• Title/Summary/Keyword: Heat rate

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Thermophilic Biohydrogen Production from Glucose with a Long-term Operation of CSTR (CSTR의 장기운전을 통한 포도당으로부터의 고온 수소생산)

  • Ahn, Yeong-Hee;Oh, You-Kwan;Park, Sung-Hoon
    • KSBB Journal
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    • v.20 no.6
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    • pp.425-430
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    • 2005
  • Thermophilic $H_2$ was produced for 1 year using a bench-scale continuous stirred tank reactor(CSTR). The CSTR was inoculated with anaerobically digested sludge after heat treatment and fed with a glucose-based medium. The reactor showed relatively short start-up period(30 days) and high maximal $H_2$ yield(2.4 mol $H_2/mol$ glucose). Keeping pH 5.0 or less suppressed methanogenic activity. Bacteria affiliated with Thermoanaerobacterium thermosaccharolyticum kept being dominant from approximately 40 days as determined by DGGE. Environmental perturbation(pH or temperature) caused the decrease of biomass concentration in the reactor and the instability of reactor performance, $H_2$ production rate and $H_2$ yield. The unstable performance was accompanied with high concentration of lactate in the effluent. Taken together, the poor recovery of CSTR after perturbations could be partly explained by low biomass concentration and/or metabolic shift of the major population in the CSTR.

The Cycling Performance of Graphite Electrode Coated with Tin Oxide for Lithium Ion Battery (리튬이온전지용 주석산화물이 도포된 흑연전극의 싸이클 성능)

  • Kang, Tae-Hyuk;Kim, Hyung-Sun;Cho, Won-Il;Cho, Byung-Won;Ju, Jeh-Beck
    • Journal of the Korean Electrochemical Society
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    • v.5 no.2
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    • pp.52-56
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    • 2002
  • Tin oxide was coated on graphite particle by sol-gel method and an electrode with this material having microcrystalline structure for lithium ion battery was obtained by heat treatment in the range $400-600^{\circ}C$. The content of tin oxide was controlled within the range of $2.25wt\%\~11.1wt\%$. The discharge capacity increased with the content of tin oxide and also initial irreversible capacity increased. The discharge capacity of tin oxide electrode showed more than 350 mAh/g at the initial cycle and 300 mAh/g after the 30th cycle in propylene carbonate(PC) based electrolyte whereas graphite electrode without surface modification showed 140 mAh/g. When the charge and discharge rate was changed from C/5 to C/2, The discharge capacity of tin oxide and graphite electrode showed $92\%\;and\;77\%$ of initial capacity, respectively. It has been considered that such an enhancement of electrode characteristics was caused because lithium $oxide(Li_2O)$ passive film formed from the reaction between tin oxide and lithium ion prevented the exfoliation of graphite electrode and also reduced tin enhanced the electrical conduction between graphite particles to improve the current distribution of electrode.

Selection of Acid-tolerant and Hetero-fermentative Lactic Acid Bacteria Producing Non-proteinaceous Anti-bacterial Substances for Kimchi Fermentation (비단백질성 항균물질을 생산하는 김치발효용 내산성 Hetero 발효형 유산균주 선발)

  • Kim, Hye-Rim;Lee, Jong-Hoon
    • Microbiology and Biotechnology Letters
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    • v.41 no.1
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    • pp.119-127
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    • 2013
  • Twenty-three strains of Leuconostoc species and 45 strains of Weissella species inhibiting the growth of Lactobacillus sakei, one of the most populous lactic acid bacteria in over-ripened kimchi, were isolated from kimchi in our previous study. Among these hetero-fermentative 68 strains, Leuconostoc mesenteroides CK0128, Weissella cibaria CK0633, and W. cibaria KK0797 exhibited a relatively high survival rate in MRS medium, which was adjusted to pH 4.3 using an acid mixture consisting of acetic and lactic acids, and produced a large amount of exopolysaccharides. The culture supernatants of 3 strains were fractionated by a molecular weight cutter and lyophilized. The fractions with a molecular weight smaller than 3,000 Da showed antagonistic activity against Staphylococcus aureus and Lb. sakei. The anti-bacterial substances were very stable to heat treatments ($121^{\circ}C$, 15 min) and active at acidic conditions below pH 5. ${\alpha}$-Amylase, lipase, and proteolytic enzymes (proteinase K and pepsin) did not affect their activities. These non-proteinaceous anti-bacterial substances inhibited the growth of several food pathogens.

A numerical study on the dispersion of the Yangtze River water in the Yellow and East China Seas

  • Park, Tea-Wook;Oh, Im-Sang
    • Journal of the korean society of oceanography
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    • v.39 no.2
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    • pp.119-135
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    • 2004
  • A three-dimensional numerical model using POM (the Princeton Ocean Model) is established in order to understand the dispersion processes of the Yangtze River water in the Yellow and East China Seas. The circulation experiments for the seas are conducted first, and then on the bases of the results the dispersion experiments for the river water are executed. For the experiments, we focus on the tide effects and wind effects on the processes. Four cases of systematic experiments are conducted. They comprise the followings: a reference case with no tide and no wind, of tide only, of wind only, and of both tide and wind. Throughout this study, monthly mean values are used for the Kuroshio Current input in the southern boundary of the model domain, for the transport through the Korea Strait, for the river discharge, for the sea surface wind, and for the heat exchange rate across the air-sea interface. From the experiments, we obtained the following results. The circulation of the seas in winter is dependent on the very strong monsoon wind as several previous studies reported. The wintertime dispersion of the Yangtze River water follows the circulation pattern flowing southward along the east coast of China due to the strong monsoon wind. Some observed salinity distributions support these calculation results. In summertime, generally, low-salinity water from the river tends to spread southward and eastward as a result of energetic vertical mixing processes due to the strong tidal current, and to spread more eastward due to the southerly wind. The tide effect for the circulation and dispersion of the river water near the river mouth is a dominant factor, but the southerly wind is still also a considerable factor. Due to both effects, two major flow directions appear near the river mouth. One of them is a northern branch flow in the northeast area of the river mouth moving eastward mainly due to the weakened southerly wind. The other is a southern branch flow directed toward the southeastern area off the river mouth mostly caused by tide and wind effects. In this case, however, the tide effect is more dominant than the wind effect. The distribution of the low salinity water follows the circulation pattern fairly well.

A New process for the Solid phase Crystallization of a-Si by the thin film heaters (박막히터를 사용한 비정질 실리콘의 고상결정화)

  • 김병동;정인영;송남규;주승기
    • Journal of the Korean Vacuum Society
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    • v.12 no.3
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    • pp.168-173
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    • 2003
  • Recently, according to the rapid progress in Flat-panel-display industry, there has been a growing interest in the poly-Si process. Compared with a-Si, poly-Si offers significantly high carrier mobility, so it has many advantages to high response rate in Thin Film Transistors (TFT's). We have investigated a new process for the high temperature Solid Phase Crystallization (SPC) of a-Si films without any damages on glass substrates using thin film heater. because the thin film heater annealing method is a very rapid thermal process, it has very low thermal budget compared to the conventional furnace annealing. therefore it has some characteristics such as selective area crystallization, high temperature annealing using glass substrates. A 500 $\AA$-thick a-Si film was crystallized by the heat transferred from the resistively heated thin film heaters through $SiO_2$ intermediate layer. a 1000 $\AA$-thick $TiSi_2$ thin film confined to have 15 $\textrm{mm}^{-1}$ length and various line width from 200 to 400 $\mu\textrm{m}$ was used as the thin film heater. By this method, we successfully crystallized 500 $\AA$-thick a-Si thin films at a high temperature estimated above $850^{\circ}C$ in a few seconds without any thermal deformation of g1ass substrates. These surprising results were due to the very small thermal budget of the thin film heaters and rapid thermal behavior such as fast heating and cooling. Moreover, we investigated the time dependency of the SPC of a-Si films by observing the crystallization phenomena at every 20 seconds during annealing process. We suggests the individual managements of nucleation and grain growth steps of poly-Si in SPC of a-Si with the precise control of annealing temperature. In conclusion, we show the SPC of a-Si by the thin film heaters and many advantages of the thin film heater annealing over other processes

Microstructures and Mechanical Properties of GTD 111DS Welds by $CO_2$ Laser Welding ($CO_2$ 레이저를 이용한 GTD111DS 초합금 용접부의 미세조직과 기계적 성질)

  • Lee, Tack-Woon;Yang, Sung-Ho;Kim, Sang-Hun
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.108-108
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    • 2009
  • Precipitation hardening nickel base alloys strengthened by intermetallic compounds are extensively used to manufacture on the components of the hot section of gas turbine engines. To ensure structural stability and maintenance of strength properties for a long time, nickel alloys are normally subjected to complex alloying with elements to form ${\gamma}'$(gamma prime). Such alloys have a limited weldability, are normally welded in high temperature. However, laser welding have a merit that applies in room temperature as easy control of welding parameter and heat input. In this study, $CO_2$ laser welding is applied on STS304 plate with good ductility and precipitation hardening nickel base alloy (GTD111DS) used blade material. Also, several welding parameters are applied on powder, power and travel speed. There are no cracks in Rene 80 and IN 625 powder when STS304 plate is used. But IN 625 powder has no cracks and Rene 80 have some cracks in welds with GTD111DS substrate. Adjusting of welding parameter is tried to apply Rene 80 having a good strength compare to IN 625. In the result of adjusted welding parameter, optimized welding parameters are set with low power, low feed rate and high welding speed. Tensile strength of GTD111DS substrate with Rene 80 powder is same and over than the one of base metal in room temp and high temp($760^{\circ}C$).

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Improving the Corrosion Resistance of Cold-Rolled Carbon Steel by Treatment with a Hybrid Organic/Inorganic Coating Solution (유/무기 하이브리드 코팅액에 의한 냉간압연강판의 내식특성)

  • Kim, Jung-Ryang;Choi, Chang-Min;Nam, Ki-Woo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.4
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    • pp.405-412
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    • 2012
  • In the past, a very popular way to reduce the corrosion rate of zinc was the use of chemical conversion layers based on $Cr^{+6}$. However, the use of chromium salts is now restricted because of environmental protection legislation. Previous research investigated the optimum corrosion resistance of galvanized steel treated with an organic/inorganic solution containing Si. The result showed that the optimum corrosion resistance occurred by heat treatment of $190^{\circ}C$ in 5 min. In this study, one organic and three hybrid organic/inorganic coating solutions were applied to cold-rolled (CR) carbon steel. The coatings were then evaluated for corrosion resistance under a salt spray test. The coating solutions examined in this study consisted of urethane-only, urethane-Si, urethane-Si-Ti, and urethane-Si-Ti-epoxy. The results of the 7 h salt spray test showed that the urethane-Si-Ti and urethane-Si-Ti-epoxy coating solutions had superior corrosion resistance on CR steel.

Method for Preventing Asphyxiation Accidents by a CO2 Extinguishing System on a Ship (선박 내 CO2 소화설비에 의한 질식사고 방지 기법)

  • Ha, Yeon-Chul;Seo, Jung-Kwan;Hwang, Jun-Ho;Im, Kichang;Ryu, Sang-Hoon
    • Fire Science and Engineering
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    • v.29 no.6
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    • pp.57-64
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    • 2015
  • Carbon dioxide extinguishing systems are broadly used for onshore and offshore fire accidents because of excellent performance and low cost. However, there is risk with carbon dioxide systems, which have caused many injuries and deaths by suffocation associated with industrial and marine fire protection applications. In this study, a numerical analysis was performed to predict the fire suppression characteristics of a carbon dioxide system in the compressor room of ships. A double protection safety system is suggested to prevent suffocation accidents from carbon dioxide extinguishing systems. Four scenarios were selected to study the variation of the heat release rate, maximum temperature, a $CO_2$ and $O_2$ mole fraction, and fire suppression characteristics with the carbon dioxide system. The importance of proper design is suggested for a ventilation system in the compressor room of ships.

A Study on Fire Performance Evaluation of EIFS on Anti-Flaming Finish by Cone Calorimeter Test (콘칼로리미터에 의한 외단열시스템의 방염 화재성능평가를 위한 연구)

  • Min, Se-Hong;Sun, Ju-Seok;Kim, Sang-Chul;Choi, Yong-Mook;Lee, Seok-Ki
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.106-111
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    • 2012
  • In this study, EIFS (Exterior insulation finish system) of exterior cladding was applied Cone calorimeter test to confirm the effect of flame retardant. As a results, the initial ignition points in accordance with the coated form and concentration of the flame retardant was delayed. But flame resistant treatment of EIFS cladding to control the fire will not affect confirmed that. In addition, EIFS that uses high-density and low-density due to difference in the density of the impact of the fire was no difference. The exterior of the ignition experiment occurred before and after 40 seconds, heat release rate to 100 seconds appears to occur about 90 % compared with the other exterior wall materials, the initial fire spread very fast was confirmed. EIFS cladding in order to prevent the spread of fire in the application of EIFS legally use is limited by the use of the building. And flame spread can be prevented, such as a vertical outer wall compartment measures are urgently needed.

Mapping Monthly Temperature Normals Across North Korea at a Landscape Scale (북한지역 평년의 경관규모 기온분포도 제작)

  • Kim, Soo-Ock;Yun, Jin-I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.13 no.1
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    • pp.28-34
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    • 2011
  • This study was carried out to estimate monthly mean of daily maximum and minimum temperature across North Korea at a 30 m grid spacing for a climatological normal year (1971-2000) and the 4 decadal averages (1971-1980, 1981-1990, 1991-2000, and 2001-2010). A geospatial climate interpolation method, which has been successfully used to produce the so-called 'High-Definition Digital Climate Maps' (HD-DCM), was used in conjunction with the 27 North Korean and 17 South Korean synoptic data. Correction modules including local effects of cold air drainage, thermal belt, ocean, solar irradiance and urban heat island were applied to adjust the synoptic temperature data in addition to the lapse rate correction. According to the final temperature estimates for a normal year, North Korean winter is expected colder than South Korean winter by $7^{\circ}C$ in average, while the spatial mean summer temperature is lower by $3^{\circ}C$ than that for South Korea. Warming trend in North Korea for the recent 40 years (1971-2010) was most remarkable in spring and fall, showing a 7.4% increase in the land area with 15 or higher daily maximum temperature for April.