• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.3
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• pp.397-410
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• 2023

This study examined the efficacy of various chlorinating agents in partitioning light water reactor spent fuel, with the aim of optimizing the chlorination process. Through thermodynamic equilibrium calculations, we assessed the outcomes of employing MgCl₂, NH₄Cl, and Cl₂ as chlorinating agents. A comparison was drawn between using a single agent and a sequential approach involving all three agents (MgCl₂, NH₄Cl, and Cl₂). Following heat treatment, the utilization of MgCl₂ as the sole chlorinating agent resulted in a moderate separation. Specifically, this method yielded a solid separation with 96.9% mass retention, 31.7% radioactivity, and 44.2% decay heat, relative to the initial spent fuel. In contrast, the sequential application of the chlorinating agents following heat treatment led to a final solid separation characterized by 93.1% mass retention, 5.1% radioactivity, and 15.4% decay heat, relative to the original spent fuel. The findings underscore the potential effectiveness of a sequential chlorination strategy for partitioning spent fuel. This approach holds promise as a standalone technique or as a complementary process alongside other partitioning processes such as pyroprocessing. Overall, our findings contribute to the advancement of spent fuel management strategies.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.6
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• pp.465-474
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• 2014

To validate the accuracy of the boiling heat flux partitioning model, an experiment was performed to investigate how the wall heat flux is divided into the three heat transfer modes of evaporation, quenching, and single-phase convection during subcooled nucleate boiling on a vertical wall. For the experimental partitioning of the wall heat flux, the wall heat flux and liquid-vapor distributions were simultaneously obtained using synchronized infrared thermometry and the total reflection technique. Boiling experiments of water with subcooling of $10^{\circ}C$ were conducted under atmospheric pressure, and the results obtained at the wall superheat of $12^{\circ}C$ and average heat flux of $283kW/m^2$were analyzed. There was a large difference in the heat flux partitioning results between the experiment and correlation, and the bubble departure diameter and bubble influence factor, which account for a portion of the surrounding superheated liquid layer detached by the departure of a bubble, were found to be important fundamental boiling parameters.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.7
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• pp.457-470
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• 2016

Most CFD codes, that mainly adopt the heat partitioning model as the wall boiling model, have shown low accuracies in predicting the two-phase flow parameters of subcooled boiling phenomena under low pressure conditions. In this study, a number of subcooled boiling experiments in vertical channels were analyzed using a thermal-hydraulic component code, CUPID. The prediction of the void fraction distribution using the CUPID code agreed well with experimental data at high-pressure conditions; whereas at low-pressure conditions, the predicted void fraction deviated considerably from measured ones. Sensitivity tests were performed on the submodels for major parameters in the heat partitioning model to find the optimized sets of empirical correlations suitable for low-pressure subcooled flow boiling. The effect of the K-factor on the void fraction distribution was also evaluated.

• Preventive Nutrition and Food Science
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• v.16 no.3
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• pp.267-271
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• 2011

Static Headspace Gas Chromatographic analysis was used to study the partitioning behavior of five organic printing ink solvents between chocolate cookie/air systems. Three cookie sample formulations varied with respect to chocolate type and overall percentage of constituents. Major considerations involved differences in fat content and type and resulting variability in chemical and physical structure. Each of the solvents studied (ethyl acetate, hexane, isopropanol, methyl ethyl ketone, toluene) represents a general class of printing ink solvents based on predominate functional group. Values of the partitioning coefficient (Kp) were determined at equilibrium using measured quantities of both solvent and cookie sample in closed systems at temperature of 25, 35, and $45^{\circ}C$. In each of the three cookies at the three test temperatures, toluene always exhibited the greatest value of partitioning to cookie and hexane always exhibited the least. Results also showed that the partitioning behavior of solvents is generally inversely related to temperature and that solvent affinity, though constant for a particular cookie type over all test temperatures, varies significantly among the three cookie types. The preference of each of the five solvents for each cookie sample was also found to vary with temperature. No correlation was found between the extent of partitioning and cookie formulation or physical characteristic of solvent. The Hildebrand parameter, related to ${\Delta}Hmix$ (heat of mixing), may be used to describe differences in partitioning based on the overall potential of a solvent/cookie interaction to occur. The potential for interaction is dependent upon the chemical structure of the cookie sample and thus the availability of 'active-sites' required for a given solvent.

• Korean Journal of Materials Research
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• v.19 no.6
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• pp.305-312
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• 2009

The effects of Quenching and Partitioning (Q&P) and Annealed Martensite (AM) heat treatment on the microstructure and tensile properties were investigated for 0.24C-0.5Si-1.5Mn-1Al steels. The Q&P steels were annealed at a single phase ($\gamma$) or a dual phase (${\gamma}+{\alpha}$), followed by quenching to a temperature between $M_s$ and $M_f$. Then, enriching carbon was conducted to stabilize the austenite through the partitioning, followed by water quenching. The AM steels were intercritically annealed at a dual phase (${\gamma}+{\alpha}$) temperature and austempered at $M_s$ and $M_s{\pm}50^{\circ}C$, followed by cooling in oil quenching. The dual phase Q&P steels showed lower tensile strength and yieldyield strength than those of the single phase Q&P steels, and tThe elongation for the dual phase Q&P steel was partitioning 100s higher than that of that for the single phase Q&P steels as the partitioning time was less than 100s up to partitioning 100s. For AM steels, the tensile/yield strength decreased and the total elongation increased as the austempering temperature increased. The stability of the retained austenite controlled the elongation for Q&P steels and the volume fraction of the retained austenite controlled the elongation for AM steels.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.103-108
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• 2003

The control of flame shapes in a laminar pre-mixed flame has been experimentally investigated for propane/air pre-mixed laminar flames. Flames of different size and shapes are observed with heated wires or by controlling the equivalence ratio and flow rate of a mixture. The characteristics of the partitioning of a flame or the merge of flames are analyzed and explained by considering the balance between laminar flame speed and upstream mixture velocity. A combustor might be sized down while maintaining its heat production rate the same by partitioning a flame established in it. When the equivalence ratio of mixture is decreased, individual flames are merged together and the upstream mixture velocity can be practically decreased on a nozzle having opening ratio less than unity. As a result, the flame shape is to he adjusted until the newly established balanced condition is satisfied, and then. the stable combustion can be achieved again.

• Korean Journal of Materials Research
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• v.19 no.6
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• pp.293-299
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• 2009

The microstructures and mechanical properties of Dual Phase (DP), Transformation-Induced Plasticity (TRIP), and Quenching & Partitioning (Q&P) steels were investigated in order to define the strengthening mechanism of 0.2 C steel. An intercritical annealing between Ac1 and Ac3 was conducted to produce DP and TRIP steel, followed by quenching the DP and TRIP steel being quenched at to room temperature and by the TRIP steel being austemperingaustempered-air cooling cooled the steel toat room temperature, respectively. The Q&P steel was produced from full austenization, followed by quenching to the temperature between $M_s$ and $M_f$, and then enriching the carbon to stabilize the austenite throughout the heat treatment. For the DP and TRIP steels, as the intercritical annealing temperature increased, the tensile strength increased and the elongation decreased. The strength variation was due to the amount of hard phases, i.e., martensite and bainite, respectively in the DP and TRIP steels. It was also found that the elongation also decreased with the amount of soft ferrite in the DP and TRIP steels and with the amount of the that was retained in the austenite phasein the TRIP steel, respectively for the DP and TRIP steels. For the Q&P steel, as the partitioning time increased, the elongation and the tensile strength increased slightly. This was due to the stabilized austenite that was enriched with carbon, even when the amount of retained austenite decreased as the partitioning time increased from 30 seconds to 100 seconds.

• Nuclear Engineering and Technology
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• v.54 no.6
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• pp.2276-2296
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• 2022

This study validates the applicability of the CUPID code for simulating subcooled wall boiling under high-pressure conditions against number of DEBORA tests. In addition, a new numerical technique in which the interfacial momentum non-drag forces are calculated at the cell faces rather than the center is presented. This method reduced the numerical instability often triggered by calculating these terms at the cell center. Simulation results showed good agreement against the experimental data except for the bubble sizes in the bulk. Thus, a new model to calculate the Sauter mean diameter is proposed. Next, the effect of the relationship between the bubble departure diameter (D_dep) and the nucleation site density (N) on the performance of the Wall Heat Flux Partitioning (WHFP) model is investigated. Three correlations for D_dep and two for N are grouped into six combinations. Results by the different combinations show that despite the significant difference in the calculated D_dep, most combinations reasonably predict vapor distribution and liquid temperature. Analysis of the axial propagations of wall boiling parameters shows that the N term stabilizes the inconsistences in D_dep values by following a behavior reflective of D_dep to keep the total energy balance. Moreover, ratio of the heat flux components vary widely along the flow depending on the combinations. These results suggest that separate validation of D_dep correlations may be insufficient since its performance relies on the accompanying N correlations.

• Proceedings of the KSRS Conference
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• 2005.10a
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• pp.415-417
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• 2005

In order to retrieve the latent and sensible heat fluxes, high-resolution airborne imageries with visible, near infrared, and thermal infrared bands and ground-base meteorology measurements are utilized in this paper. The retrieval scheme is based on the balance of surface energy budget and momentum equations. There are three basic surface parameters including surface albedo $(\alpha)$, normalized difference vegetation index (NOVI) and surface kinetic temperature (TO). Lowtran 7 code is used to correct the atmosphere effect. The imageries were taken on 28 April and 5 May 2003. From the scattering plot of data set, we observed the extreme dry and wet pixels to derive the fitting of dry and wet controlled lines, respectively. Then the sensible heat and latent heat fluxes are derived from through a partitioning factor A. The retrieved latent and sensible heat fluxes are compared with in situ measurements, including eddy correlation and porometer measurements. It is shown that the retrieved fluxes from our scheme match with the measurements better than those derived from the S-SEBI model.

• Advances in aircraft and spacecraft science
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• v.5 no.4
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• pp.411-430
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• 2018

This computational study examines the augmentation of classic 2-D Rayleigh-$B{\acute{e}}nard$ convection by the addition of periodically-spaced transverse fins. The fins are attached to the heated base of the cavity and serve to partition the cavity into 'units' with different aspect ratios. The respective impacts upon heat transfer of the fin configuration parameters - including spacing, height, thickness and thermal conductivity - are systematically examined through numerical simulations for a range of laminar Rayleigh numbers (0 < Ra < $2{\times}10^5$) and reported in terms of an average Nusselt number. The selection of the low Rayleigh number regime is linked to likely scenarios within aerospace applications (e.g. avionics cooling) where the cavity length scale and/or gravitational acceleration is small. The net heat transfer augmentation is found to result from a combination of competing fin effects, most of which are hydrodynamic in nature. Heat transfer enhancement of up to $1.2{\times}$ that for a Rayleigh-$B{\acute{e}}nard$ cavity without fins was found to occur under favorable fin configurations. Such configurations are generally characterized by short, thin fins with half-spacings somewhat less than the convection cell diameter from classic Rayleigh-$B{\acute{e}}nard$ theory. In contrast, for unfavorable configurations, it is found that the introduction of fins can result in a significant reduction in the heat transfer performance.