• 제목/요약/키워드: Heat stability

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가스호환성 판정에 편리한 새로운 화염안정영역의 도시법의 제안 및 유용성 검토 (Proposal and Validation of a New Flame Stability Diagram to Gas Estimate Interchangeability)

  • 이창언;김종민;황철홍;김종현
    • 한국연소학회지
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    • 제13권3호
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    • pp.1-8
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    • 2008
  • A flame stability diagram in a partially premixed flame is typically expressed using the axis coordinates of heat input rate and equivalence ratio. These diagrams are inadequate for identifying changes in combustion conditions and flame stability when a reference fuel is substituted with other fuels under identical operating conditions. This study proposes a new type of diagram and validates it experimentally. In this new diagram, the axis coordinates are air flow rate and Wobbe fuel flow rate, defined as the fuel flow rate multiplied by the square root of the relative density. The diagram was validated in trials using various fuels, including $CH_4$, $C_{3}H_{8}$, and LFG-$C_{3}H_{8}$ mixed fuels, in a domestic gas-range and an gas interchangeability test burner. The results of these trials show that the new diagram can provide information useful for assessing gas interchangeability of combustion conditions and flame stability when one fuel is substituted with another under identical operating conditions.

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차량 안정성을 고려한 인휠모터 방식 연료전지 전기자동차용 회생제동 알고리즘 개발 (Development of Regenerative Braking Control Algorithm for In-wheel Motor Type Fuel Cell Electric Vehicles Considering Vehicle Stability)

  • 양동호;박진현;황성호
    • 유공압시스템학회논문집
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    • 제7권2호
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    • pp.7-12
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    • 2010
  • In these days, the researches about hybrid and fuel cell electric vehicles are actively performed due to the environmental contamination and resource exhaust. Specially, the technology of regenerative braking, converting heat energy to electric energy, is one of the most effective technologies to improve fuel economy. This paper developed a regenerative braking control algorithm that is considered vehicle stability. The vehicle has a inline motor at front drive shaft and has a EHB(Electo-hydraulic Brake) system. The control logic and regenerative braking control algorithm are analyzed by MATLAB/Simulink. The vehicle model is carried out by CarSim and the driving simulation is performed by using co-simulation of CarSim and MATLAB/Simulink. From the simulation results, a regenerative braking control algorithm is verified to improve the vehicle stability as well as fuel economy.

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각종 편성소재에 따른 스포츠양말의 위생성과 형태안정성에 관한 연구 (A Study of Sports Socks Varying Knitted Fabrics on Hygienic and stability Properties)

  • 이명자;김칠순
    • 복식문화연구
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    • 제7권5호
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    • pp.165-176
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    • 1999
  • The purpose of this study was to evaluate the effect of various knitted fabrics of sports socks on their properties of hygiene and stability. Seventeen men\`s sports socks to represent five groups with different fiber content, knit structure, yarn fineness, and finishing were used. Properties of hygiene and stability of socks were determined. The results were as follows ; 1. Evaluation of Water, vapor and heat transport properties in socks with varing fiber content showed that cotton 100% socks had the highest drop absorbency, wickability, water absorbency and water retention. Polypropylene 100% socks had an excellent wickability and moisture permeability. Acrylic blend socks had the highest thermal resistance. 2. The greatest knit stretch and knit growth of socks having lower power were found to be with cotton 100% socks had the lowest stretch. Acrylic blend socks had a excellent stretch but low fabric growth, which could give a good fir sensation during wear. 3. The commerical antimicrobial finished socks showed excellent durability after repeated cycles of laundering. 4. Length and width shrinkages were found in all laundered samples during initial cycles due to rearrangement by mechanical relaxation. Shrinkages showed no further changes and reached equilibriums after 5 cycles. Cotton 100% or cotton blend socks showed lower dimensional stability than other socks during fabric care.

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Stability and normal zone propagation in YBCO tapes with Cu stabilizer depending on cooling conditions at 77 K

  • Kruglov, S.L.;Polyakov, A.V.;Shutova, D.I.;Topeshkin, D.A.
    • 한국초전도ㆍ저온공학회논문지
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    • 제22권4호
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    • pp.14-19
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    • 2020
  • Here we present the comparative experimental study of the stability of the superconducting state in 4 mm YBCO tapes with copper lamination against local heat disturbances at 77 K. The samples are either directly cooled by immersing a bare YBCO tape into a liquid nitrogen pool or operate in nearly-adiabatic conditions when the tape is covered by a 0.6 mm layer of Kapton insulation. Main quench characteristics, i.e. minimum quench energies (MQEs) and normal zone propagation (NZP) velocities for both samples are measured and compared. Minimum NZP currents are determined by a low ohmic resistor technique eligible for obtaining V - I curves with a negative differential resistance. The region of transport currents satisfying the stationary stability criterion is found for the different cooling conditions. Finally, we use the critical temperature margin as a universal scaling parameter to compare the MQEs obtained in this work for YBCO tapes at 77 K with those taken from literature for low-temperature superconductors in vacuum at 4.2 K, as well as for MgB2 wires cooled with a cryocooler down to 20 K.

Effect of Cross-Linking Characteristic on the Physical Properties and Storage Stability of Acrylic Rubber

  • Seong-Guk Bae;Min-Jun Gim;Woong Kim;Min-Keun Oh;Ju-Ho Yun;Jung-Soo Kim
    • Elastomers and Composites
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    • 제58권3호
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    • pp.136-141
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    • 2023
  • Polyacrylic rubber (ACM) is well known for its excellent heat resistance and chemical stability. Additionally, its performance can be readily manipulated by modifying its functional groups, rendering it highly attractive to various industries. However, extreme climate changes have necessitated an expansion of the operating temperature range and lifespan of ACM products. This requires the optimization of both the compounding process and functional-group design. Hence, we investigated the relationship between the cross-linking system and mechanical properties of an ACM with a carboxylic cure site. The crosslink density is determined by chemical kinetics according to the structure of additives, such as diamine crosslinkers and guanidine accelerators. This interaction enables the manipulation of the scotch time and mechanical properties of the compound. This fundamental study on the correlation analysis between cross-linking systems, physical properties, and storage stability can provide a foundation for material research aimed at satisfying the increasingly demanding service conditions of rubber products.

Stability analysis in BWRs with double subdiffusion effects: Reduced order fractional model (DS-F-ROM)

  • Gilberto Espinosa-Paredes;Ricardo I. Cazares-Ramirez;Vishwesh A. Vyawahare;Erick-G. Espinosa-Martinez
    • Nuclear Engineering and Technology
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    • 제56권4호
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    • pp.1296-1309
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    • 2024
  • The aim of this work is to explore the effect of the double subdiffusion on the stability in BWRs. A BWR novel reduced order model with double subdiffusion effects: reduced order fractional model (DS-F-ROM) to describe the neutron and heat transfer processes was proposed for this study. The double subdiffusion was developed with a fractional-order two-equation model, and with different fractional-orders and relaxation times. The stability analysis was carried out using the root-locus method and change from the s to the W domain and were confirmed using the time-domain evolution of neutron flux for a unit step change in reactivity. The results obtained using the reduced fractional-order model are presented for different anomalous diffusion coefficient values. Results are compared with normal diffusion and P1 equations, which are obtained straightforwardly with DS-ROM when relaxation time tends to zero, and when the anomalous diffusion coefficient tends to one, respectively.

동결융해 심도를 고려한 암반사면의 안정성 해석에 관한 연구 (Stability Analysis of Rock Slope with Consideration of Freezing-Thawing Depth)

  • 백용
    • 지질공학
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    • 제11권1호
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    • pp.13-23
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    • 2001
  • 도로나 철도 변에 나타나는 암반사면은 외부 기온에 영향을 받아 동절기부터 이른봄에 걸쳐 동결융해작용을 반복해서 받는다. 본 연구의 목적은 불연속성 암반이 동결융해작용을 반복하여 받을 경우 열화현상을 겪게 되고 이에 따른 암반의 안정성이 어떻게 변화되는가를 해석한다. 해석방법으로는 균질화법을 이용하여 불연속성 암반의 강도특성을 밝히고 파괴기준으로는 드러커-플래커 기준을 이용한다. 또한 실제 암석의 열화특성은 응회암을 채취하여 실내 동결융해실험에 의하여 열화특성을 정량화 하여 암반의 안정성 해석의 기초 자료로 이용한다. 현장사면에서 동결융해에 의한 열화의 깊이를 추정하기 위하여 일차원 열전도 방정식을 이용하여 온도에 영향을 받는 깊이를 구한다. 모델 사면의 동결융해 깊이를 결정한 후 모델 암반사면에서 암반의 강도 값의 변화양상을 해석한다. 암반의 작용하는 외력은 자중에 의한 중력만이 작용한다고 가정하고 안전율 해석을 실시한다. 그 결과 암반의 안정성 변화양상을 정량적으로 분석한다. 대상으로 하는 두 도시의 경우 동결융해 영향을 받는 깊이는 1.0m 내외 였으며 10년 경과 후에는 암반의 붕괴 조짐을 나타나는 것을 추측할 수 있다.

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분리 강남콩 단백질의 유화특성에 관한 연구 (A study of the Emulsifying Properties of Kidney Bean Protein Isolate)

  • 최희령;손경희;민성희
    • 한국식품조리과학회지
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    • 제5권2호
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    • pp.9-17
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    • 1989
  • This study was carried out in order to study the emulsifying properties of kidney bean protein isolate. Kidney bean protein isolate was tested for the purpose of finding out the effect of pH, addition of NaCl, and heat treatment on the solbulity and emulsion capacity, emulsion stability, surface hydropobicity and emulsion viscosity. The results were summarized as follows. 1 The solubility of kidney bean protein isolate was affected by pH and showed the lowest value at pll 4.5 which is isoelectric point of kidney bean isolate. When the kidney bean protein isolate was heated, the highest value observed at pH 2 and pH 7 was 96.11%, 97.41% respectively. 2. The emulsion capacity of kidney bean protein isolate was not significantly different with each pH. With addition of NaCl, emulsion capacity decreased steadily. When heated thr highest value observed at pH 2 and pH 7 was 82.91 ml oil/100 mg protein ($60^{\circ}C$), 82.08 m1 oil/100 mg protein ($80^{\circ}C$) respectively. 3. The emulsion stability was significantly higher at pH 4.5 than that of pH 2 and pH 7 (p 0.05) When NaCl was added, emulsion stability was generally increased after 2hrs. When heated, the highest value observed at pH 2 and pH 7 was 21.25% ($80^{\circ}C$),23.7%($100^{\circ}C$) respectively after 2hrs. 4. Surface hydrophobicity increased sharply as 0.2 M NaCl was added to pH 4.5. When heated, the surface hydrophobicity increased as the temperature increased. 5. The highest value of emulsion viscosity was observed at pH 4.5 and pH 7 when 0.2 M NaCl was added. Under heat treatment, the highest value was 48,000 cps at pH 4.5 ($40^{\circ}C$). In the case of pH 7, the highest value was 105,000 cpa at $100^{\circ}C$.

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Stability of Soybean Isoflavone Isomers According to Extraction Conditions

  • Choi, Yeon-Bae;Kim, Kang-Sung
    • 한국환경보건학회지
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    • 제31권6호
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    • pp.498-503
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    • 2005
  • Stability of soybean isoflavone isomers according to extraction conditions such as temperature, pH, and extracting solvents was investigated. Heating induced three chemical reactions to occur for malony1 derivatives of isoflavones, namely decarboxylation of malony1 groups into acety1 derivatives, deesterification of malony1 residues, and hydrolysis of $\beta$-glycosidic bonds. Among the twelve isoflavone isomers, change in concentrations of acety1glycosides were most pronounced: Acety1 derivatives were present only in trace amounts in unheated hypocotyls, but the content increased dramatically during heating. As for the glycosides, concentrations of daidzin and glycitin increased due to heat treatment, though that of genistin remained almost unchanged. Heat decomposition rates and the patterns differed among the three malony1 derivatives. After 120 min at $80^{circ}C$, the relative concentrations of daidzin, glycitin and genistin were increased from $9.2\%$, $12.4\%$ and $3.3\%$ to $19.3\%$, $21.9\%$ and $6.2\%$, respectively. When crude isoflavones were solubilized in glycine buffer (pH 10.0) and incubated at $80^{circ}C$, deesterification occurred faster than at pH 7.0. When the pH of isoflavone solution was increased, the malony1glycosides were hydrolyzed to their respective glycosides at increased rate. Both acetyl and aglycone forms were unchanged and only de-esterification reactions occurred. At the acidic pH, malonylglycosides were much stable both at 60 and $80^{circ}C$. However at pH 10, $80^{circ}C$ and 1 hr, $75-80\%$ of malonylglycosides were transformed to their deesterified glycosides. When isoflavones were extracted with $60\%$ aqueous ethanol at $60^{circ}C$, isoflavone isomers were stable and the deesterification reactions did not occur in these conditions. However, at $80^{circ}C$ deesterification of malonyiglycosides occurred significantly with $15-20\%$ of malonylglycosides being hydrolyzed into their respective glycosides. This experiment showed that malonylglycosides undergo decomposition when heated or exposed to alkaline conditions. Also, aqueous ethanol was preferred to aqueous methanol as solubilizing media for obtaining extract with minimum degradation of malonylglycosides.

Hsp90을 이용한 유기용매에서의 과산화효소 안정화 연구 (Stabilization of HRP Using Hsp90 in Water-miscible Organic Solvent)

  • 정자희;최유성;송승훈;유영제
    • Korean Chemical Engineering Research
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    • 제44권1호
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    • pp.92-96
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    • 2006
  • 유기용매에서 효소를 이용하면 다양한 선택적 반응을 쉽게 수행할 수 있어 산업적 적용 가능성이 매우 높지만, 효소의 안정성 저하는 아직까지 큰 문제 중의 하나로 남아있다. 유기용매에서 효소 반응시 효소의 실활 원인과 효소의 안정화 방법 연구를 위하여 단백질의 folding에 관여하는 molecular chaperone의 일종인 heat-shock protein Hsp90을 이용하여, 대표적인 유기용매 반응시스템에서의 과산화효소 HRP 안정성 향상 연구를 수행하였다. 그 결과 Hsp90은 30% DMSO, 30% 및 50% dioxane 완충용액에서 HRP의 실활 방지 효과를 보였고, 실활된 효소의 재생에도 탁월한 효과를 보였다. 그리고 형광분석과 CD(circular dichroism)에 의한 구조분석을 수행하여 Hsp90이 유기용매에 의해 unfolding되어 있는 효소를 다시 refolding하는 데 기여함을 알았다.