• Title/Summary/Keyword: High pure gas

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Fabrication of NO sensor integrated SiC micro heaters for harsh environments and its characteristics (SiC 마이크로 히터가 내장된 극한 환경용 NO 센서의 제작과 특성)

  • Kim, Kang-San;Chung, Gwiy-Sang
    • Journal of Sensor Science and Technology
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    • v.19 no.3
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    • pp.197-201
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    • 2010
  • This paper describes the fabrication and characteristics of a NO sensor using ZnO thin film integrated 3C-SiC micro heater based on polycrystalline 3C-SiC thin film of operation in harsh environments. The sensitivity, response time, and operating properties in high temperature and voltages of NO sensors based SiC MEMS are measured and analyzed. The sensitivity of device with pure ZnO thin film at the heater operating power of 13.5 mW ($300^{\circ}C$) is 0.875 in NO gas concentration of 0.046 ppm. In the case of Pt doping, the sensitivity of at power consumption of 5.9 mW ($250^{\circ}C$) was 1.92 at same gas flow rate. The ZnO with doped Pt was showed higher sensitivity, lower working temperature and faster adsorption characteristics to NO gas than pure ZnO thin film. The NO gas sensor integrated SiC micro heater is more strength than others in high voltage and temperature environments.

Improvement of Cooling Technology through Atmosphere Gas Management

  • Renard, Michel;Dosogne, Edgar;Crutzen, Jean-Pierre;Raick, Jean-Marc;Ma, Jia Ji;Lv, Jun;Ma, Bing Zhi
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.217-222
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    • 2009
  • The production of advanced high strength steels requires the improvement of cooling technology. The use of high cooling rates allows relatively low levels of expensive alloying additions to ensure sufficient hardenability. In classical annealing and hot-dip galvanizing lines a mixing station is used to provide atmosphere gas containing 3-5% hydrogen and 97-95% nitrogen in the various sections of the furnace, including the rapid cooling section. Heat exchange enhancement in this cooling section can be insured by the increased hydrogen concentration. Drever International developed a patented improvement of cooling technology based on the following features: pure hydrogen gas is injected only in the rapid cooling section whereas the different sections of the furnace are supplied with pure nitrogen gas; the control of flows through atmosphere gas management allows to get high hydrogen concentration in cooling section and low hydrogen content in the other furnace zones. This cooling technology development insures higher cooling rates without additional expensive hydrogen gas consumption and without the use of complex sealing equipments between zones. In addition reduction in electrical energy consumption is obtained. This atmosphere control development can be combined with geometrical design improvements in order to get optimised cooling technology providing high cooling rates as well as reduced strip vibration amplitudes. Extensive validation of theoretical research has been conducted on industrial lines. New lines as well as existing lines, with limited modifications, can be equipped with this new development. Up to now this technology has successfully been implemented on 6 existing and 7 new lines in Europe and Asia.

Removal potential of dissolved gas in gas hydrate desalination process by reverse osmosis (역삼투막을 이용한 가스하이드레이트 해수담수화 공정 내 용존 가스의 제거 가능성 평가)

  • Ryu, Hyunwook;Kim, Minseok;Lim, Jun-Heok;Kim, Joung Ha;Lee, Ju Dong;Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.635-643
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    • 2016
  • Gas hydrate (GH)-based desalination process have a potential as a novel unit desalination process. GHs are nonstoichiometric crystalline inclusion compounds formed at low temperature and a high pressure condition by water and a number of guest gas molecules. After formation, pure GHs are separated from the remaining concentrated seawater and they are dissociated into guest gas and pure water in a low temperature and a high pressure condition. The condition of GH formation is different depending on the type of guest gas. This is the reason why the guest gas is a key to success of GH desalination process. The salt rejection of GH based desalination process appeared 60.5-93%, post treatment process is needed to finally meet the product water quality. This study adopted reverse osmosis (RO) as a post treatment. However, the test about gas rejection by RO process have to be performed because the guest gas will be dissolved in a GH product (RO feed). In this research, removal potential of dissolved gas by RO process is performed using lab-scale RO system and GC/MS analysis. The relation between RO membrane characteristics and gas removal rate were analyzed based on the GC/MS measurement.

Improvements of the luminous efficiency of mercury-free fluorescent lamps via structural and complex gas mixture changes

  • Oh, Byung-Joo;Jung, Jae-Chul;Seo, In-Woo;Kim, Hyuk;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.809-812
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    • 2008
  • Structural parameter variation effects (changing the coplanar gap under different discharge dimensions) and use of complex gas mixtures (He, Ne, Ar and Xe) in mercury-free fluorescent lamps are studied in this paper. Pure Neon gas is the best buffer gas for obtaining high luminous efficiency in mercury-free fluorescent lamps. It is shown that with a shorter coplanar gap (30mm), a high luminous efficiency can be obtained at low operating voltage, as well as high luminance uniformity and stable discharge with a Ne-Xe 20% gas mixture.

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Creep Life Prediction of Aircraft Gas Turbine material by ISM (ISM에 의한 항공기용 가스터빈 재료의 크리프 수명예측)

  • 공유식
    • Journal of Ocean Engineering and Technology
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    • v.15 no.3
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    • pp.43-48
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    • 2001
  • In this paper, the real-time prediction of high temperature creep strength and creep for nickel-based superalloy Udimet 720 (high-temperature and high-pressure gas turbine engine materials) was performed on round-bar type specimens under pure load at the temperatures of 538, 649 and 704$^{\circ}C$. The predictive equation of ISM creep has better reliability than that of LMP and LMP-ISM, and its reliability is getting better for long time creep prediction ($10^3~10^5$h).

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Highly Sensitive and Selective Trimethylamine Sensor Using Yolk-shell Structured Mo-doped Co3O4 Spheres

  • Kim, Tae-Hyung;Kim, Ki Beom;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.28 no.5
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    • pp.271-276
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    • 2019
  • Pure and 0.5, 1, 2, 5, and 10 at% of Mo-doped $Co_3O_4$ yolk-shell spheres were synthesized by ultrasonic spray pyrolysis of droplets containing Co nitrate, ammonium molybdate, and sucrose and their gas sensing characteristics to 5 ppm trimethylamine (TMA), ethanol, p-xylene, toluene, ammonia, carbon monoxide, and benzene were measured at $225-325^{\circ}C$. The sensor using pure $Co_3O_4$ yolk-shell spheres showed the highest response to p-xylene and very low response to TMA at $250^{\circ}C$, while the doping of Mo into $Co_3O_4$ tended to increase the overall responses of gas sensors. In particular, the sensor using 5 at% Mo-doped $Co_3O_4$ yolk-shell spheres exhibited the high response to TMA with low cross-responses to other interfering gases. The high response and selectivity of Mo-doped $Co_3O_4$ yolk-shell spheres to TMA are attributed to the electronic sensitization by higher valent Mo doping and acid-base interaction between TMA and Mo components.

Experimental and Simulation Study of PEMFC based on Ammonia Decomposition Gas as Fuel

  • Zhao, Jian Feng;Liang, Yi Fan;Liang, Qian Chaos;Li, Meng Jie;Hu, Jin Yi
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.63-70
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    • 2022
  • Compared with hydrogen, ammonia has the advantages of high gravimetric hydrogen densities (17.8 wt.%), ease of storage and transportation as a chemical hydrogen storage medium, while its application in small-scale on-site hydrogen production scenarios is limited by the need for complex separation equipment during high purity hydrogen production. Therefore, the study of PEMFC, which can directly utilize ammonia decomposition gas, can greatly expand the application of fuel cells. In this paper, the output characteristics, fuel efficiency and the variation trend of hydrogen concentration and local current density in the anode channel of fuel cell with the output voltage of PEMFC fueled by ammonia decomposition gas were studied by experiment and simulation. The results indicate that the maximum output power of the hybrid fuel decreases by 9.6% compared with that of the pure hydrogen fuel at the same inlet hydrogen equivalent. When the molar concentration of hydrogen in the anode channel is less than 0.12, the output characteristics of PEMFC will be seriously affected. Employing ammonia decomposition gas as fuel, the efficiency corresponding to the maximum output power of PEMFC is approximately 47%, which is 10% lower than the maximum efficiency of pure hydrogen.

The Electrical and CO Gas Sensing Properties of SnO$_2$-WO$_3$Composite Ceramics (SnO$_2$-WO$_3$복합체의 전기적특성과 일산화탄소 가스 감응특성)

  • 김태원;정승우;최우성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.347-349
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    • 1997
  • In order to investigate CO sensing property of a SnO$_2$-WO$_3$composite ceramic. we prepared pure SnO$_2$and WO$_3$added SnO$_2$compostie ceramics. Using XRD and SEM, a phase analysis and microstructure were investigated. The resistances as a function of gas atmosphere were measured by High Voltage Measure/source Unit. The measured 1000ppm CO gas sensitivity of SnO$_2$-WO$_3$composite ceramics were smaller than that of pure SnO$_2$.

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Amorphization Process of Cr-N Alloy System by Mechanical Alloying (기계적 합금화에 의한 Cr-N계 합금의 비정질화 과정)

  • 이충효;이성희;이상진;권영순
    • Journal of Powder Materials
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    • v.10 no.4
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    • pp.288-293
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    • 2003
  • Mechanical alloying (MA) by high energy ball mill of Pure chromium Powders was carried out under the nitrogen gas atmosphere. Cr-N amorphous alloy powders have been produced through the solid-gas reaction subjected to MA. The atomic structure during amorphization process was observed by X-ray and neutron diffractions. An advantage of the neutron diffraction technique allows us to observe the local atomic structure surrounding a nitrogen atom. The coordination number of metal atoms around a N atom turns out to be 5.5 atoms. This implies that a nitrogen atom is located at both of centers of the tetrahedron and octahedron formed by metal atoms to stabilize an amorphous Cr-N structure. Also, we have revealed that a Cr-N amorphous alloy may produced from a mixture of pure Cr and Cr nitrides powders by solid-solid reaction during mechanical alloying.

Trimethylamine Sensing Characteristics of Molybdenum doped ZnO Hollow Nanofibers Prepared by Electrospinning (전기방사방법에 의해 합성된 ZnO 중공 나노섬유의 trimethylamine 가스 감응 특성)

  • Kim, Bo-Young;Yoon, Ji-Wook;Lee, Chul-Soon;Park, Joon-Shik;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.24 no.6
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    • pp.419-422
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    • 2015
  • Pure and Mo-doped ZnO hollow nanofibers were prepared by single capillary electrospinning and their gas sensing characteristics toward 5 ppm ethanol, trimethylamine (TMA), CO and $H_2$ were investigated. The gas responses and responding kinetics were dependent upon sensing temperature and Mo doping. Mo-doped ZnO hollow nanofibers showed high response to 5 ppm TMA ($R_a/R_g=111.7$, $R_a$: resistance in air, $R_g$: resistance in gas) at $400^{\circ}C$, while the responses of pure ZnO hollow nanofibers was low ($R_a/R_g=47.1$). In addition, the doping of Mo enhanced selectivity toward TMA. The enhancement of gas response and selectivity to TMA by Mo doping to ZnO nanofibers was discussed in relation to the interaction between basic analyte gas and acidic additive materials.