• Title/Summary/Keyword: HAAs

Search Result 121, Processing Time 0.037 seconds

Formation Characteristics of DBPs by Chlorination in Water Treatment Plant (정수장에서 소독부산물의 생성특성)

  • Rhee, Dong-Seok;Min, Byoung-Seob;Park, Sun-Ku;Kim, Joung-Hwa;Rhyu, Jae-Keun
    • Journal of Korean Society on Water Environment
    • /
    • v.20 no.1
    • /
    • pp.55-62
    • /
    • 2004
  • This study was carried out to investigate the formation of DBPs(Disinfection By-products) such as trihalomethane(THMs) and haloacetic acid(HAAs) by chlorination in raw water and finished water of Water Treatment Plant(WTP). The formation of THMs was increased with the increase of pH and reaction time. HAAs was found as a high formation at a pH 7 and low formation at pH 9. THMFP(Trihalomethane Formation Potential) was the highest formation potential in raw water of Pu-1 and the lowest in raw water of Pa-1. In case of HAAFP(Haloacetic acid formation potential), So-1 showed the highest value, while Pa-1 showed the lowest value. It was investigated the relationship between HAAs and organic matters which were described as DOC(dissolved organic carbon) and $UV_{254}$. In both DOC and $UV_{254}$ versus HAAFP, Pu-1 showed the good correlation coefficients($r^2$) with 0.95 and 0.84, respectively. For three WTP investigated, DBPs(THMs + HAAs) was shown over the range of $42.00{\sim}49.36{\mu}g/L$. This result might be due to the different characteristic of organic matters in raw water and the difference of chlorine dosage for a water treatment.

Shubnikov-de Haas Oscillations in an Individual Single-Crystalline Semimetal Bismuth Nanowire (단결정 반금속 비스무스 단일 나노선의 Shubnikov-de Haas 진동)

  • Kim, Jeong-Min;Ham, Jin-Hee;Shim, Woo-Young;Lee, Kyoung-Il;Jeon, Kye-Jin;Jeung, Won-Young;Lee, Woo Young
    • Korean Journal of Materials Research
    • /
    • v.18 no.2
    • /
    • pp.103-106
    • /
    • 2008
  • The magneto-transport properties of an individual single crystalline Bi nanowire grown by a spontaneous growth method are reported. A four-terminal device based on an individual 400-nm-diameter nanowire was successfully fabricated using a plasma etching technique that removed an oxide layer that had formed on the surface of the nanowire. Large transverse ordinary magnetoresistance (1401%) and negative longitudinal ordinary magnetoresistance (-38%) were measured at 2 K. It was observed that the period of Shubnikov-de Haas oscillations in transverse geometry was $0.074^{T-1}$, $0.16^{T-1}$ and $0.77^{T-1}$, which is in good agreement with those of bulk Bi. However, it was found that the period of SdH oscillation in longitudinal geometry is $0.24^{T-1}$, which is larger than the value of $0.16^{T-1}$ reported for bulk Bi. The deviation is attributable to the spatial confinement arising from scattering at the nanowire surface boundary.

Formation of Disinfection By-Products from Blue-green Algae by Chlorination (남조류의 염소처리에 따른 미량의 염소 소독부산물 생성에 관한 연구)

  • Son, Hee-Jong;Jung, Jong-Moon;Yeom, Hoon-Sik;Choi, Jin-Taek;Jang, Seong-Ho
    • Journal of Environmental Science International
    • /
    • v.21 no.8
    • /
    • pp.1015-1021
    • /
    • 2012
  • Formation of disinfection by-products (DBPs) including trihalomethans (THMs), haloacetic acid (HAAs), haloacetonitriles (HANs) and others from chlorination of algogenic organic matter (AOM) of Microcystis sp., a blue-green algae. AOM of Microcystis sp. exhibited a high potential for DBPs formation. HAAs formation potential was higher than THMs and HANs formation potential. The percentages of dichloroacetic acid (DCAA) and trichloroacetic acid (TCAA) formation potential were 43.4% and 51.4% in the total HAAs formation potential. In the case of HANs formation potential, percentage of dichloroacetonitrile (DCAN) formation potential was 97.7%. Other DBPs were aldehydes and nitriles such as acetaldehyde, methylene chloride, isobutyronitrile, cyclobutanecarbonitrile, pentanenitrile, benzaldehyde, propanal, 2-methyl, benzyl chloride, (2-chloroethyl)-benzene, benzyl nitrile, 2-probenenitrile and hexanal.

A Study on Formation Pattern of DBPs by Disinfection of Drinking Raw Water II (음용 원수의 염소소독에 의한 소독부산물 생성패턴에 관한 연구 II)

  • Lee, Kang Jin;Hong, Jee Eun;Pyo, Heesoo;Park, Song-Ja;Yoo, Je Kang;Lee, Dae Woon
    • Analytical Science and Technology
    • /
    • v.17 no.1
    • /
    • pp.69-81
    • /
    • 2004
  • The formation pattern of DBPs (disinfection by-products) in raw water treated with hypochlorite, chlorine disinfectant was studied. TOC (total organic carbon), residual chlorine, turbidity and 14 DBPs in raw water from Han-river and Nakdong river during 1 ~ 14 days were determined. Total DBPs in Han river was 101.3 ng/mL (789.6 nM) after 7days and THMs (trihalomethanes) are the dominant portion of 68%. HAAs (haloacetic acids) and chloral hydrate were determined 19% and 10% respectively. In Nakdong river total DBPs was 98.4 ng/mL (678.6 nM) and dominant class was HAAs. (55.8 ng/mL, 57%) THMs(34%) and N-compounds like HANs (haloacetonitriles, 5%) and chloropicrin were increased. It may be explained that high concentration of NH4-N in Nakdong river react with chlorine produced chloramine and this formed different pattern of DBPs. As a result, total DBPs formation pattern depends on raw water and disinfectant and in generally the initial concentration of acidic HAAs was high and THMs was increased gradually.

The Periods of Shubnikov-de Haas Oscillations in an Individual Single-Crystalline Bi Nanowire Grown by On-Film Formation of Nanowires

  • Kim, Jeong-Min;Ham, Jin-Hee;Lee, Seung-Hyun;Lee, Woo-Young
    • Proceedings of the Korean Magnestics Society Conference
    • /
    • 2010.06a
    • /
    • pp.80-81
    • /
    • 2010
  • We observed period of SdH oscillation in an individual Bi nanowire with the transverse and longitudinal magnetic fields along the axis of the nanowire grown by OFF-ON. Our results provide good qualitative description of the cyclotron behavior of the single-crystalline Bi nanowire in the ballistic regime.

  • PDF

Influence of Food Ingredients on the Formation of Heterocyclic Aromatic Amine in Cooked Pork Patties

  • Shin, Han-Seung
    • Food Science and Biotechnology
    • /
    • v.14 no.5
    • /
    • pp.572-575
    • /
    • 2005
  • The effects of cooking method, cooking time and various food ingredients on the formation/ inhibition of heterocyclic aromatic amines (HAAs) in pork products were investigated. Three HAAs, 2-amino-3,8-dimethylimidazo [4,5-f] quinoxaline ($MeIQ_x$), 2-amino-3,4,8-trimethylimidazo [4,5-f] quinoxaline ($DiMeIQ_x$) and 2-amino-1-methyl-6-phenylimidazo [4,5-b] pyridine (PhIP) were measured in pork products using solid-phase extraction and HPLC. Pork patties were boiled, oven-broiled and pan-fried to internal temperatures of 71, 77 and $88^{\circ}C$. Generally, HAA concentrations increased with increasing internal temperature, and HAA formation was greatest with pan-fried. Selected food ingredients (vitamin E, sodium nitrite, sodium tripolyphosphate, sodium ascorbate, Nanking cherry tissue and cherry tissue extract) inhibited HAA formation in pork patties fried at $225^{\circ}C$ for 10 min/side, with the greater inhibition provided by cherry tissue and its methanolic extract.

A Study on Ion Exchange Characteristics with Composition and Concentration of Solution (용액의 성분 및 농도에 따른 이온교환 특성 연구)

  • Jeong, Hyun-Jun;Ahn, Hyun-Kyoung;Lee, In-Hyoung
    • Proceedings of the KAIS Fall Conference
    • /
    • 2006.05a
    • /
    • pp.599-601
    • /
    • 2006
  • 본 논문에서는 용액의 농도가 이온교환 특성에 미치는 영향을 조사하기 위하여 농도는 $Na^+\;50$, 125, 250ppm, $Cl^-\;165$, 315, 610ppm, 입자성 물질의 유입 농도 0ppm, 유속 500ml/min, 이온교환 수지는 ROHM&HAAS IR 120 양이온 수지와 ROHM&HAAS IRA 402 음이온 수지를 사용하였다. 수지탑 배열은 혼상-혼상-음이온 수지탑 순으로, 이온교환 수지탑의 양 음이온교환 수지의 조성 비율은 1:2 로 실험한 결과 이온교환 수지탑 성능은 유입 용액 성분 및 농도에 영향을 받는 것으로 나타났다. 이온교환 수지탑 배열 순서에 따라 파과시점이 연장되며, 파과순서는 음이온의 경우 $Cl^-\;<\;NO_3\;^-\;<\;F^-$, 양이온의 경우 $Na^+\;<\;K^+\;<\;Ca^{2+}$ 순 이였으며, 용액의 농도가 증가할수록 파과시간이 단축되었다.

  • PDF

Effect of Pad Buffing process on Material Removal Characteristics in Silicon Chemical Mechanical Polishing (실리콘 연마에서 패드 버핑 공정이 연마특성에 미치는 영향)

  • Park, Ki-Hyun;Jeong, Hae-Do;Park, Jae-Hong;Kinoshita, Masaharu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.20 no.4
    • /
    • pp.303-307
    • /
    • 2007
  • This paper investigated the effect of the pad buffing process on the material removal characteristics and pad stabilization during silicon chemical mechanical polishing. The pads surface were controlled by the buffing process using a buffer made by the sandpaper. The buffing process is based on abrasive machining by using a high speed sandpaper. The controlled pad by the buffing process show less deformation deviation and stable material removal rate during the CMP process. In addition, the controlled pad ensure better uniformity of removal rate than comparative pads. As a result of monitoring, the controlled pad by the buffing process demonstrated constant and stable friction force signals from initial polishing stage. Therefore, the tufting process could control the pad surface to be uniform and improve the performance of the polishing pad.

Effects of barrier height on electron scattering mechanisms in $\delta-doped$ InAlAs/InGaAs/InAlAs Heterostructures

  • Park, H.S.;Vang, S.J.;Kim, J.I.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2004.07b
    • /
    • pp.955-959
    • /
    • 2004
  • The effects of conduction band offset on 2 dimensional electron gas (2DEG) in N-InAlAs(AlAsSb)/InGaAs/InAlAs (AlAsSb) metamorphic heterostructures (MMHS) are studied. A combination of the Shubnikov-deHaas oscillations and the Hall measurements is used to investigate the electron transport properties of these structures. The mobility in the second subband is higher than that in the first subband in all heterostructures. This is attributed to the fact that electrons in the first subband we, on average, closer to the interface and are therefore scattered more strongly by ionized impurities. The results suggest that intersubband scattering rate is more dominant in structures with higher conduction band offset whereas alloy scattering is found to be more dominant in the higher band offset system.

  • PDF