• Title/Summary/Keyword: Heat of Fusion

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The Effects of Blend Composition and Blending Time on the Ester Interchange Reaction and Tensile Properties of PLA/LPCL/HPCL Blends

  • Yoon, Cheol-Soo;Ji, Dong-Sun
    • Fibers and Polymers
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    • v.4 no.2
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    • pp.59-65
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    • 2003
  • PLA/LPCL/HPCL blends composed of poly(lactic acid) (PLA), low molecular weight poly($\varepsilon$-caprolactone) (LPCL), and high molecular weight poly($\varepsilon$-caprolactone) (HPCL) were prepared by melt blending for bioabsorbable fila-ment sutures. The effects of blend composition and blending time on the ester interchange reaction by alcoholysis in the PLA/LPCL/HPCL blends were studied. Their thermal properties and the miscibility due to the ester interchange reaction were investigated by $^1{H-NMR}$, DSC, X-ray, and UTM analyses. The hydroxyl group contents of LPCL in the blends decreafed by the ester interchange reaction due to alcoholysis. Thus, the copolymer was formed by the ester interchange reaction at $200^{\circ}C$ for 30-60 minutes. The thermal properties of PLA/LPCL/HPCL blends such as melting temperature and heat of fusion decreased with increasing ester interchange reaction levels. However, the miscibility among the three poly-mers was improved greatly by ester interchange reaction. Tensile strength and modulus of PLA/LPCL/HPCL blend fibers increased with increasing HPCL content, while the elongation at break of the blend fibers increased with increasing LPCL content.

Preparation and Properties of Electrically Conductive Clothing materials (전기전도성 의류소재의 제조 및 물성에 관한 연구)

  • 홍경희;오경화
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.4
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    • pp.584-592
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    • 1999
  • Highly conductive polyaniline(PAn)-nylon 6 composite fabric was prepared by immersing the nylon 6 fabric in 0.5M aniline+0.35M HCl aqueous solution at 4$0^{\circ}C$ for 2hours, Polymerization was then followed by mixing the prepared oxidant and dopant solution(0.5M(NH4)2S2O+0.35M HCl) to the diffusion bath at 5$^{\circ}C$ for 30 minutes. The conductivity of prepared PAn-nylon 6 composite fabrics reached as high as 0.5$\times$10-1S/cm. Their conductivity were significantly affected by the aniline and oxidant concentration. As compared to those of nylon 6 fabric heat of fusion melting point the degree of crystallinity and tensile strength of PAn-nylon 6 did not significantly changed by inclusion of PAn. In the aspect of serviceability wheras the fabric conductivity was significantly decreased after multiple washion no significant changes in the fabric conductivity were observed after abrading the composite fabric over 50 cycles. However we found that the fabric conductivity could be recovered by acid re-doping with HCl.

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HAZ Crack Growth Behavior of Cr-Mo Steel at Elevated Temperature (Cr-Mo강 용접열영향부에서의 고온 균열성장거동 연구)

  • 윤기봉;신규인;정용근;이해무
    • Proceedings of the KWS Conference
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    • 1997.05a
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    • pp.65-68
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    • 1997
  • Fracture behavior of ex-serviced 1Cr-0.5Mo steel was measured at room(24$^{\circ}C$) and elevated(538$^{\circ}C$) temperature and compared with that measured with virgin 1Cr-0.5Mo steel. Compact C(T) specimens were machined from the base and welded test materials. In case of the C(T) specimens of the weld, fatigue precrack was introduced along the fusion line so that a crack growth should occur along the region of heat affected zone. It was observed that the J-R curve of the serviced material was significantly lower than that of the virgin material at room temperature. Brittle fracture was observed in the serviced material. On the other hand at elevated temperature no noticeable difference was found between the J-R curves of the virgin and the serviced material. The measured J-R curves were also compared with those of the 1.25Cr-0.5Mo steel from other literatures. Optical microscopy and SEM examination of the serviced material reveal the carbide in/along the grain boundary which shows material degradation due to long-term usage.

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THE EFFECTS OF TiN PARTICLES ON THE HAZ MICROSTRUCTURE AND TOUGHNESS IN HIGH NITROGEN TiN STEEL

  • Jeong, Hong-Chul;An, Young-Ho;Choo, Wung-Yong
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.217-221
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    • 2002
  • In the coarse grain HAZ adjacent to the fusion line, most of the TiN particles in conventional Ti added steel are dissolved and austenite grain growth is easily occupied during welding process. To avoid this difficulty, thermal stability of TiN particle is improved by increasing the nitrogen content in steel. In this study, the effect of high nitrogen TiN particle on preventing austenite grain growth in HAZ was investigated. Increased thermal stability of TiN particle is helpful for preventing the austenite grain growth by pinning effect. High nitrogen TiN particle in simulated HAZ were not dissolved even at high temperature such as 1400 C and prevented the austenite grain growth in simulated HAZ. Owing to small austenite grain size in HAZ the width of coarse grain HAZ in high nitrogen TiN steel was decreased to 1/10 of conventional TiN steel. Even high heat input welding, the microstructure of coarse grain HAZ consisted of fine polygonal ferrite and pearlite and toughness of coarse grain HAZ was significantly improved.

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Thermal Flow Analysis and Design of KSTAR Thermal Shield Panel by Numerical Method (수치해석을 통한 KSTAR 주장치 열차폐 패널 열.유동 특성해석)

  • 김동락;김광선;노영미;조승연;김승현
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.2
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    • pp.73-77
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    • 2002
  • In order to derive the detailed design of Thermal Shield Cryopanel. which plays a role to make the Tokamak Nuclear Fusion Equipment work at both static and efficient conditions the commercially available software package FLUENT Version 5.3, was utilized. This study investigated the effects of thermal sources and distributions on the temperatures of Lid. Body. Base. and EH-Port Cryopanel by the numerical technique whose grid generations cover the solid and 9as region of the panel. The physical model of the Thermal Shield Cryopanel is that the 10mm diameter of the pipe with 1mm thickness is soldered on the Stainless steel Panel with 4mm thickness. The heat fluxes to the panel are assumed to be by thermal radiation in the vacuum space and by conduction through the supporters. The inlet conditions of Helium gas are 20 atmospheric Pressures and 60K temperature. The panel shapes with cooling Pipes and the operational conditions to keep appropriate temperature distribution of Thermal Shield Cryopanel Have been found and suggested.

A Study on the Characteristics of Pollution Load in Biomass Power Plant with Ammonium Sulfate Injection (황산암모늄 주입시 바이오매스 발전소의 오염부하 특성 연구)

  • Lee, Chang-Yeol;Kim, Sung-Hoo;Chung, Jin-Do
    • Journal of Korea Society of Waste Management
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    • v.35 no.7
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    • pp.640-646
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    • 2018
  • Biomass-fired power plants produce electricity and heat by burning biomass in a boiler. However, one of the most serious problems faced by these plants is severe corrosion. In biomass boilers, corrosion comes from burnt fuels containing alkali, chlorine, and other corrosive substances, causing boiler tube failures, leakages, and shorter lifetimes. To mitigate the problem, various approaches implying the use of additives have been proposed; for example, ammonium sulfate is added to convert the alkali chlorides (mainly KCl) into the less corrosive alkali sulfates. Among these approaches, the high temperature corrosion prevention technology based on ammonium sulfate has few power plants being applied to domestic power plants. This study presents the results obtained during the co-combustion of wood chips and waste in a circulating fluidized bed boiler. The aim was to investigate the characteristics of pollution load in domestic biomass power plants with ammonium sulfate injection. By injecting the ammonium sulfate, the KCl content decreased from 68.9 to 5 ppm and the NOx were reduced by 18.5 ppm, but $SO_2$ and HCl were increased by 93.3 and 68 ppm, respectively.

Enhancement of Physical Properties in Partially Crosslinked Waste High Density Polyethylene (재활용 고밀도 폴리에틸렌의 가교에 의한 물성 향상 연구)

  • Lee, Jong-Rok;Lee, Dong-Gun;Hong, Soon-Man;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.31 no.1
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    • pp.25-30
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    • 2007
  • The characteristics of crosslinking and physical properties in partially crosslinked waste high density polyethylene (HDPE) were studied by introducing reactive melt processing with perbutyl peroxide (PBP). It was found that impurities in waste HDPE affected the crosslinking kinetics. Decrease in density and heat of fusion were observed in partially crosslinked HDPE while its melt viscosity increased. It was explained that impurities in waste HDPE enhanced the crosslinking compared to pure HDPE As a result, dramatic mechanical property improvement was achieved in the waste HDPE by crosslinking reaction.

Cloning, Expression, and Characterization of Thermostable DNA Polymerase from Thermoanaerobacter yonseiensis

  • Kim, Dae-Jin;Jang, Hyeung-Jin;Pyun, Yu-Ryang;Kim, Yu-Sam
    • BMB Reports
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    • v.35 no.3
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    • pp.320-329
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    • 2002
  • A gene, coined tay, for a thermostable DNA polymerase from the novel, extremely thermophilic bacterium Thermoanaerobacter yonseiensis was cloned and expressed in E. coli. Using a DNA polymerase homologous PCR product as a hybridization probe, tay was isolated and sequenced to consist of 2621 nucleotides that encode 872 amino acids. A database analysis showed that DNA polymerase, coined Tay, from T. yonseiensis shared a 39% to 47% identity in the amino acid sequence with those from other DNA polymerases. Tay was overexpressed in E. coli as a fusion protein with a poly-histidine tag at the C-terminus. It was purified by heat treatment, followed by a $Ni^{2+}$-chelate column. The molecular weight of purified Tay was approximately 97 kDa, as shown by SDS PAGE, and it showed high DNA polymerase activity and thermostability. However, it had no 3'$\rightarrow$5' exonuclease activity.

TOKAMAK REACTOR SYSTEM ANALYSIS CODE FOR THE CONCEPTUAL DEVELOPMENT OF DEMO REACTOR

  • Hong, Bong-Guen;Lee, Dong-Won;In, Sang-Ryul
    • Nuclear Engineering and Technology
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    • v.40 no.1
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    • pp.87-92
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    • 2008
  • Tokamak reactor system analysis code was developed at KAERI (Korea Atomic Energy Research Institute) and is used here for the conceptual development of a DEMO reactor. In the system analysis code, prospects of the development of plasma physics and the relevant technology are included in a simple mathematical model, i.e., the overall plant power balance equation and the plasma power balance equation. This system analysis code provides satisfactory results for developing the concept of a DEMO reactor and for identifying the necessary R&D areas, both in the physics and technology areas for the realization of the concept. With this system analysis code, the performance of a DEMO reactor with a limited extension of the plasma physics and technology adopted in the ITER design. The main requirements for the DEMO reactor were selected as: 1) demonstrate tritium self-sufficiency, 2) generate net electricity, and 3) achieve a steady-state operation. It was shown that to access an operational region for higher performance, the main restrictions are presented by the divertor heat load and the steady-state operation requirements.

Hybrid Welding Process for Sheet Metal and Narrow Gap Fill Pass (하이브리드 용접방식을 이용한 박판 및 후판용접공정)

  • Choi, Hae-Woon;Shin, Hyun-Myung;Im, Moon-Hyuk
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.11
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    • pp.978-983
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    • 2008
  • An application of innovative laser+GMA hybrid welding process is presented for reducing bead humping defects in high speed welding and increasing side wall fusion in narrow groove welding without torch or wire oscillation. In this hybrid process, the laser heat input is applied adjacent to the weld pool at a relatively low power density to produce a wider, flatter weld bead. In bead on plate in sheet metal gauges, the hybrid process was able to produce hump-free welds from 70ipm (${\sim}1780mm/min$) to over 150ipm (${\sim}3810mm/min$) of the travel speed compared to the un-assisted GMAW process. A square-butt joint in 15mm A572 Gr50 steel welds was investigated. A square butt joint with a gap of 3.2mm was filled with 6 passes. Liquid Nitrogen calorimetry and innovative $CO_2$ laser reflective optics were also developed to demonstrate the concept of hybrid welding.