• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.1
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• pp.88-94
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• 2012

One of the effective ways to reduce both $NO_x$ and PM at the same time in a diesel CI engine is to operate the engine in low temperature combustion (LTC) regimes. In general, two strategies are used to realize the LTC operation-dilution controlled LTC and late injection LTC - and in this study, the former approach was used. In the dilution controlled regime, LTC is achieved by supplying a large amount of EGR to the cylinder. The significant EGR gas increases the heat capacity of in-cylinder charge mixture while decreasing oxygen concentration of the charge, activating low temperature oxidation reaction and lowering PM and $NO_x$ emissions. However, use of high EGR levels also deteriorates combustion efficiency and engine power output. Therefore, it is widely considered to use increased intake pressure as a way to resolve this issue. In this study, the effects of intake pressure variations on performance and emission characteristics of a single cylinder diesel engine operated in LTC regimes were examined. LTC operation was achieved in less than 8% $O_2$ concentration and thus a simultaneous reduction of both PM and $NO_x$ emission was confirmed. As intake pressure increased, combustion efficiency was improved so that THC and CO emissions were decreased. A shift of the peak Soot location was also observed to lower $O_2$ concentration while $NO_x$ levels were kept nearly zero. In addition, an elevation of intake pressure enhanced engine power output as well as indicated thermal efficiency in LTC regimes. All these results suggested that LTC operation range can be extended and emissions can be further reduced by adjusting intake pressure.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.5
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• pp.217-221
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• 2003

In this work, chemical-solution derived silicate fibers were prepared by mixing tetraethyl orthosilicate, ethanol, distilled water, and hydrochloric acid in order to investigate surface roughness of fiber. Silicate fibers were drawn by using a viscous solution after evaporation at $80^{\circ}C$. The dried gel fibers were finally annealed at $1000^{\circ}C$, $1100^{\circ}C$, $1200^{\circ}C$ and $^1300{\circ}C$ for 60 min in dried air (flow rate = ∼200 ml/min). The crystallinity of the heat-treated silica fiber was analyzed by the X-ray diffraction $\theta$-2$\theta$ scan. A field emission-scanning electron microscope and an atomic force microscope were used to evaluate surface properties. The silicate fiber annealed at $1300^{\circ}C$ showed high value of root mean square roughness and had a relatively inhomogeneous surface structure.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.5
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• pp.9-16
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• 2007

Since the liquid phase LPG injection(LPLI) system has an advantage of higher power and lower emission characteristics than the mixer type fuel supply system, many studies and applications have been conducted. However, the heat extraction, due to the evaporation of liquid fuel, causes not only a dropping of LPG fuel but also icing phenomenon that is a frost of moisture in the air around the nozzle tip. Because both lead to a difficulty in the control of accurate air fuel ratio, it can result in poor engine performance and a large amount of HC emissions. The experimental investigation was carried out on the bench test rig in this study. It was found that n-butane, that has a relatively high boiling point($-0.5^{\circ}C$), was a main species of droplet composition and also found that the droplet problem was improved by the use of a large inner to outer bore ratio nozzle whose surface roughness is smooth. The icing phenomena were decreased when the an engine head temperature was increased, although a large amount of icing deposit was still observed in the case of $87^{\circ}C$. Also, it was observed that the icing phenomenon is improved by using anti-icing bushing.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.11.2-11.2
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• 2011

Polymer based organic photovoltaics have attracted a great deal of attention due to the potential cost-effectiveness of light-weight and flexible solar cells. However, most BHJ polymer solar cells are not thermally stable as subsequent exposure to heat drives further development of the morphology towards a state of macrophase separation in the micrometer scale. Here we would like to show three different approaches for developing new electroactive polymers to improve the thermal stability of the BHJ solar cells, which is a critical problem for the commercialization of these solar cells. For one of the examples, we report a new series of functionalized polythiophene (PT-x) copolymers for use in solution processed organic photovoltaics (OPVs). PT-x copolymers were synthesized from two different monomers, where the ratio of the monomers was carefully controlled to achieve a UV photo-crosslinkable layer while leaving the ${\pi}-{\pi}$ stacking feature of conjugated polymers unchanged. The crosslinking stabilizes PT-x/PCBM blend morphology preventing the macro phase separation between two components, which lead to OPVs with remarkably enhanced thermal stability. The drastic improvement in thermal stabilities is further characterized by microscopy as well as grazing incidence X-ray scattering (GIXS). In the second part of talk, we will discuss the use of block copolymers as active materials for WOLEDs in which phosphorescent emitter isolation can be achieved. We have exploited the use of triarylamine (TPA) oxadiazole (OXA) diblock copolymers (TPA-b-OXA), which have been used as host materials due to their high triplet energy and charge-transport properties enabling a balance of holes and electrons. Organization of phosphorescent domains in TPA-b-OXA block copolymers is demonstrated to yield dual emission for white electroluminescence. Our approach minimizes energy transfer between two colored species by site isolation through morphology control, allowing higher loading concentration of red emitters with improved device performance. Furthermore, by varying the molecular weight of TPA-b-OXA and the ratio of blue to red emitters, we have investigated the effect of domain spacing on the electroluminescence spectrum and device performance.

• Journal of IKEEE
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• v.21 no.2
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• pp.123-129
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• 2017

Proton Exchange Membrane Fuel Cell (FEMFC) is a strong candidate for future automobile and power generation because of its high power density, low emission and low operation temperature. The major concerns of the gas diffusion layer (GDL) inside a FEMFC is water management. The GDL is typically comprised of carbon for electrical conductivity and PTFE for Hydrophobicity. In this simulation, GDL flooding was investigated using a simplified approach method of an established equation models(Fick' Law, Darcy, Law, Stefan-Maxwell diffusion). The performance of GDL was shown using result of the inner heat, water density and oxygen density of the cell using model equations. The catalyst layer mode in FEMFC showed results of effectiveness factor, Butler-volmer and hydrogen flux density. These results are interesting because the influence of several factors has been shown and the information will be helpful for fuel cell design.

• Journal of ILASS-Korea
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• v.12 no.1
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• pp.38-44
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• 2007

Since the Liquid Phase LPG injection (LPLI) system has Advantages in power generation and emission characteristics compared to the mixer-type fuel-supply system, a variety of studies regarding LPLi system has been conducted and its applications are made in automobile industry. However, the heat extraction due to the evaporation of liquid fuel, causes not only a post-accumulation of fuel but also an icing phenomenon which is a frost of moisture in the air around the nozzle tip. Since there exists a difficulty in the accurate control of air fuel ratio in both fuel supply systems, it can result in poor engine performance and a large amount of harmful emissions. This research examines the characteristics of icing phenomenon and develops anti-icing bushing to prevent an icing on the surface of the injection tip. It was found that n-butane, which has a relatively high boiling point ($-0.5^{\circ}C$), was a main species of post-accumulation. Also the results show that the post-accumulation problem was allevaited the utilization of a large inner to outer bore ratio and smooth surface roughness. In addition, an icing phenomenon and its formation process were found to be mainly affected by the humidity and the temperature of inlet air in an inlet duct. Also, it was observed that an icing phenomenon is lessened using aluminum bushing whose end coincides with the end of fuel injection tip in length.

• International Journal of Fluid Machinery and Systems
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• v.5 no.3
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• pp.134-142
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• 2012

The competition to deliver ultra-low emitting vehicles at a reasonable cost is driving the automotive industry to invest significant manpower and test laboratory resources in the design optimization of increasingly complex exhaust after-treatment systems. Optimization can no longer be based on traditional approaches, which are intensive in hardware use and laboratory testing. The CFD is in high demand for the analysis and design in order to reduce developing cost and time consuming in experiments. This paper describes the development of a comprehensive practical model based on experiments for simulating the performance of automotive three-way catalytic converters, which are employed to reduce engine exhaust emissions. An experiment is conducted to measure species concentrations before and after catalytic converter for different loads on engine. The model simulates the emission system behavior by using an exhaust system heat conservation and catalyst chemical kinetic sub-model. CFD simulation is used to study the performance of automotive catalytic converter. The substrate is modeled as a porous media in FLUENT and the standard k-e model is used for turbulence. The flow pattern is changed from axial to radial by changing the substrate model inside the catalytic converter and the flow distribution and the conversion efficiency of CO, HC and NOx are achieved first, and the predictions are in good agreement with the experimental measurements. It is found that the conversion from axial to radial flow makes the catalytic converter more efficient. These studies help to understand better the performance of the catalytic converter in order to optimize the converter design.

• Journal of the Korean Ceramic Society
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• v.56 no.4
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• pp.360-364
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• 2019

PZT suspensions for photo-curable 3D printing were fabricated and their characteristics were evaluated. After mixing the PZT, photopolymer, photo-initiator, and dispersant for 10 min by using a high-shear mixer, the viscosity characteristics were investigated based on the powder content. To determine an appropriate dispersant content, the dispersant was mixed at 1, 3, and 5 wt% of the powder and a precipitation test was conducted for two hours. Consequently, it was confirmed that the dispersibility was excellent at 3 wt%. Through thermogravimetric analysis, it was confirmed that weight reduction occurred in the photopolymer between 120? and 500?, thereby providing a debinding heat treatment profile. The fabricated suspensions were cured using UV light, and the polymer was removed through debinding. Subsequently, the density and surface characteristics were analyzed by using the Archimedes method and field-emission scanning electron microscopy. Consequently, compared with the theoretical density, an excellent characteristic of 97% was shown at a powder content of 87 wt%. Through X-ray diffraction analysis, it was confirmed that the crystallizability improved as the solid content increased. At the mixing ratio of 87 wt% powder and 13 wt% photo-curable resin, the viscosity was 3,100 cps, confirming an appropriate viscosity characteristic as a stereolithography suspension for 3D printing.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.1
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• pp.103-108
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• 2016

Carbon Capture and Storage technologies are recognized as key solution to meet greenhouse gas emission standards to avoid climate change. Although MEA (monoethanolamine) is an effective amine solvent in $CO_2$ capture process, the application is limited by high energy consumption, i.e., reduction of 10% of efficiency of coal-fired power plants. Therefore the development of new solvent and improvement of $CO_2$ capture process are positively necessary. In this study, improvement of $CO_2$ capture process was investigated and applied to Test Bed for reducing energy consumption. Previously reported technologies were examined and prospective methods were determined by simulation. Among the prospective methods, four applicable methods were selected for applying to 0.1 MW Test Bed, such as change of packing material in absorption column, installing the Intercooling System to absorption column, installing Rich Amine Heater and remodeling of Amines Heat Exchanger. After the improvement construction of 0.1 MW Test Bed, the effects of each suggested method were evaluated by experimental results.

• Journal of the Korean Institute of Gas
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• v.12 no.3
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• pp.13-19
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• 2008

Among the various prime movers for combined heat and power (CHP) system, the CNG engine is the most commonly used power generation equipment of which power is less than 1MW. The 300 kW class CNG engine for CHP can meet stringent emission regulations with the adoption of stoichiometric air-fuel ratio control and three way catalyst. As the thermal efficiency of the stoichiometric ratio engine is lower than that of lean burn engine, it is necessary to operate the stoichiometric engine at its minimum spark advance for the best torque (MBT). However, knock control should be introduced for the engine under high intake air temperature conditions because MBT operating conditions are generally very close to those of knock occurrence. In this study, engine performances and knocking characteristics were experimentally investigated for the CNG engine that needs to be operated at higher intake air temperature conditions than normal conditions.