• Title/Summary/Keyword: Hardened Material

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An Fundamental Study on the Earth Wall Material Development by using of Lime Composition and Earth (석회복합체와 흙을 이용한 흙벽체 재료 개발에 관한 기초적 연구)

  • Hwang, Hey zoo;Kang, Nam Yi
    • KIEAE Journal
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    • v.10 no.5
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    • pp.115-121
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    • 2010
  • Lime was the solidifier mostly used at the fields of construction and civil works in the past. however, the development of Portland cement remarkably reduced the use of it. Recently as the concernment on circumstances gets higher, lime wined attention again as an eco-friendly material and was used at earth-using construction. This study examined the physical and chemical capacity of lime complexes with lime capacity improved, and performed fundamental study on the way to concretize by mixing it with earth. As a result, lime complex pressure strength was lower than cement pressure strength but it showed the possibility that its strength was improved by W/B control. The measurement of XRD after paste formation confirmed a compound generated by the reaction of Ca2+ion and Si, Al, and Fe from pozzolan reaction. A earth wall experiment by using lime complexes and earth showed that the higher, WB or the lower the quantity of unit combined materials, the lower the pressure strength was. The maximum pressure strength was maximum 11MPa when the quantity of unit combined materials was 450. It is because the composed earth particles had a high content of micro powder less than silt, so a lot of combination are demanded to secure fluidity. As a result of peptization experiment, after hardening, the material was not dissolved, which informed of the possibility of use as an outer subsidiary material. If the material is hardened by mold formation method, natural hardening crack appears. Cast expresses smart surface quality and enables to design for multiple purpose. The result shows the possibility of construction of low-story structures by using earth wall made of lime complexes and earth.

Evaluation of NOx Removal Efficiency of Photocatalytic Concrete for Road Structure (도로구조물 적용을 위한 광촉매 콘크리트의 질소산화물(NOx) 제거효율 평가)

  • Kim, Young Kyu;Hong, Seong Jae;Lee, Kyung Bae;Lee, Seung Woo
    • International Journal of Highway Engineering
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    • v.16 no.5
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    • pp.49-58
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    • 2014
  • PURPOSES : In areas of high traffic volume, such as expressway across large cities, the amount of nitrogen oxides (NOx) emitted into the atmosphere as air pollution can be significant since NOx gases are the major cause of smog and acid rain. Recently, the importance of NOx removal has arisen in the world. Titanium dioxide ($TiO_2$), that is one of photocatalytic reaction material, is very efficient for removing NOx. The NOx removing mechanism of $TiO_2$ is the reaction of solar photocatalysis. Therefore, $TiO_2$ in road structure concrete need to be contacted with ultraviolet rays (UV) to be activated. In general, $TiO_2$ concretes are produced by replacement of $TiO_2$ as a part of concrete binder. However, considerable portion of $TiO_2$ in concrete cannot contact with the pollutant in the air and UV. Therefore, $TiO_2$ penetration method using the surface penetration agents is attempted as an alternative in order to locate $TiO_2$ to the surface of concrete structure. METHODS : This study aimed to evaluate the NOx removal efficiency of photocatalytic concrete due to various $TiO_2$ application method such as mix with $TiO_2$, surface spray($TiO_2$ penetration method) on hardened concrete and fresh concrete using surface penetration agents. The NOx removal efficiency of $TiO_2$ concrete was confirmed by NOx Analyzing System based on the specification of ISO 22197-1. RESULTS : The NOx removal efficiency of mix with $TiO_2$ increased from 11 to 25% with increasing of replacement ratio from 3 to 7%. In case of surface spray on hardened concrete, the NOx removal efficiency was about 50% due to application amount of $TiO_2$ with surface penetration agents as 300, 500 and 700g/m2. The NOx removal efficiency of surface spray on fresh concrete due to all experimental conditions, on the other hand, which was very low within 10%. CONCLUSIONS : It was known that the $TiO_2$ penetration method as surface spray on hardened concrete was a good alternative in order to remove the NOx gases for concrete road structures.

Fundamental Properties of Magnesia-Prosphate Composite Considering Mix Conditions and Curing Temperature (배합조건 및 양생온도에 따른 마그네시아 인산염 복합체의 기초물성 평가)

  • Cho, Hyun Woo;Kang, Su Tae;Shin, Hyun Seop;Lee, Jang Hwa
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.163-170
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    • 2012
  • With the advantage of a rapid exothermic reaction property, jet set concrete may be used as a cold weather concrete because it can reach the required strength before being damaged by cold weathers. And it can be hardened more quickly if the field temperature is properly compensated by heating. Because ordinary concrete cannot be hardened well under sub-zero temperatures, anti-freeze agents are typically added to prevent the frost damage and to ensure the proper hardening of concrete. While the addition of a large amount of anti-freeze agent is effective to prevent concrete from freezing and accelerates cement hydration resulting in shortening the setting time and enhancing the initial strength, it induces problems in long-term strength growth. Also, it is not economically feasible because most anti-freeze agents are mainly composed of chlorides. Recent studies reported that magnesia-phosphate composites can be hardened very quickly and hydrated even in low temperatures, which can be used as an alternative of cold weather concrete for cold weathers and very cold places. As a preliminary study, to obtain the material properties, mortar specimens with different mixture proportions of magnesia-phosphate composites were manufactured and series of experiments were conducted varying the curing temperature. From the experimental results, an appropriate mixture design for cold weathers and very cold places is suggested.

A Study on the Toughness of Die Steel Coated with VC (vanadium carbide) by Immersing in Molten Borax Bath (용융염 침적법에 의한 VC Coating 금형강의 인성에 관한 연구)

  • Lee, B.K.;Nam, T.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.2
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    • pp.59-69
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    • 1993
  • Bending fracture strength test and impact strength test were made for VC coated die steels treated by immersing in molten borax bath and for hardened steels which were quenched and tempered, in order to clarify the effect of VC coating at $1000^{\circ}C$. The material used in this investigation was representative cold and hot work die steels STD11, STD61. The results obtained are as follows. 1) The bending fracture strength of VC coated die steel (STD11, STD61) was lessened with increasing the thickness of the VC coated layer. 2) With increasing the immersing time (imcreasing the thickness of the VC coated layer) the maximum hardness was obtained at 480 minutes holding, after that holding time hardness was decreased. 3) The impact strength of the VC coated die steel was not decreased. In the casse of STD11, it was higher than that of the quenched condition especially at low tempering temperature, and vice versa at high tempering temperature. However in the case of STD61 shows the result to the contrary.

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The Strength Properties of Concrete Used Stone Powder Sludge as Siliceous Material (실리카질 재료로서 석분 슬러지를 사용한 콘크리트의 강도 특성)

  • Jeong Ji Yong;Choi Sun Mi;Kawg Eun Gu;Choi Se Jin;Lee Seong Yeon;Kim Jin Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.85-88
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    • 2005
  • The stone powder sludge occurred at aggregate production process is classified the specified waste, so it is disposed by appropriate method. But the problems of the shortage of the disposal-site, the environment pollution, and the increase of disposal cost can be occurred in handling process, therefore the stone powder sludge is required the development of recycling technique. The stone powder sludge includes SiO2 of about $63\%$. This characteristic is important at the production of hardened specimens under condition of hydro-thermal reaction. In this study, we investigated the strength properties of concrete used stone powder sludge as siliceous material. The test results under condition of hydro-thermal reaction shows the two main facts. The first, the stone powder sludge is affected to fluidity because the surface of the stone powder sludge has characteristics of flakily and angularity. The second, weight content of the stone powder sludge, is not effective factor to the properties of strength.

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The Variation of Response on Humidity in CNT Thin Film by Silane Binders (실란 바인더에 의한 탄소나노튜브 박막의 감습 특성 변화)

  • Kim, Seong-Jeen
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.10
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    • pp.782-787
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    • 2010
  • Recently the solution-based thin film technology has often been treated in the field of device fabrication owing to easy process and convenience for the development of various semiconductor devices and sensors. We deposited on glass substrate single-walled carbon nanotubes (SWNTs)/silane hybrid thin films by multiple spray-coating which is one of solution-based processes, and examined their electrical response for humidity. Generally silane binders which are often mixed in carbon nanotube (CNT) solution to adhere CNTs to substrate well form easily each own functionalized group on the surface of CNTs after they are hardened by way of the hydrolysis reaction. In this work, we investigated how silane binders (TEOS (tetraethoxy silane), MTMS (methyltrimethoxysilane) and VTMS (vinyltrimethoxysilane)) in CNT thin films make effect to their electrical response on humidity. As the result, we found that the resistance in the samples using TEOS was changed dramatically while it was almost invariant in the samples using MTMS and VTMS for increasing humidity.

Processing and Properties of Engine Valve-shaped TiAl-Mn Intermetallics by Reactive Sintering (반응소결법에 의해 엔진밸브 형상으로 제조한 TiAl-Mn 금속간화합물의 특성)

  • 김영진
    • Journal of Powder Materials
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    • v.4 no.4
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    • pp.243-251
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    • 1997
  • Engine valve-shaped TiAl-Mn intermetallics containing 43.5 to 47.5at%Al (Mn/Al=0.036) are successively fabricated by reactive sintering the elemental powder mixtures near-net shaped by extrusion and die forging. A duplex structure consisted of lamellar grains and equiaxed $\gamma$ grains is developed for all compositions, and the areal fraction of the lamellar grains(or equiaxed $\gamma$ grains) decreases (or increases) with increasing Al content. As Al content increased, the elongation increases with accompanying decrease in yield strength and ultimate tensile strength at both room temperature and 80$0^{\circ}C$. This indicates that the suitable composition is Ti-45at%Al-1.6at%Mn in considering the balance of ambient and elevated tensile properties. The reactive-sintered Ti-45Al-1.6Mn alloy shows superior oxidation resistance not only to the plasma arc melted one but also to the heat resistance steel STR35(representative exhaust valve head material for automotive engine). The reactive-sintered Ti-45Al-1.6Mn alloy coated with an oxidizing scale exhibits a better wear resistance than induction hardened martensitic steel STR11(representative exhaust valve tip material for automotive engine).

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Fundamental Electro-Mechanical Characteristics of Ballooning-Resistant Bi-2223 HTS Tapes (벌루닝 손상에 강한 Bi-2223 테이프의 기본적인 전기-기계적 특성)

  • Dizon, John Ryan C;Shin, Hyung-Seop;Ha, Dong-Woo;Cho, Jeon-Wook;Oh, Sang-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.26-27
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    • 2006
  • The fundamental mechanical characteristics under tensile and bending deformations of hermetically-sealed reinforced Bi-2223 tape and CTOP processed Bi-2223 tape were examined at 77K. Also, the Tensile strain dependence of the critical current, $I_c$, was obtained at 77K and self-field. The reinforced hermetic tape showed higher tensile strength and a better Tensile strain tolerance than the CTOP processed tape. For bending tests, a rho-shaped sample holder was used giving multiple bending strains. in increasing order. In the same case under bending deformation, the hermetic tape showed a higher bending strain tolerance than the CTOP processed tape. This higher strength of the hermetic tape can be attributed to the thick hardened copper reinforcement layer.

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Characterization and Early Age Physical Properties of Ambient Cured Geopolymer Mortar Based on Class C Fly Ash

  • Kotwal, Ashley Russell;Kim, Yoo Jae;Hu, Jiong;Sriraman, Vedaraman
    • International Journal of Concrete Structures and Materials
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    • v.9 no.1
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    • pp.35-43
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    • 2015
  • The critical element for sustainable growth in the construction industry is the development of alternative cements. A new technological process called geopolymerization provides an innovative solution, and the presence of aluminum and silicon oxides in fly ash has encouraged its use as a source material. Many previous investigations have involved curing the binder in a heated environment. To reduce energy consumption during the synthesis of geopolymers, the present study investigated the properties of ambient cured geopolymer mortar at early ages. An experimental program was executed to establish a relationship between the activator composition and the properties of geopolymer mortar in fresh and hardened states. Concentrations of sodium hydroxide and sodium silicate were ascertained that are advantageous for constructability and mechanical behavior. Scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction techniques were also used to characterize the material. Test results indicate that there is potential for the concrete industry to use fly ash based geopolymer as an alternative to portland cement.

Surface Characteristics of TiC Layer Formed on Ti Alloys by Plasma Ion Carburizing (플라즈마 이온 확산법에 의해 타이타늄 합금 표면층에 형성된 TiC층에 관한 연구)

  • Lee, Doh-Jae;Choi, Dap-Chon;Yang, Hyeon-Sam;Jung, Hyun-Yeong;Bae, Dae-Sung;Lee, Kyung-Ku
    • Journal of Korea Foundry Society
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    • v.27 no.4
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    • pp.179-183
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    • 2007
  • The TiC layer was formed on Ti and Ti alloys by plasma carburizing method. The main experimental parameters for plasma car boozing were temperature and time. XRD, EDX, hardness test and corrosion test were employed to analyze the evolution and material properties of the layer. The preferred orientation of TiC layers is (220) at treated temperature of $700^{\circ}C\;and\;880^{\circ}C$ However, it is changed to (200) at temperature of $800^{\circ}C$ The thickness of carbide layer increase with increasing carburizing temperature. Highest hardness of hardened layer formed on CP-Ti was obtained at the carburizing condition of processing temperature $880^{\circ}C$ and processing time 1080min. The corrosion potential of carburizing specimen was higher than untreated CP-titanium, and corrosion potential increased as carburizing temperature and time increased. Thus the corrosion resistance of CP-Ti was greatly enhanced after plasma carburizing treatment.