• Title/Summary/Keyword: HFCs

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Quality Change of High Fructose Corn Syrups During Storage (과당시럽의 저장중 품질 변화)

  • Nahmgoong, Bae;Shin, Dong-Bin;Jeong, Mun-Cheol;Kim, Oui-Woung;Kim, Byeong-Sam
    • Applied Biological Chemistry
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    • v.38 no.3
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    • pp.232-238
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    • 1995
  • Quality changes of high fructose corn syrups (HFCS) were investigated during storage at $-5{\sim}60^{\circ}C$. Color properties such as spectrophotometric properties, HMF and Hunter color value increased continuously during storage period. And the change was most evident as storage temperature and fructose content were elevated. High fructose corn syrups all showed flow behaviors as dilatant fluid and their viscosities increased slightly during storage. Content of fructose decreased, while glucose, maltose and oligosaccharide contents increased during storage. Especially, crystallization of what was observed below $13^{\circ}C$ during storage.

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Estimation of The Global Warming Potential of Fluorinated Green House Gases (불화온실가스의 흡수단면적 측정을 통한 지구온난화지수의 추정)

  • Kim, Jihye;Lee, Jeongsoon
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.4
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    • pp.387-397
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    • 2014
  • This work aims at estimating global warming potentials (GWP) of $CF_3Br$ and HFC-134a among green house gases. It has been reported that they have much higher GWP than $CO_2$ in the atmosphere. $CF_3Br$, halon 1301 which is well known to be a fire extinguisher, as one of the bromine-containing halons has been banned since 2003 due to destruction of ozone. HFCs, a kind of chiller which replaced chlorofluorocarbons (CFCs) are one of greenhouse gases regulated by the Kyoto Protocol. In this study, we produced GWPs of $CF_3Br$ and HFC-134a by calculating a life time and measuring an absorption cross section to obtain a radiative forcing (RF). Their absorption cross sections were measured by using Fourier-transformed infrared spectroscopy (FTS) with a gas cell filled with their certified reference materials at room temperature. As a result, the RFs of $CF_3Br$ and HFC-134a were 0.32 and $0.168Wm^{-2}ppb^{-1}$, respectively and the GWPs were calculated as 7989, 6076, 3903 for $CF_3Br$ and 3855, 1300, 656 for HFC-134a for the time horizon of 20, 100, 500 years, respectively. Overall, uncertainty of the estimated GWPs can be estimated to be about 2.6%. Our results were compared with those proposed by the previous studies (IPCC, 2007; WMO, 1999).

Effects of Refrigerant Oils and Molecular Sieve on Air Conditioner using Alternative Refrigerant (대체냉매를 사용한 에어콘에서 합성오일과 건조제(M/S)의 영향)

  • Choa, S.H.;Hong, C.K.;Kim, C.K.;Yoon, B.;Kang, S.C.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.473-483
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    • 1996
  • To protect the ozone layer, R22 will be replaced with HFCs. R407C is a leading candidate as alternative refrigerant for air conditioner due to its similar thermodynamic characteristics with R22. In replacing R22 with R407C, the compatibility with lubricating oil is of major concern. Polyol ester (POE) oil among the synthetic oils is considered to be the best lubricant for use with R407C because of good electrical properties and miscibility. However, lubricating ability of mixture of R407C/POE oil is lower than that of R22/mineral oil due to the production of acid by hydrolysis which causes corrosive wear. Therefore, to minimize water content, it is needed to develop a molecular sieve desiccant which is compatible with R407C and ester oil. This paper discusses (1) the change of properties of POE oil when current molecular seive is used, (2) the effects of POE oils and additives on durability of compressor. Through compressor life test and bench wear test, it was found that inadequate use of POE oils and additives may promote the deteriation of molecular sieve, resulting in decrease of durability of compressor.

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Survey of American food trends and the growing obesity epidemic

  • Shao, Qin;Chin, Khew-Voon
    • Nutrition Research and Practice
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    • v.5 no.3
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    • pp.253-259
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    • 2011
  • The rapid rise in the incidence of obesity has emerged as one of the most pressing global public health issues in recent years. The underlying etiological causes of obesity, whether behavioral, environmental, genetic, or a combination of several of them, have not been completely elucidated. The obesity epidemic has been attributed to the ready availability, abundance, and overconsumption of high-energy content food. We determined here by Pearson's correlation the relationship between food type consumption and rising obesity using the loss-adjusted food availability data from the United States Department of Agriculture (USDA) Economic Research Services (ERS) as well as the obesity prevalence data from the Behavioral Risk Factor Surveillance System (BRFSS) and the National Health and Nutrition Examination Survey (NHANES) at the Centers for Disease Control and Prevention (CDC). Our analysis showed that total calorie intake and consumption of high fructose com syrup (HFCS) did not correlate with rising obesity trends. Intake of other major food types, including chicken, dairy fats, salad and cooking oils, and cheese also did not correlate with obesity trends. However, our results surprisingly revealed that consumption of com products correlated with rising obesity and was independent of gender and race/ethnicity among population dynamics in the U.S. Therefore, we were able to demonstrate a novel link between the consumption of com products and rising obesity trends that has not been previously attributed to the obesity epidemic. This correlation coincides with the introduction of bioengineered corns into the human food chain, thus raising a new hypothesis that should be tested in molecular and animal models of obesity.

Morphological study of $SF_6$ clathrate hydrate crystal ($SF_6$ 하이드레이트 결정 성장의 특성)

  • Lee, Yoon-Seok;Lee, Hyun-Ju;Lee, Eun-Kyung;Kim, Soo-Min;Lee, Ju-Dong;Kim, Yang-Do
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.711-711
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    • 2009
  • Global warming has been widely recognized as a serious problem threatening the future of human beings. It is caused by the buildup in the atmosphere of greenhouse gases, such as carbon dioxide, methane, hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF6). Particularly, SF6 has extremely high global warming potential compare to those of other global warming gases. One option for mitigating this greenhouse gas is the development of an effective process for capturing and separating these gases from anthropogenic sources. In general, gas hydrates can be formed under high pressure and low temperature. However, SF6 gas is known to form hydrate under relatively milder conditions. Therefore, technological and economical effects could be expected for the separation of SF6 gas from waste gas mixtures. In this study, we carried out morphological study for the SF6 hydrate crystals to understand its formation and growth mechanisms. The observations were made in high-pressure optical cell charged with liquid water and SF6 gas at constant pressure and temperature. Initially SF6 hydrate formed at the surface between gas and liquid regions, and then subsequent dendrite crystals grew at the wall above the gas/water interface. The visual observations of crystal nucleation, migration, growth and interference were reported. The detailed growth characteristics of SF6 hydrate crystals were discussed in this study.

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Estimation of Economics thorough Prediction of Methane Generation using IPCC Guideline from C Sanitary Landfill (IPCC가이드라인을 이용한 중소도시 C위생매립장의 메탄가스 발생량 예측을 통한 경제성 평가)

  • Lee, Sang-Woo;Park, Seo-Yun;Chang, In-Soo;Kang, Byung-Wook;Park, Sang-Chan;Yeon, Ik-Jun
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.189.1-189.1
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    • 2011
  • Global warming effect was intensified due to rapid growth of fossil fuel consumption caused by urbanization and industrialization. Various efforts was being done to solve the problems leading to anomaly climate such as flood, downpour, heavy snow. As a results of international efforts for management of global warming, Kyoto Protocol, which was passed in Kyoto, Japan in 1997, designated $CO_2$, $CH_4$, $N_2O$, HFCs, PFCs, $SF_6$ as a global warming gases. And IPCC(Intergovernmental Panel on Climate Change) suggested IPCC guideline for systematic establishment of national greenhouse gas inventory. Among five categories in IPCC guideline, the representative emission source of waste category is SWDS(solid waste disposal site). The concentrative research should progress for effective management of greenhouse gas related with waste. In this study, Tier1 and Tier2 methods which was suggested by 2006 IPCC(Intergovernmental Panel on Climate Change) guideline, was used to predict methane generation from C sanitary landfill located in Chungju area. To predict methane generation from C sanitary landfill, all factors were defaults values that were provided by 2006 IPCC guideline and Korea emission factors for Tier1 and Tier2 method. And economics of generated methane was estimated. From the predicted result using IPCC guideline, the methane generation was persistingly increased over a 9-year period(2000 ~ 2008). Aggregated amount of methane generation was about 3,017ton and 3,170ton predicted by Tier1 and Tier2, respectively. From the results of estimated economic value gained by generated methane from the C sanitary landfill for ten years from now(2010 ~ 2020), the profit was about 2.39 ~ 2.76 hundred million won.

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Characteristics of Rigid Polyurethane Foams Blown by HFCs for LNG Storage Tank (HFC계 발포제를 사용한 LNG 저장탱크용 폴리우레탄 폼 단열재의 특성)

  • Lee Yeongbeom;Choi Sunghee;Choi Gunhyung
    • Journal of the Korean Institute of Gas
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    • v.9 no.1 s.26
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    • pp.16-20
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    • 2005
  • CFC-11 and HCFC-l4lb have been used as blowing agents for rigid polyurethane foam insulation of LNG storage tank. But CFC-11 and HCFC- l4lb deplete ozone layer in the stratosphere. So in leading countries, the use of CFC-11 has been prohibited since 1995 and the use of HCFC-l4lb will be prohibited from 2005. Much efforts and studies have been done about alternative blowing agents and insulations blown by alternative blowing agents. This paper deals with polyurethane foams (PUFs) blown by HFC-365mfc, shows their physical and mechanical characteristics and thermal performance. These data are compared with the results of PUFs blown by HCFC-l4lb. From these test results, PUFs blown by HFC-365mfc show good mechanical and thermal characteristics. It is possible to use PUFs blown by HFC-365mfc as main insulation of membrane type LNG storage tank.

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Friction and Wear Characteristics of the Micro-dimple Surfaces in Rotary Compressor with Carbon Dioxide as Refrigerants ($CO_2$ 환경하에서 접촉 표면에 적용한 마이크로 딤플 패턴이 마찰 및 마멸에 미치는 영향 연구)

  • Lee, Young-Ze;Jeon, Hong-Gyu;Han, Kyu-Cheol;Choi, Jin-Ho;Kim, Gyu-Man;Cho, Sung-Ouk
    • Tribology and Lubricants
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    • v.24 no.6
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    • pp.374-377
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    • 2008
  • Due to the environmental concerns, especially the greenhouse effect and GWP (Global Warming Potential), the carbon dioxide was investigated as an alternative natural refrigerant to replace HFCs (HydroFluoroCarbons) in refrigerator or air conditioning systems. Because new compressor with carbon dioxide is going to be operated under the high pressure, the tribology of sliding surfaces in the compressor becomes very important. To improve of wear resistance in compressor parts, especially rotary type, the friction and wear characteristics of improved sliding surfaces between vane and flange were evaluated in this paper. The method of reformed sliding surface, such as micro-dimple processes, was applied on surfaces in order to improve the tribological characteristics, and their performances were evaluated experimentally. The vane-on-flange type lubricated sliding tests were performed with a high pressure wear tester using carbon dioxide. Test results showed that the reformed surfaces were very effective to reduce the friction and the wear amounts of vane surfaces. The method of improved surfaces showed good tribological properties at vane and flange.

Chloride Ion Penetration Properties of Normal Strength High-Fluidity Concrete Using Lime Stone Powder (석회석 미분말을 활용한 보통강도 고유동 콘크리트의 염소이온 침투특성)

  • Choi, Yun-Wang;Moon, Jae-Heum;Eom, Joo-Han
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.4
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    • pp.160-168
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    • 2010
  • Recently, there are a lot of researches related to the high-fluidity concrete (HFC) with field applications. However, most applications and studies are with concretes with high strength level so there are little studies about durability evaluations such as chloride ion penetration properties with normal strength concrete. Therefore, to evaluate the durability of HFC with normal strength level, this study performed the chloride ion penetration test and observed the micro pore distribution with normal strength HFC which contains limestone powder. Experimental results showed that most micro-pores have diameters between 0.005 to 0.05 ${\mu}m$ with HFCs using limestone powder and the average diameter becomes larger with the increase of limestone powder content. Also, it was shown that, with the increase of the limestone powder content, penetration depth and diffusion coefficient of chloride ion increased and diffusion coefficient had good relationships with compressive strength and average pore diameter with the coefficient of determination over 0.90.

The Operation Characteristics of a Sea Water Source Heat Pump System (해수열원 히트펌프 시스템의 운전특성)

  • Chang, Ki-Chang;Baik, Young-Jin;Ra, Ho-Sang;Kim, Ji-Young;Lee, Jae-Hoon
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.1353-1357
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    • 2008
  • A sea water source cascade heat pump was designed and tested in this study. The system was designed to perform a single stage operation in summer, as well as a cascade operation in winter to ensure the high temperature lift. A steady-state simulation model was developed to analyze and optimize its performance. The simulation results show that the R717 exhibits best performance among combinations considered in this study. A R410A also exhibits the highest performance among HFCs with the smallest compressor displacement. A 15-RT R410A-R134a pilot system was installed in the 5-story commercial building at Samcheok City by the East Sea. A scroll type R410A compressor, a reciprocating type R134a compressor, plate type condenser/ evaporator/ cascade heat exchanger and two electronic expansion valves were used to build a pilot. A titanium plate type heat exchanger is also used for the heat exchanging with a sea water. The heat source/sink water is supplied from the well below the seashore in the depth of 5 m. In the initial test of the system, supply water temperature was rising up to $67^{\circ}C$ using a sea water heat source of $9^{\circ}C$, while an ambient temperature was $4.5^{\circ}C$.

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