• Korean Journal of Materials Research
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• v.20 no.12
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• pp.669-675
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• 2010

One of the greatest challenges for our society is providing powerful electrochemical energy conversion and storage devices. Rechargeable lithium-ion batteries and fuel cells are among the most promising candidates in terms of energy and power density. As the starting material, $TiCl_4{\cdot}YCl_3$ solution and dispersing agent (HCP) were mixed and synthesized using ammonia as the precipitation agent, in order to prepare the nano size Y doped spherical $TiO_2$ precursor. Then, the $Li_4Ti_5O_{12}$ was synthesized using solid state reaction method through the stoichiometric mixture of Y doped spherical $TiO_2$ precursor and LiOH. The Ti mole increased the concentration of the spherical particle size due to the addition of HPC with a similar particle size distribution in a well in which $Li_4Ti_5O_{12}$ spherical particles could be obtained. The optimal synthesis conditions and the molar ratio of the Ti 0.05 mol reaction at $50^{\circ}C$ for 30 minutes and at $850^{\circ}C$ for 6 hours heat treatment time were optimized. $Li_4Ti_5O_{12}$ was prepared by the above conditions as a working electrode after generating the Coin cell; then, electrochemical properties were evaluated when the voltage range of 1.5V was flat, the initial capacity was 141 mAh/g, and cycle retention rate was 86%; also, redox reactions between 1.5 and 1.7V, which arose from the insertion and deintercalation of 0.005 mole of Y doping is not a case of doping because the C-rate characteristics were significantly better.

• Polymer(Korea)
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• v.24 no.1
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• pp.97-104
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• 2000

PAN-based activated carbon fibers/phenolic resin matrix composites (ACFCs) were manufactured via molding process with oxidized carbon fabrics (plain-type) and phenolic resin (resole-type) compounded by 70 : 30 wt%. The green body (as molded) was submitted to carbonization (at 100$0^{\circ}C$) in an inert environment and activation (at 700, 800, 900 and 100$0^{\circ}C$) in a $CO_2$ environment. In this work, the influence of activation temperatures was investigated in surface properties, such as pH, acid- and base-values by titration method, and in adsorption properties, i.e., specific surface area and pore structures by BET-method of the composites. Also, the pressure drops of the specimens were calibrated by ASTM. As a result, the activation temperature influenced the surface property of ACFCs. When the activation temperature was higher than 90$0^{\circ}C$, the surface was gradually developed in basic nature. And, the evolutions of specific surface area, total pore volume and pore size distribution of ACFCs could be easily confirmed the dependence on the activation temperature. Among them, well-developed pore structure from adsorption characteristics was changed of the ACFCs activated at 90$0^{\circ}C$. Also, the pressure drop was slightly decreased with increasing the temperature due to increasing the burn-off with heat treatment temperature of ACFCs.

• Journal of the Korea Institute of Building Construction
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• v.17 no.5
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• pp.411-418
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• 2017

This study classified oyster shells that produced as a industrial waste into 3 distribution by washing, drying and processing them. Mortar specimens with a constant ratio by using this to substitute fine aggregates were made, and the specimens were heated under the heating conditions of $300^{\circ}C$, $600^{\circ}C$ and $900^{\circ}C$ based on the 28-day age. On the age of 28 days, the plain flexural strength was found to be 9.2MPa, and in O 0.15, it was shown to be 4.4~7.9MPa depending on the substitution rate. It was found to be 4.4~7.7MPa in O 1.2~2.5 depending on the substitution rate, and last but not least, it was shown to be 6.1~8.8MPa in case of O 2.5~5.0 depending on the substitution rate. In case of the compressive strength of the 28-day age, it showed the difference of 23.6~43.2MPa in O 0.15 depending on the substitution rate, and 20.4~45.1MPa in O 1.2~2.5 depending on the substitution rate, and last but not least, 17.1~40.4MPa in case of O 2.5~5.0. As a result of measuring the residual strength through heating, in case of substituting fine aggregates less than O 0.15 by 100%, it showed the lowest strength reduction ratio, and it is expected that the heat-resisting property could be achieved through processing and proper mixing of oyster shells through these results.

• Korean Chemical Engineering Research
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• v.43 no.6
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• pp.745-750
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• 2005

Naphtha cracking bottoms(NCB) oil was reformed by varying the heat treatment temperature, treatment time, and nitrogen flow rate in preparation of precursor pitch for isotropic pitch-based carbon fibers and activated carbon fibers. The reformed pitches were investigated in the yield, softening point, elementary analysis, and molecular weight distribution, and then the precursors reformed were melt spun to certify the optimum reforming conditions. The optimum precursor pitch was prepared when the NCB oil was reformed at $380^{\circ}C$, 3 h and 1.25 vvm $N_2$, and it's the softening point was around $240^{\circ}C$. The reforming resulted in product yield of 21 wt％. The C/H mole ratio of the precursor pitch increased from 1.07 to 1.34, the aromaticity increased from 0.85 to 0.88. The insolubles in benzene and quinoline were 30.0 wt％ and 1.5 wt％, respectively. The spinning temperature was about $50^{\circ}C$ higher than the softening point. The molecular weights of the precursor components were distributed from 250 to 1250, and 80％ of them were in the range of 250 to 700.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.3
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• pp.1033-1041
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• 2014

Rapid urbanization of Korea was an unprecedented example in the world and urban population increased significantly. As a result, unbalanced distribution of population is serious problem in Korea because approximately 50% of the population is concentrated in the capital area that is 10% of nation's territory, thereby occurring various urban problems including UHI. Hence, Sejong Special Autonomous City was inaugurated officially on 2 July 2012 in order to decentralize population of capital area and induce more balanced regional development. The Sejong City has been changed drastically over a period of years as developed practically since the late 2000's and is expected to have new problems of urbanization. The land cover change due to urbanization is the main cause of UHI that urban area is significantly warmer than its surrounding areas and UHI is not only affecting urban climate change but also natural environment. So the purpose of this research is to analyze level of urbanization and UHI effect and to provide the correlation analysis between Land Surface Temperature and spectral indices. To achieve this, satellite imagery from LANDSAT were used. NDVI, NDBI, and UI were calculated using red, near-infrared, mid-infrared ($0.63{\mu}m-1.75{\mu}m$) images and LST was retrieved utilizing thermal infrared ($10.4{\mu}m-12.5{\mu}m$) image. Based on each index and LST, Changes of NDVI, UI and UHI through TVI were analyzed in Sejong City. UHI effect increased around newly constructed multi-functional administrative city, the correlation between LST and NDVI was negative and UI was strong positive.

• Journal of the Korean Electrochemical Society
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• v.5 no.2
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• pp.52-56
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• 2002

Tin oxide was coated on graphite particle by sol-gel method and an electrode with this material having microcrystalline structure for lithium ion battery was obtained by heat treatment in the range $400-600^{\circ}C$. The content of tin oxide was controlled within the range of $2.25wt\%\~11.1wt\%$. The discharge capacity increased with the content of tin oxide and also initial irreversible capacity increased. The discharge capacity of tin oxide electrode showed more than 350 mAh/g at the initial cycle and 300 mAh/g after the 30th cycle in propylene carbonate(PC) based electrolyte whereas graphite electrode without surface modification showed 140 mAh/g. When the charge and discharge rate was changed from C/5 to C/2, The discharge capacity of tin oxide and graphite electrode showed $92\%\;and\;77\%$ of initial capacity, respectively. It has been considered that such an enhancement of electrode characteristics was caused because lithium $oxide(Li_2O)$ passive film formed from the reaction between tin oxide and lithium ion prevented the exfoliation of graphite electrode and also reduced tin enhanced the electrical conduction between graphite particles to improve the current distribution of electrode.

• Journal of the korean society of oceanography
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• v.39 no.2
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• pp.119-135
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• 2004

A three-dimensional numerical model using POM (the Princeton Ocean Model) is established in order to understand the dispersion processes of the Yangtze River water in the Yellow and East China Seas. The circulation experiments for the seas are conducted first, and then on the bases of the results the dispersion experiments for the river water are executed. For the experiments, we focus on the tide effects and wind effects on the processes. Four cases of systematic experiments are conducted. They comprise the followings: a reference case with no tide and no wind, of tide only, of wind only, and of both tide and wind. Throughout this study, monthly mean values are used for the Kuroshio Current input in the southern boundary of the model domain, for the transport through the Korea Strait, for the river discharge, for the sea surface wind, and for the heat exchange rate across the air-sea interface. From the experiments, we obtained the following results. The circulation of the seas in winter is dependent on the very strong monsoon wind as several previous studies reported. The wintertime dispersion of the Yangtze River water follows the circulation pattern flowing southward along the east coast of China due to the strong monsoon wind. Some observed salinity distributions support these calculation results. In summertime, generally, low-salinity water from the river tends to spread southward and eastward as a result of energetic vertical mixing processes due to the strong tidal current, and to spread more eastward due to the southerly wind. The tide effect for the circulation and dispersion of the river water near the river mouth is a dominant factor, but the southerly wind is still also a considerable factor. Due to both effects, two major flow directions appear near the river mouth. One of them is a northern branch flow in the northeast area of the river mouth moving eastward mainly due to the weakened southerly wind. The other is a southern branch flow directed toward the southeastern area off the river mouth mostly caused by tide and wind effects. In this case, however, the tide effect is more dominant than the wind effect. The distribution of the low salinity water follows the circulation pattern fairly well.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.36 no.4
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• pp.329-336
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• 2000

Welding is a important technological method in mechanical engineering. $CO_2$MAG(metal active gas) welding means that metal part in double capstan drum for the inshore and costal vessels are joined by melting(with or without a filler material) or that new material is added to a metal part by melting. The thermal stresses appear due to a non-uniform temperature field, inhomogeneous material properties, external restraint and volume changes during phase transformations. In this study analysis the elasto-plastic thermal stresses distribution of welding part in double capstan drum for the inshore and costal vessels using finite element method (FBM). Therefore it calculates the numerical value that can be applied to the optimum design of welding parts and the shapes. The significant results obtained in this study are summarized as fellows. At early stage of the cooling after welding process, the abrupt thermal stresses gradient has been shown in the vicinity of welding part. In the thermal stresses analysis due to temperature gradient and heat shocking maximum stress was occurred of welding part and stresses were distributed from 54MPa~48MPa.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.13 no.4
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• pp.283-293
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• 2015

The buffer is a key component of the engineered barrier system in a high-level radioactive waste (HLW) repository. The present study reviewed the requirements and functional criteria of the buffer reported in literature, and also based on the results, proposed an approach to establish a buffer concept which is applicable to an HLW repository in Korea. The hydraulic conductivity, radionuclide-retarding capacity (equilibrium distribution coefficient and diffusion coefficient), swelling pressure, thermal conductivity, mechanical properties, organic carbon content, and illitization rate were considered as major technical parameters for the functional criteria of the buffer. Domestic bentonite (Ca-bentonite) and, as an alternative, MX-80 (Na-bentonite) were proposed for the buffer of an HLW repository in Korea. The technical specifications for those proposed bentonites were set to parameter values that conservatively satisfy Korea's functional criteria for the Ca-bentonite and Swedish criteria for the Na-bentonite. The thickness of the buffer was determined by evaluating the means of shear behavior, radionuclide release, and heat conduction, which resulted in the proper buffer thickness of 0.25 to 0.5 m. However, the final thickness of the buffer should be determined by considering coupled thermal-hydraulic-mechanical evaluation and economics and engineering aspects as well.

• Journal of Korea Water Resources Association
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• v.33 no.4
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• pp.471-482
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• 2000

Surface energy balance components were evaluated by Landsat TM data and GIS with meteorological data. Calibration and validation for the applicability of this methodology were made through the estimating of the large-scale evapotranspiration (ET). In addition, sensitivity and error analysis was conducted to see the effects of the surface energy balance components on ET and the accuracy of each components. Bochong-chon located on the upper part of Guem River basin was selected as the case study area. Spatial distribution map of ET were produced for five dates: Jan. 1, Apr. 3, May. 10, and Nov. 27, 1995. The study results showed tat ET was greatly varied with the aspect and theland use type on the surface. In the case of having northeast and southeast in the aspect, ET was linearly increased depending on growing net radiation. While surface temperature has a high value, NDVI(Normalized Difference Vegetation Index) has a low value in the vegetated area. Therefore, ground heat flux was increased but ET was relatively decreased. The results of sensitivity and error analysis showed that net radiation is most sensitive and effective, ranging from 12.5% to 23.6% of sensitivity. Furthermore, the surface temperature, air temperature, and wind speed have the significant effects on ET estimation using remotely sensed data.