• 제목/요약/키워드: Heavymetal

검색결과 14건 처리시간 0.03초

중금속폐수에서 구리의 전기화학적 침전처리 (Electrochemical Precipitation Treatment of Copper from an Heavymetal Wastewater)

  • 김재우;이재동;이우식;지은상
    • 한국환경보건학회지
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    • 제23권3호
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    • pp.1-6
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    • 1997
  • This research was conducted in the laboratory to investigate an alternative of Copper(Cu) removal from an heavymetal wastewater using the electrochemical precipitation(ECP) process. The ECP unit consisted of an electrolytic cell made of Titanium plate and Steel plate representing anode and cathode. The DC power source applied to the ECP unit had electrical potential(E) of 50$\pm$ 1V, respectively. The synthetic wastewater used in the experiments contained Cu in the 10 mg/l concentration and the electrode separation were 2, 3, 4 cm and the initial pH were 3, 6, 9, 12, and electrolytic concentration were 0.005, 0.0125, 0.025, 0.0375 mole, and the real heavymetal wastewater used in the experiments. From the experiment for removal efficiency according to pH variation, the low pH area doesn't give the coagulation effect by Ti(OH)$_4$ because process interfere with the coagulation and oxidation reaction, therefore the optimum pH was 4-7. The removal rate was 97.75% after the lapse of 30 minutes when copper concentration and electrolytic concentration were respectively 10 mg/l and 0.025 mole. The removal rate was 96.41% after the lapse of 30minutes when the real heavymetal wastewater used. The optimum consumption of power showed 27KWh/m$^3$ when copper concentration, electrolyte concentration and cell potential were respectively 10 mg/l, 0.025 mole and 50$\pm$ 1 Volt.

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구리흡착 단백질 유전자를 함유하는 재조합 효모의 중금속 흡착 (Heavy-Metal Adsorption by Recombinant Saccharomyces cerevisiae Harboring Multiple Copies of the CUP1 Gene)

  • 서진호;박상옥;김명동;한기철;전영석;안장우;한남수
    • KSBB Journal
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    • 제17권1호
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    • pp.38-43
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    • 2002
  • 중금속 결합 단백질인 metallothionein (MT)를 발현하는 CUP1 유전자를 다중으로 함유하는 재조합 Saccharomyces cerevisiae의 균체성장과 중금속 제거특성을 조사하였다. CUP1 유전자를 다중으로 함유하는 재조합 효모는 중금속을 포함한 배지에서의 균체성장과 중금속 흡착능이 중금속에 대하여 내성을 가지고 있는 야생효모나 숙주세포에 비하여 우수하였다. 서로 다른 플라스미드를 함유하는 중금속을 함유하는 배지에서의 균체성장과 중금속 흡착능의 차이는 중금속에 대한 내성과 중금속 흡착에 MT 단백질의 발현 수준이 중요한 영향을 미치는 것으로 추정되었다. 구리를 함유하지 않고 고농도의 아연과 망간을 함유하는 배지에서 재조합 효모는 높은 균체 농도와 중금속 제거능을 나타내었는데, 이는 MT 단백질을 발현하는 CUP1 promoter가 아연과 망간에 의해서도 발현이 유도된다는 것을 알 수 있었다. MT 단백질을 효율적으로 발현하여 재조합 효모에 의한 중금속 흡착을 최대화 할 수 있는 최적의 구리농도는 0.31 mM로 결정되었으며, 비이온계 계면활성제인 Triton X-100은 재조합 효모의 균체성장과 중금속 흡착을 증가시켰지만, 대사 저해제는 균체성장과 중금속 흡착을 모두 저해하였다.

서울시 인근의 한강 본류 및 지류에 대한 하상 저질의 중금속오염 평가 (An Assessment of the Heavy Metal Contamination of Sediment in Main Stream and Tributaries of the Han River in the Vicinity of Seoul)

  • 노수미;이홍근
    • 한국환경보건학회지
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    • 제20권4호
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    • pp.17-35
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    • 1994
  • This study was performed to investigate and assess the heavy metal contamination of sediment in main stream and tributaries of the Han-river in the vicinity of Seoul. Sediment were sampled at eight locations of main stream and eighteen locations of tributaries in the spring, summer, and fall in 1993. Six heavy metals of Cd, Cu, Pb, Zn, Cr, and Hg, were assessed. For an assessment of heavy metal contamination in sediment, the assessment method of Hakanson was modified to estimate for Han-river, then classification method of Muller in sediment quality was applied. For an assessment of contamination in each heavy metal, Contamination factor C$_f^i$ which was defined the ratio of concentration of i heavy metal in investigated location to background concentration of i heavy metal in uncontaminated upper area was used. The sediment quality in each heavymetal was classified as follows if C$_f^i$<1, Class I for Non contamination, if 1 < C$_f^i$ < 3, Class II for Low contamination, if 3< C$_f^i$ <6, Class III for Moderate contamination, if 6< C$_f^i$ <12, Class IV for Considerable contamination, and if C$_f^i$ > 12, Class V for High contamination.(abbreviation)

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2008년 대전지역에서 발생한 황사의 중금속 오염도 (Pollution Level of Heavy Metals of Asian Dust in Daejeon Area, 2008)

  • 이평구;배법근
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제19권1호
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    • pp.8-25
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    • 2014
  • The aims of this study were to determine concentrations of selected metals in Asian and non-Asian dust collected in Daejeon, Korea between February 2008 and December 2008 and to estimate the pollution level. The geochemical analyses of Asian dust (AD) and Non Asian dust (NAD) show that the mean concentrations of As, Cd, Cu, Pb, Zn, Zr, Sb, Mo and S reached levels up to 16, 209, 31, 43, 81, 28, 31, 122 and 302 times higher, respectively, than those in uncontaminated Chinese desert soils. These results indicate that both AD and NAD serve as an atmospheric repository for trace and heavymetal accumulation. The the enrichment factor (EF) and pollution index (PI) show that AD and NAD were severely contaminated by S, Mo, Zr, Cd, Pb, Zn, Sb, Cu, and As. All indices for these metals showed either strong or notably high level of pollution relative to Chinese desert soil, principally due to the severe atmospheric pollution derived from anthropogenic activities in heavily industrial Chinese cities. Therefore, Mo, Cd, Zr, As, Cu, Sb, Pb, and Zn are the ones most strongly affected by anthropogenic inputs such as airborne pollutants.

산업부산물을 이용한 오염농경지 복원을 위한 현장실증시험 적용 (Pilot-test for the Restoratoin of Contaminated Farmland using Industrial By-products)

  • 유찬;백승환;윤성욱;박진철;이정훈;임영철;최승진;장민
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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    • pp.914-919
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    • 2008
  • This present was carried out to evaluate the adaptability of stabilization method which was used industrial byproducts as the stabilization agency in the abandoned mine site. In order to investigate stabilization effect on As-contaminated soils treated by industrial by-products, batch tests and column tests were carried out with As-contaminated soils collected from farmland around the abandoned mine site. ZVI(zero valent iron) and SRS(steel refining slag) was shown a good treatment effect. After the column test, sequential extraction test and simple bioavailability extraction test(SBET) were carried out to analysis of the soil, and scanning electron micrograph(SEM) analysis was carried out to compare the morphology and structure of ZVI and SRS before and after reacting with arsenic in the soil. As a result, ZVI and SRS were shown 93%, 62% reduction of As concentration respectively by comparison with untreated soils. Therefore, if ZVI and SRS are used as treatment materials in As-contaminated soils, it is expected that the As leaching from soils is reduced effectively.

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영가철 및 산업폐기물을 활용한 비소오염토양의 안정화 효과조사 (Investigation of Stabilization Effect on Arsenic Contamination Soils using Zerovalent Iron and Industrial by-products)

  • 유찬;윤성욱;백승환;박진철;이정훈;임영철;최승진;장민
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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    • pp.229-241
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    • 2008
  • In order to investigate stabilization effect on As-contaminated soils treated by zero-valent iron(ZVI) and industrial by-products, batch tests and column tests were carried out with As-contaminated soils collected from farmland around the abandoned mine site. In batch tests, ZVI and industrial by-products(blast furnace slag, steel refining slag and oyster shell powder) were used as treatment materials to reduce As. Industrial by-products were mixed with As-contaminated soils, in the ratio of 1%, 3%, 5% and 7% on the weight base of dried soil. After incubation, all samples showed the reduction of As concentration and it was expected that ZVI and steel refining slag were effective treatment materials to remove As among treatment materials used in batch test. In column tests, columns were made by acrylic with the dimension of diameter=10cm, height=100cm, thickness=1cm and these columns were filled with untreated soils and treated soils mixed with ZVI and steel refining slag(mixing ratio=3%). Distilled water was discharged into the columns with the velocity of 1 pore-volume/day. During test, pH, EC, Eh and As concentration were measured in the regular term(1 pore-volume). As a result, ZVI and steel refining slag were shown 93%, 62% reduction of As concentration respectively by comparison with untreated soils. Therefore, if ZVI and steel refining slag are used as treatment materials in As-contaminated soils, it is expected that the As concentration in soils is reduced effectively.

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홍조류, 갈조류, 녹조류를 이용한 바이오에탄올 생산 및 폐 해조류 슬러리의 중금속 생물흡착 (Ethanol Production from Red, Brown and Green Seaweeds and Biosorption of Heavy Metals by Waste Seaweed Slurry from Ethanol Production)

  • 선우인영;라채훈;권성진;허지희;김예진;김지우;신지호;안은주;조유경;김성구
    • KSBB Journal
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    • 제29권6호
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    • pp.414-420
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    • 2014
  • The seaweeds with high carbohydrate ratio Gelidium amansii, Saccharina japonica and Enteromorpha intestinalis were used as red, brown, and green seaweeds, respectively. Thermal acid hydrolysis, enzymatic saccharification and fermentation were carried out using those seaweeds to produce ethanol. The ethanol concentrations from red, brown and green seaweed were 14.8 g/L, 11.6 g/L and 9.9 g/L, respectively. After the production of ethanol, the seaweeds were reused to absorb heavy metal. The maximum biosorption ratio was Cu(II) (89.6%), Cr(III) (82.9%), Ni(II) (66.1%). Cu(II) had the highest affinity with 3 waste seaweeds. Red seaweed was verified the most effective substrates to both process.