• Title/Summary/Keyword: Heavy metals contamination

Search Result 472, Processing Time 0.038 seconds

Heavy Metal Contamination around the Abandoned Au-Ag and Base Metal Mine Sites in Korea (국내 전형적 금은 및 비(base)금속 폐광산지역의 중금속 오염특성)

  • Chon Hyo-Taek;Ahn Joo Sung;Jung Myung Chae
    • Economic and Environmental Geology
    • /
    • v.38 no.2 s.171
    • /
    • pp.101-111
    • /
    • 2005
  • The objectives of this study we to assess the extent and degree of environmental contamination and to draw general conclusions on the fate of toxic elements derived from mining activities in Korea. 인t abandoned mines with four base-metal mines and four Au-Ag mines were selected and the results of environmental surveys in those areas were discussed. In the base-metal mining areas, the Sambo Pb-Zn-barite, the Shinyemi Pb-Zn-Fe, the Geodo Cu-Fe and the Shiheung Cu-Pb-Zn mine, significant levels of Cd, Cu, Pb and Zn were found in mine dump soils developed over mine waste materials, tailings and slag. Furthermore, agricultural soils, stream sediments and stream water near the mines were severely contaminated by the metals mainly due to the continuing dispersion downstream and downslope from the sites, which was controlled by the feature of geography, prevailing wind directions and the distance from the mine. In e Au-Ag mining areas, the Kubong, the Samkwang, the Keumwang and the Kilkok mines, elevated levels of As, Cd, Cu, Pb and Zn were found in tailings and mine dump soils. These levels may have caused increased concentrations of those elements in stream sediments and waters due to direct dis-charge downstream from tailings and mine dumps. In the Au-Ag mines, As would be the most characteristic contaminant in the nearby environment. Arsenic and heavy metals were found to be mainly associated with sulfide gangue minerals, and mobility of these metals would be enhanced by the effect of oxidation. According to sequential extraction of metals in soils, most heavy metals were identified as non-residual chemical forms, and those are very susceptible to the change of ambient conditions of a nearby environment. As application of pollution index (PI), giving data on multi-element contamination in soils, over 1.0 value of the PI was found in soils sampled at and around the mining areas.

The Concentrations of Heavy Metals in Sediment Seawater and Oyster (Crassostrea gigas) in Coastal Region of Industrial Complex in Korea (한국 임해 공단 연안에서 퇴적물 해수 및 굴 (Crassostrea gigas)의 중금속 함량)

  • Lee, I.S.;B.j. Rho;J.I. Song;E.J. Kim
    • The Korean Journal of Ecology
    • /
    • v.19 no.3
    • /
    • pp.261-270
    • /
    • 1996
  • To investigate the degree of contamination from Korean coastal region, the concentrations of Cu, Pb, Zn and Cd in sediments, seawater and oyster (Crassostrea gigas) at Masan Bay, Onsan Bay, Daesan industrial complex and their control areas were analysed. Values for sediments, seawater and oyster in the industrial complex coastal region were higher than those in the control area except for seawater in Daesan. The values for dissolved phasc of Cu, Pb, Zn and Cd in seawater showed 0.3~1.75 ${\mu}g/l$, 0.013~0.12 ${\mu}g/l$, 0.20~6.14 ${\mu}g/l$ and 0.007~0.021 ${\mu}g/l$, respectively. The concentrations of Cu, Pb, Zn and Cd in sediments werd 12.0~47.8 ${\mu}g/g$, 6.16~59.5 ${\mu}g/g$, 43.0~230 ${\mu}g/g$ and 0.52~11.2 ${\mu}g/g$, respectively. The concentrations of Cu, Pb, Zn and Cd in oyster showed 12.1~85.6 ${\mu}g/g$, 0.267~1.48 ${\mu}g/g$, 1, 070~3, 250 ${\mu}g/g$ and 3.23~7.71 ${\mu}g/g$, respectively. The contents of heavy metals in oysters at industrial complex coastal region showed that they were not seriously contaminated compared with those of Mussel Watch (1992).

  • PDF

Heavy Metals in Sediments and Organisms from Tidal Flats along the Mokpo Coastal Area (목포연안 갯벌 및 서식생물에서의 중금속 함량)

  • 나춘기
    • Economic and Environmental Geology
    • /
    • v.37 no.3
    • /
    • pp.335-345
    • /
    • 2004
  • Total and extractable contents of heavy metals were measured in sediment and seafood from Bukhang and Boggil-ri tidal flats along the Mokpo coastal area, south-western part of Korean peninsular in order to assess the degree of metal pollution, metal bioavailability and metal hioaccumulation. The metal concentrations, except Pb were found to be greater than the background concentrations of sediments indicating the progress of cumulative contamination by anthropogenic origin of metals. The order of extractable metal concentrations in sediments were Mn(32-53 mg/kg)>Zn(14-42 mg/tg)>Cu(2.5-17.0 mg/kg)>Pb(2.4-6.8 mg/kg)>Cd(0.5-0.7 mg/kg). However, the amount of metals associated with extractable fraction of sediments were significantly high in Bukhang relative to Boggil-ri. Significant bioaccumulation of all metals, except Pb were observed in seaweed and benthos. The order of bioaccumulation of metals were: in concentration; all biota commonly, Mn(129-374 mg/kg)>Zn(19-106 mg/kg)>Cu(6-87 mg/kg)>Cd(4.6-7.6 mg/kg)>Pb(0.2-3.7 mg/kg), in BCF; Enteromorpha, Cd>Mn>Cu>Zn>Pb, Ilyoplax deschampsi, Cu>Cd>Mn>Zn>Pb, Urechis unicinctus, Cd>Zn>Mn>Cu>Pb. Some metal concentrations of Enteromorpha, especially Cu, Zn, weakly Pb in bukhang, Mn, Cd in boggili-ri, were correlate well with concentrations in sediment, indicating relatively more contaminated by the anthropogenic origin of metals in each tidal flat. The results clearly indicate that the seafood of bukhang, even of Boggili-ri known as clean area, are contaminated with metals.

Assessment of Pollution Characteristics of Surface Sediments from Andong Lake(I): Studies on Characteristics of Pollution of Sediments from Andong Dam (안동댐 퇴적물의 오염도 평가(I): 안동댐 퇴적물의 오염 특성 연구)

  • Kim, Young Hun;Park, Jae Chung;Shin, Tae Cheon;Kim, Jeong Jin
    • Korean Journal of Mineralogy and Petrology
    • /
    • v.33 no.4
    • /
    • pp.377-389
    • /
    • 2020
  • In this study, pollution characteristics were investigated for the Andong Dam sediments in the Nakdong River. Sediment samples were collected from the middle, left, and right points of the lake up to 40km upstream of the Andong Dam at intervals of about 5km by stratification and turnover period. In the case of nutrients and total organics such as loss of ignition, total nitrogen, and phosphorus, the degree of contamination is low, but heavy metals of arsenic and cadmium is very high. The contamination level of sediments in the dam area is higher than that of the branch of river and the control group, and concentration of chromium, copper, and lead are higher in the stratification period, and that of zinc is higher in turnover period. Arsenic, cadmium, manganese, and zinc showed contamination variation between upstream and downstream but chromium, copper, mercury, iron and lead didn't show the variation.

Characterization of Urease-Producing Bacteria Isolated from Heavy Metal Contaminated Mine Soil

  • Park, Min-Jeong;Yoon, Min-Ho;Nam, In-Hyun
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.47 no.6
    • /
    • pp.391-397
    • /
    • 2014
  • Acid mine drainage occurrence is a serious environmental problem by mining industry; it usually contain high levels of metal ions, such as iron, copper, zinc, aluminum, and manganese, as well as metalloids of which arsenic is generally of greatest concern. It causes mine impacted soil pollution with mining and smelting activities, fossil fuel combustion, and waste disposal. In the present study, three bacterial strains capable of producing urease were isolated by selective enrichment of heavy metal contaminated soils from a minei-mpacted area. All isolated bacterial strains were identified Sporosarcina pasteurii with more than 98% of similarity, therefore they were named Sporosarcina sp. KM-01, KM-07, and KM-12. The heavy metals detected from the collected mine soils containing bacterial isolates as Mn ($170.50mg\;kg^{-1}$), As ($114.05mg\;kg^{-1}$), Zn ($92.07mg\;kg^{-1}$), Cu ($62.44mg\;kg^{-1}$), and Pb ($40.29mg\;kg^{-1}$). The KM-01, KM-07, and KM-12 strains were shown to be able to precipitate calcium carbonate using urea as a energy source that was amended with calcium chloride. SEM-EDS analyses showed that calcium carbonate was successfully produced and increased with time. To confirm the calcium carbonate precipitation ability, urease activity and precipitate weight were also measured and compared. These results demonstrate that all isolated bacterial strains could potentially be used in the bioremediation of acidic soil contaminated by heavy metals by mining activity.

Analysis of Pathogenic Microorganism's Contamination and Heavy Metals on Kimchi Cabbage by Cultivation Methods in Korea (재배농법에 따른 국내산 배추의 위해미생물 및 중금속 오염평가)

  • Oh, Soh-Young;Nam, Ki-Woong;Yoon, Deok-Hoon
    • Journal of Food Hygiene and Safety
    • /
    • v.32 no.6
    • /
    • pp.500-506
    • /
    • 2017
  • Kimchi cabbage is one of the four major vegetable crops in Korea. The total annual production of kimchi cabbage, the main material of kimchi, was 20,559 tons in 2015. Kimchi cabbage is one of the majer crops produced by farmers which accounts for about 80% of the total leaf vegetable production in Korea. As the consumption of environmental-friendly agricultural products increases, food safety is one of the major public health concerns. We analyzed the biological hazards of kimchi cabbage produced by two types of cultivation methos such as organic farming and conventional farming using various culture media and microscopy. A total of 432 samples were analysed for presence of sanitary indicator microorganisms (aerobic plate count, coliform count, yeast & mold) and food-borne pathogens (Staphylococcus aureus, environmental Listeria, Bacillus cereus). The population of sanitary indicating microorganisms and food borne pathogens was under 5 Log CFU/g in all tested samples. The results of total microorganism numbers of leaf surface showed a positive correlation to those of soil samples. Additionally, we examined chemical factors such as pesticide residues and heavy metals in soil samples. All tested samples did not shown contamination levels higher than the standard limit.

Contamination Characteristics of Heavy Metals in Indoor, Outdoor and Playground of Schools in the Gochang-Gun, Chonbuk Province of South Korea (전북 고창지역 학교 실내외 환경의 중금속 오염 특성)

  • Kim, Yong-Hwan;Chung, Duk-Ho;Cho, Kyu-Seong
    • Journal of the Korean earth science society
    • /
    • v.27 no.1
    • /
    • pp.73-82
    • /
    • 2006
  • Dust samples were collected from 10 middle and high schools in the Gochang-Gun, Korea. Heavy metal concentrations were determined for the dry-deposited dusts from indoor and outdoor of classroom and playground of each sampling site. Concentrations of Cd, Cu, Pb and Zn in indoor's dusts were highly concentrated. Also concentrations of Cu, Ni, Pb and Zn in outdoor's dusts were highly concentrated. Concentrations of Cd, Cu and Zn in the dusts were much higher than the world average contents in soil and environmental orientation value. These levels are similar to those of the dust samples at middle schools and high schools located in Jeonju-city, Korea. Compared with concentrations of heavy metals in soils and dusts in Korea, the environment of indoor and outdoor of classroom is highly concentrated except for Cu, Zn. The concentrations of playground is less than that of residential dust and main road dust and playground in Jeonju-city. Playground dusts in 1 school exhibited the enhanced heavy metal pollution with a pollution index (Kloke, 1979) greater than 1.0, but indoor and outdoor dusts in 7 schools exhibited the enhanced heavy metal pollution with a pollution index (by Kloke) yester than 1.0.

Distribution of $NO_3\;^-,\;SO_4\;^{2-}$ and Heavy Metals in Some Urban-forest Soils of Central Korea (중부 지역 도시 자연녹지 토양중 $NO_3\;^-,\;SO_4\;^{2-}$ 및 중금속 분포)

  • Kim, Kye-Hoon;Park, Soon-Nam
    • Korean Journal of Environmental Agriculture
    • /
    • v.19 no.4
    • /
    • pp.351-357
    • /
    • 2000
  • This study was carried out to find out characteristics and contamination status of the urban-forest soils. Both topsoil (0-20 cm) and subsoil (40-60 cm) samples were collected from Namsan, Changdeok-palace, Seongjusan and Odaesan (control). The samples were analyzed for physicochemical properties, heavy metal (Cd, Cu, Pb, Zn) and anion $(NO_3\;^-,\;SO_4\;^{2-})$ contents. Soil pH of Odaesan was the highest followed by Namsan, Changdeok-palace and Seongjusan. The anion concentrations of the soil samples were in the order of Namsan, Seongjusan > Changdeok-palace > Odaesan. The relationships between soil pH and the anion concentrations showed highly significant negative correlation, which indicated acidification of soil due to air pollutants such as $NO_3\;^-$ and $SO_4\;^{2-}$ was going on. The heavy metal contents of the soils of urban-forest were higher than those of control. Heavy metal contents in the topsoil were higher than those in the subsoil. Since urban-forest soils were quite vulnerable to acidification and heavy metal accumulation due to chronic exposure to air pollutants such as automobile exhaust, a comprehensive countermeasure not to deteriorate urban-forest ecology must be prepared in the near future.

  • PDF

Assessing the Pollution Trend in Water and Sediments of Tancheon Down the Stream (탄천 상.하류의 하천수 및 퇴적물 오염도 연구)

  • Baek, Yong-Wook;Lee, Yong-Han;Kim, Hack-Kyu;Jung, Da-Un;An, Youn-Joo
    • Korean Journal of Ecology and Environment
    • /
    • v.43 no.1
    • /
    • pp.11-18
    • /
    • 2010
  • The contamination of a suite of heavy metals were evaluated in water and sediments of urban stream, Tancheon down the stream. Tancheon is a urban stream which goes all the way across the urban area where various pollution sources are present. The sixteen study sites from seven different areas were designated down the stream. The heavy metal levels of the streams were detected in the order of Zn>Cu>Ni>Pb>Cd>Cr>Sb. There was a difference in the relative order of the concentration ranking in lake sediments. There is a trend that the heavy metal levels are higher at the sites where the construction causes inflow of soil particles to stream. Toxicity tests using pore-water in sediments were conducted for samples collected in some study sites, and pore-water in one site was proven to be toxic to Japanes medaka (Oryzias latipes). The reason may be the fecal pollution rather than heavy metal effect. Strong odor was detected in the sediment whose pore-water samples showed ecotoxicity. We did not observed the increasing concentration of heavy metals down to stream since the soil texture varied in the stream area of our study. Further study is needed to find quantitative relations between the level of contamination and its eco-effect.

The Influence of Pore Water Contamination on the Cement Treated Sandy Soil (공극수 오염이 시멘트 고화처리된 사질토에 미치는 영향)

  • Yu, Chan
    • Magazine of the Korean Society of Agricultural Engineers
    • /
    • v.45 no.6
    • /
    • pp.144-152
    • /
    • 2003
  • Laboratory experiments were carried out to investigate the influence of pore water contamination on the treatment effect of sandy soil which was solidified by Portland cement. In the experiments, setting time of hydraulic cement that was mixed with contaminated mixing water was measured using Vicat equipment and observed the tendency of setting process with the kind of contaminants, organic or inorganic components. It was shown that organic contaminants of the mixing water affect largely on the initial setting process of hydraulic cement and inorganics, expecially heavy metals, did not affect on the initial setting process, otherwise it was appeared that setting time of the sandy soil that was contaminated with inorganic components was apparently faster than the sandy soil that did not include inorganic components even though organic concentrations was relatively low level (COD=200∼300) in the mixing water. The results of unconfined compression strength test (UCST) were well consistent with the results of Vicat equipment test.