• Korean Journal of Hazardous Materials
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• v.3 no.1
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• pp.59-64
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• 2015

Semiconductor industry has large number of chemical inventory and is easily exposed to chemical release incidents. Toxic release is one of the most interested area in evaluating consequence to the vicinity of industry facilities handling hazardous materials. Hydrofluoric acid is one of the typical chemical used in semiconductor facility and is selected and toxic release is evaluated to assess the risk impacted to its off-site. Accident scenarios were listed using process safety information. The scenarios having effect to the off-site were selected and assessed further according to guideline provided by Korea government. Worst case and alternative scenarios including other interested scenarios were evaluated using ALOHA. Each evaluated scenario was assessed further considering countermeasures. The results showed that the facility handling hydroflooric acid is safe enough and needed no further protections at the moment.

• Journal of Environmental Health Sciences
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• v.49 no.4
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• pp.179-182
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• 2023

The Chemical Substances Control Act has been legislated to counter the risks posed by chemical substances to public health and the environment, but a number of small- and large-scaled incidents related to hazardous chemicals continue to occur every year. The Korean Ministry of Environment takes legal responsibility for prevention, preparedness, and response to nationwide chemical accidents under the Chemical Substances Control Act. The determination of chemical accidents that occur during hazardous chemical handling processes is based on the Article 2 (Definitions) of the law and the administrative criteria for judgement of chemical accidents. However, there are certain ambiguities in the scientific basis for determining chemical accidents under the current regulations. Whether or not a chemical accident has a direct influence on penalties and administrative measures for a workplace where an accident occurred, it is necessary to find reasonable criteria for determining chemical accident based on legal and scientific evidence.

• Journal of the Korean Society of Safety
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• v.6 no.1
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• pp.39-53
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• 1991

Prior to being prepared the surveilance method and the surveilance system of chemical hazards, the employer's investigastion of the newly-registered-chemical hazards has been to be under obligation along with legislation of the Hazardous Chemicals Control Act and revision of the Industrial Safety & Health Act in 1990. In order to make up the chemical hazards examining plan and to frame the chemical hazards investigating system about the newly-registered chemicals and the existing hazardous chemicals in worksite environments, the KISCO's chemical hazards surveilance program is methodologically researched and presented.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.493-497
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• 2020

Hazardous area classification is designed to prevent chemical plant explosions in advance. Generally, the duration of the explosive atmosphere is used for zone type classification. Herein, IEC code, a quantitative zone type classification methodology, was used to achieve Zone 2 NE, which indicates a practical non-explosion condition. This study analyzed the operating pressure of a vessel handling propane to achieve Zone 2 NE by applying the IEC code via MATLAB. The resulting zone type and hazardous area grades were compared with the results from other design standards, namely API and EI codes. According to the IEC code, the operating pressure of vessels handling propane should be between 101325-116560.59 Pa. In contrast, the zone type classification criteria used by API and EI codes are abstract. Therefore, since these codes could interpret excessively explosive atmospheres, care is required while using them for hazardous area classification design.

• Journal of environmental and Sanitary engineering
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• v.9 no.2
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• pp.58-62
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• 1994

Until 1960 water pollution was caused by virus but now in according to industrial develop cent it has been continued environmental pollution by surfactant heavy metal, and hazardous chemical substance erst.. It is possible to Prevent contamination by virus owing to development of antibiotic but not to dissolve basely health effect by hazardous chemical substances because it takes very long time, about 5-40 years, average 20 years, in appearing a disease after exposure by then To maintain human life for 75 years, it need 55 ton of water. In the experiment of Public Health Institute, Tokyo, they reported that over 200 chemical substances can be detected in case of human being to drink tap water of Tokyo(1989) continuously. In our country, elevation of life style and development of industry result in increase of water use and overappreciation of pesticides in farm land a(sects drinking water quality. We estimated analytical item of drinking water hygienically by dividing into 5 groups such as physical effect item health hazardous inorganic item and health hazardous organic item ect. based on hygienic purpose.

• Journal of the Korean Society of Safety
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• v.31 no.3
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• pp.53-59
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• 2016

Considering the chemical reaction between concrete which is the raw material of the dike bottoms and hazardous chemicals, some chemicals can have negative effects on the impermeability of concrete dike bottoms. The impermeable standards for the concrete bottom of dikes have been made in the recent study, but the previous study was based on the exposure test to crude oil which is not corrosive and not related to the chemical reaction. It can be concluded that the test of crude oil can't represent all kinds of hazardous chemicals, especially highly corrosive chemicals. Meanwhile, this study has conducted the exposure test to nitric acid that is strongly corrosive and very hazardous. The results have showed that nitric acid has been penetrated at the maximum penetration depth of 2.9 cm for 7 days and the impermeable standards are better than the germany standard. Through this study with severe chemical, the scientific basis on the installation standards of all dike bottoms which are generally used in the industry has been obtained.

• Korean Journal of Hazardous Materials
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• v.3 no.1
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• pp.52-58
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• 2015

Since the HF release in 2012 in Korea, it became one of the most significant to evaluate consequence to the vicinity of industry facilities handling hazardous materials. BTX plant is selected to assess off-site risk to check whether the facility satisfies the Chemical Control Law by Korea Government. Accident scenarios were listed using process safety information. The scenarios having effect to the off-site were selected and assessed further according to guideline provided by Korea government. Worst case and alternative scenarios including other interested scenarios were evaluated using ALOHA. Each evaluated scenario was assessed further considering countermeasures. The results showed that the facility handling chloric acid is safe enough and needed no further protections at the moment.

• Journal of the Korean Society of Safety
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• v.39 no.3
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• pp.20-26
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• 2024

The Chemical Substances Control Act of South Korea mandates submission of transportation plans containing information on the transportation of hazardous chemicals, with over 600,000 submissions recorded annually. In this study, big data analysis was performed on 2,506,985 transportation plans to identify trends and assess their correlation with chemical transportation accidents. The analysis confirmed that despite NaOH accounting for 20.7% of transportation plans, HCl constitutes 40% of chemical transportation accidents, which indicates a correlation of these accidents with the chemical properties of hazardous substances rather than with the number of submitted transportation plans. Furthermore, chemical transportation accidents show a higher probability of occurrence in the 6-8 am and 6-8 pm windows, which is in agreement with higher incidence and fatality rates. The departure points of transportation plans are closely related to the characteristics of local chemical industrial complexes such as Ulsan, Yeosu, and Gunsan, whereas the arrival points are closely related to Pyeongtaek, Hwaseong, and Icheon, which are the locations of semiconductor industries. Ultimately, achievement of safety by consideration of characteristics of transported chemicals, enhancement of driver concentration during specific times, and implementation of preventive measures tailored to local government characteristics are strategies anticipated to contribute to a reduction in chemical transportation accidents.

• 대한예방의학회:학술대회논문집
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• 1994.02a
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• pp.405-411
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• 1994

Hazardous wastes released into the general environment are of concern to the public and to public health authorities. In response to this concern, the Comprehensive Environmental Response, Compensation, and Liability Act, as amended (commonly called Superfund), was enacted in 1980 to provide a framework for environmental, public health, and legal actions concerning uncontrolled releases of hazardous substances. The Agency for Toxic Substances and Disease Registry (ATSDR) was created by Superfund to address the public health issues of hazardous wastes in the community environment. Two key Agency programs, Public Health Assessments and Toxicological Profiles, are designed to assess the risk to human health of exposures to hazardous substances that migrate from waste sites or through emergency releases (e.g., chemical spills). The Agency's public health assessment is a structured process that permits ATSDR to identify which waste sites or other point sources require traditional public health actions (e.g.. human exposure studies, health studies, registries, health surveillance, health advisories). The ATSDR qualitative public health assessment complements the U.S. Environmental Protection Agency's quantitative risk assessment. For Superfund purposes, both assessments are sitespecific. ATSDR's toxicological profiles are prepared for priority hazardous substances found most frequently at Superfund sites. Each profile presents the current toxicologic and human health effects information about the substance being profiled. Each profile also contains Minimal Risk Levels (MRLs), a type of risk assessment value. This paper covers ATSDR's experience in conducting public health assessments and developing MRLs, and it relates this experience to recommendations on how to improve chemical risk assessments.

• Journal of the Korean Institute of Gas
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• v.28 no.1
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• pp.19-26
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• 2024

In workplaces handling flammable gas such as hydrogen, hazardous area is determined through KS C IEC 60079-10-1 standard. Because this standard determines the hazardous distance based on the release characteristic regardless of the type of gas, indoor/outdoor conditions, and atmospheric conditions, concerns are being raised about the effectiveness. In this study, simulations (PHAST, HyRAM) were performed to calculate the hazardous distance for hydrogen under various release characteristics and atmospheric conditions, and compared these results to IEC standard log-log graph. Also, we performed regression analysis according to each result. we found that the simulation results were 0.6 to 3.8 times less than the IEC standard, presented convenient linear regression equations. In addition, We confirmed that the results of hazardous distance varied based on wind velocity and atmospheric stability at the same release characteristic. In addition, we derived linear regression equations for release characteristics and hazardous distance that can be conveniently utilized. So, when classifying hazardous area in workplaces where they handle the hydrogen, the integrated graph and linear regression equation are helpful for confirming the hazardous area. Moreover, it is expected that the economic burden will be minimized by being able to classify reasonable hazardous area and to greatly reduce the risk of hydrogen explosion.