• Title/Summary/Keyword: Heat Condition

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Photochromic Properties of Cellulose Derivatives Having Spirobenzopyran Group (스피로벤조피란을 포함하는 셀룰로오스 유도체의 광변색 특성)

  • Xiangdan, Li;Kim, Eun-Kyoung;Lee, Myong-Hoon
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.25-31
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    • 2005
  • Cellulose acetate derivatives containing 6-(p-hexyloxyphenyl)carbonyl spirobenzopyran (CA-COSP) were prepared from base-catalyzed etherification of cellulose acetate, and their physical and photochromic properties were characterized. The degree of substitution of COSP was calculated from the amount of residual hydroxyl groups in cellulose acetate measured by the $^1H$-NMR and UV spectrometric data. It was ranging from 0.87 to 45.5% depending on the reaction condition. UV/vis spectrometry of the resulting CA-COSP revealed that the polymer shows a reversible color change by changing its color from colorless to blue upon UV irradiation forming a merocyanine structure, and returning back again to colorless spiropyran structure by visible light or by heat. The rate of color change was faster in solution than in the film. In the more polar solvent, the more stable was the resulting merocyanine, and the slower was the rate of reverse reaction to spiropyran. Compared to COSP blended with cellulose acetate, in which a phase separation was observed for samples containing more than 0.9 wt% of COSP, up to 48 wt% of COSP could be blended in CA-COSP without phase separation.

Analysis of Factors Affecting the Hygroscopic Performance of Thermally Treated Pinus koraiensis Wood (잣나무열처리재의 흡방습성능에 미치는 영향인자 분석)

  • Chang, Yoon-Seong;Han, Yeon-Jung;Eom, Chang-Deuk;Park, Joo-Saeng;Park, Moon-Jae;Choi, In-Gyu;Yeo, Hwan-Myeong
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.1
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    • pp.10-18
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    • 2012
  • A high airtightness is required for the residential spaces constructed recently to save cooling and heating energy through improving insulation performance. Because the chances to release steam formed by human activity in building and inflow of water vapor in outdoor air to residential space are reduced, the natural humidity control performance of interior materials has become more important. In this study, hygroscopic performance of thermo-physically treated wood (Pinus koraiensis) was estimated. At various relative humidity condition, the water vapor adsorption and desorption rates of wooden materials were measured as well as equilibrium moisture content. Effects of roughness and surface microstructure as physical factors and functional groups as chemical factors on the hygroscopicity were analyzed. It is expected that the results from this study and further study of measuring moisture generation in residential spaces could contribute to install a system for evaluating the hygrothermal performance of wooden building.

A ground theory approach on fatigue of the female elderly with osteoarthritis (관절염을 앓고 있는 노인 여성 피로 경험의 근거 이론적 접근)

  • Kwon, Young-Eun;Chung, Myung-Sill
    • Journal of muscle and joint health
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    • v.3 no.1
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    • pp.50-62
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    • 1996
  • The purpose of this study was to identify and construct a substantive theory about the experience of fatigue among the female elderly with osteoarthritis. The interviewees were 6 female elderly with osteoarthritis. Of them 3 were admitted General hospital, the remaining 3 didn't admitted hospital. The data were collected through in-depth interviews by the investigators from May 20th, 1995 to June 19th, 1995. The collected data were coded into concepts and categories according to Strauss & Corbin's grounded method. The data thus collected were analyzed immediatly after interviews and fed into next round of interviews until the data collection reaches the saturation point where no additional concepts emerge. The 35 concepts were from analyzing the grounded data. The results of this study were as follows : 'change of the health condition','change of the life pattern', 'physiologic change', 'change of the coping pattern', 'performance of homework', 'activity daily living', 'tireness', 'ache', 'change of general apperance', 'sleep disturbance', 'powerlessness'. 'Physiologic unbalance', 'change of the family dynamics', 'physical imbalance', 'loss of the control', aviodance', 'conversion', 'leaving', 'indifference', 'hesitation', 'the pursue of information and trial', 'the western therapy', 'heat therapy', 'the oriental therapy','exercise', 'weight control', 'support', 'solution', 'being as before', 'adding more'. Six categories emerged from the analysis of ground data. They were as follows : 'stimuli', 'fatigue', 'passive coping', 'active coping', 'disolution', 'remains'. 13 hypothesis were derived from the integration of categories as follows : 1. The stronger the stimulus as perceived by the subjects, the more the fatigue will exrerience. 2. The more severe the fatigue, the more severe the tireness. 3. The more severe the fatigue, the more the hardness. 4. The more severe the fatigue, the more the variability of appear will experience. 5. The more severe the fatigue, the more the pain will experience. 6. The more severe the fatigue, the more the insomnia will experience. 7. The more severe the fatigue, the more the powerless will experience. 8 The more severe the fatigue, the more the psychological unbalance will experience. 9. The more severe the fatigue, the more variability of the family dynamics will experience. 10. The more severe the fatigue, the more the physical unbalance will experience. 11. The more severe the fatigue, the more loss of control will experience. 12. The subjects who experienced the fatigue will be to show passive coping and active coping mechanism.

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A Study of King Kyung-jong's strange diseases according to Medical records from 『The Daily Records of Royal Secretariat of Chosun Dynasty』 (『승정원일기(承政院日記)』의안(醫案)을 통해 살펴본 경종(景宗)의 기질(奇疾)에 대한 이해)

  • Kim, Dong-Ryul;Kim, Namil;Cha, Wung-Seok
    • The Journal of Korean Medical History
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    • v.26 no.1
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    • pp.41-53
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    • 2013
  • In this paper, King Kyung-Jong's strange diseases which had been exacerbated by the Sinim-Sahwa(辛壬士禍) are researched and discussed. The subject will be described mostly based on health and medical records from "The Daily Records of Royal Secretariat of Chosun Dynasty(承政院日記)" and "The Annals of the Choson Dynasty(朝鮮王朝實錄)". Sinim-Sahwa had occurred for two years. It is thought that the beginning of it was 'a controversy on a proclamation of a crown prince, Yeon Ing Goon'. At the first year of Kyung-Jong's ruling, August 21, the No-Ron demanded a king's heir be decided as soon as possible, the king asked Yeon Ing Goon as his successor because of his 'strange diseases'. In October of the same year, the conflict between No-Ron and So-Ron parties reached its peak after a dispute about 'regency from behind the veil for the crown prince' at that time. Kyung-jong added that he had a mysterious and heavy disease and there was little hope to recover from it. Some opposing courtiers emphasized the king was in his good health and there weren't any actual diseases he suffered. But Kyung-Jong stubbornly persisted the diseases he had were so heavy that he couldn't get well readily. In detail, he announced his disease had so deeply rooted in internal organs that he could feel some kind of heat and fire arousal form his heart, then rage and resent soaring. Eventually, on 16th, the No-Ron party followed the king's demand, thus the king's health and illness condition itself was gradually getting off the subject. It seems that Kyung-jong's strange diseases was hwa-byung(火病). His symtoms are similar to the symtoms of hwa-byung. Environment he lived, was enough to cause hwa-byung. as a result, Sinim-Sahwa was the event what his hwa(火) was erupted.

Experimental Study on the Extinguishing Characteristics of Twin-fluid Nozzle using a Small-scale Hexane Pool Fire (소규모 헥산 풀화재를 이용한 2유체노즐의 소화 특성에 대한 실험적 연구)

  • Jeong, Chan Seok;Lee, Chi Young
    • Fire Science and Engineering
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    • v.32 no.3
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    • pp.35-41
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    • 2018
  • Experiments were performed on 140 ml hexane pool fire extinguishment using a twin-fluid nozzle. For this pool fire, the area of the fire source (round shape of 80 mm in diameter) was $0.005027m^2$ and the measured heat release rate was 2.81 kW. The flow rates of water and gas (air and nitrogen) supplied to the twin-fluid nozzle were 156-483 g/min (~0.156-0.483 l/min) and 30-70 l/min, respectively. In the present experimental ranges, the high gas flow rate conditions led to the successful extinguishing of the pool fire. Under the low gas flow rate conditions in the extinguishment regime, the extinguishment time was long and the estimated water consumption was high. Under high gas flow rate conditions, however, the water flow rate conditions did not appear to have a great impact on the extinguishment time and estimated water consumption. On the other hand, in the present experimental ranges, the types of supply gas did not appear to affect the extinguishable flow rate condition, extinguishment time, and estimated water consumption. Finally, using the present experimental results with previous ones using a single-fluid nozzle, the water consumption of twin-fluid and single-fluid nozzles for extinguishing a 140 ml hexane pool fire were preliminarily compared and discussed.

Physicochemical quality characteristics of hot water extracts of processed ginseng based on different heat treatments (열처리 방법에 따른 가공 인삼 열수추출물의 이화학적 품질 특성)

  • Kang, Yoon-Han;Zhou, Rui;Kim, Hyo Jin;Kim, Ji Eun;Shin, Il Shik
    • Food Science and Preservation
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    • v.25 no.1
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    • pp.155-163
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    • 2018
  • The present study was carried out to investigate the physicochemical properties of hot water extracts of red ginseng powder prepared by two-stage hot air drying method using steamed ginseng and steaming liquid for 2.5 h under high-temperature and high-pressure autoclave condition. The total polyphenols, total flavonoids, total sugar, acid polysaccharides and crude saponin in hot water extracts from red ginseng powder were analyzed and determined, and the flavor components of ginseng were measured using color difference meter and an electronic tongue. The total polyphenol, total flavonoid, total polysaccharide, and acid polysaccharide of the red ginseng hot water extract obtained by autoclaving (ARG) were 9.06 mg GAE/g, 3.38 mg NE/g, 35.22 g/100 g, and 10.90 g/100 g, respectively. The final contents of the total polyphenols, total flavonoids, crude saponin were higher than those determined using other red ginseng methods; the time required for steamed red ginseng production reduced. The total ginsenoside content of ginseng including Rb1 was 10.69 mg/g, which is the lowest ARG. The processing conditions affected the conversion to ginsenosides unique to red ginseng. Red ginseng and steaming liquid obtained from the autoclave are expected to be in need for non-food materials and products as well as foods by improving the flavor components through conversion of red ginseng components into low molecular weight.

Effects of Intake Gas Mixture Cooling on Enhancement of The Maximum Brake Power in a 2.4 L Hydrogen Spark-ignition Engine (수소 내연기관의 흡기 냉각 방법에 따른 최고 출력 향상에 관한 연구)

  • Kim, Yongrae;Park, Cheolwoong;Oh, Sechul;Choi, Young;Lee, Jeongwoo
    • Journal of the Korean Institute of Gas
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    • v.25 no.5
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    • pp.11-18
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    • 2021
  • Since hydrogen has the lower minimum ignition energy than that of gasoline, hydrogen could be also appropriate for the IC engine systems. However, due to the low ignition energy, there might be a 'back-fire' and 'pre-ignition' problems with hydrogen SI(Spark-ignition) combustion. In this research, cooling effects of intake gas mixture on the improvement of the maximum power output were evaluated in a 2.4 L SI engine. There were two ways to cool intake gas mixtures. The first one was cooling intake fresh air by adjusting inter-cooler system after turbocharger. The other one was cooling hydrogen fuel before supplying by using heat ex-changer. Cooling hydrogen was performed under natural aspired condition. The result showed that cooling fresh air from 40 ℃ to 20~30 ℃ improved the maximum brake power up to 6.5~8.6 % and cooling hydrogen fuel as -6 ℃ enhanced the maximum brake power likewise.

Enhanced supply of methionine regulates protein synthesis in bovine mammary epithelial cells under hyperthermia condition

  • Zhou, Jia;Yue, Shuangming;Xue, Benchu;Wang, Zhisheng;Wang, Lizhi;Peng, Quanhui;Xue, Bai
    • Journal of Animal Science and Technology
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    • v.63 no.5
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    • pp.1126-1141
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    • 2021
  • Recent evidence has shown that methionine (Met) supplementation can improve milk protein synthesis under hyperthermia (which reduces milk production). To explore the mechanism by which milk protein synthesis is affected by Met supplementation under hyperthermia, mammary alveolar (MAC-T) cells were incubated at a hyperthermic temperature of 42℃ for 6 h in media with different concentrations of Met. While the control group (CON) contained a normal amino acid concentration profile (60 ㎍/mL of Met), the three treatment groups were supplemented with Met at concentrations of 10 ㎍/mL (MET70, 70 ㎍/mL of Met), 20 ㎍/mL (MET80, 80 ㎍/mL of Met), and 30 ㎍/mL (MET90,90 ㎍/mL of Met). Our results show that additional Met supplementation increases the mRNA and protein levels of BCL2 (B-cell lymphoma-2, an anti-apoptosis agent), and decreases the mRNA and protein levels of BAX (Bcl-2-associated X protein, a pro-apoptosis agent), especially at an additional supplementary concentration of 20 ㎍/mL (group Met80). Supplementation with higher concentrations of Met decreased the mRNA levels of Caspase-3 and Caspase-9, and increased protein levels of heat shock protein (HSP70). The total protein levels of the mechanistic target of rapamycin (mTOR) and the mTOR signalling pathway-related proteins, AKT, ribosomal protein S6 kinase B1 (RPS6KB1), and ribosomal protein S6 (RPS6), increased with increasing Met supplementation, and peaked at 80 ㎍/mL Met (group Met80). In addition, we also found that additional Met supplementation upregulated the gene expression of αS1-casein (CSN1S1), β-casein (CSN2), and the amino acid transporter genes SLC38A2, SLC38A3 which are known to be mTOR targets. Additional Met supplementation, however, had no effect on the gene expression of κ-casein (CSN3) and solute carrier family 34 member 2 (SLC34A2). Our results suggest that additional Met supplementation with 20 ㎍/mL may promote the synthesis of milk proteins in bovine mammary epithelial cells under hyperthermia by inhibiting apoptosis, activating the AKT-mTOR-RPS6KB1 signalling pathway, and regulating the entry of amino acids into these cells.

High Temperature Corrosion Effect of Superheater Materials by Alkali Chlorides (염화알칼리에 의한 과열기 소재의 고온부식 영향)

  • Kim, Beomjong;Jeong, Soohwa;Kim, Hyesoo;Ryu, Changkook;Lee, Uendo
    • Clean Technology
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    • v.24 no.4
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    • pp.339-347
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    • 2018
  • In order to cope with environmental problems and climate change caused by fossil fuels, renewable energy supply is increasing year by year. Currently, waste energy accounts for 60% of renewable energy production. However, waste has a lower calorific value than fossil fuels and contains various harmful substances, which causes serious problems when applied to power generation boilers. In particular, the chlorine in the waste fuel increases slagging and fouling of boiler heat exchangers, leading to a reduction in thermal efficiency and the main cause of high temperature corrosion, lowering facility operation rate and increasing operating cost. In this study, the high temperature corrosion experiments of superheater materials (ASME SA213/ASTM A213 T2, T12 and T22 alloy steel) by alkali chlorides were conducted, and their corrosion characteristics were analyzed by the weight loss method and SEM-EDS. Experiments show that the higher the temperature and chloride content, the more corrosion occurs, and KCl further corrodes the materials compared to NaCl under the same condition. In addition, the higher the chromium content of the material, the better the corrosion resistance to the alkali chlorides.

A Study on The Thickness Shrinkage of Injection Molded Parts with The Variation of Injection Mold Core and Molding Materials (사출금형코어 및 성형수지 변화에 따른 두께 방향 수축률에 관한 연구)

  • Shin, Sung-Hyun;Jeong, Eui-Chul;Kim, Mi-Ae;Chae, Bo-Hye;Son, Jung-Eon;Kim, Sang-Yoon;Yoon, Kyung-Hwan;Lee, Sung-Hee
    • Design & Manufacturing
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    • v.13 no.2
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    • pp.17-21
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    • 2019
  • In this study, selective laser sintered 3D printing mold core and metal core were used to investigate the difference of the thickness shrinkage from the gate of the injection molded part at a constant interval. SLS 3D printing mold core was made of nylon-based PA2200 powder and the metal core was manufactured by conventional machining method. As the PA2200 powder material has low strength, thermal conductivity and high specific heat characteristics compared with metal, molding conditions were set with the consideration of molten temperature and injection pressure. Crystalline resin(PP) and amorphous resin(PS) with low melting temperature and viscosity were selected for the injection molding experiment. Cooling time for processing condition was selected by checking the temperature change of the cores with a cavity temperature sensor. The cooling time of the 3D printing core was required a longer time than that of the metal core. The thickness shrinkage of the molded part compared to the core depth was measured from the gate by a constant interval. It was shown that the thickness shrinkage of the 3D printing core was 2.02 ~ 4.34% larger than that of metal core. In additions, in the case of metal core, thickness shrinkage was increased with distance from the gate, on the contrary, in the case of polymer core showed reversed aspect.