• Title/Summary/Keyword: Heat of Fusion

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Synthesis of Single Crystal Diamond by Variation of Deposition Pressure by HFCVD (HFCVD에 의한 증착압력 변화에 따른 Single Crystal Diamond 합성)

  • Kim, Min Su;Bae, Mun Ki;Kim, Seong-Woo;Kim, Tae Gyu
    • Journal of the Korean Society for Heat Treatment
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    • v.33 no.1
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    • pp.20-24
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    • 2020
  • Single crystal diamonds are in great demand in such fields as mechanical, electronic applications and optoelectronics. Large area single crystal diamonds are attracting attention in future industries for mass production and low cost. In this study, hot filament CVD (HFCVD) is used to grow large area single crystal diamond. However, the growth rate of large area single crystal diamond using HFCVD is known to be very low. The goal of this study is to use single crystal diamond substrates in HFCVD with methane-hydrogen gas mixtures to increase the growth rate of single crystal diamond and to optimize the conditions by analysing the effects of deposition conditions for high quality crystallinity. The deposition pressure, the ratio of CH4/H2 gas, the substrate temperature and the distance between the filament and the substrate were optimized. The sample used a 4×4 (mm2) size single crystal diamond substrate (100), the CH4/H2 gas ratio was fixed at 5%, the substrate temperature was synthesized to about 1000℃. At this time, the deposition pressure was changed to three types of 50, 75, 85 Torr and deposited. Finally, optimization was investigated under pressure conditions to analyse the growth rate and quality of single crystal diamond.

Effect of Up-and-Down Torch Oscillation for Providing Uniform Heat Input along the Sidewall of Gap on Ultra Narrow Gap Welding (울트라 내로우 갭 용접에서 갭 내 고른 아크입열 분포를 위한 상ㆍ하 토치요동 효과)

  • 김두영;나석주
    • Journal of Welding and Joining
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    • v.21 no.3
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    • pp.85-91
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    • 2003
  • Narrow gap welding has many advantages over conventional V-grooved butt welding such as high productivity, small deformation and improved mechanical property of joints. With narrower groove gap, less arc heat input is expected will all the other advantages of narrow gap welding. The main defects of narrow gap welding include the lack of root fusion, convex bead surface and irregular surface, all of which have negative effects on the next welding pass. This paper suggests an up-and-down torch oscillation for ultra narrow gap welding with gap size of 5mm and investigates the proper welding conditions to fulfill the reliable and high welding quality. First, GMA welding model was suggested for ultra narrow gap welding system with Halmoy's model referenced for wire melting modeling. And the arc length in ultra narrow gap was defined. Secondly, based on the experimental results of up-and-down torch oscillation welding, phase shift of current and wire extension length were simulated for varying oscillation frequency to show that weld the bead shape in ultra narrow gap welding can be predicted. As the result, it was confirmed that reliable weld quality in ultra narrow gap welding can be achieved with up-and-down torch oscillation above 15Hz due to its ability to provide uniform heat input along the sidewall of gap.

Effect of Hot-Stamping on Mechanical Properties and Microstructures of CO2 Laser Welded Boron Steel coated with Al-Si layer (Al-Si 용융 도금된 보론강 CO2 레이저 용접부의 미세조직과 기계적 성질에 미치는 핫스탬핑 처리의 영향)

  • Oh, Myeonghwan;Kong, Jongpan;Shin, Hyeonjeong;Kwon, Minsuck;Jung, Byunghun;Kang, Chungyun
    • Laser Solutions
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    • v.16 no.3
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    • pp.1-10
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    • 2013
  • In this study, Al-Si coated boron steel(1.2 mm) were laser welded by $CO_2$ laser and hot-stamping was applied to the laser joints. Tensile properties and microstructures of the joints were investigated before and after hot-stamping. Tensile and yield strengths of the as welded specimen similar with base metal and fracture occurred base metal of boron steel. Although, in case of heat treated specimen, fracture occurred fusion zone that Al segregated zone near the bond line. These could be explained by the existence of ferrite, in the Al segregated zone near the bond line and base metal of boron steel. Before hot-stamping, hardness of base metal is lower than fusion zone and heat affected zone in spite of exist Al segregation zone($Fe_3$(Al,Si)). So fracture occurred base metal. Although, after hot-stamping, microstructure of base metal and welds zone transformed to martensite and bainite except in Al segregation zone near the bond line that $Fe_3$(Al,Si) transformed to a-ferrite. So fracture occurred Al segregation zone near the bond line.

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The Heat Shock Protein 27 (Hsp27) Operates Predominantly by Blocking the Mitochondrial-Independent/Extrinsic Pathway of Cellular Apoptosis

  • Tan, Cheau Yih;Ban, Hongseok;Kim, Young-Hee;Lee, Sang-Kyung
    • Molecules and Cells
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    • v.27 no.5
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    • pp.533-538
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    • 2009
  • Heat shock protein 27 (Hsp27) is a molecular chaperone protein which regulates cell apoptosis by interacting directly with the caspase activation components in the apoptotic pathways. With the assistance of the Tat protein transduction domain we directly delivered the Hsp27 into the myocardial cell line, H9c2 and demonstrate that this protein can reverse hypoxia-induced apoptosis of cells. In order to characterize the contribution of Hsp27 in blocking the two major apoptotic pathways operational within cells, we exposed H9c2 cells to staurosporine and cobalt chloride, agents that induce mitochondria-dependent (intrinsic) and -independent (extrinsic) pathways of apoptosis in cells respectively. The Tat-Hsp27 fusion protein showed a greater propensity to inhibit the effect induced by the cobalt chloride treatment. These data suggest that the Hsp27 predominantly exerts its protective effect by interfering with the components of the extrinsic pathway of apoptosis.

Change in Fracture Toughness within Heat-Affected Zone of SA-Welded 9% Ni Steel (LNG 저장탱크 내조용 9% Ni강의 SAW 용접열영향부내 파괴인성 변화 평가)

  • Jang, Jae-Il;Lee, Jeong-Seok;Lee, Baek-U;Ju, Jang-Bok;Gwon, Dong-Il;Kim, U-Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.3
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    • pp.528-536
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    • 2002
  • As one step for the safety performance of LNG storage tank, the change in fracture toughness within the X-grooved weld heat-affected zone (HAZ) of newly developed 9% Ni steel, which was submerged arc (SA)-welded, was investigated. Both crack initiation fracture toughness and crack arrest fracture toughness were evaluated by the crack tip opening displacement (CTOD) tests and compact crack arrest (CCA) tests. As the evaluated region approached the fusion line, each test result shorted different tendency, that is, crack initiation toughness decreased while crack arrest toughness increased. The results were discussed through the observation of the microstructural change.

Characterization of Mechanical Properties in the Heat Affected Zones of Alloy 82/182 Dissimilar Metal Weld Joint (Alloy 82/182 이종금속 용접부 열영향부의 기계적물성치 특성 파악)

  • Kim, Jin-Weon;Kim, Jong-Sung;Lee, Kyung-Soo
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.73-78
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    • 2008
  • The paper presents the characteristics of mechanical properties within the heat affected zone (HAZ) of dissimilar metal weld between SA508 Gr.1a and F316 stainless steel (SS) with Alloy 82/182 filler metal. Tensile tests were performed using small-size specimens taken from the HAZ regions close to both fusion lines of weld, and the micro-structures were examined using optical microscope (OM) and transmission microscope (TEM). The results showed that significant gradients of the yield stress (YS), ultimate tensile stress (UTS), and elongations were observed within the HAZ of SA508 Gr.1a. This was attributed to the different microstructures within the HAZ. In the HAZ of F316 SS, however, the welding effect dominated the YS and elongation rather than UTS, and TEM micrographs conformed the strengthening in the HAZ of F316 SS was associated with a dislocation-induced strain hardening.

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Hydrogen Absorption/Desorption and Heat Transfer Modeling in a Concentric Horizontal ZrCo Bed (수평식 이중원통형 ZrCo 용기 내 수소 흡탈장 및 열전달 모델링)

  • Park, Jongcheol;Lee, Jungmin;Koo, Daeseo;Yun, Sei-Hun;Paek, Seungwoo;Chung, Hongsuk
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.4
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    • pp.295-301
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    • 2013
  • Long-term global energy-demand growth is expected to increase driven by strong energy-demand growth from developing countries. Fusion power offers the prospect of an almost inexhaustible source of energy for future generations, even though it also presents so far insurmountable scientific and engineering challenges. One of the challenges is safe handling of hydrogen isotopes. Metal hydrides such as depleted uranium hydride or ZrCo hydride are used as a storage medium for hydrogen isotopes reversibly. The metal hydrides bind with hydrogen very strongly. In this paper, we carried out a modeling and simulation work for absorption/desorption of hydrogen by ZrCo in a horizontal annulus cylinder bed. A comprehensive mathematical description of a metal hydride hydrogen storage vessel was developed. This model was calibrated against experimental data obtained from our experimental system containing ZrCo metal hydride. The model was capable of predicting the performance of the bed for not only both the storage and delivery processes but also heat transfer operations. This model should thus be very useful for the design and development of the next generation of metal hydride hydrogen isotope storage systems.

Rapid Cooling Performance Evaluation of a ZrCo bed for a Hydrogen Isotope Storage (수소동위원소 저장용 ZrCo용기의 급속 냉각 성능 평가)

  • Lee, Jungmin;Park, Jongchul;Koo, Daeseo;Chung, Dongyou;Yun, Sei-Hun;paek, Seungwoo;Chung, Hongsuk
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.2
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    • pp.128-135
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    • 2013
  • The nuclear fuel cycle plant is composed of various subsystems such as a fuel storage and delivery system (SDS), a tokamak exhaust processing system, a hydrogen isotope separation system, and a tritium plant analytical system. Korea is sharing in the construction of the International Thermonuclear Experimental Reactor (ITER) fuel cycle plant with the EU, Japan, and the US, and is responsible for the development and supply of the SDS. Hydrogen isotopes are the main fuel for nuclear fusion reactors. Metal hydrides offer a safe and convenient method for hydrogen isotope storage. The storage of hydrogen isotopes is carried out by absorption and desorption in a metal hydride bed. These reactions require heat removal and supply respectively. Accordingly, the rapid storage and delivery of hydrogen isotopes are enabled by a rapid cooling and heating of the metal hydride bed. In this study, we designed and manufactured a vertical-type hydrogen isotope storage bed, which is used to enhance the cooling performance. We present the experimental details of the cooling performances of the bed using various cooling parameters. We also present the modeling results to estimate the heat transport phenomena. We compared the cooling performance of the bed by testing different cooling modes, such as an isolation mode, a natural convection mode, and an outer jacket helium circulation mode. We found that helium circulation mode is the most effective which was confirmed in our model calculations. Thus we can expect a more efficient bed design by employing a forced helium circulation method for new beds.

A Study on Laser Weldability of Al-Si Coated 22MnB5 Steel for TWB Hot Stamping (Al-Si 도금된 22MnB5강의 핫스탬핑 TWB 적용을 위한 레이저용접성 고찰)

  • Kim, Yong;Park, Ki-Young;Lee, Bo-Young
    • Journal of Welding and Joining
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    • v.31 no.2
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    • pp.30-36
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    • 2013
  • Recently the use of ultra high strength steels(UHSS) in structural and safety component is rapidly increasing in the automotive industry. Furthermore, it commonly use in tailor welded blank laser welding process before hot stamping to reduce lightweight vehicle. However TWB process is to be a problem about welded strength after hot stamping because it's welded before heat treatment. Therefore, in this study, laser welds of TWB after heat treatment were analyzed for changes in the characteristics, especially the impact on the oxidation and decarburization in order to prevent pre-coated Al-Si layer welds on the properties for intensive investigation. As a result, the degradation of the TWB weldments changes in the heat treatment conditions alone, without any pre-treatment of the coating layer has confirmed that there is a limitation on the improvement. Furthermore Al-Si elements are overall distributed on the weldment and it specially concentrated along the fusion line. Hardness value of Al-Si segregation area is less than 350Hv and tensile strength showed just 78~83% compared with substrate. Accordingly, we proved that both side Al-Si coating should be removed in order to ensure the strength of the substrate.

Characteristics of Friction Stir Welded AZ31 Mg Alloys with Shoulder Diameter and Rotating Speed (숄더 지름과 회전 속도에 따른 AZ31 마그네슘합금의 마찰교반접합 특성)

  • Jun, Sang-Hyuk;Ko, Young-Bong;Park, Kyeung-Chae
    • Journal of the Korean institute of surface engineering
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    • v.46 no.1
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    • pp.36-41
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    • 2013
  • Friction stir welding (FSW) is a relatively new joining technique particularly for magnesium and aluminum alloys that are difficult to fusion weld. In this study, AZ31 Mg alloys were joined by FSW with shoulder diameter 11, 19 mm and rotating speed 900, 1200, 1500, 1800 rpm. The shoulder diameter and welding speed depended on the heat input during FSW process. As a result, the microstructures of stir zone were a fine grain by dynamic recrystallization. According to the larger shoulder diameter and the higher rotating speed, refined grain sizes of stir zone were grown by higher heat input, and the microhardness of stir zone was lower. The tensile strength at the shoulder diameter 19 mm, rotating speed 900 rpm was obtained maximum value. This value compared with the base metal was over 93%.