• Title/Summary/Keyword: HNT

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Optimal flammability and thermal buckling resistance of eco-friendly abaca fiber/ polypropylene/egg shell powder/halloysite nanotubes composites

  • Saeed Kamarian;Reza Barbaz-Isfahani;Thanh Mai Nguyen Tran;Jung-Il Song
    • Advances in nano research
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    • v.16 no.2
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    • pp.127-140
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    • 2024
  • Upon direct/indirect exposure to flame or heat, composite structures may burn or thermally buckle. This issue becomes more important in the natural fiber-based composite structures with higher flammability and lower mechanical properties. The main goal of the present study was to obtain an optimal eco-friendly composite system with low flammability and high thermal buckling resistance. The studied composite consisted of polypropylene (PP) and short abaca fiber (AF) with eggshell powder (ESP) and halloysite clay nanotubes (HNTs) additives. An optimal base composite, consisting of 30 wt.% AF and 70 wt.% PP, abbreviated as OAP, was initially introduced based on burning rate (BR) and the Young's modulus determined by horizontal burning test (HBT) and tensile test, respectively. The effects of adding ESP to the base composite were then investigated with the same experimental tests. The results indicated that though the BR significantly decreased with the increase of ESP content up to 6 wt.%, it had a very destructive influence on the stiffness of the composite. To compensate for the damaging effect of ESP, small amount of HNT was used. The performance of OAP composite with 6 wt.% ESP and 3 wt.% HNT (OAPEH) was explored by conducting HBT, cone calorimeter test (CCT) and tensile test. The experimental results indicated a 9~23 % reduction in almost all flammability parameters such as heat release rate (HRR), total heat released (THR), maximum average rate of heat emission (MARHE), total smoke released (TSR), total smoke production (TSP), and mass loss (ML) during combustion. Furthermore, the combination of 6 wt.% ESP and 3 wt.% HNT reduced the stiffness of OAP to an insignificant amount by maximum 3%. Moreover, the char residue analysis revealed the distinct differences in the formation of char between AF/PP and AF/PP/ESP/HNT composites. Afterward, dilatometry test was carried out to examine the coefficient of thermal expansion (CTE) of OAP and OAPEH samples. The obtained results showed that the CTE of OAPEH composite was about 18% less than that of OAP. Finally, a theoretical model was used based on first-order shear deformation theory (FSDT) to predict the critical bucking temperatures of the OAP and OAPEH composite plates. It was shown that in the absence of mechanical load, the critical buckling temperatures of OAPEH composite plates were higher than those of OAP composites, such that the difference between the buckling temperatures increased with the increase of thickness. On the contrary, the positive effect of CTE reduction on the buckling temperature decreased by raising the axial compressive mechanical load on the composite plates which can be assigned to the reduction of stiffness after the incorporation of ESP. The results of present study generally stated that a suitable combination of AF, PP, ESP, and HNT can result in a relatively optimal and environmentally friendly composite with proper flame and thermal buckling resistance with no significant decline in the stiffness.

Predicting ESP and HNT effects on the mechanical properties of eco-friendly composites subjected to micro-indentation test

  • Saeed Kamarian;Ali Khalvandi;Thanh Mai Nguyen Tran;Reza Barbaz-Isfahani;Saeed Saber-Samandari;Jung-Il Song
    • Advances in nano research
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    • v.15 no.4
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    • pp.315-328
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    • 2023
  • The main goal of the present study was to assess the effects of eggshell powder (ESP) and halloysite nanotubes (HNTs) on the mechanical properties of abaca fiber (AF)-reinforced natural composites. For this purpose, a limited number of indentation tests were first performed on the AF/polypropylene (PP) composites for different HNT and ESP loadings (0 wt.% ~ 6 wt.%), load amplitudes (150, 200, and 250 N), and two types of indenters (Vickers or conical). The Young's modulus, hardness and plasticity index of each specimen were calculated using the indentation test results and Oliver-Pharr method. The accuracy of the experimental results was confirmed by comparing the values of the Young's modulus obtained from the indentation test with the results of the conventional tensile test. Then, a feed-forward shallow artificial neural network (ANN) with high efficiency was trained based on the obtained experimental data. The trained ANN could properly predict the variations of the mentioned mechanical properties of AF/PP composites incorporated with different HNT and ESP loadings. Furthermore, the trained ANN demonstrated that HNTs increase the elastic modulus and hardness of the composite, while the incorporation of ESP reduces these properties. For instance, the Young's modulus of composites incorporated with 3 wt.% of ESP decreased by 30.7% compared with the pure composite, while increasing the weight fraction of ESP up to 6% decreased the Young's modulus by 34.8%. Moreover, the trained ANN indicated that HNTs have a more significant effect on reducing the plasticity index than ESP.

Antibacterial effects of Chitosanon-ascorbate Treated Kwamaegi Prepared on Microorganism Contamination (Chitosan-ascorbate 처리 과메기에 있어서 오염미생물에 대한 저해효과)

  • Kim, Young-Sook;oh, Seung-Hee;Kim, Soon-Dong
    • KSBB Journal
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    • v.24 no.2
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    • pp.156-162
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    • 2009
  • We examined saury, herring, gizzard shad kwamaegi to measure of microbic contamination rate of kwamegi that are sold in the market now. In the total bacteria, staphylococcus, peroxide value, and microorganisms is inhibited that from sample that we treated a substance with chitosan-ascorbate (CA) and other orders deep water (DW), ginseng steamed red and wine (GRW), NT (not treated). When we compared between SGRW and SNT, SCA show us more inhibition effect 0.22-0.49 log cycle in the total aerobacter. When we compared between HDW and HNT, HCA restraint 0.05-0.45log cycle, and when we compared between GDW and GNT, GCA inhibited 0.45 log cycle. In the coliform and E. coli, growths of microorganisms were inhibited followed order by treatment of CA, NT, and DW. GDW, HCA and HNT checked enough amount of water from the moisture measurement; but SGW, GCA, HEW and SCA showed 7-15% lack of moisture, and SNT and GNT have 10% more moisture. Peroxide value is changed to 41-51meq/kg when we did treat CA in there and a side that didn't add antimicrobial expressed the result numerically that 56-58meq/kg. In the sensory evaluation, customer gave preference to followed by Saury kwamaegi, herring, and gizzard shad kwamaegi. We have a point of view when kwamaeki manufactured if we add natural antibiotic and it uses to vacuum drying, we would inhibited of multiplication of microorganism, and of peroxides.

First Report of Cucumber mosaic virus Isolated from Sambungai (Gynura procumbens) (명월초에서 분리한 오이모자이크바이러스의 감염 첫 보고)

  • Kwon, June;Hong, Jin-Sung
    • Research in Plant Disease
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    • v.23 no.4
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    • pp.379-382
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    • 2017
  • In March 2016, an isolate of Cucumber mosaic virus (named Gyp-CMV) was isolated from the Sambungai (Gynura procumbens) showing the symptoms of mosaic and chlorosis. The isolate Gyp-CMV was characterized by disease reactions in several indicator plants, reverse transcription-polymerase chain reaction (RT-PCR), PCR-restriction fragment length polymorphism, and sequence analysis of movement protein (3a) and coat protein (CP) genes. Tobacco, tomato, pepper, ground cherry, and lambsquarters (Chenopodium quinoa and C. amaranticolor) appeared typical CMV symptoms, but zucchini and cucumber were not infected. Phylogenetic analysis of the 3a and CP gene indicated that Gyp-CMV belongs to the CMV subgroup II. Sequence identities of the Gyp-CMV 3a and CP genes showed 99.3% and 100% to that of Hnt-CMV at amino acid level. To our knowledge, this is the first report of CMV infection in Gynura procumbens.

A Study on Fire Resistance of Abaca/Vinyl-ester Composites (마닐라 삼/비닐에스터 복합재료의 내화성 연구)

  • Lee, Dong-Woo;Park, Byung-Jin;Song, Jung-Il
    • Composites Research
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    • v.30 no.1
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    • pp.59-64
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    • 2017
  • Eco-convivial composites with improved properties are essential to present polymer scenario and can be made easily by replacing partially/completely renewable materials either matrix or reinforcement along with few % of additives. In these investigations, Abaca fabric have been used as reinforcement for manufacturing of Vinyl ester composites through VARTM technique and study the effect of alkali surface treatment of abaca fabric and flame retardant additives i.e., ammonium polyphosphate (APP) with halloysite nano-clay (HNT) on mechanical and flame retardant properties. The results concluded that, surface treatment deceased the hydrophilic nature of fabric and enhanced the interfacial bonding with hydrophobic matrix and eventually increased mechanical properties slightly of developed composites. Similarly, the flame retardancy of the composites improved significantly and increases the burning time by varying the wt% of filler concentration.

Analysis of Herbal formulation on Wolgug-hwan Series (동의보감(東醫寶鑑) 월국환가미방(越鞠丸加味方)의 방제학적(方劑學的) 분석(分析))

  • Park, Seong-Gyu;Byun, Sung-Hui;Lee, Byung-Wook;Kim, Sang-Chan
    • Herbal Formula Science
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    • v.19 no.1
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    • pp.79-90
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    • 2011
  • Objectives : This study was performed to analysis the composition of herbal formulations about a series of Wolgug-Hwan(WGH, formed by Gukchur-won and Sagung-san) in Dongeuibogam written by Heo Jun. Methods : The series of WGH in Dongeuibogam were selected by 'Prescription Lineage Graph' (http://164.125.206.43/PrescriptionLineageGraph.aspx) established by prof. Lee at Pusan National University. In the analysis of a series of WGH, we used some formulation books including classics. Results : Gaeuldogi-tang(GDT) is formed by WGH, Yeonggangchulgam-tang(YGT), Yugil-san (YIS) and Gungchul-san. Cheongul-san(CUS) is formed by WGH, Ijin-tang(IJT), YGT and Haegeum -hwan(HGH). Sosikcheongul-san(SCS) is formed by CUS and IJT. Jeungmiijin-tang(JIT) is formed by WGH, IJT, Sambaek-tang and Gyullyeonjichul-hwan. Sihoeokgan-tang(SET) is formed by WGH, Sihosogan-san(SSS) and Jigolpi-eum. Wolgukbohwa-hwan(WBH) is formed by WGH, Bohwa-hwan, Mokyangjichul-hwan and Hwangnyeon-tang(HNT). Chimsa-hwan(CSH) is formed by WGH, Injinho-tang(IHT), Yungmisamneung-hwan, Jeungmisamul-tang and Sinseongugi-tang. Conclusions : SCS, CUS, or JIT has been used frequently in case of phlegm-fire. These are formulated by the combination of WGH and IJT with Samseon-san or HGH or Jichul-hwan according to the special symptoms, respectively. SET which is formulated by WGH and SSS has been used in case of stagnation of liver-qi. GDT, WBH or CSH has been used in damp-heat. These are formulated by the combination of WGH with YIS, HNT, or IHT, respectively.

Evaluation of polymethyl methacrylate resin mechanical properties with incorporated halloysite nanotubes

  • Abdallah, Reham M.
    • The Journal of Advanced Prosthodontics
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    • v.8 no.3
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    • pp.167-171
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    • 2016
  • PURPOSE. This study inspects the effect of incorporating halloysite nanotubes (HNTs) into polymethyl methacrylate (PMMA) resin on its flexural strength, hardness, and Young's modulus. MATERIALS AND METHODS. Four groups of acrylic resin powder were prepared. One group without HNTs was used as a control group and the other three groups contained 0.3, 0.6 and 0.9 wt% HNTs. For each one, flexural strength, Young's modulus and hardness values were measured. One-way ANOVA and Tukey's test were used for comparison (P<.05). RESULTS. At lower concentration (0.3 wt%) of HNT, there was a significant increase of hardness values but no significant increase in both flexural strength and Young's modulus values of PMMA resin. In contrast, at higher concentration (0.6 and 0.9 wt%), there was a significant decrease in hardness values but no significant decrease in flexural strength and Young's modulus values compared to those of the control group. CONCLUSION. Addition of lower concentration of halloysite nanotubes to denture base materials could improve some of their mechanical properties. Improving the mechanical properties of acrylic resin base material could increase the patient satisfaction.

Improved T-Vector for the Cloning of PCR DNA Using Green Fluorescent Protein

  • Park, Kill-Soon;Park, Seong-Weon;Choi, Soon-Yong
    • Journal of Microbiology and Biotechnology
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    • v.10 no.2
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    • pp.264-266
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    • 2000
  • A new GFP-based T-vector for cloning of PCR products was developed by using a green fluorescent protein (GFP) as a mafker. In order to facilitate the DNA inserts, multiple restriction sites, SP6 and T7 RNA polymerase promoter sites, were introduced close to the PCR DNA insertion site of a pCRGv vector. The XcmI-digested pHNT plasmid can be used to clone a 3' A-overhanged PCR DNA amplified by Taq DNA polymerase. A potential method of easing some difficulties from its use along with its cost savings proveded by this vector are likely to lead to the replacement of other T-vectors for PCR DNA cloning.

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Eine methodische Betrachtung fur die Erstellung des koreanisch-deutschen WordNets (한독 워드넷 구축을 위한 기본 방법론 고찰)

  • Nam Yu-Sun
    • Koreanishche Zeitschrift fur Deutsche Sprachwissenschaft
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    • v.9
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    • pp.217-236
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    • 2004
  • Das Ziel dieser Arbeit ist es, als eine methodische Grundlage zur Erstellung des koreanisch-deutschen WordNets das Grundwissen $\"{u}ber$ das WordNet und einige bisherige Untersuchungen des WordNets darzulegen. Ais erster Schritt wurde einige grundlegende Punkte $f\"{u}r$ das WordNet im Rahmen des WordNets fur Englisch in Betracht gebracht. Dabei ging es um lexikalische Hierarchie, und um semantische Relationen zwischen den Synsets(Zusammensetzen der synonymen $W\"{o}rter$) wie Synonymy, Antonymy, Hyponymy, Mronymy, Troponomy und Entailment. $Anschlie{\ss}end$ wurden EuroNet und GermaNet in kurzer Form vorgestellt, die auf dem Princeton WordNet basierten. EuroNet ist eine multilinguale Datenbasis mit WordNets $f\"{u}r$ einige europaische Sprachen (hollandisch, italienisch, spanisch, deutsch, franzasisch, tschechisch und estnisch). Dieses auf das Deutsch bezogenen WordNet kann wichtige Hinweise $f\"{u}r$ die Erstellung des koreanisch-deutschen WordNets geben. In Korea wurden auch verschiedene Untersuchungen uber das WordNet $f\"{u}r$ Koreanisch unternommen. Darunter kann insbesondere KORTERM WordNet $f\"f{u}r$ Koreanisch als ein umfassendes System $erw\"{a}hnt$ werden, in dem Nomen, Verben, Adjektive und Adverbien miteinander interagieren. KORTERM WordNet fur Koreanisch ist eine multilinguale Datenbasis mit WordNets $f\"{u}r$ einige asiatische Sprachen (koreanisch, japanisch und chinesisch) und versucht noch die weiteren Sprachen in diese multilinguale Datenbasis hineinzubringen. Nach diesem WordNet wird das koreanisch-deutsche WordNet erstellt.

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Die Bedeutung und die Grenze der $\"{U}bersetzungswissenschaft$ (번역학의 의미와 한계)

  • Jee Kwangsin
    • Koreanishche Zeitschrift fur Deutsche Sprachwissenschaft
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    • v.4
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    • pp.267-287
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    • 2001
  • In dieser Arbeit habe ich die $M\"{o}glichkeit$ und die Grenze der Interpretation in der $\"{U}bersetzung$ behandelt, wobei das Wesen der Bedeutung in Betracht kommt. In diesem Zusammenhang wollte ich auch feststellen, was libersetzt werden soll. Dazu wird zuerst betrachtet, was $f\"{u}r$ die Bedeutung eines Wortes charakteristisch ist und worauf die Mehrdeutigkeit beruht. $Anschlie{\ss}end\;wird\;\"{u}ber\;die\;\"{A}quivalenz$ bei der $\"{U}bersetzung\;und\;die\;Universalit\"{a}t$ im Gedanken und in der Sprache $erw\"{a}hnt.\;Abschlie{\ss}end$ habe ich einige Beispiele $angef\"{u}hrt$, die Unterschiede im Sprachgebrauch und in der sprachlichen Struktur zeigen. Coseriu stimme ich in dem Punkt zu, dass 'nicht all das in einem Text gemeinte, sondern ... nur das in diesem Text sprachlich Gesagte, d.h. das durch die Sprache in ihrer Zeichenfunktion $Ausgedr\"{u}ckte$, das Verbalisierte,' $\"{u}bersetzt$ werden soll, was jedoch nicht $hei{\ss}t$, dass die $W\"{o}rter\;oder\;die\;S\"{a}tze\;\"{u}bersetzt$ werden soll. Trotz der Verschiedenheit der einzelsprachlichen Gestaltung der Bedeutungen und der Sprachstrukturen kann man mit Hilfe der Bedeutung die gleiche Bezeichnung und den gleichen Sinn in einer anderen Sprache wiedergeben, wobei der Kontext und die $Universalit\"{a}t$ im Gedanken und in der Sprache eine $gro{\ss}e$ Rolle spielt. In diesem Zusammenhang findet man einerseits die Bedeutung der $\"{U}bersetzungswissenschaft$, deren Aufgaben darin bestehen, den Unteschied und die Gemeinsamkeit zwischen den Sprache sowohl im Hinblick auf die sprachlichen Struktur als auch auf den Gebrauch festzustellen. Die Grenze der $\"{U}bersetzungswissenschaft$ besteht andererseits darin, 'dass man eigentlich nicht alles, was man meinen, auch sagen kann und dass nicht alles, was gesagt werden kann, auch von anderen verstanden werden kann'.

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