• Journal of Industrial Technology
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• v.16
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• pp.169-174
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• 1996

Microstructural analyses of synthetic arsenic-containing heavy metal sludges solidified with Portland cement were performed. Heavy metal sludges containing 0.04M of cadmium, chromium, copper, lead, and arsenic were prepared by sodium hydroxide precipitation and successive vacuum filtration. The sludges mixed with cement were cured for 14 days. The solidified sample was characterized by 1) leaching test, 2) scanning electron microscopy and 3) X-ray diffractometry. Of the metals tested, only Pb concentration in the leachate exceeded the Korean regulatory limit. The level of lead in the leachate was as high as 10 times the regulatory limit. X-ray analysis suggested that the metal hydroxides might be present in complex or impure crystalline phases.

• Applied Chemistry for Engineering
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• v.34 no.1
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• pp.86-93
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• 2023

In this study, we investigated the various adsorption factors influencing the adsorption of heavy metal ions based on the study of the composition and physicochemical properties of scoria dispersed throughout Jeju Island. Analysis of the distribution characteristics of scoria samples collected from five areas of Jeju showed that reddish-brown-colored scoria were predominant. Analysis of scoria collected from Jeju Island showed that its mineral components are ordered as follows: SiO₂ > Al₂O₃ > Fe₂O₃ > CaO and MgO. The experimental data did not show a linear relationship in the pseudo-first-order adsorption kinetics. In contrast, a pseudo-second-order model yielded a positive linear relationship, and this model was subsequently used. It could be concluded based on an intraparticle diffusion model indicating linear relationships that the capture of metal ions on scoria is dominated by the primary adsorption step.

• Journal of Environmental Impact Assessment
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• v.20 no.5
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• pp.675-684
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• 2011

In nature, the overall effect of heavy metals on the biota can be influenced by a number of environmental factors like soil characteristics and air pollution by elevated $CO_2$. Pillbugs (Isopoda, Armadillium vulgare) take up heavy metals with their food and store them mainly in the vesicles of hepatopancreas. They accumulate certain metals, occur in relatively large numbers, are easily collected and identified, and provide sufficient material for analysis. The species are decomposing litter well and soil impurities into N and P. Therefore, it has been suggested that total body concentration of metals in pillbugs could be positively correlated to the levels of environmental exposure and that pillbugs could be used as biological indicators of metal pollution and global change by $CO_2$. The aim of the study is to determine effects of heavy metal concentrations in soil and elevated $CO_2$ on pillbugs' body accumulation of heavy metal and growth rate. In this study, the concentrations of six metals (Fe, Mg Cu, Zn, Pb, Cd) have been determined. Pillbugs (N=287) were collected at five sites during Jul-Aug, 2006. Cu and Zn concentrations in the body were much higher than in the soils(1.39-41.70 times). This indicated that bioaccumulation of some of the heavy metals were increasing in the food-chain. The high bioconcentration of lead in Sangam may be partly associated with reclaimed land uses.

• Journal of Soil and Groundwater Environment
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• v.16 no.6
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• pp.95-105
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• 2011

Total extraction method and environmental standards for heavy metals in soils were revised in regulation recently. In case of Area 3, as the law amended, the soil pollution level has gone up to 4 to 13 times higher depending on the type of heavy metal. In this study, it compares the properties of heavy metals of soil by sequential extraction and total extraction methods depending on the analysis method, using the soil around mine. In case of arsenic, the soil pollution level has gone up to 4 times higher, but 6 to 10 times in the sample soil. Also, according to the results of portability evaluation depending on the type of existence form of heavy metal it exists as residual form in mine waste rock, which is less likely to move, while it exists as migrated form in tailing. Therefore, it should be considered to evaluate the soil pollution and decide the contaminated bounds depending on the existence form of heavy metals on soil to restore the polluted soil.

• Journal of Environmental Science International
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• v.17 no.1
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• pp.57-66
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• 2008

The frequency analysis and the probability plot were applied to heavy metal contents of soils collected from the Goseong Cu mine area as a statistic method for the determination of the threshold value which was able to partition a population comprising largely dispersed heavy metal contents into the background and the anomalous populations. Almost all the heavy metal contents of soil showed a positively skewed distributions and their cumulative percentage frequencies plotted as a curved lines on logarithmic probability plot which represent a mixture of two or more overlapping populations. Total Cu, Pb and Cd data and extractable Cu and Pb data could be partitioned into background and anomalous populations by using the inflection in each curve. The others showed a normally distributed population or an largely overlapped populations. The threshold values obtained from replotted frequency distributions with the partitioned populations were Cu 400 mg/kg, Pb 450 mg/kg and Cd 3.5 mg/kg in total contents and Cu 40 mg/kg and Pb 12 mg/kg in extractable contents, respectively. The thresholds for total contents are much higher than the tolerable level of soil pollution proposed by Kloke(Cu 100 mg/kg, Pb 100 mg/kg, Cd 3 mg/kg), but those for extractable contents are not exceeded the worrying level of soil pollution proposed by Ministry of Environment(Cu 50 mg/kg, Pb 100 mg/kg). When the threshold values were used as the criteria of soil pollution in the study area, $9{\sim}19%$ of investigated soil population was in polluted level. The spatial distributions of heavy metal contents greater than threshold values showed that polluted soils with heavy metals are restricted within the mountain soils in the vicinity of abandoned mines.

• Environmental Analysis Health and Toxicology
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• v.10 no.3_4
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• pp.7-13
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• 1995

The most periodlengths($\tau$) of conidiation of Neurospora were shortened in the medium with Li$^+$, Rb$^+$, and Cs$^+$ under the blue or green light. The higher the concentration of the heavy metal elements are, the shorter the circadian lengths are. The largest differences between the maxima- and minima circadian lengths showed in the medium with LiCI, RbCl, and CsCI under the blue lights at 150 Lux, while the little differences of circadian lengths presented in 1 mM heavy metal elements at the 270Lux blue light. Li$^+$ under the blue light effected extremely much and in the order of Rb$^+$ and Cs$^+$ on the conidiation of Neurospora. Under the green lights at 270Lux, the smallest changes of the circadian lengths are resulted in the medium with heavy metal elements. The other way at the green light 150Lux, the conidiation is stimulated by lmM LiCI or RbCl for the average 0.71h and 0.29h longer than the periodlength of control 28.34h. The medium with Li$^+$ under the green light has less effect on the conidiation rhythm of Neurospora than with Rb$^+$ or Cs$^+$.

• Journal of Environmental Science International
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• v.29 no.7
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• pp.739-748
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• 2020

The characteristics of heavy metal ion (Ni²⁺, Zn²⁺, and Cr³⁺) adsorption by zeolite synthesized from Jeju scoria using the fusion and hydrothermal method, were studied. The synthetic zeolite was identified as a Na-A zeolite by X-ray diffraction analysis and scanning electron microscopy images. The equilibrium of heavy metal ion adsorption by synthetic zeolite was reached within 60 min for Ni²⁺ and Zn²⁺, and 90 min for Cr³⁺. The uptake of heavy metal ions increased with increasing pH in the range of pH 3-6 and the uptake decreased in the order of Cr³⁺ > Zn²⁺ > Ni²⁺. For initial heavy metal concentrations of 20-250 mg/L at nonadjusted pH, the adsoption of heavy metal ions was well described by the pseudo second-order kinetic model and was well fitted by the Langmuir isotherm model. The maximum uptake of heavy metal ions obtained from the Langmuir model, decreased in the order of Zn²⁺ > Ni²⁺ > Cr³⁺, differing from the effect of pH on the uptake, which was mainly based on the different pH of the solutions.

• Journal of Korean Society of Water Science and Technology
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• v.26 no.6
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• pp.43-51
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• 2018

In order to systematically and scientifically manage the organic and heavy metals against sediment at Daecheon Port, this study conducted particle composition, organic materials and heavy metals irradiation studies of sediments. Analysis of the grain size composition of sediments in the target study area showed the distribution characteristics of the mix of sand, silt and clay. That is, Station C (Stn. C) showed superior by fine-grained sediment, Station A and B (Stn. A and B) showed superior by coarse-grained sediment. The organic matter(COD, TOC, and IL) of Stn. C was appeared to be heavily polluted more than Stn. A and B. These data for the spatial properties in sediment showed that organic matter was related positively to the sediment silt-clay content. Also, in the case of heavy metals contamination in surface sediments, Stn. C was higher than Stn. A and B. Particularly, at the Stn. C, high organic matter concentration and C/N ratio value( >10) indicated that the sediment was composed highly of land-derived organic matter. From these results, it considered that the correlation analysis among to silt-clay, organic matter and heavy metal was found to have a good interrelationship.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.15 no.6
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• pp.217-221
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• 2005

The evaporation amounts of volatile Cd, Pb and Zn were characterized by measuring their total concentrations in the EAF dust-clay bodies with various mixing ratio and heat treatment temperature. TCLP test was conducted for evaluating the chemical stabilities of the heavy metal elements. Evaporation amounts and leaching concentrations of heavy metal components were strongly dependent on the mixing ratio and heat treatment temperature. The evaporation of the heavy metal components in EAF dust was effectively suppressed by increasing the clay content. The leaching concentrations of heavy metal components were decreased with increasing clay content and temperature. 20 wt% EAF dust-80 wt% clay sample shows nearly zero evaporation and leaching concentrations of heavy metal components. XRD analysis showed that peak intensities of major crystalline phases such as franklinite and quartz were decreased with increasing the heat treatment temperature which means that the stabilization mechanism of the heavy metals was related with the vitrification process of the $SiO_2$ in the clay.

• Journal of Environmental Health Sciences
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• v.27 no.1
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• pp.51-55
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• 2001

The pollution characteristics of water quality analysis and the heavy metal analysis of river sediment in the Western Nakdong river, and then a commercial tile using the polluted sediment was produced. The analytical results of the riverbed structure and the depth distribution in the Western Nakdong river were that Macdo Stream(site 2) was the deepest(13 ft). The analytical result of water quality showed that BOD was the highest in the Hogei Stream(site 6); COD, Syanduengchi Island(site 1);SS, Macdo Stream(site 2);T-N, Suanduengchi Island(site 1);T-P, Macdo Stream(site 2). Therefore the deeper the site was the higher the pollution concentration was. The result of heavy metal analysis of the river sediment was that Pb and Cr were the highest in Kangdong Bridge(site 9); Cd, Macdo Stream(site 2), so the deeper the site was the higher the pollution concentration was. The production of tile using the mixure of the polluted sediment and the raw material was successful, so the reuse of polluted sediment was possible.