• 한국윤활학회:학술대회논문집
• /
• 한국윤활학회 1997년도 제26회 추계학술대회
• /
• pp.211-216
• /
• 1997

The tungsten disulfide (WS$_2$) solid lubricant was synthesized by two different reaction processes, and the chemical and physical characteristics of synthesized WS$_2$ powder were analyzed in terms of the average particle size, morphology, crystalline phase. The solid WO$_3$ powder with the average size of 0.2 $\mu$m was reacted with CS$_2$ gas flowed with N$_2$ or 96% N$_2$ + 4% H$_2$ forming gas for 36 h and 24 h at 900$\circ$C respectively. In the case of vapour phase transport method, the 3.5 wt% iodine was added as a vapour transport reagent into the composition of tungsten and sulfur powders maintaining a constant molar ratio of W : S = 1 : 2.2. The mixture was then heat treated at 850$\circ$C for 2 weeks in vacuum The reaction product obtained showed the average size of 12 $\mu$m and the hexagonal plate shape of typical solid lubricant with 2H-WS$_2$ crystalline phase.

• 한국세라믹학회지
• /
• 제25권2호
• /
• pp.95-100
• /
• 1988

Single crystals of sapphire were grown from solution by slow cooling method using B2O3 and PbO as flux agents. The morphology of grown crystals was tube, rhombohedral, or hexagonal-plate. It was found that the morphology and the size of grown crystal were highly dependent on the amount of fluxes in the solution, the ratio of B2O3 vs. PbO, and cooling rate.

• Computers and Concrete
• /
• 제27권4호
• /
• pp.369-383
• /
• 2021

This article deals with the frequency analysis of viscoelastic sandwich disk with graphene nano-platelets (GPLs) reinforced viscoelastic concrete (GPLRVC) face sheets and honeycomb core. The honeycomb core is made of aluminum due to its low weight and high stiffness. The rule of the mixture and modified Halpin-Tsai model are engaged to provide the effective material constant of the concrete. By employing Hamilton's principle, the governing equations of the structure are derived and solved with the aid of the Generalize Differential Quadrature Method (GDQM). In this paper, viscoelastic properties are modeled according to Kelvin-Voigt viscoelasticity. The deflection as the function of time can be solved by the fourth-order Runge-Kutta numerical method. Afterward, a parametric study is carried out to investigate the effects of the outer to inner radius ratio, hexagonal core angle, thickness to length ratio of the concrete, the weight fraction of GPLs into concrete, and the thickness of honeycomb core to inner radius ratio on the frequency of the viscoelastic sandwich disk with honeycomb core and FG-GPLRVC face sheet.

• Steel and Composite Structures
• /
• 제25권6호
• /
• pp.671-684
• /
• 2017

Elastic-plastic shear buckling behaviors of the web-post in a Castellated Steel Beam (CSB) with hexagonal web openings under vertical shear force were investigated further using Finite Element Model (FEM) based on a sub-model, which took the upper part of the web-post under horizontal shear force to represent the whole web-post under vertical shear force. A simplified design method for the web-post elastic-plastic shear buckling strength was proposed based on simulation results of the sub-model. Proper boundary conditions were applied to the sub-model to assure that its behaviors were identical to those of the whole web-post. The equation to calculate the thin plate elastic shear buckling strength was adopted as the basic form to build the design equation for elastic-plastic buckling strength of the sub-model. Parameters that might affect the elastic-plastic shear buckling strength of the whole web-post were studied. After obtaining the vertical shear buckling strength of a sub-model through FEM, the shear buckling coefficient k can be obtained through the back analysis. A practical calculation method for k was proposed through curving fitting the parameter study results. The elastic-plastic shear buckling strength of the web-post calculated using the proposed shear buckling coefficient k agreed well with that obtained from the FEM and test results. And it was more precise than those obtained from EC3 based on the strut model.

• 한국세라믹학회지
• /
• 제39권4호
• /
• pp.327-335
• /
• 2002

Experiments were conducted to investigate the synthesis characteristics of Precipitated Calcium Carbonate(for short PCC) in Ca(OH)$_2-CO_2-H_2O$ system by the continuous drop method of Ca(OH)$_2$ slurry into the solution containing $CO_2$(aq). When the flow rate of $CO_2$(g) increases and the concentration of Ca(OH)$_2$ slurry become low, the absorption rate of $CO_2$(g) become faster than the dissolution rate of Ca(OH)$_2$. Consequently, the growth of the calcite crystal plane is facilitated resulting in synthesis of $1.0{\mu}m$ of rhombohedral calcite. On the other hand, when the flow rate of $CO_2$(g) decreases and the concentration of Ca(OH)$_2-CO_2-H_2O$ slurry become high, new nuclei is created along with the crystal growth resulting in synthesis of $0.1{\mu}m$ of prismatic calcite. Maintaining 1.0wt% of Ca(OH)$_2-CO_2-H_2O$ slurry, 120 drops/min of drop rate and $25^{circ}C$ of temperature, the shape of PCC shows colloidal and spherical agglomerate at 100 mL/min of the flow rate of $CO_2$(g); the mixture of rhombohedral and plate-shaped calcite, at 200∼500 mL/min. Therefore, as the flow rate of $CO_2$(g) increases, the shape of PCC changes from colloidal and rhombohedral calcite to plate-shaped calcite. Maintaining 500 mL/min of the flow rate of $CO_2$(g), 120 drops/min of the drop rate of Ca(OH)$_2$ slurry, and $25^{circ}C$ of temperature, the shape of PCC shows the plate-shaped calcite at 1.0∼3.0 wt% of Ca(OH)$_2$ slurry; the hexagonal plate-shape calcite of the thickness of $0.1{\mu}m$ and the width of $1.0{\mu}m$, at 4.0 wt%.

• Tribology and Lubricants
• /
• 제13권4호
• /
• pp.60-65
• /
• 1997

The tungsten disulfide $(WS_2)$ solid lubricant was synthesized by two different reaction processes, i.e., the reaction between $CS_2$ gas phase and solid $WO_3$powder, and the vapour phase transport method of tungsten and sulfur in a high vacuum. The chemical and physical characteristics of synthesized $WS_2$powder were analyzed in terms of the average particle size, morphology, crystalline phase etc. in comparison with those of commercial $WS_2$powder. The solid $WO_3$ powder with the average size of 0.2 ${\mu}{\textrm}{m}$ was reacted with $CS_2$gas flowed with$N_2$or 96%$N_2{\times}4%H_2$forming gas for 36 h and 24 h at 90$0^{\circ}C$ respectively. $WS_2$ crystalline phase was then formed through the intermediate phase of .$W_{20}O_{58}$ In the case of vapour phase transport method, the 3.5 wt% iodine was added as a vapour transport reagent into the composition of tungsten and sulfur powders maintaining a constant molar ratio of W:S=1:2.2. The mixture was then heat treated at 85$0^{\circ}C$ for 2 weeks in vacuum. The reaction product obtained showed the average size of 12 ${\mu}{\textrm}{m}$ and the hexagonal plate shape of typical solid lubricant with 2H-$WS_2$crystalline phase.

• 한국결정성장학회지
• /
• 제7권2호
• /
• pp.191-196
• /
• 1997

다양한 미세결함분석기술(OM, TEM, AFM)을 이용하여 승화법에 의해서 성장된 6H-Sic 단결정 wafer의 내부미소결함을 분석하였다. Wafer내부에는 6각판상헝의 석출물 및 micropipes들이 독립적으로 혹은 혼합적으로 존재하고 있음이 확인되었고, TEM 분석에 의한 비정질상의 검출로 이들은 불안정한 결정성장 인자나 비화학양론적 $Si_{1-x}_xC_x$ 화합물 형성에 기인한다는 사실을 확인하였다.

• 한국세라믹학회지
• /
• 제32권12호
• /
• pp.1383-1391
• /
• 1995

Hexagonal $\delta$-FeOOH was coated with Ba-Sol, which was produced by hydrolizing Ba(OC2H5)2, Ba-Sol coated $\delta$-FeOOH spread on a stainless plate, dried at 8$0^{\circ}C$ and then heat-treated. In this way, Ba-ferrite fine particles were produced. although there was a difference in a degree of hydrolysis of Ba(OC2H5)2, crystalline phase of Ba-ferrite appeared around 617$^{\circ}C$, and Ba-ferrite single phase was obtained after heat treatment at 80$0^{\circ}C$ for 2 hr. When Ba-ferrite was made from Ba-Sol coated $\delta$-FeOOH, $\delta$-FeOOH was thermally decomposed to $\alpha$-Fe2O3 at $700^{\circ}C$, producing a porous structure which was observed by TEM photographs. But the porous structure was not observed at 80$0^{\circ}C$. Ba-ferrite, heat-treated at 80$0^{\circ}C$ for 2 hr, had mean particle size of 1000$\AA$, lattice parameter of a0=5.889243 $\AA$ and c0=23.214502 $\AA$, a saturation magnetization ($\sigma$8) of 45.3 emu/g and a coercive force (Hc) of 5200Oe.

• 한국재료학회지
• /
• 제18권1호
• /
• pp.51-56
• /
• 2008

The crystal structures and morphologies of precipitates in $L1_0$-ordered TiAl intermetallics containing nitrogen were investigated by transmission electron microscopy (TEM). Under aging at an approximate temperature of 1073 K after quenching from 1423 K, TiAl hardens appreciably due to the nitride precipitation. TEM observations revealed that needle-like precipitates, which lie only in one direction parallel to the [001] axis of the $L1_0$-TiAl matrix, appear in the matrix preferentially at the dislocations. Selected area electron diffraction (SAED) pattern analyses showed that the needle-shaped precipitate is perovskite-type $Ti_3AlN$ (P-phase). The orientation relationship between the P-phase and the $L1_0$-TiAl matrix was found to be $(001)_P//(001)_{TiAl}\;and\;[010]_P//[010]_{TiAl}$. By aging at higher temperatures or for longer periods at 1073 K, plate-like precipitates of $Ti_2AlN$ (H-phase) with a hexagonal structure formed on the {111} planes of the $L1_0$-TiAl matrix. The orientation relationship between the $Ti_2AlN$ and the $L1_0$-TiAl matrix is $(0001)_H//(111)_{TiAl}\;and\;_H//_{TiAl}$.

• 한국항공우주학회지
• /
• 제32권8호
• /
• pp.82-90
• /
• 2004

등방성의 2차원 단위 셀 형상을 지닌 세 종류의 심재-삼각형 심재, 육각형 심재와 starcell 심재-에 대하여 샌드위치 구조물 내에서의 응용과 관련된 기계적 특성을 연구하였다. 세 종류의 심재에 대하여 축 방향 Young 계수, 전단 계수를 계산하여 비교하고, 심재의 셀 벽을 압축 하중과 전단 하중을 받고 있는 판재로 가정하여 축 방향 압축 좌굴 강도와 전단 좌굴 강도를 산출하였다. 심재의 유연성을 나타내는 평면탄성계수를 비교하고 쌍축 굴곡 실험 (biaxial flexural test)을 실시하여 유연성을 측정하였다. 세 가지 심재 모두 축 방향으로 같은 강성을 가지고 있었으나, 삼각형 심재는 다른 두 종류의 심재에 비하여 낮은 강도를 나타내었고, starcell 심재는 다른 심재들에 비해 월등히 높은 유연성 을 나타내었다. 이러한 유연성은 starcell 심재가 곡면에 적용되는 샌드위치 구조물의 심재로서 응용될 수 있음을 보여주었다.