• Title/Summary/Keyword: HEM

Search Result 339, Processing Time 0.029 seconds

Effects of Mechanically Activated Milling and Calcination Process on the Phase Stability and Particle Morphology of Monoclinic Zirconia Synthesized by Hydrolysis of ZrOCl2 Solution

  • Lee, Young-Geun;Ur, Soon-Chul;Mahmud, Iqbal;Yoon, Man-Soon
    • Korean Journal of Materials Research
    • /
    • v.23 no.10
    • /
    • pp.543-549
    • /
    • 2013
  • The purpose of this paper was to investigate the effect of a high-energy milling (HEM) process on the particle morphology and the correlation between a thermal treatment and tetragonal/monoclinic nanostructured zirconia powders obtained by a precipitation process. To eliminate chloride residue ions from hydrous zirconia, a modified washing method was used. It was found that the used washing method was effective in removing the chloride from the precipitated gel. In order to investigate the effect of a pre-milling process on the particle morphology of the precipitate, dried $Zr(OH)_4$ was milled using a HEM machine with distilled water. The particle size of the $Zr(OH)_4$ powder exposed to HEM reduced to 100~150 nm, whereas that of fresh $Zr(OH)_4$ powder without a pre-milling process had a large and irregular size of 100 nm~1.5 ${\mu}m$. Additionally, modified heat treatment process was proposed to achieve nano-sized zirconia having a pure monoclinic phase. It was evident that two-step calcining process was effective in perfectly eliminating the tetragonal phase, having a small average particle of ~100 nm with good uniformity compared to the sample calcined by a single-step process, showing a large average particle size of ~300 nm with an irregular particle shape and a broad particle size distribution. The modified method is considered to be a promising process for nano-sized zirconia having a fully monoclinic phase.

Pollutants Unit Loadings of the Stormwater Runoff in Industrial Complex (강우시 산업단지에서의 유출오염부하량 원단위 산정)

  • Lee, Jun-Ho;Bang, Ki-Woong;Choi, Jong-Soo
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.2
    • /
    • pp.355-362
    • /
    • 2000
  • The objective of this paper is to estimate the pollutant load based on event mear concentrations(EMC) in industrial complex. Eight sub-basins in the Chongju industrial complex were selected for sampling and study with different characteristics during the period from June 1997 to August 1998. During the storm events, measured EMC ranges of $BOD_5$, COD, SS, TKN, TP, HEM, $NO_3-N$, $PO_4-P$, Cr, Pb, Cu and Fe in the industrial complex watersheds were 11~176mg/L, 40~502mg/L, 23~633mg/L, 104~20.9mg/L, 0.22~7.51mg/L, 12.7~548.7mg/L, 0.06~2.66mg/L, 0.12~3.39mg/L, 0.01~0.50mg/L. 0.02~0.42mg/L, 0.01~0.15mg/L and 1.29~11.51mg/L respectively. And the calculated annual average pollutant unit loadings of $BOD_5$ COD, SS, TKN, $NO_3-N$, $PO_4-P$, TP, HEM, Cr, Pb, Cu and Fe were 374.4kg/ha/yr 924.1kg/ha/yr, 983.6kg/ha/yr, 48.8kg/ha/yr, 8.1kg/ha/yr, 9.7kg/ha/yr, 17.8kg/ha/yr 943.0kg/ha/yr, 0.7kg/ha/yr, 0.9kg/ha/yr, 0.3kg/ha/yr and 28.9kg/ha/yr, respectively.

  • PDF

Optimizing the Production of 5-Aminolevulinic Acid by Recombinant Escherichia coli Containing the Rhodobacter capsulatus hemA Gene (Rhodobacter capsulatus hemA 유전자 발현 대장균에 의한 5-Aminolevulinic Acid 생산의 최적화)

  • Yang, Dong-Soo;Park, Moon-Won;Lim, Soo-Jin;Kim, Min-Jeong;Shin, Yu-Ri;Park, Chan-Soo;Hyun, Young;Kang, Dae-Kyung
    • Microbiology and Biotechnology Letters
    • /
    • v.37 no.2
    • /
    • pp.153-159
    • /
    • 2009
  • Recombinant Escherichia coli BLR(DE3) harboring the hemA gene from Rhodobacter capsulatus under the control of a constitutive promoter, which we constructed previously, was used for the extracellular production of 5-aminolevulinic acid (ALA). The effects of several factors on ALA production were investigated in flask culture. ALA production by the recombinant E. coli was more efficient at $30^{\circ}C$ than $37^{\circ}C$. The glycine concentration had an important effect on cell growth. Glycine and succinic acid concentration of 5-10 and 10-20 g/L, respectively, resulted in high ALA production. In addition, the partial replacement of succinic acid by sodium glutamate increased the ALA production. The ALA production was inhibited by the presence of glucose in the medium. Using the optimal conditions, an ALA concentration of 8.2 g/L was achieved in jar fermentation without an added inducer or ALA dehydratase inhibitor; this is the highest reported concentration.

MS-HEMs: An On-line Management System for High-Energy Molecules at ADD and BMDRC in Korea

  • Lee, Sung-Kwang;Cho, Soo-Gyeong;Park, Jae-Sung;Kim, Kwang-Yeon;No, Kyoung-Tae
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.3
    • /
    • pp.855-861
    • /
    • 2012
  • A pioneering version of an on-line management system for high-energy molecules (MS-HEMs) was developed by the ADD and BMDRC in Korea. The current system can manage the physicochemical and explosive properties of virtual and existing HEMs. The on-line MS-HEMs consist of three main routines: management, calculation, and search. The management routine contains a user-friendly interface to store and manage molecular structures and other properties of the new HEMs. The calculation routine automatically calculates a number of compositional and topological molecular descriptors when a new HEM is stored in the MS-HEMs. Physical properties, such as the heat of formation and density, can also be calculated using group additivity methods. In addition, the calculation routine for the impact sensitivity can be used to obtain the safety nature of new HEMs. The impact sensitivity was estimated in a knowledge-based manner using in-house neural network code. The search routine enables general users to find an exact HEM and its properties by sketching a 2D chemical structure, or to retrieve HEMs and their properties by giving a range of properties. These on-line MS-HEMs are expected be powerful tool for deriving novel promising HEMs.

Home Energy Management System for Interconnecting and Sensing of Electric Appliances

  • Cho, Wei-Ting;Lai, Chin-Feng;Huang, Yueh-Min;Lee, Wei-Tsong;Huang, Sing-Wei
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • v.5 no.7
    • /
    • pp.1274-1292
    • /
    • 2011
  • Due to the variety of household electric devices and different power consumption habits of consumers at present, general home energy management (HEM) systems suffer from the lack of dynamic identification of various household appliances and a unidirectional information display. This study presented a set of intelligent interconnection network systems for electric appliances, which can measure the power consumption of household appliances through a current sensing device based on OSGi platform. The system establishes the characteristics and categories of related electric appliances, and searches the corresponding cluster data and eliminates noise for recognition functionality and error detection mechanism of electric appliances by applying the clustering algorithm. The system also integrates household appliance control network services so as to control them according to users' power consumption plans or through mobile devices, thus realizing a bidirectional monitoring service. When the system detects an abnormal operating state, it can automatically shut off electric appliances to avoid accidents. In practical tests, the system reached a recognition rate of 95%, and could successfully control general household appliances through the ZigBee network.

A Study on the Size of the Alterated School Uniforms of High School Girls in Cheju and the Level of Their Satisfaction (제주지역 여고생의 교복 변형에 따른 치수 및 교복만족도에 관한 연구)

  • Kwon, Sook-Hee;Kim, Hye-Jung
    • Korean Journal of Human Ecology
    • /
    • v.11 no.4
    • /
    • pp.401-413
    • /
    • 2002
  • The purpose of this study was to survey the high school girls' alteration of school uniforms concerned about both size satisfaction and dissatisfaction and to improve the size of school uniforms. The subjects were 1,007 girls attending high schools in Cheju. The questionnaire survey was done from July 8th to Sep. 21th, 2001. According to the survey, 67.3 percentile of the interviewed girls alterated their uniforms. It was appeared that they alterated skirts more than blouses as a way of shortening. The main reason of alteration is ill-fitting uniforms, most of girls had a positive idea to alterate uniforms. Dissatisfaction of uniforms is mainly caused by the large size not by the small size. It was appeared that dissatisfaction rate of skirt was higher than that of blouse. The large part of dissatisfaction was appeared on waist circumference of blouse and hem circumference of skirt. The girls who experienced alterating the part of uniforms such as waist circumference of skirt, skirt length and hem circumference had high satisfaction rate. And a result of analyzing the level of satisfaction with uniforms-size-satisfaction/dissatisfaction showed the significant differences in fashion, factors-aesthetics and factors-activity of skirt and blouse.

  • PDF

Analysis of Heme Biosynthetic Pathways in a Recombinant Escherichia coli

  • Pranawidjaja, Stephanie;Choi, Su-In;Lay, Bibiana W.;Kim, Pil
    • Journal of Microbiology and Biotechnology
    • /
    • v.25 no.6
    • /
    • pp.880-886
    • /
    • 2015
  • Bacterial heme was produced from a genetic-engineered Escherichia coli via the porphyrin pathway and it was useful as an iron resource for animal feed. The amount of the E. coli-synthesized heme, however, was only few milligrams in a culture broth and it was not enough for industrial applications. To analyze heme biosynthetic pathways, an engineered E. coli artificially overexpressing ALA synthase (hemA from Rhodobacter sphaeroides) and pantothenate kinase (coaA gene from self geneome) was constructed as a bacterial heme-producing strain, and both the transcription levels of pathway genes and the intermediates concentrations were determined from batch and continuous cultures. Transcription levels of the pathway genes were not significantly changed among the tested conditions. Intracellular intermediate concentrations indicated that aminolevulinic acid (ALA) and coenzyme A (CoA) were enhanced by the hemA-coaA co-expression. Intracellular coproporphyrinogen I and protoporphyrin IX accumulation suggested that the bottleneck steps in the heme biosynthetic pathway could be the spontaneous conversion of HMB to coproporphyrinogen I and the limited conversion of protoporphyrin IX to heme, respectively. A strategy to increase the conversion of ALA to heme is discussed based on the results.

An Analysis to the Actual Condition of Tight Skirts Construction According to the Difference Between Body Size and Products Size (신체치수와 제품치수의 차이로 본 타이트 스커트의 구성 실태분석)

  • 정옥임
    • Journal of the Korean Home Economics Association
    • /
    • v.38 no.1
    • /
    • pp.1-8
    • /
    • 2000
  • In this study 61private brand skirts and 67 brand name skirts were compared to see if the skirts from the different markets were suitable for both comfort and movement. The researcher chose size 66 skirts with a waist circumference of 68~70cm and hip circumference of 92cm. The resets are as follows. (1) In the waist measurement, the minor brand skirts were made at the maximum measurement (70cm) and the department store brand skirts were at the minimum (68cm). (2) Compared with the standard back split length of 9cm for a 48cm-long skirt, the minor brand skirts had a split of only 4.5cm, while the department store brand skirts were 3cm less (split length-6cm). From this result, we see that both of them are less practical than they are supposed to be (3) For the department store skirts, the hip circumference and waist circumference show a significant correlation to skirt length (p<0.05) and back split length (p<0.001). Larger waist & hip measurements equal longer split length. For the minor brand skirts, the length of the split shows a significant correlation to the depth of the hem-line Shorter split equals smaller hem depth. From these results, it can be concluded that the two groups of skirts do not differ except for back split length and waist circumference, but regarding the split length, both of them should be modified for else of movement and comfort.

  • PDF