• Title/Summary/Keyword: HCN

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A supervised-learning-based spatial performance prediction framework for heterogeneous communication networks

  • Mukherjee, Shubhabrata;Choi, Taesang;Islam, Md Tajul;Choi, Baek-Young;Beard, Cory;Won, Seuck Ho;Song, Sejun
    • ETRI Journal
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    • v.42 no.5
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    • pp.686-699
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    • 2020
  • In this paper, we propose a supervised-learning-based spatial performance prediction (SLPP) framework for next-generation heterogeneous communication networks (HCNs). Adaptive asset placement, dynamic resource allocation, and load balancing are critical network functions in an HCN to ensure seamless network management and enhance service quality. Although many existing systems use measurement data to react to network performance changes, it is highly beneficial to perform accurate performance prediction for different systems to support various network functions. Recent advancements in complex statistical algorithms and computational efficiency have made machine-learning ubiquitous for accurate data-based prediction. A robust network performance prediction framework for optimizing performance and resource utilization through a linear discriminant analysis-based prediction approach has been proposed in this paper. Comparison results with different machine-learning techniques on real-world data demonstrate that SLPP provides superior accuracy and computational efficiency for both stationary and mobile user conditions.

KINEMATICS AND CHEMISTRY OF THE S140/L1204 MOLECULAR COMPLEX

  • Park, Yong-Sun;Minh, Young-Chul
    • Journal of The Korean Astronomical Society
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    • v.28 no.2
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    • pp.255-264
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    • 1995
  • The HII region S140 and the associated molecular cloud L1204 have been observed with 10 molecular transitions, CO (1-0), $^{13}CO$ (1-0), $C^{18}O$ (1-0), CS (2-1), $HCO^+$ (1-0), HCN (1-0), SO (${2_2}-{1_1}$), $SO_2(2_{20}-3_{13})$, OCS (8-7), and $HNCO\;(4_{04}-3_{03})$ with ${\sim}50"$ angular resolutions. More than 7,000 spectra were obtained in total. The morphology of this region shows a massive fragment (the S140 core) and the extended envelope to the northeast. Several gas condensations have been identified in the envelope, having masses of ${\sim}10^{3}M_{\odot}$ and gas number densities of ${\lesssim}10^{4}cm^{-3}$ to $3{\times}10^{5}cm^{-3}$ in their cores. The column densities of the observed molecular species toward the S140 core appear to be the typical warm clouds' abundances. It seems to be that the S140 core and L1204 have been swept up by an expanding shell called the Cepheus bubble. The large value of $L_{IR}$(embedded\;stars)/$M_{cloud}\;{\sim}\;5\;L_{\odot}$/$M_{\odot}$ of the S140 core may suggest that the star formation has been stimulated by the HII region, but the shock velocity and the pressure of the region seem to give a hint of the spontaneous star formation by the self gravity.

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PROPERTIES OF THE MOLECULAR CLUMP AND THE ASSOCIATED ULTRACOMPACT H II REGION IN THE GAS SHELL OF THE EXPANDING H II REGION SH 2-104

  • Minh, Young Chol;Kim, Kee-Tae;Yan, Chi-Hung;Park, Yong-Sun;Lee, Seokho;Lal, Dharam Vil;Hasegawa, Tatsuhiko;Zhang, X.Z.;Kuan, Yi-Jeng
    • Journal of The Korean Astronomical Society
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    • v.47 no.5
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    • pp.179-185
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    • 2014
  • We study the physical and chemical properties of the molecular clump hosting a young stellar cluster, IRAS 20160+3636, which is believed to have formed via the "collect and collapse" process. Physical parameters of the UC H II region associated with the embedded cluster are measured from the radio continuum observations. This source is found to be a typical Galactic UC H II region, with a B0.5 type exciting star, if it is ionized by a single star. We derive a CN/HCN abundance ratio larger than 1 over this region, which may suggest that this clump is being affected by the UV radiation from the H II region.

CoMP Transmission for Safeguarding Dense Heterogeneous Networks with Imperfect CSI

  • XU, Yunjia;HUANG, Kaizhi;HU, Xin;ZOU, Yi;CHEN, Yajun;JIANG, Wenyu
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.13 no.1
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    • pp.110-132
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    • 2019
  • To ensure reliable and secure communication in heterogeneous cellular network (HCN) with imperfect channel state information (CSI), we proposed a coordinated multipoint (CoMP) transmission scheme based on dual-threshold optimization, in which only base stations (BSs) with good channel conditions are selected for transmission. First, we present a candidate BSs formation policy to increase access efficiency, which provides a candidate region of serving BSs. Then, we design a CoMP networking strategy to select serving BSs from the set of candidate BSs, which degrades the influence of channel estimation errors and guarantees qualities of communication links. Finally, we analyze the performance of the proposed scheme, and present a dual-threshold optimization model to further support the performance. Numerical results are presented to verify our theoretical analysis, which draw a conclusion that the CoMP transmission scheme can ensure reliable and secure communication in dense HCNs with imperfect CSI.

Cyanide detection based on natural dyes reaction from blue butterfly pea flowers (Clitoria Ternatea)

  • Chotichayapong, Chatrachatchaya;Kuchaiyaphum, Pusita;Butwong, Nutthaya;Bua-ngern, Worapong
    • Analytical Science and Technology
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    • v.35 no.4
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    • pp.153-160
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    • 2022
  • A green spectrophotometric method for the determination of cyanide has been proposed using, a green reagent, aqueous extract of blue butterfly pea. The test tube was filled with anthocyanin rich extract (pH 6) and cyanide solution. The reaction was kept constant for 10 minutes at room temperature. The reaction mixture changed color from blue to green as the amount of CN-ions increased. The 620 nm peak intensity increased with CN concentration. Therefore, this wavelength was used for all cyanide analyses. The cyanide calibration curve had a linear range of 0.25-1.00, 1.00-4.00, and 4.00-10.00 mg/L, with a satisfactory correlation coefficient of 0.99 and a LOD of 0.57 mg/L. The recovery ranged from 8.33 to 76.94 percent, indicating that this method is inaccurate at low cyanide concentrations. The intra-day and intermediate precision relative deviations were 0.391-0.871 % and 1.112-1.583 %. An H-bond forms between the C-4 group of the B-carbonyl ring and the HCN molecule according to the B3LYP/TZVP calculation. The method is convenient for cyanide concentrations above the LOQ of 1.09 mg/L, cost-effective, and capable of reducing toxic solvents with acceptable precision. The method could also be used to detect total cyanide in biological, environmental, and industrial waste samples.

Acid-Catalyzed Hydrolysis of Hexacyanoferrate (III) to Prussian Blue via Sequential Mechanism

  • Youngjin Jeon
    • Journal of the Korean Chemical Society
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    • v.68 no.3
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    • pp.139-145
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    • 2024
  • This study aims to elucidate the mechanism involved in the hydrolysis of the hexacyanoferrate(III) complex ion (Fe(CN)63-) and the mechanism leading to the formation of Prussian blue (FeIII4[FeII(CN)6]3·xH2O, PB) in acidic aqueous solutions at moderately elevated temperatures. Hydrolysis constitutes a crucial step in generating PB through the widely used single-source or precursor method. Recent PB syntheses predominantly rely on the single-source method, where hexacyanoferrate(II/III) is the exclusive reactant, as opposed to the co-precipitation method employing bare metal ions and hexacyanometalate ions. Despite the widespread adoption of the single-source method, mechanistic exploration remains largely unexplored and speculative. Utilizing UV-vis spectrophotometry, negative-ion mode liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS), and a devised reaction, this study identifies crucial intermediates, including aqueous Fe2+/3+ ions and hydrocyanic acid (HCN) in the solution. These two intermediates eventually combine to form thermodynamically stable PB. The findings presented in this research significantly contribute to understanding the fundamental mechanism underlying the acid-catalyzed hydrolysis of the hexacyanoferrate(III) complex ion and the subsequent formation of PB, as proposed in the sequential mechanism introduced herein. This finding might contribute to the cost-effective synthesis of PB by incorporating diverse metal ions and potassium cyanide.

Molecular environments of a Planck Cold Clump: G108.8-00.8

  • Kim, Jungha;Lee, Jeong-Eun;Liu, Tie;Kim, Kee-Tae;Menten, Karl;Wu, Yuefang;Thompson, Mark;Yuan, Sheng
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.53.2-53.2
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    • 2015
  • We present preliminary results from a series of observations toward G108.8-00.8, which is one of Planck Cold Clumps and a promising candidate of massive prestellar cores. In the integrated intensity map of SCUBA 850 micron dust continuum emission, highly fragmented structures appear. These are distributed along one long filamentary structure seen in the CO 1-0 and 13CO 1-0 integrated intensity maps obtained with the PMO 13.7 m telescope. The northern part of the filament is divided into two parts, as seen in the CO 2-1, 13CO 2-1, and C18O 2-1 integrated intensity maps obtained with the CSO 10 m telescope. The observations of HCO+ 1-0, N2H+ 1-0, and HCN 1-0 with the IRAM 30 m telescope focus on the northern part of the CSO maps, which show a head-tail structure. NH3 (1,1) also shows similar distribution with IRAM maps. The depletion factors, derived by the comparison between the dust continuum and C18O 2-1 emission, varies from 1.5 to 6 over the region, suggesting different evolutionary status of each component. To study the chemical and physical environments of G108.8-00.8, more detailed analysis is in progress.

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A Study on Noxious Gases Analysis of Polyurethane foams (Polyurethane foam의 유해가스 분석에 관한 연구)

  • 이창우;김정환;현성호
    • Fire Science and Engineering
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    • v.14 no.2
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    • pp.7-13
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    • 2000
  • We had investigated thermal stability, Ignition temperature and fire gas for polyurethane foams used for manikin, cushion and interior finishing material. Decomposition of polyurethane foams with temperature was investigated using a DSC and the weight loss with temperature increase using a TGA in order to find the thermal hazard of polyurethane foams, and the ignition temperature of polyurethane foams according to species. We studied constant temperature among ignition temperature measuring methods. In addition, noxious gases for polyurethane foams according to combustion condition were analyzed using gas analyzer and GASTEC. As results, initial decomposition temperature of polyurethane foam used for interior finishing material was lower than those for manikin and cushion, and exothermic energy was higher. Ignition temperature of polyurethane foam of interior finishing material was $420^{\circ}$. All of combustion forms at $427^{\circ}$ and under were smoldering combustion, and it was combustion at $500^{\circ}$. As furnace temperature was increased, concentration of noxious gases such as carbon oxide, carbon dioxide, and hydrogen cyanide was increased. And nitrogen oxide at combustion condition($500^{\circ}$) was over 10 ppm.

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Characterization of Bacillus luciferensis Strain KJ2C12 from Pepper Root, a Biocontrol Agent of Phytophthora Blight of Pepper

  • Kim, Hye-Sook;Sang, Mee-Kyung;Myung, Inn-Shik;Chun, Se-Chul;Kim, Ki-Deok
    • The Plant Pathology Journal
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    • v.25 no.1
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    • pp.62-69
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    • 2009
  • In this study, we characterized the bacterial strain KJ2C12 in relation with its biocontrol activity against Phytophthora capsici on pepper, and identified this strain using morphological, physiological, biochemical, fatty acid methyl ester, and 16S rRNA gene sequence analyses. Strain KJ2C12 significantly (P=0.05) reduced both final disease severity and areas under the disease progress curves of 5-week-old pepper plants inoculated with P. capsici compared to buffer-treated controls. As for the production of antibiotics, biofilms, biosurfactant, extracellular enzyme, HCN, and swarming activity, strain KJ2C12 produced an extracellular enzyme with protease activity, but no other productions or swarming activity. However, Escherichia coli produced weak biofilm only. Strain KJ2C12 could colonize pepper roots more effectively in a gnotobiotic system using sterile quartz sand compared to E. coli over 4 weeks after treatments. However, no bacterial populations were detected in 10 mM $MgSO_4$ buffer-treated controls. Strain KJ2C12 produced significantly higher microbial activity than the $MgSO_4$-treated control or E. coli over 4 weeks after treatments. Bacterial strain KJ2C12 was identified as Bacillus luciferensis based on morphological, physiological, and biochemical characteristics as well as FAME and 16S rRNA gene sequence analyses. In addition, these results suggested that B. luciferensis strain KJ2C12 could reduce Phytophthora blight of pepper by protecting infection courts through enhanced effective root colonization with protease production and an increase of soil microbial activity.

The Development of Eco-friendly Fiber Materials for Transport (수송용 친환경 섬유소재 개발)

  • Bok, Jin-Seon;Lee, Hyun-Seok;Jeong, Geung-Sik;Lee, Ki-Young;Park, Chang-Seok
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.18-18
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    • 2012
  • 전 세계적으로 이산화탄소 배출량 저잠을 위해 모든 산업분야에서 연구개발의 중점을 두고 있다. 그의 일환으로 자동차 산업에서는 EU규제에 따라 리사이클이 가능한 소재 개발이 요구되고 있으며, 그중 많은 양이 사용되고 있는 PU Foam의 대체 재료 개발이 시급한 실정이다. 기존 자동차의 흡음재로 주로 사용되고 있는 PU Foam 소재는 통기성이 부족할 뿐만 아니라 연소 시 인체에 유해한 HCN Gas를 발생시키고, 한번 성형된 부품은 Recycle 및 Re-Use가 불가능하다는 단점이 있다. 또한 장시간 사용시 황변 발생과 악취가 발생하는 등으로 최근 대두되고 있는 자동차 내장재 감성품질 향상 측면에 한계를 나타내고 있다. 이러한 Low Melting 성능을 가지는 PET 부직포 소재의 한계를 극복하기 위하여 저융점 성능의 Elastic Fiber의 개발과 함께 고탄성 복합부직포 소재의 개발을 통해 높은 변형률과 우수한 복원력을 나타내는 환경친화형 열가소성 탄성체(Thermoplastic Elastomer) 개발을 추진하고 있다. 고탄성 복합부직포는 자동차 내장재 성형 시 열을 가하더라도 Elastomer 자체의 탄성 발현을 통해 초기의 Bulky성을 유지할 수 있으며, Recycle 및 Re-use가 가능하여 환경 친화적인 측면에서도 큰 장점을 갖고 있다. 자동차용 흡음 내장재뿐만 아니라 각종 수송용 차량의 경량화 및 쾌적성 향상을 위한 용도로써 자동차 내장용 PU Foam의 57% 이상을 차지하고 있는 Seat Cushion재 등의 대체가 가능하며, 다양한 산업분야에서 사용되고 있는 PU Foam의 대체로 다양한 용도 전개가 가능할 것으로 예상된다. 본 연구에서는 PU Foam의 대체 재료로 각광받고 있는 Elastic PET를 개발하여 자동차 내장재로의 적용 가능성을 검토하였다.

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