In order to develop a new separation technology, supercritical fluid extraction process was used to produce high purity pigments and fatty acids from seaweed (Undaria pinnatifida). Supercritical carbon dioxide was used as a solvent and ethanol as an entrainer. The sample was treated by a frozen drier and experiments were conducted with a semi-batch flow system at various operating conditions (pressure range, $10.3\~17.2$ MPa; temperature range, $30\~45^{\circ}C$: particle size, $500\~1,000{\mu}m$ extraction time, 60 min). Characteristics of the recovered pigment (chlorophyll a) and fatty acids were determined by UV-spectrophotometry and gas chromatography, respectively. The highest extraction efficiency for fatty acids and pigments was achieved at 12.4 MPa, $35^{\circ}C$, $500{\mu}m$of seaweed size.
Ahn, Byung Hun;Moon, Dong Ju;Yoo, Kye Sang;Ho, Chia Chi
Korean Chemical Engineering Research
/
v.43
no.2
/
pp.236-242
/
2005
Membrane fouling by protein mixtures during microfiltration has been investigated for binary mixtures of bovine serum albumin (BSA), casein, lysozyme, pepsin, and ovalbumin. Filtration experiments were carried out using $0.2{\mu}m$ polycarbonate track-etched (PCTE) membrane in a stirred cell under constant transmembrane pressure (14 kPa) and concentration of hydrogen ion (pH=11) to study the effect of mixture composition on filtrate flux decline. Flux decline data were analyzed using a pore blockage-cake formation model developed recently. It was found that the model is in a good agreement with the experimental data. Fouling parameters such as the rate of pore blockage(${\alpha}$), the initial resistance of the protein deposit ($R_{po}$) and the increasing rate of the protein layer resistance(${\beta}$) were used to evaluate the rate of filtrate flow by membrane fouling in the binary mixture system. Generally, the trend of ${\alpha}$ is comparable with that of filtrate flux decline. It was also found that fast flux decreasing was observed over the binary mixture containing casein. The result is due to high value of the initial resistance of the protein deposit ($R_{po}$) over casein.
Jo, Hyeong-Je;Min, Dea-Kee;Kim, Jong-Won;Lee, Ju-Kyung;Beak, Jong-Hoon
Journal of Korean Tunnelling and Underground Space Association
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v.19
no.2
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pp.319-333
/
2017
The construction of long sub-sea tunnel does not provide the favorable condition for the installation of ventilation system to be used during construction due to the constrained construction space. For the ventilation system required during construction, the artificial island where ventilation shaft is located is constructed at some location along the sub-sea tunnel route, which requires a high construction cost. Therefore, it is intended, as much as possible technically, to minimize the construction of artificial island. However, this requires a longer distance between ventilation shafts, there-by causing increased air leakage at the ventilation duct connection points due to the higher fan pressure being required to deliver ventilation air. Previously the air leakage was studied as an important issue. In this study experiments were carried out to develop the improved duct connection method considering various conditions such as, tunnel length, etc. Additionally, its performance results with leakage rates are shown and compared to the "S" class leakage rate of SIA. As a result, the new duct coupling type of improved method is analyzed as applicable to such a 30 km long tunnel with the leakage rate of $1.46mm^2/m^2$, which is better performance than SIA leakage rates.
There are many results in which acoustical conditions of a classroom play an important role for studying effects and academic achievement of students. However, there are very few guidelines or design proposals which could make appropriate acoustic environment when classrooms are built or renovated. The present study suggests various design proposals satisfying acoustic standards of classrooms based on theoretical calculation and acoustic field experiments. At first, minimum area of sound absorption was calculated which is required to satisfy the acoustic standard for domestic middle and high schools. Also, room acoustic measurements were carried out in order to investigate the acoustic performance of an existing classroom by changing interior finishing materials on ceiling and rear walls. As a result, it was revealed that reverberation time standard below 0.8 s can be acquired even if there is no sound absorption on ceiling which is a general practice executed in Korea. Specially, it was found that if partial area of ceiling would be treated as reflective with the ratio of sound absorption and reflection as 2:1, almost similar acoustic parameters of $C_{50}$, $D_{50}$, RASTI (Rapid Speech Transmission Index) and higher sound levels could be acquired in comparison with the case of entire sound absorption on ceiling.
The accumulator is a passive safety injection device for emergency core cooling systems. As an important safety feature for providing a high-speed injection flow to the core by compressed nitrogen gas pressure during a loss-of-coolant accident (LOCA), the accumulator injects its precharged nitrogen into the system after its coolant has been emptied. Attention has been drawn to the possible negative effects caused by such a nitrogen injection in passive safety nuclear power plants. Although some experimental work on the nitrogen injection has been done, there have been no comparative tests in which the effects on the system responses and the core safety have been clearly assessed. In this study, a new thermal hydraulic integral test facility-the advanced core-cooling mechanism experiment (ACME)-was designed and constructed to support the CAP1400 safety review. The ACME test facility was used to study the nitrogen injection effects on the system responses to the small break loss-of-coolant accident LOCA (SBLOCA) transient. Two comparison test groups-a 2-inch cold leg break and a double-ended direct-vessel-injection (DEDVI) line break-were conducted. Each group consists of a nitrogen injection test and a nitrogen isolation comparison test with the same break conditions. To assess the nitrogen injection effects, the experimental data that are representative of the system responses and the core safety were compared and analyzed. The results of the comparison show that the effects of nitrogen injection on system responses and core safety are significantly different between the 2-inch and DEDVI breaks. The mechanisms of the different effects on the transient were also investigated. The amount of nitrogen injected, along with its heat absorption, was likewise evaluated in order to assess its effect on the system depressurization process. The results of the comparison and analyses in this study are important for recognizing and understanding the potential negative effects on the passive core cooling performance caused by nitrogen injection during the SBLOCA transient.
Journal of Korean Society of Environmental Engineers
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v.38
no.6
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pp.323-328
/
2016
Pressurized membrane used for side-stream MBR process requires fouling control strategy both for normal and abnormal operation conditions for stable operation of the facilities. In this study, $85m^3/day$ of pilot-scale side-stream MBR process was constructed for the evaluation of fouling mitigation by air bubble injection into the membrane module. In addition, fouling phenomena at abnormal operation conditions of low influent and/or loading rate were also investigated. Injection of air bubble was found to be effective in delaying transmembrane pressure (TMP) increase mainly due to scouring effect on the membrane surface, resulting in expanded filtration cycle at a high flux of $40L/m^2{\cdot}h$ (LMH). At abnormal operation condition, injection of PACl (53 mg/L as Al) into the bioreactor showed 19% reduction of TMP increase. However, inhibition of nitrifying bacteria by continuous PACl injection was observed from batch experiments. In contrast, injection of powdered activated carbon (PAC, 0.6 g/L) was able to maintain the initial TMP of $0.2kg/cm^2$ for 5 days at the abnormal conditions. It may have been caused from the adsorption of extracellular polymeric substances (EPS), which was known to be excessively released during growth inhibition condition and act as the major foulants in MBR operations.
Kim Su-Yeon;Shim Seo-Hoon;Shin Dong-Myeong;Lee Joo-Sung;Jung Hyun-Wook;Hyun Jae-Chun
Proceedings of the Korean Society of Rheology Conference
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2006.06a
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pp.81-84
/
2006
Slot coating process, in continuous and patch modes, has been applied for the many precise coating products, e.g., flat panel displays and second batteries. However, manufacturing uniform coating products is not a trivial task at high-speed operations because various flow instabilities or defects such as leaking, bubbles, ribbing, and rivulets are frequently observed in this process. It is no wonder, therefore, that many efforts to understand the various aspects of dynamics and coating windows of this process have been made both in academia and industry. In this study, as the first topic, flow dynamics within the coating bead in slot coating process has been investigated using the one-dimensional viscocapillary model by lubrication approximation and two-dimensional model by Flow-3D software. Especially, operability windows in both 1D and 2D cases with various slot die lip designs have been successfully portrayed. Also, effects of process conditions like viscosity and coating gap size on slot coating window have been analyzed. Also, some experiments to find minimum coating thickness and coating windows have been conducted using slot die coater implemented with flow visualization device, corroborating the numerical results. As the second topic, flow dynamics of both Newtonian and Non-Newtonian fluids in patch or pattern slot coating process, which is employed in manufacturing IT products such as secondary batteries, has been investigated for the purpose of optimal process designs. As a matter of fact, the flow control in this system is more difficult than in continuous case because od its transient or time-dependent nature. The internal die and die lip designs for patterned uniform coating products have been obtained by controlling flow behaviors of coating liquids issuing from slot. Numerical simulations have been performed using Fluent and Flow-3D packages. Flow behavior and pressure distribution inside the slot die has been compared with various die internal shapes and geometries. In the coating bead region, efforts to reduce irregular coating defects in head and tail parts of one patterned coating unit have been tried by changing die lip shapes. It has been concluded that optimal die internal design gas been developed, guaranteeing uniform velocity distribution of both Newtonian and shear thinning fluids at the die exit. And also optimal die lip design has been established, providing the longer uniform coating layer thickness within one coating unit.
Journal of Korean Society of Coastal and Ocean Engineers
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v.32
no.6
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pp.384-395
/
2020
Breaking waves generated by wave shoaling in coastal areas have a close relationship with various physical phenomena in coastal regions, such as sediment transport, longshore currents, and shock wave pressure. Therefore, it is crucial to accurately predict breaker index such as breaking wave height and breaking depth, when designing coastal structures. Numerous scientific efforts have been made in the past by many researchers to identify and predict the breaking phenomenon. Representative studies on wave breaking provide many empirical formulas for the prediction of breaking index, mainly through hydraulic model experiments. However, the existing empirical formulas for breaking index determine the coefficients of the assumed equation through statistical analysis of data under the assumption of a specific equation. In this paper, we applied a representative linear-based supervised machine learning algorithms that show high predictive performance in various research fields related to regression or classification problems. Based on the used machine learning methods, a model for prediction of the breaking index is developed from previously published experimental data on the breaking wave, and a new linear equation for prediction of breaker index is presented from the trained model. The newly proposed breaker index formula showed similar predictive performance compared to the existing empirical formula, although it was a simple linear equation.
The social need for stable hydrogen storage technologies that respond to the increasing demand for hydrogen energy is increasing. Among them, underground hydrogen storage is recognized as the most economical and reasonable storage method because of its vast hydrogen storage capacity. In Korea, low-depth hydrogen storage using artificial protective structures is being considered. Further, establishing corresponding safety standards and ground stability evaluation is becoming essential. This study evaluated the hydro-mechanical behavior of the ground during a hydrogen gas leak from a low-depth underground hydrogen storage facility through the HM coupled analysis model. The predictive reliability of the simulation model was verified through benchmark experiments. A parameter study was performed using a metamodel to analyze the sensitivity of factors affecting the surface uplift caused by the upward infiltration of high-pressure hydrogen gas. Accordingly, it was confirmed that the elastic modulus of the ground was the largest. The simulation results are considered to be valuable primary data for evaluating the complex analysis of hydrogen gas explosions as well as hydrogen gas leaks in the future.
Jo, Ha Nui;Nam, Do Hyeon;Kim, Mi Hyun;Lee, Jae Sung
Journal of Conservation Science
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v.37
no.6
/
pp.821-830
/
2021
The weapons excavated from the de-militarized zones (DMZ) of Korea are vulnerable to corrosion due to the immediate and drastic environmental change. Especially, the chloride ions (Cl-) in iron weapons cause active corrosion and require removal. In this study, conservation treatment and de-salination was performed for the discovered weapons from excavation sites of soldiers killed in action during the Korean War. Furthermore, an attempt was made to prepare the most stable plan for conservation treatment through the comparative study of soaking weapons in distilled water without chemicals and in a solution of sodium (SSC) at different temperatures. In the preliminarily experiments, the comparison of the eluted Cl- ions according to different conditions of de-salination showed that the highest number of ions were detected from the de-salination with SSC at a temperature of 100℃, and its duration was much smaller, i.e., 1~2 weeks. Accordingly, for the parts from the guns and rifles amongst other objects, a six-time de-salination was conducted in the SSC solution for 8 hours at 100℃ and subsequently, for 16 hours at room temperature during which the distilled water and SSC were exchanged every week. However, in the case of a loaded rifle, the de-salination was not conducted, considering the risk that the high temperature and pressure by impregnation in vacuum could cause an explosion
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