• 임산에너지
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• 제23권1호
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• pp.45-68
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• 2004

The word of lignin is derived from the Latin word 'ligum' meaning wood. Lignin is complex polymer consisting of coniferyl alcohol, sinapyl alcohol and p-coumaryl alcohol unit and has an amorphous, three dimensional network structure which is hard to be hydrolyzed by acid. Lignin is found in the cell wall of plants lignified. The mode of polymerization of these alcohols in the cell wall lead to a heterogeneous branched and cross-linked polymer in which phenyl propane units are linked by carbon-carbon and carbon-oxygen bonds. This polymerization of precursors, p-coumaryl alcohol, coniferyl alcohol and sinapyl alcohol to lignin is formed by enzymic dehydrolyzation. The reaction is initiated by an electron transfer which results in the formation of resonance-stabilized phenoxy radical. The combination of these radicals produces a variety of dimers, trimers and oligomers and so on. Lignin research has been divided into basic and practical application field. The basic studies contains biosynthesis, chemical structure, distribution in the cell wall and reactivity by reductants, oxidants and organic solvents. The application research will be approached the reaction of lignin in various pulp making involving pulp bleaching and its effect on pulp qualities. Lignin also will be studied for the production of fine chemicals, polymer products and the conservation into an energy source like petroleum oil because the amount of lignin produced in pulp making process is more than 51,000,000 tons per year in the world. Both basic and application research must lay emphasis on the development for the utilization of lignin and the pulping process. But these researches can not be completed without understanding lignin structure containing functional groups. Therefore, this paper was focused on the review of lignin formulation which has been studied since 1948 in chronological order. This review was based on monomers, dimers, trimers and tetramers of phenyl propane unit structures which were isolated and identified by different methods from various wood.ious wood.

• 한국경제지리학회지
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• 제17권2호
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• pp.296-320
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• 2014

축산의 산업화와 농업의 기계화로 인해 우리나라에서 소의 의미는 역우에서 육우로 변화해 왔다. 아울러 최근 수십년 간에 걸친 쇠고기에 대한 수요 증가와 글로벌화에 따른 무역의 자유화로 인해 해외로부터의 쇠고기 수입이 지속적으로 진전되어 왔다. 이러한 변화 속에서 국내 쇠고기 생산은 전업화, 대형화되기 시작하였고, 이에 따라 한우 상품사슬은 기존과는 다른 특징을 보인다. 육류등급제, 위해요소중점관리제(HACCP), 한우 브랜드화제도는 현재의 한우 생산에 가장 결정적인 영향을 미치고 있고, 이러한 거시적인 제도와 더불어 로컬 스케일에서의 미시적 제도와 행위자들은 그 지역만의 한우 상품사슬을 특징짓고 있다. 연구 지역인 함평은 낙후되고 쇠락한 농촌의 이미지가 강한 지역이었으나, 낙후한 경제적 상황을 타개하기 위해 최근 우시장의 전통성을 활용한 한우 산업이 발전되고 있다. 함평의 한우 생산은 거시적인 제도적 영향과 함께 지역의 제도적 영향이 더해져 지역의 사회적 공간적 변화에 큰 영향을 미치고 있었으며 다양한 층위의 행위자들이 상품사슬을 구성하고 있다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1367-1370
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• 2005

Microcellular foam processing of polymers requires a nucleated cell density greater than $10^9\;cells/cm^3$ so that the fully grown cells are smaller than 10 mm. A microcellular foam can be developed by first saturating a polymer sample with a volatile blowing agent, followed by rapidly decreasing its solubility in the polymer. In general, the cellular structure of crystalline polymer foams is difficult to control, compared to that of amorphous polymer foams. Since the gas does not dissolved in the crystallites, the polymer/gas solution formed during the microcellular processing is nonuniform. Moreover, the bubble nucleation is nonhomogeneous because of the heterogeneous nature of the crystalline polymer. In this paper, the effects of the crystallinity and morphology of crystalline polymers on the microcellular foam processing and on reflectivity of products are investigated. First, polymer specimens with various morphology and amount of solved blowing agent were prepared by varying the saturation pressure, saturation time and foaming condition. Then, cell morphologies according to several conditions were studied. The specimens with differing gas amount of solved and morphologies were foamed and their cellular structures were compared. The experimental results of reflectivity are compared to raw specimen and another specimen of different experimental conditions. After the experiments, recognize whether how reflectivity changes according to solved gas amount. And the effect of cell density and cell size on reflectivity is studied

• 정보처리학회논문지C
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• 제8C권5호
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• pp.607-614
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• 2001

정보통신과 컴퓨터기술의 발전으로 인하여 불법침입으로 인한 정보 파괴, 서비스거부공격 그리고 컴퓨터 바이러스 등에 의한 역기능이 날로 증가하고 있는 추세이다. 또한, 이러한 공격들로부터 네트워크를 보호하기 위해서 침입차단시스템(일명：방화벽), 침입탐지시스템, 접근제어시스템 등 많은 보안제품들이 개발 및 적용되고 있다. 그러나 이러한 보안 제품들에 대한 관리를 위해서는 많은 작업과 비용이 소요된다. 따라서, 이들 보안제품들에 대한 효율적인 관리와 일관된 보안 정책을 적용할 수 있는 정책 기반의 통합보안관리시스템의 정책모델이 필요하게 되었다. 본 논문에서는 정책계층의 개념을 기반으로 상위계층의 추상적이고 개념적인 정책을 보다 구체적인 형태의 정책으로 정제(refinement)하는 정책기반의 통합보안관리시스템의 계층적 정책모델을 제시하였다. 정책의 정형화된 표현을 위해서 Z-Notation을 적용하였으며, 이는 수학적 논리와 집합이론을 기반으로 스키마형태로 표현된다.

• Journal of Gastric Cancer
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• 제1권3호
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• pp.129-135
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• 2001

Purpose: Dysplasia or flat adenoma of the stomach is regarded as a precancerous lesion. However, the frequency and the evolutionary process of malignant transformation of gastric dysplasia are still debated. In order to see whether the lesion was a monoclonal or a polyclonal proliferation, clonality was assayed by X-linked HUMARA polymorphism. Materials and Methods: DNA was extracted from the paraffin-embedded tissue of 16 consecutive cases of endoscopic biopsy, eight of which supplied both dysplastic and nondysplastic tissue for comparison. HUMARA was amplified by PCR with or without pretreatment with methylationsensitive restriction enzyme, HpaII. The amplification products were electrophoresed on polyacrylamide gel and silver-stained. Results: Among the 16 cases, 13 cases were informative and 3 cases noninformative. Of the 13 cases, one case showed skewed lyonization, rendering 12 cases to be analyzed further. A monoclonal band pattern was noted in 2 cases, and a polyclonal band pattern in 10 cases. A review of the histopathologies of the monoclonal and the polyclonal cases did not reveal features discriminating the two groups. Conclusion: These results suggest that gastric dysplasia is a disease entity heterogeneous in the genetic level, and many cases may be non-neoplastic.

• East Asian Economic Review
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• 제20권3호
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• pp.279-309
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• 2016

The proposed Trans-Pacific Partnership (TPP) is a free trade agreement among 12 Pacific Rim countries whose joint gross domestic products (GDPs) account for 36 percent of world GDP and whose mutual trade accounts for approximately 24 percent of world trade. As for most proposed free trade agreements (FTAs), trade economists have provided ex ante computable general equilibrium (CGE) estimates to predict the trade, employment, and real per capita income effects of this agreement, such as ITC (2016). This paper-intended to complement these studies-examines the potential impacts of TPP beyond such traditional CGE estimates, taking a broader economic, governance, and historical perspective. First, we contrast these traditional CGE trade and welfare estimates that treat all firms within an industry as homogeneous with more recent CGE analyses that allow firms' productivities to be heterogeneous. We show that the latter models' trade predictions are much more consistent with ex post empirical evidence of average trade effects of FTAs. Second, empirical evidence now strongly confirms the existence of FTA "contagion." We review this evidence and show that predictive models of the evolution of FTAs indicate that the TPP should be formed. With China now having formed 12 FTAs and negotiating five new ones (including a sixteen member Asia-Pacific FTA), the United States would likely face considerable trade diversion without the TPP. Third, we examine empirical evidence on the likely further economic growth implications of FTAs by reducing firms' uncertainty over trade relations and trade policies. Fourth, we examine empirical evidence on the additional impact of FTAs on consolidating democratic institutions in countries. The TPP would likely help consolidate some of the less mature democracies. Fifth, we examine empirical evidence on the reductions of conflicts (and enhanced peace) between countries owing to the formations of FTAs. We conclude the paper noting that the potential net benefits to member countries of the proposed TPP extend well beyond the real income gains to households based upon traditional CGE models.

• 한국분말재료학회지
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• 제18권3호
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• pp.290-296
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• 2011

Titanium carbonitride is more perspective materials compared to titanium carbide. It can be used in tool industry and special products because of its higher strength, abrasive wear-resistance and especially its strong chemical stability at high temperatures. We produced STS+TiCxNy composite by the spark plasma sintering for higher strength and studied the characteristics. The planar and cross-sectional microstructures of the specimens were observed by scanning electron microscopy. Characterizations of the carbon and nitride phases on the surface of composite were carried out using an X-ray diffractometer. During annealing TiCxNy particles diffusion into STS 430 was observed. After annealing, sintering isolations between particles were formed. It causes decreasing of mechanical strength. In addition when annealing temperature was increased hardness increased. Heterogeneous distribution of alloying elements particles was observed. After annealing composites, highest value of hardness was 738.1 MHV.

• 공업화학
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• 제25권2호
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• pp.215-221
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• 2014

염기 처리에 의한 간단한 방법으로 합성된 $MnO_2$ (B-$MnO_2$)는 불균일 촉매시스템으로 호기성 조건에서 효과적인 아민 산화반응을 보여주었다. 이 B-$MnO_2$ 촉매는 다양한 종류의 방향족, 이원자 화합물, 비활성 지방족 등의 아민의 전환에 높은 활성과 선택성을 보여주었다. 이러한 산화반응은 온화한 온도($50^{\circ}C$)와 대기압의 공기 조건하에서 아민을 중간체인 이민으로 전환하고 자가 축합(self-condensation) 또는 산화적 탈수소화(oxidative dehydrogenation)을 통해 다이이민(diimine) 또는 나이트릴(nitrile)을 생성하였다. 사용된 촉매는 여과로 쉽게 분리할 수 있었고 5번 이상의 재사용 실험에서도 일정이상의 높은 수율을 보여주었다. 따라서 B-$MnO_2$는 아민 산화반응을 통해 이민과 나이트릴을 얻음에 있어 경제적으로나 환경친환적으로 효과적인 면을 보여 줌으로써, 그린화학(green chemistry)의 목적에 적합하다.

• 산업경영시스템학회지
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• 제38권1호
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• pp.170-181
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• 2015

Generally, because individual agricultural product possesses its own distinctive characteristics and shows different characteristics at each stage of the agricultural supply chain, it is necessary to develop a proper enterprise architecture for managing information system. In this paper, we propose an enterprise architecture based on RFID/USN technology that can be used as a reference enterprise architecture for u-IT application in the agriculture sectors, which is called the u-Farm enterprise architecture with taking heterogeneous characteristics of agricultural products into account for. In addition, we also developed the RFID/USN middleware platform as a core infrastructure technology. Fo evaluation of the performance of the proposed u-Farm architecture and the RFID/USN middleware platform, the field-trial evaluation at the apple Agricultural Processing Center (APC) has been executed and the results shows that the proposed architecture and platform perform well in terms of information integration over the whole SCM process from the farming stage to delivering statge to the customers. It is expected that the proposed u-Farm enterprise architecture can be utilized as a standard information architecture, and the RFID/USN middleware platform can be a infrastructure platform for future u-IT based information technology applications and services in the agricultural environment.

• 청정기술
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• 제20권2호
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• pp.116-122
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• 2014

수열합성 또는 후처리 방법을 통해 산 또는 염기능을 나타내는 다양한 종류의 이원기능 금속-유기 구조체 물질을 제조하여 대표적인 방향제 원료 중 하나인 자스민알데하이드(jasminaldehyde)를 합성하기 위한 벤즈알데하이드(benzaldehyde, $C_6H_5CHO$)와 헵탄알(heptanal, $C_6H_{13}CHO$)의 알돌 축합반응의 촉매로 활용하였다. 실험 결과, 산 또는 염기점 모두에서 축합반응이 진행되었으며, 촉매 성능은 기능기의 도입 여부 및 종류와 금속-유기 구조체의 물리적인 특성에 크게 의존하였다. Jasminaldehyde 선택도는 황산 기능기를 도입한 경우에는 금속-유기 골격체의 종류에 상관없이 감소하였으나, 아민 기능기를 도입한 경우에는 금속-유기 골격체의 종류에 따라 상반된 경향을 나타내었다. 평가한 촉매 중 MIL-101의 촉매 성능이 가장 우수하였는데, 이러한 결과는 MIL-101이 알돌 축합반응의 촉매로 작용하기에 충분한 산량과 적당한 산세기를 가지고 있으며, 세공 크기가 넓어 크기가 큰 생성물의 물질이동 측면에서 유리하기 때문인 것으로 판단된다.