• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.1
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• pp.52-58
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• 2016

In this study we collected various substance codes, physical and chemical properties, and hazard level of the 545 HNS which was determined earlier, and constructed the Korean HNS database including International Maritime Dangerous Goods (IMDG) codes,, informations of explosive and corrosive characteristics of HNS after reviewing of US, Japan and European Database. And also problems of present HNS Database which focused mainly on land-based environment and an absence of information for chemical and physical properties of mixed substance HNS are reported. For the efficient implementation of comprehensive HNS management system, we constructed the basic model for the HNS database in marine environment and made suggestions for improvement for the future development of HNS Database to be prepared for the marine spill accidents.

• Journal of the Korea Institute of Military Science and Technology
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• v.4 no.1
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• pp.216-224
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• 2001

HNS(hexanitrostilbene), one of the most important heat resistant explosive was recrystallized using organic solvent, nitric acid and dual solvent system of acetonitrile-toluene. The purification, analysis, type conversion method and its physical properties are described.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3659-3664
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• 2013

Eight representative explosives (ammonium perchlorate (AP), ammonium nitrate (AN), trinitrotoluene (TNT), 2,4-dinitrotoluene (DNT), cyclonite (RDX), cyclotetramethylenetetranitramine (HMX), pentaerythritol tetranitrate (PETN), and hexanitrostilbene (HNS)) were comprehensively analyzed with an ion trap mass spectrometer in negative ion mode using direct infusion electrospray ionization. MS/MS experiments were performed to generate fragment ions from the major parent ion of each explosive. Explosives in salt forms such as AP or AN provided cluster parent ions with their own anions. Explosives with an aromatic ring were observed as either $[M-H]^-$ for TNT and DNT or $[M]^{{\cdot}-}$ for HNS, while explosives without an aromatic ring such as RDX, HMX, and PETN were detected as an adduct ion with a formate anion, i.e., $[M+HCOO]^-$. These findings provide a guideline for the rapid and accurate detection of explosives once portable MS instruments become more readily available.

• Journal of the Korea Institute of Military Science and Technology
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• v.16 no.4
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• pp.430-434
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• 2013

In this paper, we have investigated deformation of cup for EFI detonator in high velocity impact test. The experimental result shows that STS cup deformed 0.170 mm with the bulged shape. The numerical simulation result with static/dynamic material properties of SUS304 shows 0.166 mm of deformation. The main parameters to decrease the deformation of cup are stength, thickness and density of cup. The initial condition of SUS304 cup was strength of 215 MPa and thickness of 0.12 mm. As strength increases to 500 MPa, deformation of cup converges to 0 mm, and as thickness increases to 0.18 mm, deformation of cup converges to 0 mm. If the density of cup decreases from 8 to 2.7 g/cc, the deformation of cup decreases to 0.141 mm.

• Journal of the Korea Society for Simulation
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• v.28 no.2
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• pp.1-14
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• 2019

A full scale hydrodynamic simulation that requires an accurate reproduction of shock-induced detonation was conducted for design of an energetic component system. A detailed hydrodynamic analysis SW was developed to validate the reactive flow model for predicting the shock propagation in a train configuration and to quantify the shock sensitivity of the energetic materials. The pyrotechnic device is composed of four main components, namely a donor unit (HNS+HMX), a bulkhead (STS), an acceptor explosive (RDX), and a propellant (BPN) for gas generation. The pressurized gases generated from the burning propellant were purged into a 10 cc release chamber for study of the inherent oscillatory flow induced by the interferences between shock and rarefaction waves. The pressure fluctuations measured from experiment and calculation were investigated to further validate the peculiar peak at specific characteristic frequency (${\omega}_c=8.3kHz$). In this paper, a step-by-step numerical description of detonation of high explosive components, deflagration of propellant component, and deformation of metal component is given in order to facilitate the proper implementation of the outlined formulation into a shock physics code for a full scale hydrodynamic simulation of the energetic component system.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.5
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• pp.80-87
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• 2017

The performance of a pyrotechnic device that consists of donor/acceptor pair separated by a bulkhead relies on shock attenuation characteristics of the gap material and shock sensitivity of the donor and acceptor explosives. In this research, a micro Kapton flyer was accelerated by an exploding foil initiator (EFI) to figure out shock sensitivity of hexanitrostilbene (HNS) to impact. The averaged shock pressure and duration imparted to the explosive by flyer impact are measured by using a velocity interferometer for any reflector (VISAR) and impedance matching technique. Consequently, this research shows the possibility to determine the critical flyer velocity for initiating the miniaturized pyrotechnic unit by determining the relations between the impact velocity, the amplitude and width of impact loading.