• Title/Summary/Keyword: High functional composites

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Fabrication and Mechanical Properties of Nanostructured Al2O3-MgSiO3-SiO2 Composites Synthesized by Pulsed Current Activated Combustion of Mechanically Activated Powder (기계적 활성화된 분말로부터 펄스전류활성 연소합성에 의한 나노구조 Al2O3-MgSiO3-SiO2복합재료 제조 및 기계적 특성)

  • Shon, In-Jin;Kang, Hyun-Su;Doh, Jung-Mann;Yoon, Jin-Kook
    • Korean Journal of Metals and Materials
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    • v.49 no.7
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    • pp.565-569
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    • 2011
  • Nanopowders of MgO, $Al_2O_3$ and $SiO_2$ were made by high-energy ball milling. The fast sintering of nanostructured $Al_2O_3-MgSiO_3-SiO_2$ composites was investigated from mechanically activated powders of MgO, $Al_2O_3$ and $SiO_2$ by a pulsed-current activated sintering process. Nanocrystalline materials have received much attention as advanced engineering materials with improved physical and mechanical properties; in particular greater strength, hardness, excellent ductility and toughness. Highly dense nanostructured $Al_2O_3- MgSiO_3-SiO_2$ composites were produced with simultaneous application of 80 MPa and pulsed output current of 2800A within 2 minutes. The sintering behavior, grain size and mechanical properties of $Al_2O_3-MgSiO_3-SiO_2$ composites were investigated.

Improvement of Mechanical Properties of Epoxy Composites Using NH2-HNT Manufactured by Dry Coating Device as Filler (건식코팅장치를 이용하여 제조한 NH2-HNT를 충진재로 응용한 에폭시 복합체의 기계적 물성 향상)

  • Moon il Kim
    • Journal of the Korean Society of Industry Convergence
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    • v.27 no.2_2
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    • pp.371-375
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    • 2024
  • Epoxy resins are widely used in various fields due to their high adhesion, mechanical strength, and solvent resistance. However, as the volume decreases during the hardening process and the cooling process after hardening, stress is generated and when an external force is applied, the brittle material exhibits destruction behavior. To complement this, research has been conducted using inorganic nanofillers such as halloysite nanotube(HNT). HNT has a nanotube structure with the chemical formula of Al2Si2O5(OH)4·nH2O and is a natural sediment of aluminosilicate. It has been used as additive to improve the mechanical properties of epoxy composites with exchange of amine group as a terminal functional group. In order to simplify complicated procedures of common wet method, a dry coating machine was designed and used for amine group exchange in previous research. In this study, they were applied as filler in epoxy composites, and mechanical properties such as tensile strength and flexural strength of composites were examined.

Thermotropic Liquid Crystal Polymer or Silica Nano-particle Filled Polyester Composite Fibers

  • Kim, Seong-Hun;Kim, Jun-Young;Ahn, Seon-Hoon
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.65-66
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    • 2003
  • Ternary blend fibers (TBFs) based on melt blends of PEN, PET, and TLCP were prepared by melt blending and spinning to achieve high performance fibers. The reinforcement effect and the TLCP fibrillar structure resulted in the improvement of mechanical properties for TBFs. Molecular orientation was an important factor in determining the tensile strength and modulus of TBFs. Another part of this research is silica nano-particle filled PEN composites were melt-blended to improve mechanical and physicalproperties, and processability. The tensile modulus and strength were improved adding silica nano-particles to the PEN. The decreased melt viscosity by the fumed silica resulted in the improvement of the processability. The fumed silica may act as a nucleating agent in the PEN matrix.

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A Study on the Preocessing of high Runctional Composites and the Evaluation of Its Characteristics (고기능성 복합재료의 제조와 그 특성평가에 관한 연구)

  • 김윤해
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.2
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    • pp.139-145
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    • 1998
  • Filament winding method is widely used for composite fabrications using low viscosity liquid for-mation and processing asymmetrical structures of pressure vessel pipe rocket motor case etc. The filament winding method is affected by several parameters such as pot life of process time viscosi-ty of resin filament winding temperature and schedules curing condition and post curing condi-tion of resin. To develope high functional composite materials the rotation(5, 15, 20, 30rpm) of the winding machine was controlled by D.C motor. And the wiper to give proper tension was equipped between strand and resin bath. The resin is hooked by the design wiper. The adequate cure schedule was found by DSC. NOL ring test is carried out to investigate the basic physical properties such as design technology. The void contents in filament winding is generally higher than that of the prepreg laminated plate. These high contents of void can make a crack in resin in spite of low deformation. These problem was solved by giving tension in processing. To improve the characteristics of fiber volume fraction void contents resin/fiber bonding the winding speedc is changed under constant tension. It was found that resin impregnation was not different from in fiber contents void contents at the range of 0.5~1kg tension but it was found that resin was not impregnated at the above of 1.5kg tension. In burst test a pure PE liner was failed at a nozzle part under the $14kg/\textrm{cm}^2$ pressure but a pressure vessel of CNG was failed at a cylinder part under the $200kg/\textrm{cm}^2$ pressure.

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Effect of Anodized Carbon Fiber Surfaces on Interfacial Adhesion of Carbon Fiber-reinforced Composites (양극산화된 탄소섬유가 복합재료의 계면결합력에 미치는 영향)

  • 박수진;김문한;최선웅;이재락
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.499-504
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    • 2000
  • The effect of anodic oxidation on high strength PAN-based carbon fibers has been studied in terms of surface functionality and surface energetics of the fiber surfaces, resulting in improving the mechanical properties of composites. According to FT-IR and XPS measurements, it reveals that the oxygen functional groups on fiber surfaces induced by an anodic oxidation largely influence the surface energetics of fibers or the mechanical interfacial properties of composites, such as the interlaminar shear strength (ILSS) of composites. According to the contact angle measurements based on the wicking rate of a test liquid, it is observed that anodic oxidation does lead to an increase in surface free energy of the carbon fibers, mainly due to the increase of its specific (or polar) component. From the surface energetic point of view, it is found that good wetting plays an important role in improving the degree of adhesion at interfaces between fiber and epoxy resin matrix of the resulting composites. Also, a direct linear relationship is shown between 01s/01s ratio and ILSS or between specific component and ILSS of the composites for this system.

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Technique Status of Carbon Fibers-reinforced Composites for Aircrafts (항공기용 탄소섬유강화 복합재료의 기술동향)

  • Kim, Ki-Seok;Park, Soo-Jin
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.118-124
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    • 2011
  • Recently, the need of new materials which have excellent physical properties and functional characteristics has been increased in all industries. In particular, body weight reduction via new materials in aerospace industry was significantly emphasized by the requirement of environmental protection through the fuel savings and reduction of greenhouse gas, i.e., carbon dioxide($CO_2$). Also, for various applications, the development of high performance custom materials with excellent physical properties was the current primary goal of materials science and technology. In this respect, carbon fiber-reinforced composites were the most candidates among the various materials. Indeed, carbon fiber-reinforced composites have been lately used as essential materials for the weight reduction of aircraft and the demand has increased remarkably. Therefore, in this paper, we focused on the need of carbon fiber composites in the fields of aircraft and technique status.

Influence of Carbon Black-embed Carbon Nanotubes on Electrochemical Performance of Activated Carbon-based Electrodes (활성탄소 전극의 전기화학적 특성에 대한 카본블랙 함입된 탄소나노튜브의 효과)

  • Kim, Ki-Seok;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.133.1-133.1
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    • 2010
  • In this work, carbon black(CBs)-embed multi-walled carbon nanotubes (MWNTs) as conductive fillers for activated carbon(ACs)-based electrodes for supercapacitor were prepared by chemical reduction of oxidized MWNTs and CBs. The effect of CBs-MWNT composites on electrochemical performances of ACs-based electrodes were investigated as a function of CB-MWNT ratio. It was found that CBs-MWNTs composites were formed by the reduction reaction of the functional groups of oxidized MWNTs and CBs. It was resulted in the conjugation of CBs onto the MWNT having high surface area and aspect ratio, leading to the enhanced electrical properties of MWNTs. The electrochemical performances, such as current density, charge-discharge, and specific capacitance of the ACs/CBs-MWNT electrodes were higher than that of ACs/MWNTs and conventional ACs/CB electrodes, which was attributed to the synergistic effect of CBs-MWNTs as a conductive filler.

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A review: synthesis and applications of graphene/chitosan nanocomposites

  • Yuan, Hui;Meng, Long-Yue;Park, Soo-Jin
    • Carbon letters
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    • v.17 no.1
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    • pp.11-17
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    • 2016
  • Recently, with continuous developments in the field of materials science, graphene oxide (GO) has emerged as a promising material with excellent electrical, thermal, mechanical, and optical properties, which play important roles in most fields. Researchers have achieved considerable progress with graphene. Chitosan (CS) is a natural polymer that has been studied intensively owing to its specific formation, high chemical resistance, and excellent physical properties. These outstanding properties have led to its universal use in applications such as textile fabrics, tissue engineering, medicine and health, coatings, and paints. By combining the advantages of GO and CS, different types of promising materials can be obtained. This review discusses the preparation of GO-CS fibers, hydrogel and aerogel, and the applications of GO-CS nanocomposites. In addition, directions for future research on graphene material composites are discussed.

Preparation and Characterization of Polyimide/Carbon-Nanotube Composites

  • Kim, Bong-Sup;Bae, Sang-Hoon;Park, Young-Hwan;Kim, Ji-Heung
    • Macromolecular Research
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    • v.15 no.4
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    • pp.357-362
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    • 2007
  • Polyimide/carbon nanotube (CNT) composite films, for potential use in high performance microelectronics and aerospace applications, were prepared by mixing a polyisoimide (PII) solution and a CNT suspension in NMP, followed by casting, evaporation and thermal imidization. The CNTs were modified by a nitric acid treatment to improve the thermal and electrical properties, as well as to provide good dispersion of the CNTs in a polymer matrix. The formation of functional groups on the modified CNT was confirmed by Raman spectroscopy. Scanning electron microscopy revealed the modified CNTs to be well dispersed in the polyimide matrix, with a uniform diameter of ca. 50 nm. The thermal stability of the films containing the CNTs was improved due to the enhanced interfacial interaction and good dispersion between the polyimide matrix and modified CNTs. In addition, the thermal expansion coefficient of the composites films was slightly decreased, but the dielectric constants increased linearly with increasing CNT content.

The Coating Performance of UV Curable Urethane Acrylate Coatings for Fancy Veneer Overlayed Plywood Flooring

  • Lee, Byoung-Hoo;Kim, Hyun-Joong;Lee, Young-Kyu
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.6
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    • pp.23-35
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    • 2004
  • The goal of study was to investigate the influence of the acrylated urethane oligomer on mechanical properties, the chemical resistance and thermal resistance of the UV curable urethane acrylate coatings for fancy veneer overlayed plywood flooring. The pencil hardness and abrasion resistance of the coated fancy veneer overlayed plywood floorings increased with increasing the acrylate functionality of the acrylated urethane oligomer. In the case of the UV cured film containing hexa-functional acrylated aliphatic urethane oligomer, high discoloration of the coated fancy veneer overlayed plywood flooring was observed near the cracks at the beginning of the chemical treatment. In this study, it was found that the degradation of the UV cured film caused by an alkaline reagent was higher than that of the UV cured film caused by an acidic treatment.