• 제목/요약/키워드: Hexagonal

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ZnO Nanoparticles with Hexagonal Cone, Hexagonal Plate, and Rod Shapes: Synthesis and Characterization

  • Kim, Sun-Young;Lee, In-Su;Yeon, Yun-Seon;Park, Seung-Min;Song, Jae-Kyu
    • Bulletin of the Korean Chemical Society
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    • 제29권10호
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    • pp.1960-1964
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    • 2008
  • The roles of coordinating ligands (TOPO, OA, HDA, and TDPA) for the synthesis of ZnO nanoparticles are investigated. Various shapes (hexagonal cone, hexagonal plate, and rod) and sizes (5-100 nm) of ZnO nanoparticles are prepared in relation to the coordinating ligands. The hexagonal shapes ($\leq$ 100 nm) are synthesized with TOPO and OA, while smaller size nanorods (5 ${\times}$ 30 nm) are with TOPO and TDPA. The relative intensities of two distinctive emission bands centered at 385 and 500 nm, which are related to the exciton and defect states, respectively, depend on the crystal qualities of ZnO nanoparticles affected by the coordinating ligands. The intense UV emissions with the reduced visible emissions are found in the monodisperse nanoparticles such as hexagonal cones and nanorods, suggesting that the monodispersity as well as the crystallinity is closely related to the coordinating ligands. The blue-shift of photoluminescence and absorption edge is observed in the nanorods, because the sizes of the nanorods are in the quantum confinement regime.

초순수 용매 내 육방정 질화붕소 나노시트의 농도와 크기의 관계 (Relation between the Concentration of Hexagonal Boron Nitride Nano-Sheets Dispersed in Pure Water and Their Width and Height)

  • 조대현;박미영;하성훈
    • Tribology and Lubricants
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    • 제35권6호
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    • pp.343-349
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    • 2019
  • According to a report in 2011, hexagonal boron nitride demonstrated good solubility in pure water, even without surfactants or organic functionalization. Hexagonal boron nitride nanosheets are an effective lubricant additive, and their solubility in pure water has motivated lubrication engineers to utilize aqueous solutions containing these nanosheets as water-based lubricants. In this study, we measure the width and height of the hexagonal boron nitride nanosheets dispersed in pure water by using the Zetasizer and atomic force microscopy. Without surfactants or functionalization, aqueous solutions containing 0.10, 0.07, 0.05, and 0.01 wt% of hexagonal boron nitride nanosheets are synthesized via sonication-assisted hydrolysis. The Zetasizer provides only a one-dimensional size of approximately 410 nm, regardless of the concentration of the solution. Thus, it does not allow the estimation of the shape of the nanosheet. To acquire the three-dimensional size of the nanosheets, atomic force microscopy is employed. The aqueous solutions containing 0.10, 0.07, 0.05, and 0.01 wt% of the hexagonal boron nitride nanosheets show average values of 740, 450, 700, and 610 nm in width, and 37, 26, 33, and 32 nm in thickness, respectively. No significant trend is observed between the concentration of the solution and size of the nanosheets. Therefore, when preparing a water-based lubricant, it may be appropriate to adjust conditions such as ultrasonication time rather than the concentration.

반복하중을 받는 육각형 블록 벽체 전단내력평가 (An Estimation of Shear Capacity of Hexagonal Masonry Walls Under Cyclic Loading)

  • 장극관;서대원;한태경
    • 한국구조물진단유지관리공학회 논문집
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    • 제14권6호
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    • pp.205-214
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    • 2010
  • 일반적으로 조적조는 석재, 벽돌, 시멘트블록 등의 조적 개체와 모르타르(motar) 등 이종재료로 구성된 적층구조로서, 우리나라뿐만 아니라 전 세계적으로 가장 오래되고 광범위하게 사용되어진 구조재료이다. 그러나 수직하중에 대한 큰 저항능력에 비해 횡력에 매우 취약한 단점을 갖고 있으며, 최근에 발생한 지진피해사례에서도 저층의 조적조 건축물의 피해가 많이 보고되고 있다. 따라서 본 연구에서는 수평전단력 향상을 위하여 기존 사각형 블록 벽체에서 발생되는 횡방향 통줄눈을 방지하여 횡력에 대한 저항력을 높여줄 수 있는 육각형 형태의 블록을 개발하고, 개발된 블록을 사용한 조적 벽체의 구조실험을 수행하여 거동특성과 전단강도의 증가효과 등을 분석하며, 신축 및 건물 리모델링시에 내진보강용으로 사용할 수 있는 조적조를 제안하고자 하였다. 개발된 중공형 및 솔리드형 블록을 사용하여, 블록의 형상 및 수직 철근 보강량 및 배열위치를 변수로 육각형 블록 벽체의 구조실험을 수행 하였으며, 기존 사각형의 조적조 벽체에 비교하여 상대적으로 연성적인 거동과 전단저항 능력의 향상을 확인할 수 있었다.

육각형 렌즈 어레이로부터 요소영상을 생성하기 위한 병렬 처리 기법 (Parallel Processing Method for Generating Elemental Images from Hexagonal Lens Array)

  • 김도형;박찬;정지성;권기철;김남;류관희
    • 한국콘텐츠학회논문지
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    • 제12권6호
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    • pp.1-8
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    • 2012
  • 대부분 집적영상 기법에서는 사각형 렌즈 어레이가 사용되고 있으며, 이로 인해 집적된 빛의 분포는 사각격자 형태로 기록된다. 그러나 육각형 렌즈 어레이를 사용하면, 사각형 렌즈 어레이보다 더 높은 밀도의 빛의 분포와 이상적인 원형 렌즈에 가깝게 이미지를 기록 또는 재생 할 수 있다[4]. 육각형 렌즈 어레이 요소영상을 병렬 처리 기법을 사용하여 생성하기 위해서는 요소영상을 구성하는 각 화소에 대하여 그 화소가 속할 육각형 렌즈를 결정해야하고, 이 과정은 화면에 출력되는 모든 화소에 대하여 진행 되며 많은 계산량이 요구된다. 본 논문에서는 3D 볼륨 데이터를 사용하여 육각형 렌즈 어레이에 대한 요소영상을 생성하기 위해 OpenCL를 사용한 병렬 처리 기법을 제안한다. 제안 된 방법을 위한 실험에는 Male [$128{\times}256{\times}256$화소] 볼륨데이터를 사용하였으며, 실험 결과 $20{\times}20$개의 육각형 렌즈 어레이에 대해 요소영상을 초당 20~60장 생성할 수 있었다.

THE ASSESSMENT OF ABUTMENT SCREW STABILITY BETWEEN THE EXTERNAL AND INTERNAL HEXAGONAL JOINT UNDER CYCLIC LOADING

  • Lee, Tae-Sik;Han, Jung-Suk;Yang, Jae-Ho;Lee, Jae-Bong;Kim, Sung-Hun
    • 대한치과보철학회지
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    • 제46권6호
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    • pp.561-568
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    • 2008
  • STATEMENT OF PROBLEM: Currently, many implant systems are developed and divided into two types according to their joint connection: external or internal connection. Regardless of the connection type, screw loosening is the biggest problem in implant-supported restoration. PURPOSE: The purpose of this study is to assess the difference in stability of abutment screws between the external and internal hexagonal connection types under cyclic loading. MATERIAL AND METHODS: Each of the 15 samples of external implants and internal abutments were tightened to 30 N/cm with a digital torque gauge, and cemented with a hemispherical metal cap. Each unit was then mounted in a $30^{\circ}$ inclined jig. Then each group was divided into 2 sub-groups based on different periods of cyclic loading with the loading machine (30 N/ cm - 300 N/cm,14 Hz: first group $1{\times}10^6$, $5{\times}10^6$ cyclic loading; second group $3{\times}10^6$, $3{\times}10^6$ for a total cyclic loading of $6{\times}10^6$) The removal torque value of the screw before and after cyclic loading was checked. SPSS statistical software for Windows was used for statistical analysis. Group means were calculated and compared by ANOVA, independent t-test, and paired t-test with ${\alpha}$=0.05. RESULTS: In the external hexagonal connection, the difference between the removal torque value of the abutment screw before loading, the value after $1{\tims}10^6$ cyclic loading, and the value after $1{\times}10^6$, and additional $5{\times}10^6$ cyclic loading was not significant. The difference between the removal torque value after $3{\times}10^6$ cyclic loading and after $3{\times}10^6$, and additional $3{\times}10^6$ cyclic loading was not significant. In the internal hexagonal connection, the difference between the removal torque value before loading and the value after $1{\times}10^6$ cyclic loading was not significant, but the value after $1{\times}10^6$, and additional $5{\times}10^6$ cyclic loading was reduced and the difference was significant (P < .05). In addition, in the internal hexagonal connection, the difference between the removal torque value after $3{\times}10^6$ cyclic loading and the value after $3{\times}10^6$, and additional $3{\times}10^6$ cyclic loading was not significant. CONCLUSION: The external hexagonal connection was more stable than the internal hexagonal connection after $1{\times}10^6$, and additional $5{\times}10^6$ cyclic loading (t = 10.834, P < .001). There was no significant difference between the two systems after $3{\times}10^6$, and additional $3{\times}10^6$ cycles.

Holland 6각형 모형의 탐구형·진취형(IE) 축과 직업가치와의 관계분석 (The Analysis Study on Correlation between the Axis of Investigative·Enterprising(IE) in Holland Hexagonal Model and Job Value)

  • 최선희;조인수;서설화
    • 한국산학기술학회논문지
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    • 제18권12호
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    • pp.372-383
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    • 2017
  • 본 논문은 Holland 6각형 모형에서 내 외재적 직업가치를 가늠하는 축이 탐구형 진취형(IE)임을 검증하기 위해 직업카드분류150 검사에 참여한 19명 연구대상자의 Holland 6각형 모형과 내 외재적 직업가치를 분석하여 검증하였다. 분석 결과 첫째, 탐구형 진취형(IE) 축을 중심으로 Holland 6각형 모형이 예술형(A), 사회형(S) 쪽으로 치우쳐 있는 연구 집단은 내재적 직업가치를 나타내어 가설을 지지하였다. 둘째, 탐구형 진취형(IE) 축을 중심으로 6각형 모형이 현실형(R), 관습형(C) 쪽으로 치우쳐 있는 집단은 외재적 직업가치를 추구할 것이라고 한 가설은 기각되었다. 이는 유교문화권에서 정신문화적 가치를 추구하는 한국 특유의 문화적 맥락이 작용한 결과이며, Holland 6각형 모형이 정확하게 탐구형 진취형(IE) 축의 왼쪽에 분포되지 않은 면도 있다. 셋째, 양가적 직업가치의 집단은 탐구형 진취형(IE)축을 기준으로 Holland 6각형이 예술형(A), 사회형(S), 현실형(R), 관습형(C) 등에 걸쳐 나타낸다는 일부 가설을 지지하였다. 본 논문은 일부 가설이 기각되었음에도 불구하고 Holland 6각형 모형 중 탐구형 진취형(IE) 축이 가치를 구별하는 잣대라는 것을 처음 제시한 연구로서 Holland 6각형 모형이 직업선택 뿐만 아니라 직업가치를 예언할 수 있음을 제시하여 Holland 이론의 저변 확대를 꾀하였고, 직업학의 기초자료를 제공하는데 그 의의가 있다.

육각화소 기반의 지역적 이진패턴을 이용한 배경제거 알고리즘 (Background Subtraction Algorithm by Using the Local Binary Pattern Based on Hexagonal Spatial Sampling)

  • 최영규
    • 정보처리학회논문지B
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    • 제15B권6호
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    • pp.533-542
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    • 2008
  • 동영상에서의 배경제거는 다양한 실시간 머신 비젼 응용에서 매우 중요한 단계이다. 본 논문에서는 이러한 배경제거를 위한 육각화소 기반의 새로운 접근 방법을 제안한다. 일반적으로 육각형 샘플링 영상은 양자화 오차가 적으며, 이웃화소의 연결성 정의를 크게 개선한다고 알려져 있는데, 제안된 방법은 비매개변수형 배경제거 방법의 하나인 지역적 이진패턴 기반 알고리즘에 이러한 육각 샘플링 영상을 적용하는 것을 특징으로 한다. 이를 통해, 지역적 이진패턴의 추출과정에서 필요한 쌍선형 보간을 없애고 계산량을 줄일 수 있었다. 실험을 통해 이러한 육각화소의 적용이 배경제거 분야에 매우 효율적으로 적용될 수 있음을 확인할 수 있었다.

HoMnO3 박막의 강유전 특성의 결정상 의존성 (Dependence of Ferroelectric Properties on the Crystalline Phases of HoMnO3 Thin Film)

  • 김응수;강동호
    • 한국재료학회지
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    • 제16권6호
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    • pp.394-399
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    • 2006
  • Ferroelectric $HoMnO_3$ thin films were deposited on the Si(100) substrate at $700^{\circ}C$ for 2 hrs by metalorganic chemical vapor deposition (MOCVD) and post-annealed at 850oC by rapid thermal process (RTP). Electrical properties and crystalline phases of $HoMnO_3$ thin films were investigated as a function of postannealing time. Single phase of hexagonal symmetry with c-axis preferred orientation was obtained from $HoMnO_3$ thin films post-annealed at $850^{\circ}C$ for 5 min, while the c-axis preferred orientation was decreased with the increase of post-annealing time, and the thin films post-annealed at $850^{\circ}C$ for 15 min showed the mixture phases of hexagonal and orthorhombic symmetry. P-E (Polarization-Electric field) hysteresis loop of ferroelectric $HoMnO_3$ thin films was observed only for the single phase of hexagonal symmetry, but that was not observed for the mixture phases of the hexagonal and orthorhombic symmetry, which was discussed with the bond valence of Mn ion of crystalline phase. Leakage current density was dependent on the microstructure of thin films as well as the change of valence of Mn ion.

KOH를 이용한 N-face GaN의 습식 식각으로 인한 표면 변화 (Surface Morphology Variation During Wet Etching of N-face GaN Using KOH)

  • 김택승;한승철;김재관;이지면
    • 대한금속재료학회지
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    • 제46권4호
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    • pp.217-222
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    • 2008
  • Characteristics of etching and induced surface morphology variation by wet-etching of n-face n-type GaN were investigated using KOH solutions. It was observed that hexagonal pyramids were formed on the etched surface regardless of etching conditions. However, the size of the hexagonal pyramids was changed as the etching time and temperature increased, respectively. Initially, as the etching time and concentration of KOH solution increased, the hexagonal pyramid was observed to be dissociated into smaller pyramids. However, as the etching time increased further, the size of the hexagonal pyramids increased again, indicating that the etching of N-face n-type GaN by KOH solutions proceeded through the evolution of hexagonal pyramids, such as formation, dissociation and enlargement of pyramids. Furthermore, it was also observed that there is a correlation between the photoluminescence intensity of the etched surface and the value of root-mean-square roughness. The intensity of PL increased as the roughness value increased due to the enhancement of the extraction efficiency of the generated photons.