• 열처리공학회지
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• 제23권4호
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• pp.198-204
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• 2010

Modified 9Cr-1Mo steels possess excellent high-temperature mechanical properties and are widely used in energy conversion industries. However, in-service materials degradation, such as softening, carbide-induced embrittlement, temper embrittlement, etc., can take place during long-term operation. Evolution of microstructure due to service exposure to high temperature has a strong effect on the performance of heat resistant steels. In case of modified 9Cr-1Mo steels, precipitation of $Fe_2Mo$-type laves phases and coarsening of $M_{23}C_6$-type carbides are the primary cause of degradation of mechanical properties such as toughness, hardness, tensile strength and creep resistance. This study was aimed at finding reliable parameter for assessing the integrity of modified 9Cr-1Mo steels. Characteristic parameters were attained between mechanical and ultrasonic properties.

• 폴리머
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• 제29권1호
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• pp.96-101
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• 2005

PTFE 및 PFA 등의 불소수지는 최대 연속 사용 온도가 260$^{\circ}C$에 달하는 고온 내열성 고분자 소재로서, 본 연구에서 수행된 280 $^{\circ}C$, 7주 간의 열노화에 의해서도 충분한 열적 안정성이 유지됨을 관측하였다. 그러나 기계적 강도, 융점 및 열분해 개시 온도 등의 소재적 물성이 유지됨을 의미하는 상기한 열적 안정성은 본 연구에서 수행된 코팅막으로서의 표면접촉각, 미세 모폴로지, 내스크래치성 분석에 의한 방법을 기준하면 충분하지 못하다는 것이 확인 되었다. 공기 치환율이 제어되는 기어식 노화시험기로 진행된 불소수지 코팅막의 280 $^{\circ}C$ 열노화에 대한 분석의 결과는 심각한 표면 모폴로지의 손상과 금속기재에 대한 접착력의 손실을 지적하고 있다.

• 대한기계학회논문집A
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• 제22권1호
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• pp.73-79
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• 1998

The development of a new material which should be continuously usable under severe environment of very high temperature has been urgently requested. The conventional thermal barrier coating(TBC) is a two layer coating, but a composition and a microstructure of functionally graded material(FGM) are varied continuously from place to place in ways designed to provide it with the maximum function of mitigating the induced thermal stress. The purpose of this study is to evaluate the heat-resistant characteristics by thermal shock of laser and furnace heating. The fracture behaviors of non-FGM(NFGM) and FGM were investigated based on acoustic emission(AE) technique during thermal shock test. Therefore, it can be concluded that FGM gives higher thermal resistance compared to NFGM by AE signal and fracture surface analysis.

• 한국안전학회지
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• 제34권4호
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• pp.1-5
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• 2019

In the field of combined cycle power generation, thermal barrier coating(TBC) protects the super-heat-resistant alloy, which forms the core component of the gas turbine, from high temperature exposure. As the turbine inlet temperature(TIT) increases, TBC is more important and durability performance is also important when considering maintenance cost and safety. Therefore, studies have been made on the fabrication method of TBC and super-heat-resistant alloy in order to improve the performance of the TBC. In recent years, due to excellent properties such as high temperature creep resistance and high temperature strength, turbine blade material have been replaced by a single crystal superalloy, however there is a lack of research on TBC applied to single crystal superalloy. In this study, to understand the isothermal degradation performance of the TBC applied to the single crystal superalloy, isothermal exposure test was conducted at various temperature to derive the delamination life. The growth curve of thermally grown oxide(TGO) layer was predicted to evaluate the isothermal degradation performance. Also, microstructural analysis was performed by scanning electron microscope(SEM) and energy dispersive X-ray spectroscopy (EDS) to determine the effect of mixed oxide formation on the delamination life.

• 콘크리트학회논문집
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• 제25권5호
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• pp.497-508
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• 2013

이 논문에서는 화재 발생에 따른 구조물의 성능 변화를 평가하기 위한 철근콘크리트 부재의 수치해석모델이 제안되었다. 화재 발생 시 유발되는 전도, 대류 및 복사열의 효과를 고려한 비정상 열전달 해석을 수행하였으며 이를 통해 단면 내 온도분포를 결정하였다. 또한, 적층섬유단면을 적용하여 온도증가로 인해 단면 내 위치에 따라 달라지는 재료의 비선형성을 고려하였다. 이 때, 온도변화에 따라 유발되는 열팽창 변형률, 비정상상태 변형률, 크리프 변형률 등의 비역학적 변형특성을 단면 내 각 섬유에 대해 고려함으로써 화재 발생 시의 극심한 온도증가를 고려한 비선형 해석을 수행하였다. 제안된 해석모델의 타당성을 입증하기 위하여 철근콘크리트부재의 표준화재실험으로부터 얻어진 실험결과와 해석결과를 비교하였으며, 특히, 화재 시간에 따른 저항능력의 변화를 살펴봄으로써, 철근콘크리트 부재의 거동특성을 평가하고 이를 설계규준에서 제시하는 단면 및 저항능력과 비교하였다.

• 한국화재소방학회논문지
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• 제34권2호
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• pp.7-13
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• 2020

경질 폴리우레탄(Polyurethane) 폼(Foam)의 난연 성능을 개선하기 위하여 외부에 물유리를 코팅하였다. 무기질인 물유리 코팅층이 적용된 우레탄폼의 콘칼로리메터의 열방출율(Heat release rate)은 급격히 감소하였다. 폴리우레탄 표면에 코팅된 물유리는 화염에 노출되었거나 가열되었을 때 유리화 반응과 미 탈출 수분에 의한 발포현상으로 인해 유리질 폼을 형성하게 된다. 폴리우레탄 폼 위에 형성된 유리질 폼은 단열층이 되어 10 min 이상 폴리우레탄 폼의 연소를 억제하였다. 이러한 결과에 따라서 물유리는 경질 폴리우레탄 폼의 난연 특성을 개선할 수 있음을 확인하였다.

• Tribology and Lubricants
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• 제33권1호
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• pp.15-22
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• 2017

Because the running speed of vehicles is increasing and a shorter braking distance is required, high heat-resistant brake pads are needed to satisfy the requirements of customers and car makers. In the near future, hazardous materials such as Cu, Cr, Zn, and Sb will be restricted from use in friction materials. Ceramic composites reinforced by carbon fibers are good candidates for eco-friendly friction materials. In this study, we develop ceramic composite friction materials. The friction materials are composed of carbon fibers, Si, SiC, graphite, and phenol resin and are prepared by hot forming and heat treatment at high temperatures. The density, void ratio, and compressive strength are $1.59-1.66g/cm^3$, 16.6-20, and 70-90 MPa, respectively. Friction and wear tests are performed using a pin-on-plate-type reciprocating friction tester at 25, 100, and $200^{\circ}C$. The counterpart material is a CrMoV steel extracted from a KTX brake disc. Friction coefficient, wear amount, and wear mechanism are measured and examined. We determine that the friction coefficients depend on the temperature and the fluctuation of the friction coefficients is larger at higher temperatures. The amount of wear increases with the surface temperatures of the specimens. The tribological properties of the developed composites are similar to those of a Cu-based sintered friction material. Through this study, it is confirmed that ceramic composite materials can be used as friction materials.

• 대한기계학회논문집 C: 기술과 교육
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• 제4권2호
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• pp.101-109
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• 2016

발전소 내열강의 물성치는 고온 가동시간이 누적됨에 따라 열시효의 영향을 받는다. 본 연구에서는 제 4 세대 원자력시스템의 재료로 널리 채택되고 있는 Mod.9Cr-1Mo (ASME Grade 91)강을 대상으로 항복강도, 인장강도 및 파괴거동에 열시효가 미치는 영향에 대해 조사 및 분석하였다. 국내에서 가동 중인 초초임계(USC) 화력발전소의 배관계통에서 채취한, 73,716 시간의 가동 이력을 겪은 Gr.91 강 재료가 재료 실험을 위해 사용되었고, 동 시험결과와 가동 이력을 겪지 않은 신재의 시험결과를 비교 분석하였다. 또한 ASME 코드의 물성치와 RCC-MRx 의 물성치와 비교 분석하였고, 이들 설계기술기준 물성치의 보수성은 신재 및 가동 이력을 겪은 재료의 시험결과와 비교 분석을 통해 정량화하였다.

• Corrosion Science and Technology
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• 제9권5호
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• pp.187-195
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• 2010

Hyper duplex stainless steels have been developed in Korea for the purpose of application to the seawater system of Korean nuclear power plants. This system supplies seawater to cooling water heat exchanger tubes, related pipes and chlorine injection system. In normal operation, seawater is supplied to heat exchanger through the exit of circulating water pump headers, and the heat exchanged sea water is extracted to the discharge pipes in circulating water system connected to the circulating water discharge lines. The high flow velocity of some part of seawater system in nuclear power plants accelerates damages of components. Therefore, high strength and high corrosion resistant steels need to be applied for this environment. Hyper duplex stainless steel (27Cr-7.0Ni-2.5Mo-3.2W-0.35N) has been newly developed in Korea and is being improved for applying to nuclear power plants. In this study, the physical & mechanical properties and corrosion resistance of newly developed materials are quantitatively evaluated in comparative to commercial stainless steels in other countries. The properties of weld & HAZ (heat affected zone) are analyzed and the best compositions are suggested. The optimum conditions in welding process are derived for ensuring the volume fraction of ferrite(${\alpha}$) and austenite(${\gamma}$) in HAZ and controlling weld cracks. For applying these materials to the seawater heat exchanger, CCT and CPT in weldments are measured. As a result of all experiments, it was found that the newly developed hyper duplex stainless steel WREMBA has higher corrosion resistance and mechanical properties than those of super austenitic stainless steels including welded area. It is expected to be a promising material for seawater systems of Korean nuclear power plants.

• 한국건설순환자원학회논문집
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• 제5권2호
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• pp.83-90
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• 2010

As a reinforced fabric, asbestos has been utilized as a fire-resistant material as it has a superior flexural stiffness and heat resistance up to $1500^{\circ}C$. However, due to its harmfulness, its use has been prohibited recently and the even the installed asbestos materials are being repaired or supplemented if there is a concern about flying. Asbestos is mainly used for construction panels as a reinforced fabric and coating materials to ensure the fire-resistance of steel frames. Asbestos was used as fire-resistant materials for steel frames until 1991 and then prohibited as Act on Industrial Safety and Health limits the concentration of asbestos in the air. Classified as a designated waste according to Act on Waste Control, asbestos must be buried if there is no possibility of flying (panel-type materials) or cement-solidified and then buried if there is a possibility of flying (spray coating material) In general, it is required that a new waste landfill include a certain landfill facility for designated waste, but in reality there is an absolute storage of landfill facilities for designated waste as they only install facilities of the size required by the regulations. This could result in the 2nd environmental pollution as they cannot process asbestos wastes which will be generated in large volume in the future. This study explores a method that melts asbestos wastes at $700^{\circ}C$ rather than cement-solidifying the waste asbestos from construction sites, especially asbestos-containing spray coating. The study results showed that there was no change in the composition and shape even though asbestos wastes was melted at $1300^{\circ}C$, but there was a change for the specimen which was process in advance for low temperature melting and then melt at $900^{\circ}C$.