• Title/Summary/Keyword: HgS

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Growth mechanism of anodic oxide for MCT passivation (MCT 표면보호를 위한 양극산화막 성장)

  • 정진원;왕진석
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.352-356
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    • 1995
  • Native oxide layer on MCT (HgCdTe) has been grown uniformly in H$\_$2/O$\_$2/ electrolyte through anodic oxidation method. It has been determined that anodic oxidation of HgCdTe in H$\_$2/O$\_$2/ electrolyte proceeds immediately with the input of constant currents without any induction time required for anodic oxideation in KOH electrolyte. Oxide layer with the resistivity of 2*10$\^$10/.ohm.cm and the refractive index of 2.1 suggested the possibility of well matching combination layer with ZnS for MCT MIS device. XPS results indicated that the major components of oxide layer grown in H202 solution is TeO$\_$2/ with the possibility of small amounts of CdTeO$\_$3/.

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Failure of Intravenous Sedation due to Significant Hypertension -A Case Report- (혈압 상승으로 인한 의식하 진정 요법의 실패 -증례보고-)

  • Koh, Se-Wook
    • Journal of The Korean Dental Society of Anesthesiology
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    • v.7 no.2
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    • pp.126-130
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    • 2007
  • Sedation is often indicated for the relief of anxiety for outpatient oral surgery. In combination with local anesthesia, it is safe and effective method of treatment. However, it is not always effective in allowing the physician to complete the planned oral surgery procedure. On occasion, a procedure is left unfinished due to patient combativeness and discomfort and hypertension in spite of increase in sedative doses. Episodic increases in blood pressure were most commonly caused by light anesthesia or sedation and by the patient's experience of pain during treatment. Female patient was 42 years old. blood pressure is 150/90 mmHg. Extraction and implant surgery was done under IV sedation. During seadtion, her blood pressure was increased (200/100 mmHg). Surgery was stopped. She was done monitoring blood pressure. The blood pressure was decreased to 130/90 mmHg. Sedation was failed due to significant hypertension. Blood pressure is seldom increased during sedation but we should evaluate the patient's medical history and know guideline for hypertension crisis.

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Anion-Dependent Exocyclic Mercury(II) Coordination Polymers of Bis-dithiamacrocycle

  • Siewe, Arlette Deukam;Kim, Seulgi;Choi, Kyu Seong;Lee, Shim Sung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3459-3464
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    • 2014
  • Synthesis and structural characterization of mercury(II) halides and perchlorate complexes (1-4) of bis-$OS_2$-macrocycle (L) are reported. L reacts with mercury(II) chloride and bromide to yield an isostructural 2D coordination polymers with type $[Hg(L)X_2]_n$ (1: X = Cl and 2: X = Br). In 1, each Hg atom which lies outside the cavity is six-coordinate with a distorted octahedral geometry, being bound to four adjacent ligands via monodentate Hg-S bonds and two remaining sites are occupied by two terminal chlorido ligands to form a fishnet-like 2D structure. When reacting with mercury(II) iodide, L afforded a 1D coordination polymer $\{[Hg_2(L)I_4]{\cdot}CHCl_3\}_n$ (3) in which each exocyclic Hg atom is four-coordinate, being bound to two sulfur donors from different ligands doubly bridging the ligand molecules in a head-to-tail mode. The coordination sphere in 3 is completed by two iodo terminal ligands, adopting a distorted tetrahedral geometry. On reacting with mercury(II) perchlorate, L forms solvent-coordinated 1D coordination polymer $\{[Hg_2(L)(DMF)_6](ClO_4)_4{\cdot}2DMF\}_n$ (4) instead of the anion-coordination. In 4, the Hg atom is five-coordinate, being bound to two sulfur donors from two different ligands doubly bridging the ligand molecules in a side-by-side mode to form a ribbon-like 1D structure. The three remaining coordination sites in 4 are completed by three DMF molecules in a monodentate manner. Consequently, the different structures and connectivity patterns for the observed exocyclic coordination polymers depending on the anions used are influenced not only by the coordination ability of the anions but also by anion sizes.

Methylmercury Toxicity Is Induced by Elevation of Intracellular $Ca^{2+}$ through Activation of Phosphatidylcholine-Specific Phospholipase C

  • Chin, Mi-Reyoung;Kang, Mi-Sun;Jeong, Ju-Yeon;Jung, Sung-Yun;Seo, Ji-Heui;Kim, Dae-Kyong
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.13-13
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    • 2003
  • Methylmercury (MeHg) is a ubiquitous environmental toxicant that can be exposed to humans by ingestion of contaminated food including fish and bread. MeHg has been suggested to exert its toxicity through its high reactivity to thiols, generation of arachidonic acid and reactive oxygen species (ROS), and elevation of intracellular $Ca^{2+}$ levels ([$Ca^{2+}$$_{i}$). However, the precise mechanism has not been fully defined. Here we show that phosphatidylcholine-specific phospholipase C (PC-PLC) is a critical pathway for MeHg-induced toxicity. MeHg activated the acidic form of sphingomyelinase (A-SMase) and group IV cytosolic phospholipase $A_2$ ($cPLA_2$) downstream of PC-PLC, but these enzymes as well as protein kinase C were not linked to MeHg's toxicity. Furthermore, MeHg produced ROS, which did not cause the toxicity. However, D6O9, an inhibitor of PC-PLC, significantly reversed the toxicity in a time- and dose-dependent manner in MDCK and SH-5YSY cells. Addition of EGTA to culture media resulted in partial decrease of [$Ca^{2+}$$_{i}$ and partially blocked cell death. In contrast, D609 completely prevented cell death with parallel decreases in diacylglycerol and [$Ca^{2+}$$_{i}$. Together, our findings indicated that MeHg-induced toxicity was caused by elevation of [$Ca^{2+}$]$_{i}$ through activation of PC-PLC. The toxicity was not attributable to the signaling pathways such as $cPLA_2$, A-SMase, and PKC, or to the generation of ROS.

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Investigation of Clinical Research of Acupuncture Treatment on Hyperemesis Gravidarum in Medline (Medline 검색을 통한 임신오저에 대한 국외 침치료의 연구 동향 분석)

  • Kim, Eun-Gyung;Hwang, Deok-Sang;Lee, Jin-Moo;Lee, Chang-Hoon;Jang, Jun-Bok;Lee, Kyung-Sub
    • The Journal of Korean Obstetrics and Gynecology
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    • v.25 no.4
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    • pp.66-80
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    • 2012
  • Purpose: The purpose of this study is to examine acupuncture treatment suggested on the papers of hyperemesis gravidarum(HG) in medicine journals and to establish the future direction. Methods: The papers which were associated with acupuncture and HG published between 2000 and 2012 in Medline were searched. Results: 14 studies met the condition. They were 13 randomized controlled trial (RCT)s and 1 clinical study. 13 studies revealed that acupuncture has efficacies in HG. 1 study was shown to have no statistically significant efficacy. 2 studies revealed that acupuncture was safe treatment, and 1 study revealed that acupuncture was reliable treatment. Conclusions: From the paper research, acupuncture treatment seems to be effective on HG. However, due to the lack sufficient research of HG, it would be necessary to fulfill further study about the period of acupuncture treatment on HG and the selection of acupoint through well-designed study and establish standard of evidence of them.

Adsorptive Removal of Cu(II), Pb(II), and Hg(II) Ions from Common Surface Water Using Cellulose Fiber-Based Filter Media

  • Phani Brahma Somayajulu Rallapalli;Jeong Hyub Ha
    • Applied Chemistry for Engineering
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    • v.35 no.4
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    • pp.352-359
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    • 2024
  • Environmental pollution from heavy metal ions (HMIs) is a global concern. Recently, biosorption methods using cellulose sorbents have gained popularity. The objective of this study was to assess the removal efficiency of Cu(II), Pb(II), and Hg(II) ions at low concentration levels (100-700 ppb) from aqueous solutions using three different cellulose fiber-based filter media. Sample A was pure cellulose fiber, Sample B was 10% activated carbon-cellulose fiber, and Sample C was cellulose fiber-glass fiber-30% activated carbon-20% amorphous titanium silicate (ATS). The samples were characterized by several physicochemical techniques. The porosity measurements using N2 sorption isotherms revealed that Samples A and B are nonporous or macroporous materials, whereas the addition of 50% filler materials into the cellulose resulted in a microporous material. The Brunauer-Emmett-Teller (BET) surface area and pore volume of Sample C were found to be 320.34 m2/g and 0.162 cm3/g, respectively. The single ion batch adsorption experiments reveal that at 700 ppb initial metal ion concentration, Sample A had removal efficiencies of 7.5, 11.5, and 13.7% for Cu(II), Pb(II), and Hg(II) ions, respectively. Sample B effectively eliminated 99.6% of Cu(II) ions compared to Pb(II) (14.2%) and Hg(II) (31.9%) ions. Cu(II) (99.37%) and Pb(II) (96.3%) ions are more efficiently removed by Sample C than Hg(II) (68.2%) ions. The X-ray photoelectron spectroscopy (XPS) wild survey spectrum revealed the presence of Cu(II), Pb(II), and Hg(II) ions in HMI-adsorbed filter media. The high-resolution C1s spectra of Samples A and B reveal the presence of -C-OH and -COOH groups on their surface, which are essential for HMIs adsorption via complexation reactions. Additionally, the ATS in Sample C facilitates the adsorption of Pb(II) and Hg(II) ions through ion exchange.

The Comparision of Growth, Blood Pressure and s-Cholesterol in High School Students from Rural and Urban Area of Korea (도시-농촌지역 고등학생의 성장, 혈압 및 혈중콜레스테롤에 대한 연구)

  • Kim Lak-Hyung;Jang In-Soo;Yun Jeong-Hun;Kang Shin-Hwa;Kang Hyon-Chul
    • Journal of Society of Preventive Korean Medicine
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    • v.5 no.2
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    • pp.29-39
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    • 2001
  • Purpose: This study was conducted to investigate and compare the growth, blood pressure, and s-cholesterol of urban and rural students in Korea. Methods: April 1999, We examined the students' health of a boys high school and a girls high school in a urban area - Jeonju, Korea.(boys were 317, girls were 343). And we also examined the students' health of a high school in a rural area - Gimje, Korea.(boys were 33, girls wee 36). Height, body-weight, Body Mass Index(BMI)I, blood pressure, and s-cholesterole were checked and compared between two groups. Results and Conclusion: The mean of height in urban students was $165.25{\pm}7.79cm$, and that in rural students was $163.77{\pm}8.72cm$. There was no significant difference stastically between two groups. The mean of body-weight in urban students $(57.78{\pm}10.51kg)$ was significantly higher than that in rural students $(54.71{\pm}10.11kg)$)(p<0.05). The mean of body mass index(BMI) in urban students $(21.12{\pm}3.27kg/m2)$ was significantly higher than that in rural students $(20.30{\pm}2.69kg/m2)$(p<0.05). Obese students $(BMI{\geq}27)$ were 31(4.70%) in urban students, 3(4.35%) in rural students. The mean of systolic blood pressure in rural students $(114.99{\pm}9.50mmHg)$ was significantly higher than that in urban students $(111.89{\pm}12.42mmHg)$(p<0.05) The mean of diastolic blood pressure in rural students$(75.72{\pm}9.90mmHg)$ was very significantly higher than that of urban students $(68.45{\pm}9.40mmHg)$(p<0.001). Hypertensives (${\geq}138/86mmHg\;in\;boys,\;{\geq}130/83mmHg$ in girls) were 28(4.24%) in urban students, 13(18.84%) in rural students. The mean of s-cholesterol in urban students was $174.95{\pm}32.28mg/dL$, and that in rural students was $176.81{\pm}33.18mg/dL$. There was no significant difference stastically between two groups. Hypercholesterolemias (${\geq}198mg/dL$ in boys, ${\geq}212mg/dL$ in girls) were 130(19.70%) in urban students, 14(20.89%) in rural students. These results suggest that there are differences in body weight, BMI, and diastolic blood pressure between urban and rural students and that it is necessary to consider these differences in health examination.

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Nicardipine Hydrochloride Injectable Phase IV Clinical Trial-Study on the antihypertensive effect and safely of nicardipine for acute aortic dissection (급성대동맥해리에 대한 혈압강하요법으로서의 Nicardipine.HCI 주사액(Perdipine$^{circledR}$)의 유효성 및 안전성을 검토하기 위한 다기관 공동, 공개 제4상 임상시험)

  • Kim, Kyung-Hwan;Moon, In-Sung;Park, Jang-Sang;Koh, Yong-Bok;Ahn, Hyuk
    • Journal of Chest Surgery
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    • v.35 no.4
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    • pp.267-273
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    • 2002
  • Background: We performed a phase IV clinical trial to examine the usefulness of a continuous infusion of nicardipine hydrochloride to control hypertension in patients with acute aortic dissection. material and Method: Systolic/diastolic blood pressure, and heart rate were monitored before and after the intravenous administration of nicardipine in 31 patients with aortic diseases. The period of nicardipine administration in each patient was from 3 to 14 days. Efficacy was evaluated by determining the average amount of blood pressure reduction on the 3rd day of drug administration. The dosage of another antihypertensive agent was slowly tapered down, and ultimately replaced by the test drug. Result: 28 patients were diagnosed as acute aortic dissection, 2 patients as rupture of the aortic arch aneurysm, and 1 patient as traumatic aortic rupture. Mean age was 53.9 $\pm$ 14.9(29~89) years, and 21 patients(67.7%) were male. 14 patients(32.3%) had complications associated with underlying aortic disease: aortic insufficiency in 7, hemopericardium in 6, acute renal failure in 1, paraplegia in 1, lower extremity ischemia in 1, and hemothorax in 1. The time needed to reach the target blood pressure was within 15 minutes in 16, from 15 to 30 minutes in 10, from 30 to 45 minutes in 3 and from 45 to 60 minutes in 2, and their baseline average systolic, diastolic, and mean arterial blood pressures(mmHg) were 147$\pm$23, 82.3$\pm$ 18.6, and 104 $\pm$ 18, respectively. Average systolic, diastolic, and mean arterial blood pressures(mmHg) on the third day of nicardipine infusion were 119$\pm$ 12, 69$\pm$9, and 86$\pm$8, and they all showed statistically significant decrease(p<0.05). The average systolic, diastolic, and mean arterial blood pressure(mmHg) after the discontinuation of the nicardipine infusion were 119 $\pm$ 15, 71 $\pm$ 14, and 86$\pm$ 13, respectively. No significant difference was observed between the average pressures measured on the third day and those measured after the discontinuation of the nicardipine infusion, and no definite side effects were observed during the study period. Conclusion: Nicardipine hydrochloride was both effective and safe at controlling blood pressure in patients with acute aortic dissection.

Changes of Total Gaseous Mercury Concentration Levels and the Associated Environmental Conditions in Seoul, Korea (12년 차이를 두고 본 서울 한남동 지역 대기 중 수은의 분포특성과 환경요인의 비교)

  • Kim, Min-Young;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.22 no.3
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    • pp.237-247
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    • 2001
  • The concentrations of gaseous mercury (Hg) determined between two different time periods of the late 1980s and the late 1990s were compared to account for the effects of changes between source/sink relationships of atmospheric Hg in an urban area. The Hg concentration levels were different remarkably between the two time periods due possibly to changes in source/sink relationships. The results showed that the Hg levels in the former period were measured to be 14.4${\pm}$9.56ngm$^{-3}$ (N = 2714), whereas those of the latter period were characterized by approximately three-fold decreased values of 5.34${\pm}$3.92 ngm$^{-3}$ (N=2576). Using two independent measurement data sets, we examined the patterns of Hg distribution at different time scales. When analyzed over 24 hour scale, these data sets exhibited two distinctive distribution patterns. The former period showed enhanced concentration levels during daytime, while the latter period showed relative depletion during daytime. The patterns of the two data sets were also examined over seasonal scale. The results of two different time periods consistently showed the occurrences of maximum seasonal values during winter. The former period was characterized by seasonal patterns of fuel consumption with excessive Hg levels during winter. Conversely, no distinctive trend was apparent for the latter period with slight changes in concentration levels across seasons. In order to analyze the factors affecting Hg distributions between two different periods, we conducted both correlation and factor analysis on both all data sets and on seasonally divided data groups. The results of these analyses consistently indicate that the Hg concentration levels for two different time periods are regulated by distinctive source processes that are characteristic of each period.

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Studies on The Reduced Pressure Storage of Fruits( I ) -Comparision of The Reduced Pressure Storage to The Other Storages for The American Summer Pairman- (과실의 감압저장법에 관한 연구( I ) -감압저장과 타 저장과의 비교(축)-)

  • Kim, K.S.;Park, Y.T.;Hong, S.Y.;Sohn, T.H.
    • Applied Biological Chemistry
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    • v.11
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    • pp.67-76
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    • 1969
  • The reduced pressure storage of apple, American Summer Pairman, was investigated comparing with the other storage methods and the following results were obtained. 1. The reduced pressure storage was better to extend the storage life and freshness of apples than the controlled atomoshere storage. 2. Decreasing the pressure of chamber atmosphere to about 20 cmHg showed the best result among several pressure conditions. 3. As for the surface treatment of the apples, poly-ethylene film wrapping showed to be the most favorable method in a short-term experiment. In a long-term experiment, however, poly-ethylene film wrapping seemed to cause apples rot. Poly-vinyl acetate coating seemed to keep the apples from color changing, but it caused an unpleasant odor and a peculiar taste. No significant effect was observed in Gibberellin. 4. Total sugar and reduced sugar of apples were decreased after a certain period of increasing. Acid and Vitamin C, however, gradually decreased from the beginning of storage.

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