• Title/Summary/Keyword: Hazard point

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Measurement of Flash Points for n-hexanol+n-butyric acid and n-butanol+propionic acid by Seta-flash Closed Cup Method (Seta-flash 밀폐식 방법에 의한 n-hexanol+n-butyric acid 계와 n-butanol+propionic acid 계의 인화점 측정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Society of Safety
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    • v.29 no.6
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    • pp.76-80
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    • 2014
  • The flash point is one of the most important physical properties used to determine the fire hazard of flammable liquid mixture and defined as the lowest temperature at which a liquid produces sufficient vapor to form a combustible mixture with air. The main purpose of this paper is to measure and predict the flash point of binary flammable miscible mixtures. The flash points for n-hexanol+n-butyric acid and n-butanol+propionic acid, were measured by using Seta-flash closed cup method. The experimentally derived data were correlated with the binary interaction parameters of the van Laar and NRTL equations through the optimization method. The flash points estimated by these correlations were compared with those calculated by the method based on Raoult's law. The optimization method were found to be better than the method based on the Raoult's law.

The Flash Point Measurement for Binary Flammable Mixture (이성분계 가연성 혼합물의 인화점 측정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.60-65
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    • 2014
  • The flash point is the major physical property used to characterize the fire hazard of flammable liquid solutions. In the present study, the main focus is on measuring and estimating the flash points for binary flammable mixture. The flash points for n-propanol+propionic acid were measured by Seta flash closed cup apparatus. The experimental data were correlated with the van Laar and NRTL equations through the optimization method. The results estimated by these correlations were compared with the values calculated by the method based on Raoult's law. The optimization method were found to be better than the method based on the Raoult's law.

Long-term Prognostic Value of Dipyridamole Stress Myocardial SPECT (디피리다몰 부하 심근관류 SPECT의 장기예후 예측능)

  • Lee, Dong-Soo;Cheon, Gi-Jeong;Jang, Myung-Jin;Kang, Won-Jun;Chung, June-Key;Lee, Myoung-Mook;Lee, Myung-Chul;Kang, Wee-Chang;Lee, Young-Jo
    • The Korean Journal of Nuclear Medicine
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    • v.34 no.1
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    • pp.39-54
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    • 2000
  • Purpose: Dipyridamole stress myocardial perfusion SPECT could predict prognosis, however, long-term follow-up showed change of hazard ratio in patients with suspected coronary artery disease. We investigated how long normal SPECT could predict the benign prognosis on the long-term follow-up. Materials and Methods: We followed up 1169 patients and divided these patients into groups in whom coronary angiography were performed and were not. Total cardiac event rate and hard event rate were predicted using clinical, angiographic and SPECT findings. Predictive values of normal and abnormal SPECT were examined using survival analysis with Mantel-Haenszel method, multivariate Cox proportional hazard model analysis and newly developed statistical method to test time-invariance of hazard rate and changing point of this rate. Results: Reversible perfusion decrease on myocardial perfusion SPECT predicted higher total cardiac event rate independently and further to angiographic findings. However, myocardial SPECT showed independent but not incremental prognostic values for hard event rate. Hazard ratio of normal perfusion SPECT was changed significantly (p<0.001) and the changing point of hazard rate was 4.4 years of follows up. However, the ratio of abnormal SPECT was not. Conclusion: Dipyridamole stress myocardial perfusion SPECT provided independent prognostic information in patients with known and suspected coronary artery disease. Normal perfusion SPECT predicted least event rate for 4.4 years.

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The Measurement and Prediction of Flash Point for Binary Mixtures of Methanol, Ethanol, 2-Propanol and 1-Butanol at 101.3 kPa (Methanol, Ethanol, 2-Propanol 그리고 1-Butanol 이성분 혼합계에 대한 101.3 kPa에서의 인화점 측정 및 예측)

  • Oh, In Seok;In, Se Jin
    • Fire Science and Engineering
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    • v.29 no.5
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    • pp.1-6
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    • 2015
  • Flash point is one of the most important variables used to characterize fire and explosion hazard of liquids. The lower flash point data were measured for the binary systems {methanol + 1-butanol}, {ethanol + 1-butanol} and {2-propanol + 1-butanol} at 101.3 kPa. Experiments were performed according to the standard test method (ASTM D 3278) using a SETA closed cup flash point tester. The measured flash points were compared with the predicted values calculated using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC). The measured FP data agreed well with the predicted values of Raoult's law, Wilson, NRTL and UNIQUAC models. The average absolute deviation between the predicted and measured lower FP was less than 1.14 K.

Application of HACCP for Hygiene Control to Jabchae in Team Foodservice Facility (잡채를 중심으로 한 단체급식시설의 위생개선을 위한 HACCP 적용에 관한 연구)

  • 이선애;박경준;강성태
    • Culinary science and hospitality research
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    • v.9 no.4
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    • pp.81-97
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    • 2003
  • The purpose of this study was to evaluate hazard factors in the steps of production, holding and assembly and service of jabchae that were served by contracted management in school meal foodservice. And method of control with the Hazard Analysis Critical Control Point (HACCP)program was suggested. The hazard factors in jabchae product had come from the temperature, time, growth of microbiological equipment and utensils. Almost of raw materials, prepreparation and storage, cooking, holding, serving established the critical control point. It has shown that the microbiological quality of raw materials for jabchae was a little inferior at the time of receiving based on the total plate count(10$^3$∼10 $^{5}$ ), coliform(0∼10$^3$). However microbiological quality become acceptable level by washing and a few disinfection method. Microbiological growth has increased in 3hr at room temperature up to 5.1${\times}$10$^2$ after preparation of jobchae. In conclusion, it is extremly important to reduce hoiding and serving time and to avoid treating food within the danger zone for food safeness. In addition, the prevention of cross-contamination during mixing the ingredients with improper equipment and with insanitary treatments by workers was also important to keep the food safe in this foodservice facility.

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Duration to First Job of Korean Young Graduates: Before and After the Economic Crisis (청년층의 첫 일자리 진입 : 경제위기 전후의 비교)

  • Ahn, Joyup;Hong, Seo Yeon
    • Journal of Labour Economics
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    • v.25 no.1
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    • pp.47-74
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    • 2002
  • Since the Economic Crisis at the end of 1997, unemployment rate soared up to the record-high 8.6% (February 1999) and, for youth aged 15~29, it was 14.6% (27.8% for aged 15~19). In spite of economic recovery after the crisis, new participants in labor market at the school-to-work transition have faced with difficulties in finding their first jobs and, even further, the ratio of youth at out-of the labor force but not in school has remained at a higher level. It is important to calibrate the negative effects of nonemployment in the short-run as well as in the long-run, but there has been few study on the school-to-work transition in Korea. This study focus on the nonemployment duration to first job after formal education and comparison of its pattern before and after the crisis. A proportional hazard model, considering job prenaration before graduation (21.4% of the sample), with the semi-parametric baseline hazard is applied to the sample from the Korean Labor and Income Panel Survey(1998~2000) and its Youth Supplemental survey(2000). Interview of the Survey is conducted, by the Korea Labor Institute, to the same 5,000 household and 13,738 individual sample, guaranteeing nationwide representativeness. The Supplemental Survey consists of 3,302 young individuals aged 15 to 29 at the time of survey and 1,615 of them who are not in school and provide appropriate information is used for the analysis. The empirical results show that there exists negative duration dependence at the first three or for months at the transition period and no duration dependence since a turning point of the baseline hazard rate and that unemployment rate reflecting labor demand conditions has a positive effect on exiting the nonemployment state, which is inconsistent with a theoretical conclusion. Estimation with samples separated by the date of graduation before and after the crisis shows that the effect of unemployment rate on the hazard was negative for the pre-crisis sample but positive for the post-crisis sample.

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Clinical Outcome in Gamma Knife Radiosurgery for Metastatic Brain Tumors from the Primary Breast Cancer : Prognostic Factors in Local Treatment Failure and Survival

  • Choi, Seung Won;Kwon, Do Hoon;Kim, Chang Jin
    • Journal of Korean Neurosurgical Society
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    • v.54 no.4
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    • pp.329-335
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    • 2013
  • Objective : Brain metastases in primary breast cancer patients are considerable sources of morbidity and mortality. Gamma knife radiosurgery (GKRS) has gained popularity as an up-front therapy in treating such metastases over traditional radiation therapy due to better neurocognitive function preservation. The aim of this study was to clarify the prognostic factors for local tumor control and survival in radiosurgery for brain metastases from primary breast cancer. Methods : From March 2001 to May 2011, 124 women with metastatic brain lesions originating from a primary breast cancer underwent GKRS at a tertiary medical center in Seoul, Korea. All patients had radiosurgery as a primary treatment or salvage therapy. We retrospectively reviewed their clinical outcomes and radiological responses. The end point of this study was the date of patient's death or the last follow-up examination. Results : In total, 106 patients (268 lesions) were available for follow-up imaging. The median follow-up time was 7.5 months. The mean treated tumor volume at the time of GKRS was 6273 $mm^3$ (range, 4.5-27745 mm3) and the median dose delivered to the tumor margin was 22 Gy (range, 20-25 Gy). Local recurrence was assessed in 86 patients (216 lesions) and found to have occurred in 36 patients (83 lesions, 38.6%) with a median time of 6 months (range, 4-16 months). A treated tumor volume >5000 $mm^3$ was significantly correlated with poor local tumor control through a multivariate analysis (hazard risk=7.091, p=0.01). Overall survival was 79.9%, 48.3%, and 15.3% at 6, 12, and 24 months, respectively. The median overall survival was 11 months after GKRS (range, 6 days-113 months). Multivariate analysis showed that the pre-GKRS Karnofsky performance status, leptomeningeal seeding prior to initial GKRS, and multiple metastatic lesions were significant prognostic factors for reduced overall survival (hazard risk=1.94, p=0.001, hazard risk=7.13, p<0.001, and hazard risk=1.46, p=0.046, respectively). Conclusion : GKRS has shown to be an effective and safe treatment modality for treating brain metastases of primary breast cancer. Most metastatic brain lesions initially respond to GKRS, though, many patients have further CNS progression in subsequent periods. Patients with poor Karnofsky performance status and multiple metastatic lesions are at risk of CNS progression and poor survival, and a more frequent and strict surveillance protocol is suggested in such high-risk groups.

A System Displaying Real-time Meteorological Data Obtained from the Automated Observation Network for Verifying the Early Warning System for Agrometeorological Hazard (조기경보시스템 검증을 위한 무인기상관측망 실황자료 표출 시스템)

  • Kim, Dae-Jun;Park, Joo-Hyeon;Kim, Soo-Ock;Kim, Jin-Hee;Kim, Yongseok;Shim, Kyo-Moon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.22 no.3
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    • pp.117-127
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    • 2020
  • The Early Warning System for agrometeorological hazard of the Rural Development Administration (Korea) forecasts detailed weather for each farm based on the meteorological information provided by the Korea Meteorological Administration, and estimates the growth of crops and predicts a meteorological hazard that can occur during the growing period by using the estimated detailed meteorological information. For verification of early warning system, automated weather observation network was constructed in the study area. Moreover, a real-time web display system was built to deliver near real-time weather data collected from the observation network. The meteorological observation system collected diverse meteorological variables including temperature, humidity, solar radiation, rainfall, soil moisture, sunshine duration, wind velocity, and wind direction. These elements were collected every minute and transmitted to the server every ten minutes. The data display system is composed of three phases: the first phase builds a database of meteorological data collected from the meteorological observation system every minute; the second phase statistically analyzes the collected meteorological data at ten-minutes, one-hour, or one-day time step; and the third phase displays the collected and analyzed meteorological data on the web. The meteorological data collected in the database can be inquired through the webpage for all data points or one data point in the unit of one minute, ten minutes, one hour, or one day. Moreover, the data can be downloaded in CSV format.

Hazard Evaluation of Gas Processes Using a Multi-distinction Equipment Screening Algorithm (다중판별 장치 스크리닝 기법을 이용한 가스공정의 위험성 평가)

  • Yoon En Sup;Park Jeong Su;Ahn Sung Joon;Han Kyounghoon;Yoon Jong Phil;Kim Ku Hwoi;Shin Dongil
    • Journal of the Korean Institute of Gas
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    • v.7 no.1 s.18
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    • pp.1-9
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    • 2003
  • A Multi-distinction Equipment Screening Algorithm (MESA) is proposed. It selectively integrates Dow's F&EI as its process hazard index technique and ESA (Equipment Screening Algorithm) as qualitative hazard classification technique, and retrieves a detailed list of hazardous equipments with the total hazard indices of those equipments. The inherent expert system, which includes the accident scenarios of the equipments and processes and experts' views of them, narrows further down the list of hazardous equipments and recommends only the most notable candidates. Through the case study of distinguishing the hazardous ranking of the equipments of the LPG underground storage process, using the expert system or not, the applicability of MESA has been validated. Taking the characteristics of the process equipments with hazardous ranking in the point of process intrinsic safety, this proposed algorithm would contribute to providing engineers or managers with information on constructing safely devices and mitigation devices and on scheduling emergency response planning.

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A Study on the Improvement Plan of Electrostatic Safety Management Level through Injury Analysis (재해분석을 통한 정전기 안전관리 수준 향상 방안 연구)

  • Choi, Sang-won;Jeong, Seong-Choon;Park, Jae Suk;Yang, Jeong Yeol;Byeon, Junghwan
    • Journal of the Korean Society of Safety
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    • v.34 no.5
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    • pp.37-45
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    • 2019
  • The characteristic of fire and explosion related to electrostatic discharge is that it is difficult to reproduce the electrostatic charge and discharge phenomenon in addition to the large human and material damage. Therefore, in order to prevent accidents and disasters related to electrostatic in fire and explosion hazard areas, it is important to manage the level of electrostatic in a safe manner from the perspective of system between industrial facilities and human bodies. Rule 325 of the Occupational Safety and Health Regulations, "Prevention of Fire / Explosion due to Electrostatic", requires the use of grounding, conductive materials, humidification and electrification in order to prevent the risk of disaster caused by static explosion and electrostatic in the production process. In order to comply with these measures, related technologies, standards and systems are needed from the viewpoint of preventive measures related to electrostatic in fire and explosion hazard areas, but in Korea, it is still insufficient. Therefore, technical, institutional and managerial measures are needed as a precautionary measure to improve the level of ESD safety in fire and explosion hazard areas and prevent electrostatic related injury. In Korea, we analyzed the current status and characteristics of electrostatic related disaster by using the statistics of industrial accident and fire statistics of the Ministry of Employment and Labor. We also analyzed the current status and characteristics of electrostatic related disasters in Japan using JNIOSH accidents and disasters investigation cases and JNIOSH fire accident data of Japan Fire Bureau. The purpose of this study is to compare and analyze the current status of electrostatic related accidents and disasters in Korea and Japan in order to improve the safety management of electrostatic in fire and explosion hazard areas. In order to prevent accidents and disasters in the industrial field, The technical, institutional, and managerial measures to manage the level of electrostatic in a safe state were derived from the system point of view.