_{2}O_{3}-20TiO_{2}75SiO_{2}$. The UV-visible absorption edge of all glass compositions was below 400 nm. The measured density is in the range of 2.55-2.89, and was nearly identical to the calculated density and the refractive index of the glasses derived from the sol-gel ranges from 1.545 to 1.645. The molar additive coefficient of $TiO_{2}$ measured in this ternary system is lower than the calculated value, while the value of $La_{2}O_{3}$ is higher.

The process optimization for development of super deep black fiber (고심색용 폴리에스테르 섬유제품의 개발을 위한 공정최적화 연구)

  • Kim, Tae-Kyeong;Jeon, Jun-Hyung;Kim, Eun-Cheol
    • Textile Coloration and Finishing
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    • v.19 no.1 s.92
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    • pp.53-60
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    • 2007
  • In order to optimize the process for development of super deep black fiber, the silica-containing polyester fabric, SN2000, was investigated in terms of mass reduction process by sodium hydroxide, selection of high color strength dyes, and resin treatment. As the results, the mass reduction condition which used 15g/L of sodium hydroxide at $120^{\circ}C$ was determined and Dianix Deep Black Plus was selected for the best deep coloration at around 5% owf. Contrary to the prevailed understanding that the additional use of chromatic dyes would enhance the deep coloration, four kinds of chromatic dyes such as yellow, red, blue, and green dyes did not make great effect on the deep coloration. To increase the effect, the commercial resin that has low refractive index was used additionally and the resin made it possible to lower the lightness of the fabrics down to 8.7 which was generally accepted for super highly deep black fabric.