• 대한화학회지
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• 제6권2호
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• pp.122-124
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• 1962

The silver halide precipitate tends to separate in curdy form of flocculated colloid when it is precipitated by direct mixing of reactant solutions. This type of precipitate has a great tendency to adsorb or occlude foreign ions in the solution.When silver halide in precipitated from homogeneous solution using the slow hydrolysis of Alkyl halide or Ally halide, the precipitate becomes dense, filterable and uniform in particle size which is very advantageous in gravimetric analysis.We found that silver halide precipitates obtained from homogeneous solution with hydrogen halide formed by the hydrolysis of alkyl halide do not give the color change with fluorescein as adsorption indicater, while silver halide precipitates obtained by direct mixing method give sharply pink color which appear to be uniformly distributed through the solution in silver ion excess.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 1995년도 추계학술발표회논문집
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• pp.39-46
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• 1995

LCD. projector back light용 metal halide lamp는 최근 LCD의 고신장세에 편승 매년 30% 정도 수요가 증가하고있는 첨단제품으로 국내에서는 전량 수입에 의존하고 있는 실정이며 본 연구에서는 다음과 같은 기술 성과를 거두었다. 1. LCD projector back light용 150W metal halide lamp및 전자식 안정기의 국산화 완료 2. 초소형 metal halide lamp의 설계기술 및 제작 기반기술 확보 3. Metal halide lamp용 전자식 안정기의 설계기술 확보

• 대한화학회지
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• 제13권2호
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• pp.115-120
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• 1969

1-naphthyl methyl halide와 halide ion간의 反應을 無水 acetone에서 反應 速度論的으로 연구하였다. Substrate의 softness가 현저하게 增加하면 halide ion의 nuclepphilicity가 dipolar solvent 에서도 一般的으로 $I^->Br^->CI^-$의 순서를 갖는다는 것을 보여주고 있다. Leaving group bromide일 때는 symbiotic effect에 의해서 reaction center의 softness가 증가하여 soft halide ion과의 反應이 커질 것이나 perihydrogen atom의 steric effect때문에 chloride일 때에 비해서 약간 감소하고 있다.

• Bulletin of the Korean Chemical Society
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• 제28권9호
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• pp.1515-1518
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• 2007

A preparative method of Me2SCuX (X = Cl, Br) via one-pot reaction was developed from common chemicals such as benzyl halide, DMSO, and Cu(0). In the reaction mixture small molecules such as methyl halide and dimethyl sulfide etc. were efficiently generated in situ, resulting in the formation of Me2SCuX. Oxidation of Cu(0) in reacting with both benzyl halide (starting material) and methyl halide (in situ generated product) to Cu(I) followed by complexing with dimethyl sulfide (in situ generated product) could explain the formation of Me2SCuX. In particular we found out that heterogeneous reaction of Me2SCuX and arenediazonium tetrafluoroborate in acetonitrile was so effective to afford corresponding bromoaromatics under mild conditions.

• 한국광학회:학술대회논문집
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• 한국광학회 2000년도 제11회 정기총회 및 00년 동계학술발표회 논문집
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• pp.292-293
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• 2000

Silver-halide sensitized gelatin(SHSG)의 처리 과정에서 silver-halide입자가 감광유제(emulsion)로부터 제거되고, 노출영역과 비노출영역 사이의 gelatin경화정도로 인한 굴절률 변조로 홀로그램 이미지를 기록한다. 일반적으로 널리 사용되는 홀로그램 감광물질로는 silver-halide, dichromated gelatin, photoresist, photochrome 등이 있는데, 이중 silver-halide는 다른 감광물질과 비교하여 고해상도와 큰 감광대역폭, 높은 S/N비, 취급의 용이성과 경제적 이점, 균일한 제품으로 상용화될 수 있다는 점에서 가장 편리하게 사용되고 있는 기록 매질이다. (중략)

• Bulletin of the Korean Chemical Society
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• 제16권2호
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• pp.130-134
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• 1995

Surface-enhanced Raman (SER) scattering of 2-cyanonaphthalene (2-CN) has been investigated in silver sol. Addition of halide ions was needed to obtain authentic SER spectra of the molecule. The SER spectra thus obtained exhibited a slight but noticeable dependence on the kind of halide ions used. This halide-dependent spectral variation was attributed to the orientational change of molecule on silver sol surface. A possible mechanism for such an orientational change is proposed in terms of the competitive adsorption of 2-CN with halide ions on the so-called halide-specific sites.

• 한국재료학회지
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• 제32권11호
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• pp.449-457
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• 2022

Halide perovskites are emerging materials for next-generation display applications, thanks to their narrow emission linewidth and band gap tunability, capable of covering the entire range of visible light. Despite their short period of research, perovskite light emitting diodes (PeLEDs) have shown rapid progress in device external quantum efficiency (EQE) in the near-infrared (NIR), red, and green emission wavelengths, and the record EQE has exceeded over 20 %. However there has been limited progress with blue emission compared to the red and green counterparts. In this review, the current status and challenges of blue PeLEDs are introduced, and strategies to produce spectrally stable blue PeLEDs are discussed. The strategies include 1) a mixed halide system in the form of 3-dimensional (3D) perovskites, 2) colloidal perovskite nanocrystals and 3) low dimensional perovskites, known as quasi-2D perovskites. In the mixed halide system, previous reports based on the compositional engineering of 3D perovskites to reduce spectral instability (i.e., halide segregation) will be discussed. Since spectral instability issue originate from the mixed halide composition in perovskites, the two other strategies are based on enlarging the band gap with a single halide composition. Finally, the prospects for each strategy are discussed, for further improvement in spectrally stable blue PeLEDs.

• 세라미스트
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• 제21권1호
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• pp.24-43
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• 2018

Organic-inorganic halide perovskite materials have attracted significant attention during the last few years because of their superior properties for electronic and optoelectronic devices, such as their long charge carrier diffusion lengths and high photoluminescence quantum yields of up to 100% with tunable bandgaps over the entire visible spectral range. In addition to solar cells, light emitting diodes (LEDs) represent a fascinating application for halide perovskite materials. In this study, we review the recent progress in halide perovskite LEDs. The current strategies for improving the performance of halide LEDs, focusing on morphological engineering, dimensional engineering, compositional engineering, surface passivation, interfacial engineering, and the plasmonic effect are discussed. The challenges and perspectives for the future development of halide perovskite LEDs are also considered.

• 조명전기설비학회논문지
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• 제16권1호
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• pp.20-26
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• 2002

고압방전램프에는 고압수은램프, 고압나트륨램프와 메탈핼라이프램프가 있다. 메탈핼라이드램프는 가장 효율 좋을 램프들 중 하나이며 고효율, 고연색성과 집광능력이 좋다. 이 연구의 목적은 AC 100∼277의 프리볼트입력용 전자식안정기를 개발하여 메탈핼라이드(MH70W)를 점등시키는 것이다. 개발된 전자식안정기는 프리볼트입력용컨버터, 플라이백컨버터와 하프브리지인버터, 이그나이터와 보호기 그리고 제어기로 구성되어 있다. 실험 결과 개발된 전자식안정기는 프리볼트입력(AC 100∼277V)에 따라 메탈핼라이드램프(MH70W)가 매우 잘 점등되었다.

• KIEAE Journal
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• 제13권2호
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• pp.47-52
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• 2013

The problems of light pollution first became an issue in the 1970s when astronomers identified the degradation of the night sky due to the increase in lighting associated with development and growth. As more impacts to the environment by lighting have been identified, many attempts have been made for reducing light pollutions. To prevent light pollution and increase energy efficiency, Seoul Metropolitan Government(SMG) replaced metal halide road lighting to LED luminaire in four arterial highway in Seoul. The present study compared the lighting characteristics of metal halide and LED luminaire in terms of Korea Standard for road lighting(KS A 3701) and BUG rating from Illuminating Engineering Society of North America(IESNA). The results showed that LED luminaire increased road surface luminance up to 2 times in average compared to the metal halide environment. Also, LED luminaire reduced the glare value by 2 times and luminous flux over 50% than the metal halide luminaire. In comparison with the BUG ratings, LED luminaire rated 1 degree lower for the backlight ratings and 3-4 degrees lower for the uplight ratings. The measured values testified that the LED luminaire is effective for roadway lighting and light pollution reduction.