• 제목/요약/키워드: Heat of adsorption

검색결과 256건 처리시간 0.022초

셀룰로오스계 라이오셀 활성탄소섬유의 구리 첨착에 의한 SO2 흡착특성 변화 (SO2 Adsorption Characteristics by Cellulose-Based Lyocell Activated Carbon Fiber on Cu Additive Effects)

  • 김은애;배병철;이철위;이영석;임지선
    • 공업화학
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    • 제26권4호
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    • pp.394-399
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    • 2015
  • 본 연구에서는 Cu 촉매가 도입된 활성탄소섬유를 제조하여 고효율 $SO_2$ 흡착재를 제조하였다. 라이오셀 섬유를 내염화 및 탄화공정을 통해 탄소섬유를 얻었으며, $SO_2$ 흡착능을 향상시키기 위해 KOH 활성화를 사용하여 높은 비표면적 및 균일한 미세기공구조를 부여하였다. 활성탄소섬유에 Cu 촉매를 도입하기 위하여 $Cu(NO_3)_2{\cdot}3H_2O$ 수용액을 사용하였으며, 공정 시 i) 탄소섬유 내 산소 관능기의 분해반응을 촉진하고, ii) 산화구리 및 질산염의 분해로 oxygen radical이 생성되어 탄소섬유의 활성화 반응을 촉진시켰다. 이로 인해 활성탄소섬유의 미세공과 중기공 형성효과 및 탄소섬유 표면에 고르게 분산된 Cu 촉매를 확인하였다. Cu 촉매 도입 후, 활성탄소섬유에 비해 비표면적 및 미세공의 비율이 약 10% 이상 증가되었고, $SO_2$ 흡착능이 149% 이상 향상된 결과를 얻을 수 있었다. Cu 촉매도입공정 시, 전이금속 촉매효과에 의하여 발달된 미세공, 중기공 및 비표면적에 의한 물리적 흡착과 도입된 Cu 촉매에 의한 $SO_2$ 가스의 화학적 흡착반응의 시너지 효과에 기인하여 $SO_2$ 흡착능이 향상된 것으로 사료된다.

폭쇄처리 목재의 비표면적변화 (Changes of Specific Surface Area of the Steam Exploded Wood)

  • 양재경;김현정;이원희
    • Journal of the Korean Wood Science and Technology
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    • 제23권1호
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    • pp.54-60
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    • 1995
  • This paper reports on the changes of equilibrium moisture contents and specific surface areas of Poplar wood(Populus euramericana) for various steam explosion treatments. Equilibrium moisture contents(EMC) and specific surfaces of steam exploded woods were measured under the moisture adsorption course at 25$^{\circ}C$, and compared with those of other materials and wood meals. The EMCs of steam exploded wood meal were 1~5% less in comparison with that of wood meal. In the case of delignified steam exploded wood meal and delignified wood meal, the same tendency was appeared too. But absolute values of EMCs for delignified wood meals were larger than those of the wood meal. For the changes of EMC by the steam exploded conditions, the EMC decreased with the increase of the steam explosion pressure. On the other hand, specific surface areas were calculated from BET plots based on amounts of monomolecular vapor adsorption of various wood meals. Specific surface areas of the wood meal and delignified wood meal were 90~145, 34~90($m^2/g$) respectively, and which were greater in comparison with those of steam exploded wood meals and delignified steam exploded wood meals. From these results, it is considered that the amount of water vapor adsorption was decreased by the increase of the crystallinity, effect of heat treatment, and coating by melted lignin in during the steam explosion.

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폴리아크릴로니트릴 기반 3D 탄소나노섬유 스펀지의 제조 및 오일 흡착 특성 (Preparation and Oil Absorption Properties of PAN Based 3D Shaped Carbon Nanofiber Sponge )

  • 주혜원;강진혁;박종호;고재경;국윤수;남창우;김병석
    • Composites Research
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    • 제36권3호
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    • pp.217-223
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    • 2023
  • 본 연구에서는 폴리아크릴로니트릴계 탄소나노섬유 스펀지의 제조 및 오일 흡착 거동을 조사하였다. 제조된 탄소나노섬유 스펀지는 물과 기름의 혼합용액에서 우수한 선택적 오일 흡착 능력을 보였으며, 탄소나노섬유 스펀지의 재사용시 흡착 능력도 확인하였다. 또한, 흡착제 내부구조에 정렬된 채널을 형성함으로써, 모세관 현상에 의하여 빠른 오일 흡착 거동을 보이는 탄소나노섬유 스펀지를 제조할 수 있었다. 이후 사용 폐기된 탄소나노섬유 스펀지는 질소 분위기에서 800℃로 열처리하여, 4-아미노페놀의 전기화학적 검출을 위한 센서로의 가능성을 검토하였다.

설비공학회 분야의 최근 연구 동향 : 2015년 학회지 논문에 대한 종합적 고찰 (Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2015)

  • 이대영;김사량;김현정;김동선;박준석;임병찬
    • 설비공학논문집
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    • 제28권6호
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    • pp.256-268
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    • 2016
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2015. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering were carried out in the areas of flow, heat and mass transfer, cooling and heating, and air-conditioning, the renewable energy system and the flow inside building rooms. Research issues dealing with air-conditioning machines and fire and exhausting smoke were reduced. CFD seems to be spreading to more research areas. (2) Research works on heat transfer area were carried out in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the economic analysis of GHG emission, micro channel heat exchanger, effect of rib angle on thermal performance, the airside performance of fin-and-tube heat exchangers, theoretical analysis of a rotary heat exchanger, heat exchanger in a cryogenic environment, the performance of a cross-flow-type, indirect evaporative cooler made of paper/plastic film. In the area of pool boiling and condensing, the bubble jet loop heat pipe was studied. In the area of industrial heat exchangers, researches were performed on fin-tube heat exchanger, KSTAR PFC and vacuum vessel at baking phase, the performance of small-sized dehumidification rotor, design of gas-injection port of an asymmetric scroll compressor, effect of slot discharge-angle change on exhaust efficiency of range hood system with air curtain. (3) In the field of refrigeration, various studies were carried in the categories of refrigeration cycle, alternative refrigeration/energy system, system control. In the refrigeration cycle category, a cold-climate heat pump system, $CO_2$ cascade systems, ejector cycles and a PCM-based continuous heating system were investigated. In the alternative refrigeration/energy system category, a polymer adsorption heat pump, an alcohol absorption heat pump and a desiccant-based hybrid refrigeration system were investigated. In the system control category, turbo-refrigerator capacity controls and an absorption chiller fault diagnostics were investigated. (4) In building mechanical system research fields, eighteen studies were reported for achieving effective design of the mechanical systems, and also for maximizing the energy efficiency of buildings. The topics of the studies included energy performance, HVAC system, ventilation, and renewable energies, piping in the buildings. Proposed designs, performance tests using numerical methods and experiments provide useful information and key data which can improve the energy efficiency of the buildings. (5) The field of architectural environment was mostly focused on indoor environment and building energy. The main researches of indoor environment were related to the user and location awareness technology applied dimming lighting control system, the lighting performance evaluation for light-shelves, the improvement evaluation of air quality through analysis of ventilation efficiency and the evaluation of airtightness of sliding and LS window systems. The subjects of building energy were worked on the energy saving estimation of existing buildings, the developing model to predict heating energy usage in domestic city area and the performance evaluation of cooling applied with economizer control. The studies were also performed related to the experimental measurement of weight variation and thermal conductivity in polyurethane foam, the development of flame spread prevention system for sandwich panels, the utilization of heat from waste-incineration facility in large-scale horticultural facilities.

Prediction model of 4.5 K sorption cooler for integrating with adiabatic demagnetization refrigerator (ADR)

  • Kwon, Dohoon;Kim, Jinwook;Jeong, Sangkwon
    • 한국초전도ㆍ저온공학회논문지
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    • 제24권1호
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    • pp.23-28
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    • 2022
  • A sorption cooler, which utilizes helium-4 as a working fluid, was previously developed and tested in KAIST. The cooler consists of a sorption pump and a thermosyphon. The developed sorption cooler aims to pre-cool a certain amount of the magnetic refrigerant of an adiabatic demagnetization refrigerator (ADR) from 4.5 K to 2.5 K. To simulate the high heat capacitance of the magnetic refrigerant, liquid helium was utilized not only as a refrigerant for the sorption cooling but also as a thermal capacitor. The previous experiment, however, showed that the lowest temperature of 2.7 K which was slightly higher than the target temperature (2.5 K) was achieved due to the radiation heat leak. This excessive heat leak would not occur when the sorption cooler is completely integrated with the ADR. Thus, based on the experimentally obtained pumping speed, the prediction model for the sorption cooler is developed in this study. The presented model in this paper assumes the sorption cooler is integrated with the ADR and the heat leak is negligible. The model predicts the amount of the liquid helium and the required time for the sorption cooling process. Furthermore, it is confirmed that the performance of the sorption cooler is enhanced by reducing the volume of the thermosiphon. The detailed results and discussions are summarized.

텅스텐 결정면의 수소흡착에 관한 연구 (A Study on the Hydrogen Adsorption on the Tungsten Crystal Surfaces)

  • 김용욱;박노길;김기석;황정남;김성수;허경미;최대선
    • 한국진공학회지
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    • 제3권1호
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    • pp.17-25
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    • 1994
  • 장전자 방출법을 이용하여 Kink 또는 loosely closed pack의 텅스텐 결정면(310) (221) (211) 의 수소흡착에 대한 일함수의 변화를 측정하고 상대 흡착율을 주입량과 일함수의 변화로 결정할 수 있는 방법을 제시 하였다. 또한 (310)면과 (221)면에 대한 수소의 heat of desorption을 측정하였으며 초고진 공 장치내에서 팔라듐의 수소 source로서의 가능성을 확인하였다.

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Thermopile과 삽입된 $SnO_2$ catalyst를 이용한 NOx 센서 (A NOx gas sensor based on thennopile and embedded tin oxide catalyst)

  • 이충일;윤승일;김용준
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.1829-1832
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    • 2008
  • This paper reports a novel gas sensing method by using a thermoelectric device, thermopile in this case, with an embedded tin oxide catalyst. By using a thin catalyst film, the response time and recovery time were remarkably improved. The fabricated gas sensor was characterized through detecting NOx gas with various concentrations.

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세라믹섬유지를 사용한 허니컴 흡착소자 제조 및 VOC 흡착특성 (Fabrication of Honeycomb Adsorbents by Using the Ceramic Paper and Adsorption Characteristics of VOC)

  • 유윤종;조철희;김홍수;안영수;한문희;장건익
    • 한국세라믹학회지
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    • 제39권11호
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    • pp.1035-1041
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    • 2002
  • 세라믹섬유지에 VOC 흡착특성이 우수한 제올라이트-Y와 ZSM-5를 담지시키기 위하여 바인더로 사용된 실리카 졸의 첨가량 변화에 따른 흡착제의 표면고착특성을 고찰하였다. 세라믹섬유지에 담지된 제올라이트는 입자가 고르게 분산되어 31 wt% 정도가 고착되었으며, X-ray 회절분석결과 담지 후 열처리와 바인더의 사용에도 불구하고 제올라이트는 원래의 결정구조를 유지하였다. 담지된 제올라이트의 비표면적 감소는 메조포어의 감소에 따른 것으로, VOC 흡착에 가장 유효한 $20{\AA}$ 미만의 마이크로포어에는 영향을 미치지 않음을 알 수 있었다. 세라믹섬유지로 제조한 직경 10cm, 길이 40cm의 허니컴에 제올라이트를 담지시켜 톨루엔, MEK, Cyclohexanone에 대한 흡착실험결과 흡착제거효율이 모두 97% 이상으로 나타났으며, 회전식 흡착농축장치에 적용할 경우 VOC 농도 300 ppmv의 오염공기를 $42 Nm^3/h$ 정도 연속적으로 처리할 수 있는 흡착특성을 나타내었다.

속도 슬립모델 적용을 통한 마이크로 유체 시뮬레이션용 FEM 수치 코드 개발 (IMPLEMENTATION OF VELOCITY SLIP MODELS IN A FINITE ELEMENT NUMERICAL CODE FOR MICROSCALE FLUID SIMULATIONS)

  • ;명노신
    • 한국전산유체공학회지
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    • 제14권2호
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    • pp.46-51
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    • 2009
  • The slip effect from the molecular interaction between fluid particles and solid surface atoms plays a key role in microscale fluid transport and heat transfer since the relative importance of surface forces increases as the size of the system decreases to the microscale. There exist two models to describe the slip effect: the Maxwell slip model in which the slip correction is made on the basis of the degree of shear stress near the wall surface and the Langmuir slip model based on a theory of adsorption of gases on solids. In this study, as the first step towards developing a general purpose numerical code of the compressible Navier-Stokes equations for computational simulations of microscale fluid flow and heat transfer, two slip models are implemented into a finite element numerical code of a simplified equation. In addition, a pressure-driven gas flow in a microchannel is investigated by the numerical code in order to validate numerical results.

Iron hydrolysis and lithium uptake on mixed-bed ion exchange resin at alkaline pH

  • Olga Y. Palazhchenko;Jane P. Ferguson;William G. Cook
    • Nuclear Engineering and Technology
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    • 제55권10호
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    • pp.3665-3676
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    • 2023
  • The use of ion exchange resins to remove ionic impurities from solution is prevalent in industrial process systems, including in the primary heat transport system (PHTS) purification circuit of nuclear power plants. Despite its extensive use in the nuclear industry, our general understanding of ion exchange cannot fully explain the complex chemistry in ion exchange beds, particularly when operated at or near their saturation limit. This work investigates the behaviour of mixed-bed ion exchange resin, saturated with species representative of corrosion products in a CANDU (Canadian Deuterium Uranium) reactor PHTS, particularly with respect to iron chemistry in the resin bed and the removal of lithium ions from solution. Experiments were performed under deaerated conditions, analogous to normal PHTS operation. The results show interesting iron chemistry, suggesting the hydrolysis of cation resin bound ferrous species and the subsequent formation of either a solid hydrolysis product or the soluble, anionic Fe(OH)3-.