• Journal of Korean Society for Atmospheric Environment
• /
• v.25 no.6
• /
• pp.512-522
• /
• 2009

In this study, the removal efficiency of trimethylamine (TMA) and four reduced sulfur compounds (RSC) of $H_2S$, $CH_3SH$, DMS, and DMDS was investigated using deionized water as absorbent. To this end, two types of experiments were conducted which include: (1) by passing both RSC and TMA standard gases through water contained in an impinger system and (2) by passing TMA gases through a water spray system. In the former method, TMA standard gases were effectively removed (below detection limit) in all experiments. Likewise, minor fractions of some RSC ($CH_3SH$, DMS, and DMDS) were removed by water in line with theoretical expectations. In addition, the first type of our experiment was extended further to test some commercially available odor treatment products. The results of this test showed that removal efficiencies of RSC $(8.2\pm13.7\sim43.7\pm2.48%)$ were different significantly among 4 kinds of absorbent, while the removal of TMA was consistently good as water. In the second phase of experiment, removal efficiency of TMA was tested by passing its standard gas through a water spray system. The overall results of our study showed that the actual removal efficiency of odorants by water (as sorptive media) approached the values that can be predicted theoretically (by Henry's law).

• Proceedings of the Korea Society of Environmental Toocicology Conference
• /
• 2002.10a
• /
• pp.154-154
• /
• 2002

Benzoyl peroxide is a High Production Volume Chemical, which is produced about 1,375 tons/year in Korea as of 2001 survey. The substance is mainly used as initiators in polymerization, catalysts in the plastics industry, bleaching agents for flour and medication for acne vulgaris. The substance is one of seven chemicals of which human health and environmental risks are being assessed by National Institute of Environmental Research (NIER) under the frame of OECD SIDS Program. In this study, Quantitative Structure-Activity Relationships (QSAR) is used for getting adequate information on the physical-chemical property and the environmental fate of this chemical. For the assessment of benzoyl peroxide, models such as MPBPWIN for vapor pressure, KOWWIN for octanol/water partition coefficient, HENRYWIN for Henry's Law constant, AOPWIN for photolysis and BCFWN for bioconcentration factor (BCF) were used. These (Q)SAR model programmes were worked by using the SHILES (Simplified Molecular Input Line Entry System) notations. The physical-chemical properties and the environmental fate of benzoyl peroxide were estimated as followed : vapor pressure =0.00929 Pa, Log Kow = 3.43, Henry's Law constant = 0.00000354 atm-㎥/mole at 25 $^{\circ}C$, the half-life of photodegradation = 3 days, bioconcentration factor (BCF) = 92

• Journal of the Korean Chemical Society
• /
• v.26 no.4
• /
• pp.211-217
• /
• 1982

Assuming krypton molecules adsorbed on the graphite surface as a two-dimensional (2D) gas, 4th virial coefficient of the virial equation is calculated by the use of cluster integrals. The Henry's law constant, and 2nd and 3rd virial coefficients are also calculated. Adsorption isotherms calculated from this virial equation agree very satisfactorily with experimental results. The interaction energy of Kr-graphite surface is calculated assuming the pairwise additivity of Lennard-Jones(12,6) potential, and parametars therein are taken as; ${\varepsilon}_{gs}$/k = 71.1 K, ${\varepsilon}_{gg}$/k = 170 K, ${\sigma}_{gs}$ = 354 pm, and ${\sigma}_{gg}$ = 368 pm.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.18 no.10
• /
• pp.136-152
• /
• 2017

The thermodynamic models, PC-SAFT (Perturbed-Chain Statistical Associated Fluid Theory) state equation and the Two-model approach liquid activity coefficient model NRTL (Non Random Two Liquid) + Henry + Peng-Robinson, for modeling the Rectisol process using methanol aqueous solution as the $CO_2$ removal solvent were compared. In addition, to determine the new binary interaction parameters of the PC-SAFT state equations and the Henry's constant of the two-model approach, absorption equilibrium experiments between carbon dioxide and methanol at 273.25K and 262.35K were carried out and regression analysis was performed. The accuracy of the newly determined parameters was verified through the regression results of the experimental data. These model equations and validated parameters were used to model the carbon dioxide removal process. In the case of using the two-model approach, the methanol solvent flow rate required to remove 99.00% of $CO_2$ was estimated to be approximately 43.72% higher, the cooling water consumption in the distillation tower was 39.22% higher, and the steam consumption was 43.09% higher than that using PC-SAFT EOS. In conclusion, the Rectisol process operating under high pressure was designed to be larger than that using the PC-SAFT state equation when modeled using the liquid activity coefficient model equation with Henry's relation. For this reason, if the quantity of low-solubility gas components dissolved in a liquid at a constant temperature is proportional to the partial pressure of the gas phase, the carbon dioxide with high solubility in methanol does not predict the absorption characteristics between methanol and carbon dioxide.

• Clean Technology
• /
• v.14 no.4
• /
• pp.287-292
• /
• 2008

In this study, computer simulation works have been performed for the capture process of the $CO_2$ and $H_{2}S$ gases contained in the effluent stream using methanol aqueous solution. In order to increase the solubilities of the $CO_2$ and $H_{2}S$ in the methanol aqueous stream, the operating pressure of the absorber was raised to 30 bar and the feeding temperature of the solvent was lowered to $-20^{\circ}C$ by using refrigeration cycle. NRTL liquid activity coefficient model was used to estimate the liquid phase nonidealities for methanol and water. Soave-Redlich-Kwong equation of state was used for the vapor phase nonidealities. Henry's law option was also used to calculate the solubilities of the supercritical noncondensible gases into the methanol aqueous solvent stream.

• Journal of the Korean Institute of Gas
• /
• v.10 no.2 s.31
• /
• pp.22-26
• /
• 2006

In this study, modeling and simulation works using Aspen Plus were carried out for DME separation and purification process of pilot plant for the daily production of 50 kg of DME. For modeling of the entire DME separation unit, NRTL liquid activity coefficient model was used for the prediction of liquid phase non-idealities, Henry's law option was also used for the estimation of solubilities of light gases in solvents and SRK equation of state model was utilized for the description of vapor phase non-idealities. DME having over 98 wt% purity was obtained as a side distillate product in a DME purification column.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.04a
• /
• pp.371-376
• /
• 1998

In this study, the size effect of concrete members subjected to the axial load and bending moment is investigated using a series of C-shaped specimens of which test procedure is similar to those of Hognestad, Hanson, and McHenry's. Main test variable is a size ratio of the specimens(1:1/2:1/4) at the concrete compressive strength of 500kg/㎠. Test results show that the flexural compression strength at failure decreases as the size of specimen increases, that is, the size effect law is present. Model equation is derived using regression analyses with experimental data and it is compared with formulas for compressive strength of cylinders and shear strength of beams without stirrups. Size effects is distinct th following sequence; shear strength of beams without stirrups, compressive strength of C-shaped specimens, compressive strength of cylinders.

• Journal of Environmental Science International
• /
• v.17 no.3
• /
• pp.343-350
• /
• 2008

The fate of two cyclic ethers, THF(Tetrahydrofuran) and 1,4-Dioxane, in conventional biological wastewater treatment plants was investigated using sequential activated sludge process. Removal efficiency of THF were about 86% in average, which was greater than that of 1,4-Dioxane, 30%. However, it was not clear whether the removal of cyclic ethers in biological system was caused by microbial activity or not. Thus treatability tests were conducted by batch experiments. The effects of mixing, aeration and the addition of activated sludge on the removal of cyclic ethers were investigated in batch experiments. THF was totally removed by mixing and aeration in 24 hours while removal ratio of 1,4-Dioxane was at most 30% for the same period. This results could be ascribed to the differences in Henry's law constants between the two chemicals. In addition, biological degradation including biosorption was not obviously observed in these batch tests.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.11 no.2
• /
• pp.590-596
• /
• 2010

Through this study, we have attempted the thermodynamic analysis on the dimethyl ether (DME) separation process, which can be used for diesel alternative fuel, additive to LPG and natural gas. And we also have completed the simulation of DME separation process using PRO/II with PROVISION. As an appropriate thermodynamic models, we selected NRTL liquid activity coefficient model to describe the non-ideality between methanol and water. To estimate the vapor phase non-idealities, we have chosen the Peng-Robinson equation of state model. And we also use the Henry's law option to predict the solubilities of non-condensible gases like CO, $CO_2$, $H_2$, $CH_2$ and $N_2$ in methanol solvent. Case study showed that optimal solvent to feed molar ratio was 3.40

• Journal of Advanced Marine Engineering and Technology
• /
• v.41 no.3
• /
• pp.182-190
• /
• 2017

All liquids contain a small amount of gaseous components and the amount of gases dissolved in a liquid is in accordance with Henry's Law. In a multi-stage thermal-type seawater desalination plant, as the supplied seawater undergoes variations in temperature and pressure in each evaporator, the gases dissolved in the seawater are discharged from the liquid. The discharged gases are carbon dioxide, nitrogen, oxygen, and argon, and these emitted gases are non-condensable. From the viewpoint of convective heat transfer, the evaluation of non-condensable gas released during a vacuum evaporation process is a very important design factor because the non-condensable gases degrade the performance of the cooler. Furthermore, in a thermal-type seawater desalination plant, most evaporators operate under vacuum, which maintained through vacuum system such as a steam ejector or a vacuum pump. Therefore, for the proper design of a vacuum system, estimating the non-condensable gases released from seawater is highly crucial. In the study, non-condensable gases released in a thermal-type seawater desalination plant were calculated quantitatively. The calculation results showed that the NCG releasing rate decreased as the stage comes getting a downstream and it was proportional to the freshwater production rate.