• Journal of the Korean Ceramic Society
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• v.55 no.3
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• pp.224-229
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• 2018

OPC production requires high calorific value and emits a large amount of $CO_2$ through decarbonation of limestone, accounting for about 7% of $CO_2$ emissions. To reduce $CO_2$ emissions during the Ordinary Portland Cement (OPC) production process, there is a method of reducing the consumption of cement or lower temperature calcination for OPC product. In this study, for energy consumption reduction, we prepared Hauyne-belite cement by calcination at a low temperature compared to that used for OPC and studied the early hydration properties of the synthesized Hauyne-belite cement. We set the ratios of Hauyne and belite to 8 : 2, 5 : 5 and 3 : 7. For the hydration properties of the synthesized Hauyne-belite cement, we tested heat of hydration of paste and the compressive strength of mortar, using XRD and SEM for analysis of hydrates. As for our results, the temperature for optimum synthesis of Hauyne-belite is $1,250^{\circ}C$. Compressive strength of synthesized Hauyne-belite cement is lower than that of OPC, but it is confirmed that compressive strength of synthesized Hauyne-belite cement with mixing in of some other materials can be similar to that of OPC.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2005.10a
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• pp.355-359
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• 2005

본 연구에서는 OPC 및 hauyne 클링커의 비산재에 대한 고화특성을 검토하였다. 비산재에 대해 OPC 및 OPC에 hauyne 클링커를 20%까지 대체하였을 때의 압축강도, 길이변화율, 중금속 용출량 등을 조사하였다. 결과로서, hauyne 클링커의 첨가량에 따라 고화체의 압축 강도가 증가하였다. hauyne 클링커의 첨가량은 10%내외가 적합하였으며, 그 이상에서는 길이변화율이 증가하며 팽창하였다. 고화체의 중금속 용출시험결과 모든 배합조건에서 환경기준치이하의 값을 나타내었다.

• Proceedings of the Petrological Society of Korea Conference
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• 2009.05a
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• pp.124-128
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• 2009

• Proceedings of the Korea Concrete Institute Conference
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• 2000.04a
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• pp.205-210
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• 2000

This study concerns the cement-solidification. stabilization of the electric furnace dust. Compressive strength and leaching test of heavy metals were evaluated for varing types and ratios of cements and the effect of some additives of hauyne clinker and slag were also discussed. In this cases of using cement binders more than 30%, the compressive strength showed the values over 150kgf/cm2. so it can be used as filler for concrete precastings. Type III cement and Hauyne clinker improved the compressive strength, especially early strength. Leaching amount of heavy metals was decreased when using type III cement and adding hauyne clinker and slag. The values were especially low in the case of slag addition.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10b
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• pp.1199-1204
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• 2000

This study concerns the cement-solidification/stabilization of the municipal waste incineration fly-ash. Compressive strength and leaching test of heavy metals were evaluated for varying types and ratios of cements and the effects of some additives of Hauyne clinker and slag were also discussed. In the cases of using cement binders more than 10%, the compressive strength after 3 days showed the values over $20kgf/cm^2$. Type III cement and Hauyne clinker improved the compressive strength, especially early strength. And the values of leaching test showed that cement-solidification is effective method to stabilize heavy metals especialy when using type III cement and adding Hauyne clinker and slag,.

• Journal of the Korean Ceramic Society
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• v.37 no.6
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• pp.576-582
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• 2000

Two type of expanding cement generally referred to as CSA with Hauyne(3CaO 3Al2O3 CaSO4) and Quick lime(CaO). Hauyne is formed to ettringite when there are presented with CaO and CaSO4, and CaO reacts wtih water to form Ca(OH)2. REcently, the mechanism of compensation and expand mortar or concrete tend to same and it has been used improving on its shrink property. The volume of cement paste varies with its water content shrink with drying and re-wetting. Concrete and mortar works are required shrinking compensation and expansion properties to reduce of potential crack. The use of expansion cement may improve on its shrinking volume changes. CSA dosages for shrinking compensation limited by cement weight, but obtained difference expansion rate with varied W/C or inorganic admixture. This paper studies expansion rate according to expansion cement dosages, water and inorganic admixtures as Silica fume. Therefor, the expansion factor has to considered before the application.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.73-76
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• 1999

In recent, concrete material like specific cement and additives having many functions hsa been developed. In road pavement, ultra high early strength cement or organic material are used to open the road early, but there are many restrictions like workable time and special equipment. We aim to developed specific concrete which 1 day strength is over 300kgf/$\textrm{cm}^2$ to open the road within one day and workable time is maintained over 1 hour that can make the concrete ready mixed concrete. In this study, we are convinced if the ratio of hauyne clinker or its additive is increased early strength property is progressed and if the ratio of non hydrous gypsum is increased longtime strength is progressed. The concrete strength is 290-310 kgf/$\textrm{cm}^2$ at 1 day, 570-640 kgf/$\textrm{cm}^2$ at 28 day and the workable time is maintained over 30 minutes. As the results of this experiments We find out the possibility to developed the 1 day usable ready mixed concrete with high early strength.

• Journal of the Korean Ceramic Society
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• v.56 no.5
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• pp.468-473
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• 2019

This study focused on manufacturing an inorganic insulation material set with various amounts of calcium-sulfoaluminate (CSA) (hauyne) content for enhancing both workability (demolding, handling) and the high thermal insulating property. To carry out the experiment, the amounts of CSA utilized were 5%, 10%, 15%, and 20%, with anhydrous gypsum added in equal proportion to produce a stable formation. As the content of CSA increased, a sinking phenomenon occurred because of the hydration reaction from the slurry, so it was difficult to utilize a retarder normally used in the cement manufacturing process. However, an RCOOM surfactant was able to solve the local clumping problem from cement and CSA and obtain a rapid retarding effect, so it was included in this process at 0.3%. Furthermore, the cement fineness was not 7000 ㎠/g but rather 3300 ~ 4000 ㎠/g to prevent a rapid temperature increase in the slurry. The specific gravity of the sample manufactured with 20% CSA was approximately 0.11 g/㎤, and its thermal conductivity was 0.041 W/m·K, providing an excellent insulating property.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.289-294
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• 2001

This study concerns the cement-solidification/stabilization of the waste with high concentration heavy metals. Compressive strength and leaching test of heavy metals were evaluated for ing types of cements and the effect of the additives of Hauyne clinker and slag were also cussed. Using ordinary portland cement, rapid hardening portland cement and the cement with additives solidification materials, it shows that the strength and stability of concrete is satisfactory and superiority is in the order of rapid hardening portland cement > the cement with additives > nary portland cements.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.295-300
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• 2001

In road pavements, it is known that cement concrete pavement has superior durability, safety in compared with asphalt concrete pavement. But in reparing pavement cement concrete pavement is not usually applied because of the length of time while the road is interrupted when using Ordinary and Rapid-hardening Portland Cement. And Super High Early Strength Cement and Ultra Super High Early Strength Cement are not favorable for ready mixied concrete because of rapid setting time, high slump loss and other restrictions. We aim to develope specific cement and concrete developing 1 day strength of over 300 kg/$cm^{2}$ to open the road within one day and workable time is maintained over 1 hour that can be used as ready mixed concrete. In this study, we Produced cement using rapid-hardening cement, Hauyne clinker, anhydride gypsum and accelerator and studied on its properties. The concrete strength was over 300 kg/$cm^{2}$ at 1 day and 550 kg/$cm^{2}$ at 28 day and workable time was maintained for over 1 hour.