• 자원리싸이클링
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• 제13권6호
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• pp.9-15
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• 2004

FeSO$_4$ 용액에 NaOH를 첨가하여 FeOOH를 제조하였으며, R(=2NaOH/FeSO$_4$), FeSO$_4$의 농도, 반응온도 및 산화용 가스인 air의 유량 변화에 따른 제조변수를 통해 투명산화철의 제조 조건을 연구하였다. 수용액 중에 FeSO$_4$의 농도가 증가할수록 Fe$_3O_4$를 석출하며 입자의 크기가 증가하였다. 생성된 FeOOH는 약 200$^{\circ}C$에서 탈수반응을 일으켜 약 320$^{\circ}C$부근에서 종료하였다. 반응온도가 낮을수록 Fe(OH)$_2$의 입자의 길이가 짧아졌으며, 산화제인 air의 공급량이 클수록 용액 중에 용존산소의 량이 증가하여 Fe(OH)$_2$의 입자길이가 감소하였다.

• 자원환경지질
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• 제17권1호
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• pp.35-47
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• 1984

Combined mineralogical and geochemical studies were made on two hundred eighty one representative samples from uraniferous coaly meta-pelites of the Ogcheon metamorphic terrain. Different mineral occurrence of the areas investigated should be taken into account for chemical processes for uranium extraction. Secondary uranium minerals identified are metauranocircite, metatorbernite and autunite. These are disseminated mostly on the laumontites which infused and filled secondary openings in the coaly matrix, and are often closely associated with iron oxides. The uranium distribution show distinctly log normal. Geochemical correlation coefficient of uranium and organic carbon displays +0.624~+0.796. The relationship of the major components to uranium can be expressed by the following regression equation: Log $(U_3O_8{\times}10^4)$=1.40117-0.00076 (quartz) -0.00118 (muscovite) +0.00235 (biotite) +0.00323 (other silicates) - 0.01114 (apatite) +0.01124 (hematite) +0.00149 (limonite) -0.01823 (opaques)+0.03049 (organic carbon). Uranium in the coaly meta-pelites of the Ogcheon Group was deposited together under same physico-chemical environmental conditions. There is a considerable variation in the ${\delta}^{34}S$ values (11.2~16.8 per mil) of the pyrites from the U-bearing meta-pelites, which implies sedimentary origin. The two U-bearing coaly rocks analyzed have ${\delta}^{13}C$ values between -16.88~-18.00 per mil, which suggests organic.

• 자원환경지질
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• 제16권2호
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• pp.65-78
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• 1983

This report deals with the sedimentological study of the littoral sand of beaches in the Busan area. The purpose of this report is to know the grain size, mineralogical composition, heavy mineral and clay mineral of the beach sands, and gravity measurements of the Nagdong River Deltas. 1) As a whole, the littoral sand of the beaches are composed of uniformly medium grained, moderately sorted and nearly symmetrical. The barrier sand of the Nagdong Estuary is composed of fine grained, well sorted and nearly symmetrical. 2) The littoral sand of the beaches is transported by saltation and rolling. The barrier sand of the Nagdong Estuary is transported by suspension and saltation. 3) In the littoral sand of the beaches, the ratio of feldspar to quartz is 1 :2.31 and in the barrier sand of the Nagdong Estuary 1:1.40. 4) The content of heavy mineral of samples ranges from 0.54 to 3.87 %. The principal heavy minerals are hornblende, pyroxene, epidote, garnet, leucoxene, zircon, apatite, magnetite, hematite and ilmenite with minor accessories of rutile and olivine. 5) The x-ray diffraction analysis of the clay mineral informs the existence of quartz, feldspar, kaolinite and montmorillonite. The montmorillonite is considered to have been derived from the alteration of acidic volcanic rocks. 6) To determine the depositional structure of the Nagdong Estuary, Gravity measurements were made. Free air anomaly ranges from 14.5 mgal to 33.5 mgal and Bouguer anomaly ranges from 14.3 to 23.5 mgal and both are closely related to the topography. According to the interpreted layer structure, the upper layer composing sand, silt and clay, the intermediate layer composing sand with gravel, the lower layer composing weathered and soft rock, and bed rock composing hornfels or andesite. 7) The depositional environments of the study, the littoral area is dominated by the marine environment and the Nagdong Estuary by the mixed environment.

• 자원환경지질
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• 제5권3호
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• pp.133-144
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• 1972

The mine of our present concern is situated at Shim-ri, Gusan-myon, Changwon-gun, Kyongsang-namdo, with lattitude $128^{\circ}35^{\prime}{\sim}36^{\prime}N$ and longitude $35^{\circ}03^{\prime}{\sim}04^{\prime}E$. This mine has not been noticed until the intermittent geological survey for the ore deposits were initiated from September, 1967 till 1970. The main mineralized zones, No.1 and No.2 zones, were studied by the diamond drilling of 9 holes down to the total depth of 1,140m, and found to have ore reserves of Cu 1.99% ore, estimated to reach around $358,000{\frac{M}{T}}$ (proved $117,000{\frac{M}{T}}$, indicated $241,000{\frac{M}{T}}$), which triggered the new exploitation of this mine. Geological composition of the district near the mine is mainly from the andesite belonging to the Silla Series of Kyongsang System and the distribution is broadly spread. Ore deposits are the hydrothermal one, filling the shear zone formed alongside the andesite main joint. There are two stripes of copper bearing mineralized zone which are about 40~70 meters apart and parallel to each other, in addition to which two others are expected. The strike of the main mineralized zone lies at $N15^{\circ}{\sim}20^{\circ}W$, the dip at $60^{\circ}{\sim}70^{\circ}NE$. The principal components of the ore mineral are chalcopyrite, bornite and as secondary, cuprite, tenorite, azurite and malachite. Pyrite, magnetite, specular hematite, very little of galena, sphalerite, quartz, epidote, zoisite, chlorite and calcite are found as gangue mineral. Confirmed by the drilling, the main mineralized zone, No.1 zone, has the length of 320m, average width of 1.62m, Ag 26g/t, Cu 1.84% and the average width of the ore zone except the narrow barren andesite horse interposed in the mineralized zone is 1.32m with Ag 32g/t and Cu 2.26%. The mineralized zone No.2 is 340m long, 1.00m wide with Ag 30g/t and Cu 2.15%. Neglecting the barren andesite horse the width is 0.73m with Ag 42g/t and Cu 2.94%.

• 자원환경지질
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• 제29권2호
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• pp.193-209
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• 1996

Paleomagnetic and rock-magnetic data have been obtained from the Cretaceous rocks (Yeongdong Group, volcanic rock, and intrusive rocks) which are exposed in the Yeongdong Basin. The characteristic remanent directions of these rocks, which are mainly carried by magnetite and hematite of single and pseudo-single domain sizes, are normally magnetized (Yeongdong Group: $D/I=29.6/59.0^{\circ}C$, k=75.7, ${\alpha}_{95}=3.3^{\circ}$, N=25 sites, paleopole at $198.0^{\circ}E$, $66.4^{\circ}N$, K=46.1, $A_{95}=4.3^{\circ}$; volcanic rock: $D/I=352.8/44.1^{\circ}$, k=44.2, ${\alpha}_{95}=18.8^{\circ}$, N=3 sites, paleopole at $340.0^{\circ}E$, $78.8^{\circ}N$, $K=49.8^{\circ}E$, $A_{95}=17.6^{\circ}$X>; intrusive rocks: $D/I=358.4/51.9^{\circ}C$, k=20.0, ${\alpha}_{95}=13.8^{\circ}$, N=7 sites, paleopole at $338.1^{\circ}E$, $86.8^{\circ}N$, K=13.5, $A_{95}=17.1^{\circ}$). The stepwise unfolding of the characteristic remanent magnetization (ChRM) of the Yeongdong Group reveals that a maximum value of k is observed at 60% of unfolding with $D/I=13.0/58.6^{\circ}$ (k=124.62, ${\alpha}_{95}2.6^{\circ}$) indicating that the ChRM was aquired during ti1ting of the strata. This remagnetized ChRM in the sedimentary strata is due to acquisition of geomagnetic field direction at the time of formation of authigenic magnetic minerals, although it is not totally ruled out that the formation of authigenic magnetic minerals was affected indirect1y by the elevated temperature originated from the volcanic and intrusive rocks which intruded between Late Cretaceous and Early Tertiary.

• 자원환경지질
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• 제29권2호
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• pp.139-150
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• 1996

The Yucheon Bi deposits at Cheongha, Gyeongsangbugdo, is of a middle Paleogene (49 Ma) vein type, and is hosted in sandstone and shale of Banyawal formation in Cretaceous age. Based on mineral paragenesis, vein structure and mineral assemblages, two minera1ization stages were distinguished. The stage I consists of quartz with small amount of chlorite, pyrite, epidote, hal1oysite, vermiculite, serpentine and rutile associated with sericitization. The stage II is characterized by Bi minera1ization such as bismuthinite, Bi-Cu-Pb-S mineral, tetradymite, native gold, pyrite, pyrrhotite, arsenopyrite, wolframite, rutile, hematite, sphalerite, chalcopyrite, galena with alteration of sericite, chlorite, K-feldspar, albite and epidote. Fluid inclusion data indicate that fluid temperature and NaCl equivalent wt.% salinity range from 431 to $150^{\circ}C$ and from 19.2 to 0.18wt.% in the stage II. Evidence of boiling during the base-metal minera1ization indicates pressures 241 to 260 bars. Sulfur fugacity($-log\;f_{S2}$) deduced by mineral assemblages and compositions ranges from 5.1 to 5.7atm in early stage, from > 8.4 atm in middle stage and from 13.5 to 19.3 atm in late stage. It suggests that complex histories of progressive coo1ing, dilution and boiling were occurred by the mixing of the fluids. The ${\delta}^{34}S$, ${\delta}^{18}O$ and ${\delta}D$ data range from 2.5 to 3.9%, -0.5 to -4.1% and -29.7 to -47%, respectively. It indicated that hydrothermal fluids may be magmatic origin with boiling and mixing of meteoric water increasing paragenetic time.

• Advances in nano research
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• 제5권3호
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• pp.215-230
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• 2017

The development of hybrid systems comprising nanoparticles and polymers is an opening pathway for engineering nanocomposites exhibiting outstanding mechanical, optical, electrical, and magnetic properties. Among inorganic counterpart, iron oxide nanoparticles (IONP) exhibit high magnetization, controllable surface chemistry, spintronic properties, and biological compatibility. These characteristics enable them as a platform for biomedical applications and building blocks for bottom-up approaches, such as the layer-by-layer (LbL). In this regard, the present study is addressed to investigate IONP synthesised through co-precipitation route (average diameter around 7 nm), with either positive or negative surface charges, LbL assembled with sodium sulfonated polystyrene (PSS) or polyaniline (PANI). The surface and internal morphologies, and electrochemical properties of these nanocomposites were probed with atomic force microscopy, UV-vis and Raman spectroscopy, scanning electron microscopy, cross-sectional transmission electron microscopy, and electrochemical measurements. The nanocomposites display a globular morphology with IONP densely packed while surface dressed by polyelectrolytes. The investigation of the effect of thermal annealing (300 up to $600^{\circ}C$) on the oxidation process of IONP assembled with PSS was performed using Raman spectroscopy. Our findings showed that PSS protects IONP from oxidation/phase transformation to hematite up to $400^{\circ}C$. The electrochemical performance of nanocomposite comprising IONP and PANI were investigated in $0.5mol{\times}L^{-1}$ $Na_2SO_4$ electrolyte solution by cyclic voltammetry and chronopotentiometry. Our findings indicate this structure as promising candidate for potential application as electrodes for supercapacitors.

• Environmental Engineering Research
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• 제16권4호
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• pp.187-203
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• 2011

Chlorophenols (CPs) are widely used industrial chemicals that have been identified as being toxic to both humans and the environment. Zero valent iron (ZVI) and iron based bimetallic systems have the potential to efficiently dechlorinate CPs. This paper reviews the research conducted in this area over the past decade, with emphasis on the processes and mechanisms for the removal of CPs, as well as the characterization and role of the iron oxides formed on the ZVI surface. The removal of dissolved CPs in iron-water systems occurs via dechlorination, sorption and co-precipitation. Although ZVI has been commonly used for the dechlorination of CPs, its long term reactivity is limited due to surface passivation over time. However, iron based bimetallic systems are an effective alternative for overcoming this limitation. Bimetallic systems prepared by physically mixing ZVI and the catalyst or through reductive deposition of a catalyst onto ZVI have been shown to display superior performance over unmodified ZVI. Nonetheless, the efficiency and rate of hydrodechlorination of CPs by bimetals depend on the type of metal combinations used, properties of the metals and characteristics of the target CP. The presence and formation of various iron oxides can affect the reactivities of ZVI and bimetals. Oxides, such as green rust and magnetite, facilitate the dechlorination of CPs by ZVI and bimetals, while oxide films, such as hematite, maghemite, lepidocrocite and goethite, passivate the iron surface and hinder the dechlorination reaction. Key environmental parameters, such as solution pH, presence of dissolved oxygen and dissolved co-contaminants, exert significant impacts on the rate and extent of CP dechlorination by ZVI and bimetals.

• Corrosion Science and Technology
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• 제12권6호
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• pp.280-287
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• 2013

Flow accelerated corrosion(FAC) of the carbon steel piping in pressurized water reactors(PWRs) has been major issue in nuclear industry. Severe accident at Surry Unit 2 in 1986 initiated the worldwide interest in this area. Major parameters influencing FAC are material composition, microstructure, water chemistry, and hydrodynamics. Qualitative behaviors of FAC have been well understood but quantitative data about FAC have not been published for proprietary reason. In order to minimize the FAC in PWRs, the optimal method is to control water chemistry factors. Chemistry factors influencing FAC such as pH, corrosion potential, and hydrazine contents were reviewed in this paper. FAC rate decreased with pH up to 10 because magnetite solubility decreased with pH. Corrosion potential is generally controlled dissolved oxygen (DO) and hydrazine in secondary water. DO increased corrosion potential. FAC rate decreased with DO by stabilizing magnetite at low DO concentration or by formation of hematite at high DO concentration. Even though hydrazine is generally used to remove DO, hydrazine itself thermally decomposed to ammonia, nitrogen, and hydrogen raising pH. Hydrazine could react with iron and increased FAC rate. Effect of hydrazine on FAC is rather complex and should be careful in FAC analysis. FAC could be managed by adequate combination of pH, corrosion potential, and hydrazine.

• 자원환경지질
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• 제2권1호
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• pp.13-33
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• 1969

The Mulkum mine, located in Mulkum-myon, Yangsan-Kun, Kyeongsang Province, is one of the biggest iron mine in Korea. The geology of this mine and its vicinity consists of Chusan andesitic rocks and Datae-dong andesite porphyry of the Kyeongsang System which were intruded by biotite granite widely distributed near the vicinity of Mulkum-ni. The ore deposits, embedded in Dotae-dong andesite porphyry, are fissure-filling vein type in origin. Up to present ore bodies of Main vein, No. 2 vein, Eastern No. 1, 2 vein and Western No. 1 vein are exploited. Generally the veins strike N 10-25 E and dip to 60-90 SE. The proved length of vein is more than 500 meters and its depth 150 meters in Main vein with 3-4 meters of thickness in average. Ore minerals are mainly magnetite and locally associated with small amounts of hematite, sphecularite and chalcopyrite. Gangue minerals are quartz, epidote, chlorite, pyroxene, and garnet, etc. The modes of occurrence of vein are as follow; 1. Branching and parallel vein patterns are observed around main shaft in -1 level. 2. Multiple cymoid loops and subrectangular vein patterns are observed around main shaft in -2 level. 2. Single vein patterns are observed in -3 and -5 level. The ore-shoots plunge northeasterly about 20-30 degrees. In conclusion, the tectonically fractured zone belongs to the poorly mineralized zone and shoots are formed as single vein type. The general trends of one-shoots must be applied the prospecting of the deep-seated ore body in the deposits.