• 제목/요약/키워드: HAL

검색결과 266건 처리시간 0.022초

고효율 염료감응 태양전지를 위한 $TiO_2$의 합성 및 최적화 (optimization and synthesis of $TiO_2$ for for the high efficiency DSSC)

  • 박아름;기현철;;구할본
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
    • /
    • pp.56.2-56.2
    • /
    • 2011
  • 고효율 염료감응 태양전지를 제작하기 위해 Sol-gel법을 사용하여 $TiO_2$ 분말을 제조하였다. 제조 과정 중 다양한 양의 nitric acid를 첨가하여 pH를 조절하였다. Sol-gel법을 위한 출발 물질로 titanium (IV) isopropoxide(TTIP)와 DI water를 사용하였으며 nitric acid은 0, 0.05, 0.1, 0.15의 몰비(nitric acid/TTIP)로 첨가하였다. 첨가한 결과 pH는 $22^{\circ}C$에서 각각 5.52, 2.26, 1.68, 1.38이었다. 얻어진 $TiO_2$ 콜로이드 용액은 결정성 있는 분말로 제조 후 $5{\times}5[mm^2]$ 크기의 염료감응 태양전지를 제작하는데 사용 되였다. $TiO_2$의 결정구조 및 형태는 cell의 XRD와 FE-SEM으로 분석되었고 전기화학적 특성을 분석하기 위해 irradiation of AM 1.5 ($100mW/cm^2$) simulatedsunlight에서 I-V 곡선을 측정하였다. 측정 결과 몰비(nitric acid/TTIP) 0.05, pH가 2.26일 때 가장 우수한 효율 특성을 보였다.

  • PDF

카본 나노파이버가 도핑된 리튬이온전지의 전기화학적 특성 (Electrochemical Characteristics of Lithium-ion Battery with Doped Graphite Nanofiber)

  • ;;구할본
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
    • /
    • pp.137.1-137.1
    • /
    • 2011
  • 올리빈 구조의 $LiFePO_4$ 정극 활물질은 $650^{\circ}C$에서 고상법으로 제조되었다. $LiFePO_4$의 전자전도도를 향상시키기 위하여 graphite nanofiber(GNF)를 각각 3wt%, 5wt%, 7wt%, 9wt% 첨가하여 $LiFePO_4$-C를 제조하였다. 제조된 분말의 입자 형태를 확인하기 위하여 X-ray diffraction(XRD)과 File Electronic Scaning Electromicroscopy(FE-SEM)를 측정하였다. XRD결과로부터 제조된 분말은 모두 순수한 결정 구조를 나타내었고 입자의 크기는 약 200nm였다. 5wt% GNF를 첨가한 $LiFePO_4$-C는 기타 첨가량에 비해 방전용량이 가장 높았다. 첫 사이클의 용량은 151.73mAh/g 나타났고 50 사이클 뒤에도 92% 이상을 유지하고 있었다. 첨가하지 않은 것에 비해 43% 증가하였다. $LiFePO_4$-C(3wt%), $LiFePO_4$-C(7wt%), $LiFePO_4$-C(9wt%)의 첫 사이클 방전용량은 각각 147.94mAh/g, 136.64mAh/g, 121.07mAh/g 나타났다. $LiFePO_4$-C(5wt%)에 비해 용량은 떨어쪘지만 순수한 $LiFePO_4$보다 많이 높았다. 임피던스 결과를 보면 기타 첨가량에 비해 $LiFePO_4$-C(5wt%)의 저항 제일 낮았다. 이는 충방전 결과와 일치하였다. graphite nanofiber의 첨가로 인하여 $LiFePO_4$ 정극 활물질의 전자전도도가 높아지고, 따라서 전기화학적 특성도 크게 향상되었다.

  • PDF

금속염을 이용한 염료감응 태양전지의 고체전해질의 전기화학적 특성 (Electrochemical properties of metal salts polymer electrolyte for DSSC)

  • ;;구할본
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
    • /
    • pp.55.1-55.1
    • /
    • 2011
  • Dye-sensitized solar cell(DSSC) have been considered one of the promising alternatives to conventional solar cells, because of their low cost, easy fabrication and relatively high energy conversion efficiency. However, although the cell offers reasonable efficiency at least 11%, the use of a liquid electrolyte placed technological challenges for achieving the desired durability and operational stability of the cell. In order to prevent or reduce electrolyte leakage considerable efforts have been made, such as p-type semiconductor or organic hole-transport material that better mechanical properties and simple fabrication processes. In this work, we synthesized solid-state electrolyte containing LiI and KI metal salt with starting materials of poly ethylene oxide to substitute liquid electrolyte enhance the ionic conductivity and solar conversion efficiency. Li+ leads to faster diffusion and higher efficiency and K+ leading to higher ionic conductivity. The efficiency of poly ethylene oxide/LiI system electrolyte is 1.47% and poly ethylene oxide/potassium electrolyte is 1.21%. An efficiency of 3.24% is achieved using solid-state electrolyte containing LiI and KI concentrations. The increased solar conversion efficiency is attributed to decreased crystallinity in the polymer that leads to enhanced charge transfer.

  • PDF

Synthesis LiFePO4- poly(sodium 4-styrenesulfonate) composite cathode material for rechargeable lithium battery by hydrothermal method

  • Hiep, Nguyen Van;Wang, Wan Lin;Jin, En Mei;Gu, Hal-Bon
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
    • /
    • pp.137.2-137.2
    • /
    • 2011
  • Poly (sodium 4-styrenesulfonate) (PSS) is ionomer based on polystyrene that is electrical conductivity and isoviscosity. LiFePO4 has been a promising electrode material however its poor conductivity limits practical application. To enhance the electronic conductivity of LiFePO4, in this study we prepared LiFePO4- PSS composite by the hydrothermal method. LiFePO4 was heated at $170^{\circ}C$ for 12h and then different wt% PSS (0%, 2.91%, 4.75%, 7.36%, 10%) are added to LiFePO4 and milled at 300rpm for 10h. And then the obtained powders were subsequently heated at $500^{\circ}C$ for 1h under argon flow. The cathode electrode were made from mixtures of LiFePO4-PSS: SP-270- PVDF in a weighting ratio 75%: 25%:5%. The electrochemical properties of LiFePO4- PSS/Li batteries were analyzed by cyclic voltammetry and charge/discharge tests. LiFePO4-C/Li battery with 4.75 wt% PSS displays discharge capacity of 128 mAh g-1 at room temperature that is considerably higher than pure LiFePO4/Li battery ( 113.48 mAhg-1).

  • PDF

2 kW급 MCFC용 평편형 개질기 운전결과 (The Performance & Operation Analysis of a Plate Type Reformet for 2 kW Class MCFC Stack)

  • 서혜경;안교상;임희천;이상득
    • 한국수소및신에너지학회논문집
    • /
    • 제13권2호
    • /
    • pp.159-167
    • /
    • 2002
  • The operation results of the 2kW class plate type reformer, which has several advantages compared with the tubular burner type reformer, are analyzed. This plate type reformer is composed of six combustion chambers and five reforming chambers by turns. The methane conversion rate at 1.6 absolute pressure is about 84%, which is reasonably similar to theoretical value, 85.3%. Though the abrupt interruption was made just by the carbon deposition during heating the fuel line to combustion chambers around 200 hours operation, the overall steady state operation is more than 450 hours. These operation results show the verification of long run performance and the possibility of direct connection between plate reformer and fuel cell stack.

재생미분말을 사용한 콘크리트 제품 개발에 대한 기초적인 연구 (The Fundamental Study on Development of Concrete-Product by Using Recycled Concrete Powder)

  • 선정수;김하석;곽은구;전명훈;김봉주;김진만
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2006년도 춘계학술논문 발표대회 제6권1호
    • /
    • pp.19-22
    • /
    • 2006
  • The quantity of Recycled concrete powder is increased, because it hal been ever so often crushing for production of a good quality recycled aggregates This Study is on the Development of Concrete-Product by Using Recycled Concrete Powder and alto for know performance of concrete-producted having low water contents and it is to know for all of performance of concrete-producted having low water contents The conclusions of this study are following. The use of replacement cement is not effective, because it has strengh of less than 10MPa But It is possible to develop high strength concrete-producted having 39MPa above compressive strength by using recycled concrete powder. Because strength enhancement effects by recycled concrete powder are responsible to optimum grading. The conclusions of this study are following. The use of replacement cement is not effective, because it has strengh of less than 10MPa. It is possible to develop high strength concrete-producted having 39MPa above compressive strength by using recycled concrete powder. Because strength enhancement effects by recycled concrete powder are responsible to optimum grading.

  • PDF

열영상 광학계용 초정밀 Al 평면 미러의 설계 및 제작 (Design and Manufacture of Ultra-Precision Al Flat Mirror Using Thermal Image Optics)

  • 김대중;최철호;박용필;구할본;김상석;김정호
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 기술교육전문연구회
    • /
    • pp.136-139
    • /
    • 2003
  • Thermal imaging system is electro-optical imaging device which can make visible the difference of infrared energy naturally emitted by objects. It is acquire the same images at any time of the day or night. There it has been readily available to the night observation such as fire control systems. In this study, we are manufacturing thermal image Al flat mirror. The surface roughness 3.539nm Ra and power 0.382 fringe(at 632.8nm), irregularity 0.835 fringe(at 632.8nm) for form waviness of thermal image Al flat mirror are very satisfied. The results will be reflected for development of the ultra precision application. And a brief review of Ultra-precision system in the field of Ultra-precision at Korea photonics technology institute (KOPTI) is present in this paper.

  • PDF

Radio Frequency Plasma Power변화에 따른 ITO 특성 및 OLED의 광학적 특성 (Optical Properties of Organic Light Emitting Diode and Characteristics of ITO by Variation of Radio Frequency Plasma Power)

  • 기현철;김회종;홍경진;김은미;구할본
    • 한국전기전자재료학회논문지
    • /
    • 제22권1호
    • /
    • pp.81-85
    • /
    • 2009
  • We has been analysed optical properties of OLED(organic light emitting diode) and characteristics of ITO(Indium Tin Oxide) in terms of $O_2$ plasma treatment for manufacturing high efficiency OLED, RF power of $O_2$ plasma was changed 25, 50, 100, 200 W. $O_2$ gas flow, gas pressure and treatment time were fixed. Sheet resistance and surface roughness of ITO were measured by Hall-effect measurement system and AFM, respectively. The ranges of sheet resistance and surface roughness were $5.5{\sim}6,06\;{\Omega}$ and $2.438{\sim}3.506\;nm$ changing of RF power, respectively, PM(Passive Matrix)OLED was fabricated with the structure of ITO(plasm treatment)/TPD($400\;{\AA}$)/$Alq_3(600\;{\AA})$/LiF($5\;{\AA}$)/Al($1200\;{\AA}$). Turn-on voltage of PMOLED was 7 V and luminance was $7,371\;cd/m^2$ at the RF power of 25 W, $O_2$ plasma treatment of ITO surface was result in lowering the operating voltage and improving luminance of PMOLED.

$TiO_2$ 나노파이버를 첨가한 광전극용 $TiO_2$ 페이스트가 염료감응 태양전지의 광전변환 특성에 미치는 영향 (Effect of performance in $TiO_2$ paste for Dye-Sensitized Solar Cells by $TiO_2$ nanofiber)

  • 백형열;이호;김은미;박경희;구할본
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
    • /
    • pp.358-359
    • /
    • 2008
  • Solar cell based on dye-sensitized photoelectric conversion was studied by investigating the effects of the amount of $TiO_2$ nanofiber added to the $TiO_2$ paste, on surface morphology, good electric of the $TiO_2$ films and on the solar cell performance. Energy conversion efficiency was found to increased with $TiO_2$ nanofiber addition up to 7wt% in $TiO_2$ films. Maximum increase upto 15% in the efficiently was observed at 7 wt. % of $TiO_2$ nanofiber in $TiO_2$ electrode.

  • PDF

Quenching 법을 이용한 리튬폴리머 전지용 $LiMnO_2$ 정극활물질의 전기화학적 특성 (Electrochemical properties of $LiMnO_2$ cathode materials by quenching method)

  • 전연수;김은미;김파;박경희;박복기;사공건;구할본
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
    • /
    • pp.362-363
    • /
    • 2008
  • Well-defined o-$LiMnO_2$ cathode materials were synthesized using LiOH and $Mn_3O_4$ starting materials at $1050^{\circ}C$ in an argon flow by quenching method. The synthesized $LiMnO_2$ particles with crystalline phases were identified with X-ray diffraction (XRD, Dmax/1200, Rigaku). XRD results, demonstrated that the compound $LiMnO_2$ can be indexed to a single-phase material having the orthorhombic structure. In this paper, we analyzed the electrochemical performance of $LiMnO_2$/Li using solid polymer electrolyte and liquid electrolyte.

  • PDF