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Iron-loaded Natural Clay as Heterogeneous Catalyst for Fenton-like Discoloration of Dyeing Wastewater

  • Xu, Huan-Yan;Ha, Xiu-Lan;Wu, Ze;Shan, Lian-Wei;Zhang, Wei-Dong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.10
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    • pp.2249-2252
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    • 2009
  • The clay-based Fe-bearing catalyst was successfully prepared through ion-exchange reaction and applied as heterogeneous catalyst for discoloration of acid fuchsine (AF) in an aqueous solution by Fenton-like reaction. Experimental results demonstrated that the AF discoloration ratios increased by increasing Fe-loaded clay dosage and initial $H_2O_2$ concentration, and by decreasing the pH, respectively. The lower the initial AF concentration, the shorter the reaction time needed to achieve complete discoloration of AF. Comparative studies indicated that AF discoloration ratios were much higher in presence of Fe-loaded clay and $H_2O_2$ than those in presence of $H_2O_2$, raw natural clay or Fe-loaded clay only and raw natural clay and $H_2O_2$ jointly. After AF discoloration, there existed no new phases in the clay samples detected by XRD and no change in the clay crystal morphology observed by SEM. A mechanism proposed suggested adsorption and Fenton-like reaction were responsible for discoloration of AF.

Solvothermal Synthesis of Bi2O2CO3 Nanoplates for Efficient Photodegradation of RhB and Phenol under Simulated Solar Light Irradiation

  • Hu, Sheng-Peng;Xu, Cheng-Yan;Zhang, Bao-You;Pei, Yi;Zhen, Liang
    • Bulletin of the Korean Chemical Society
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    • v.35 no.10
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    • pp.2935-2940
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    • 2014
  • Monodispersed $Bi_2O_2CO_3$ nanoplates with an average width of 320 nm and thicknesses of 50-90 nm were successfully synthesized by a simple solvothermal method in a mixture solution of polyethylene glycol and $H_2O$. The obtained nanoplates were characterized by means of XRD, FT-IR, SEM and TEM. The effect of surfactant sodium dodecyl benzene sulfonate on the morphology of $Bi_2O_2CO_3$ product was investigated. Under simulated solar light irradiation, $Bi_2O_2CO_3$ nanoplates exhibited superior photocatalytic activities towards the degradation of RhB as well as high chemical stability upon cycling photocatalytic test. The nanoplates also showed promising photodegradation ability for eliminating refractory pollutant of phenol. The excellent photocatalytic performance of $Bi_2O_2CO_3$ nanoplates as compared with P25-$TiO_2$ endows them as promising high efficiency photocatalysts.

Speed and Current Sensor Fault Detection and Isolation Based on Adaptive Observers for IM Drives

  • Yu, Yong;Wang, Ziyuan;Xu, Dianguo;Zhou, Tao;Xu, Rong
    • Journal of Power Electronics
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    • v.14 no.5
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    • pp.967-979
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    • 2014
  • This paper focuses on speed and current sensor fault detection and isolation (FDI) for induction motor (IM) drives. A new, accurate and high-efficiency FDI approach is proposed so that a system can continue operating with good performance even in the presence of speed sensor faults, current sensor faults or both. The proposed three paralleled adaptive observers are capable of current sensor fault detection and localization. By using observers, the rotor flux and rotor speed can be estimated which allows the system to run under the speed sensorless vector control mode when a speed sensor fault occurs. In order to detect speed sensor faults, a threshold-based scheme is proposed. To verify the feasibility and effectiveness of the proposed FDI strategy, experiments are carried out under different conditions based on a dSPACE DS1104 induction motor drive platform.

Loss of Torque on Magnetic Fluid Seals with Rotating-shafts

  • Hu, Jianhui;Zhao, Meng;Wang, Lu;Zou, Jibin;Li, Yong
    • Journal of Magnetics
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    • v.22 no.2
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    • pp.286-290
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    • 2017
  • The effects of loss of torque on magnetic fluid seals with rotating-shafts and the general difficulty of studying magnetic fluid seals are the focus of this work. The mechanism underlying loss of torque on such seals is analyzed using theoretical methods that show that loss of torque can be affected by several factors, including the velocity of the rotating-shaft, the structure of the sealing device, the characteristics of the magnetic field, and the characteristics of the magnetic fluid. In this paper, a model of the loss of torque is established, and the results of finite element analysis and testing and simulations are analyzed. It is concluded that (i) the viscosity of the magnetic fluid increased with the intensity of the magnetic field within a certain range; (ii) when the magnetic fluid was saturated, the increase in loss of torque tended to gradually slow down; and (iii) although the axial active length of the magnetic fluid may decrease with increasing speed of the rotating-shaft, the loss of torque increased because of increasing friction.

Numerical Study on Coolant Flow Distribution at the Core Inlet for an Integral Pressurized Water Reactor

  • Sun, Lin;Peng, Minjun;Xia, Genglei;Lv, Xing;Li, Ren
    • Nuclear Engineering and Technology
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    • v.49 no.1
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    • pp.71-81
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    • 2017
  • When an integral pressurized water reactor is operated under low power conditions, once-through steam generator group operation strategy is applied. However, group operation strategy will cause nonuniform coolant flow distribution at the core inlet and lower plenum. To help coolant flow mix more uniformly, a flow mixing chamber (FMC) has been designed. In this paper, computational fluid dynamics methods have been used to investigate the coolant distribution by the effect of FMC. Velocity and temperature characteristics under different low power conditions and optimized FMC configuration have been analyzed. The results illustrate that the FMC can help improve the nonuniform coolant temperature distribution at the core inlet effectively; at the same time, the FMC will induce more resistance in the downcomer and lower plenum.

Experimental study of sodium fire and its characteristics under the coupling action of columnar liquid sodium flow and concrete

  • Huo, Yan;Zou, Gao-Wan;Dong, Hui;Lv, Jian-Fu;He, Jian
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.2866-2877
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    • 2021
  • The complex coupling relationship between liquid sodium and concrete materials affects both the sodium fire characteristics and concrete properties through heat and chemical erosion. In this study, experiments on direct and indirect (separated by a steel plate) contact of the columnar sodium fire with the concrete surface were performed. It was found that the combustion efficiency of liquid sodium in direct contact with concrete was significantly enhanced and accompanied by intermittent explosions and splashing of small concrete fragments. The sodium fire on the surface of the concrete considerably increased the internal temperature, pore size, and distribution density of the concrete. In addition, the depth of influence on the loosening of the concrete structure was also greatly extended. The contact of liquid sodium with the concrete substantially affected its permeability resistance. The water absorption of the concrete surface was increased by more than 70% when liquid sodium directly impacted the bare concrete surface. However, the change in water absorption in the centre of the concrete was primarily affected by the duration of the external heat.

Analysis of the performances of the CFD schemes used for coupling computation

  • Chen, Guangliang;Jiang, Hongwei;Kang, Huilun;Ma, Rui;Li, Lei;Yu, Yang;Li, Xiaochang
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2162-2173
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    • 2021
  • In this paper, the coupling of fine-mesh computational fluid dynamics (CFD) thermal-hydraulics (TH) code and neutronics code is achieved using the Ansys Fluent User Defined Function (UDF) for code development, including parallel meshing mapping, data computation, and data transfer. Also, some CFD schemes are designed for mesh mapping and data transfer to guarantee physical conservation in the coupling computation. Because there is no rigorous research that gives robust guidance on the various CFD schemes that must be obtained before the fine-mesh coupling computation, this work presents a quantitative analysis of the CFD meshing and mapping schemes to improve the accuracy of the value and location of key physical prediction. Furthermore, the effect of the sub-pin scale coupling computation is also studied. It is observed that even the pin-resolved coupling computation can also create a large deviation in the maximum value and spatial locations, which also proves the significance of the research on mesh mapping and data transfer for CFD code in a coupling computation.

Strength assessment method of ice-class propeller under the design ice load condition

  • Ye, L.Y.;Guo, C.Y.;Wang, C.;Wang, C.H.;Chang, X.
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.11 no.1
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    • pp.542-552
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    • 2019
  • The strength assessment is the most important part at the design of ice-class propeller. Based on ice rules for ice-class propeller in IACS URI3 and FEM, the strength assessment method of ice-class propeller is established in this paper. To avoid the multifarious meshing process of propeller blade, an automatic meshing method has been developed by dividing the propeller geometry into a number of 8-node hexahedron elements along radial, chordwise and thickness directions, then the loaded areas in five cases can easily be calculated and identified. The static FEM is applied to calculate the stress and deformation of propeller blade. The fair agreements between the results of the present method and ANSYS/Workbench demonstrate its robust and the feasibility, and also the method is able to produce smooth gradient field. The blade stress and deformation distributions for five load cases are studied, and then the strength of the whole blade is checked.

DL-RRT* algorithm for least dose path Re-planning in dynamic radioactive environments

  • Chao, Nan;Liu, Yong-kuo;Xia, Hong;Peng, Min-jun;Ayodeji, Abiodun
    • Nuclear Engineering and Technology
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    • v.51 no.3
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    • pp.825-836
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    • 2019
  • One of the most challenging safety precautions for workers in dynamic, radioactive environments is avoiding radiation sources and sustaining low exposure. This paper presents a sampling-based algorithm, DL-RRT*, for minimum dose walk-path re-planning in radioactive environments, expedient for occupational workers in nuclear facilities to avoid unnecessary radiation exposure. The method combines the principle of random tree star ($RRT^*$) and $D^*$ Lite, and uses the expansion strength of grid search strategy from $D^*$ Lite to quickly find a high-quality initial path to accelerate convergence rate in $RRT^*$. The algorithm inherits probabilistic completeness and asymptotic optimality from $RRT^*$ to refine the existing paths continually by sampling the search-graph obtained from the grid search process. It can not only be applied to continuous cost spaces, but also make full use of the last planning information to avoid global re-planning, so as to improve the efficiency of path planning in frequently changing environments. The effectiveness and superiority of the proposed method was verified by simulating radiation field under varying obstacles and radioactive environments, and the results were compared with $RRT^*$ algorithm output.

Distributed control system architecture for deep submergence rescue vehicles

  • Sun, Yushan;Ran, Xiangrui;Zhang, Guocheng;Wu, Fanyu;Du, Chengrong
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.11 no.1
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    • pp.274-284
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    • 2019
  • The control architectures of Chuan Suo (CS) deep submergence rescue vehicle are introduced. The hardware and software architectures are also discussed. The hardware part adopts a distributed control system composed of surface and underwater nodes. A computer is used as a surface control machine. Underwater equipment is based on a multi-board-embedded industrial computer with PC104 BUS, which contains IO, A/D, D/A, eight-channel serial, and power boards. The hardware and software parts complete data transmission through optical fibers. The software part involves an IPC of embedded Vxworks real-time operating system, upon which the operation of I/O, A/D, and D/A boards and serial ports is based on; this setup improves the real-time manipulation. The information flow is controlled by the software part, and the thrust distribution is introduced. A submergence vehicle heeling control method based on ballast water tank regulation is introduced to meet the special heeling requirements of the submergence rescue vehicle during docking. Finally, the feasibility and reliability of the entire system are verified by a pool test.