• Title/Summary/Keyword: HA coating

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Optical and Electrical Properties of $Ti_xSi_{1-x}O_y$ Films

  • Lim, Jung-Wook;Yun, Sun-Jin;Kim, Je-Ha
    • ETRI Journal
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    • 제31권6호
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    • pp.675-679
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    • 2009
  • $Ti_xSi_{1-x}O_y$ (TSO) thin films are fabricated using plasma-enhanced atomic layer deposition. The Ti content in the TSO films is controlled by adjusting the sub-cycle ratio of $TiO_2$ and $SiO_2$. The refractive indices of $SiO_2$ and $TiO_2$ are 1.4 and 2.4, respectively. Hence, tailoring of the refractivity indices from 1.4 to 2.4 is feasible. The controllability of the refractive index and film thickness enables application of an antireflection coating layer to TSO films for use as a thin film solar cell. The TSO coating layer on an Si wafer dramatically reduces reflectivity compared to a bare Si wafer. In the measurement of the current-voltage characteristics, a nonlinear coefficient of 13.6 is obtained in the TSO films.

폴리우레탄 방수재의 숯 첨가량에 따른 인장성능 변화추이 연구 (A Study on the Tensile Performance according to Quantities Characteristics of Charcoal in Poly-Urethane Waterproofing Material)

  • 박진상;김동범;박완구;하미영;김병일;오상근
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.120-121
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    • 2017
  • Polyurethane coating materials are widely used in waterproofing construction because they ensure easy workability and high performance mechanical properties, and such polyurethane coating materials are in various mixture ratios. This study carried out a test to determine the basic physical property changes of polyurethane coating material based on the amount of charcoal additives to. The results showed that he tensile strength was found to be 3.1 N / ㎟ when the charcoal amount was at 2%, displaying the highest performance rate.

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The histometric analysis of osseointegration in hydroxyapatite surface dental implants by ion beam-assisted deposition

  • Kim, Min-Kyung;Choi, Jung-Yoo;Chae, Gyung-Joon;Jung, Ui-Won;Kim, Sung-Tae;Lee, In-Seop;Cho, Kyoo-Sung;Kim, Chong-Kwan;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • 제38권sup2호
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    • pp.363-372
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    • 2008
  • Purpose: This study compared the effects of coating implants with hydroxyapatite (HA) using an ion beam-assisted deposition (IBAD) method prepared with machined, anodized, sandblasted and large-grit acid etched (SLA) surfaces in minipigs, and verified the excellency of coating method with HA using IBAD. Material and Methods: 4 male Minipigs(Prestige World Genetics, Korea), 18 to 24 months old and weighing approximately 35 to 40 kg, were chosen. All premolars and first molars of the maxilla were carefully extracted on each side. The implants were placed on the right side after an 8 week healing period. The implant stability was assessed by resonance frequency analysis (RFA) at the time of placement. 40 implants were divided into 5 groups; machined, anodized, anodized plus IBAD, SLA, and SLA plus IBAD surface implants. 4 weeks after implantation on the right side, the same surface implants were placed on the left side. After 4 weeks of healing, the minipigs were sacrificed and the implants were analyzed by RFA, histology and histometric. Results: RFA showed a mean implant stability quotient (ISQ) of $75.625{\pm}5.021$, $76.125{\pm}3.739$ ISQ and $77.941{\pm}2.947$ at placement, after 4 weeks healing and after 8 weeks, respectively. Histological analysis of the implants demonstrated newly formed, compact, mature cortical bone with a nearby marrow spaces. HA coating was not separated from the HA coated implant surfaces using IBAD. In particular, the SLA implants coated with HA using IBAD showed better contact osteogenesis. Statistical and histometric analysis showed no significant differences in the bone to implant contact and bone density among 5 tested surfaces. Conclusion: We can conclude that rough surface implants coated with HA by IBAD are more biocompatible, and clinical, histological, and histometric analysis showed no differences when compared with the other established implant surfaces in normal bone.

Shear-coating을 사용한 은 나노와이어 투명 전극 제조 및 특성 분석 (Preparation and characterization of silver nanowire transparent electrodes using shear-coating)

  • 조경수;홍기하;박준식;정중희
    • 한국표면공학회지
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    • 제53권4호
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    • pp.182-189
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    • 2020
  • Indium tin oxide (ITO) used a transparent electrode of a photoelectric device has a low sheet resistance and a high transmittance. However, ITO is disadvantageous in that the process cost is expensive, and the process time is long. Silver nanowires (AgNWs) transparent electrodes are based on a low cost solution process. In addition, it has attracted attention as a next-generation transparent electrode material that replaces ITO because it has similar electrical and optical characteristic to ITO, it is noted as a. AgNW thin films are mainly produced by spin-coating. However, the spin-coating process has a disadvantage of high material loss. In this study, the material loss was reduced by using about 2~10 ㎕ of AgNW solution on a (25 × 25) ㎟ substrate using the shear-coating method. It was also possible to align AgNWs in the drag direction by dragging the meniscus of the solution. The electro-optical properties of the AgNW thin film were adjusted by changing the experimental parameters that the amount of AgNWs suspension, the gap between the substrate and the blade, and the coating speed. As a result, AgNW thin films with a transmittance of 90.7 % at a wavelength of 550 nm and a sheet resistance of 15 Ω/□ was deposited and exhibited similar properties to similar AgNW transparent electrodes studied by other researchers.

점착필름 절단용 다이 칼날 소재에 적용된 점착 방지 코팅의 물 접촉각 및 박리강도에 관한 연구 (A Study on Water Contact Angle and Peel Strength by Anti- Adhesion Coating on Die Blade Materials for Adhesive Film Cutting)

  • 하유진;김민욱;김욱배
    • Tribology and Lubricants
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    • 제39권5호
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    • pp.190-196
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    • 2023
  • Anti-adhesion coatings are very important in the processing of adhesive materials such as optical clear adhesive (OCA) films. Choosing the appropriate release coating material for dies and tools can be quite challenging. Hydrophobic surface treatment is usually performed, and its performance is often estimated by the static water contact angle (CA). However, the relationship between the release performance and the CA is not well understood. In this study, the water CAs of surfaces coated with anti-adhesion materials and the peel strengths of the acrylic-based adhesive films are evaluated. STC5 and SUS304 are selected as the base materials. Base materials with different surface roughnesses are produced by hairline finishing, mirror-polishing, and end milling. Four fluoropolymer compounds, including a self-assembled monolayer, are selected to make the base surface hydrophobic. Static, advancing, and receding CAs are mostly increased due to the coating, but the CA hysteresis is found to increase or decrease depending on the coating material. The peel strengths all decreased after coating and are largely dependent on the coating material, with significantly lower values observed for fluorosilane and perfluoropolyether silane coatings. The peel strength is observed to correlate better with the static CA and advancing CA than with the receding CA or hysteresis. However, it is not possible to accurately predict the anti-adhesion performance based on water CA alone, as the peel strengths are not fully proportional to the CAs.

마이크로플라즈마 스프레이에 의한 HA코팅의 밀착력에 관한 연구 (A study on adhesion of HA coating by Microplasma Spray)

  • 문장원;권정대;권식철;나종주;이규인;전창수;고철웅
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2009년도 춘계학술대회 논문집
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    • pp.162-163
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    • 2009
  • 마이크로플라즈마 스프레이(Microplasma spray, MPS)를 이용하여 hydroxyapatite(HA) 코팅을 수행하여, HA코팅 층에 대한 밀착력을 측정하였다. 밀착력의 측정은 ASTM C633에 의거하였으며, 실험의 설계는 다꾸치법 (L18($2^{1}3^{7}$))을 이용하였다. 본 실험에서 HA코팅 층과 모재에 대한 밀착력 측정에서 35.8MPa의 밀착력을 얻었으며, SEM을 이용하여, 표면 형상과 밀착력 실험 후의 파단면을 관찰하였다. 또한, 나노 인덴테이션을 사용하여, 탄성계수와 미소경도를 측정하였다.

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졸-겔법에 의한 안경렌즈의 열경화형 유-무기 하이브리드 코팅 (Thermally Curable Organic-inorganic Hybrid Coatings on Ophthalmic Lenses by the Sol-Gel Method)

  • 유동식;이지호;하진욱
    • 한국산학기술학회논문지
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    • 제7권3호
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    • pp.465-470
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    • 2006
  • 코팅은 플라스틱의 표면의 물성과 렌즈의 광학적 성능을 높이기 위해 필요하다. Allyl diglycol carbonate계열 렌즈의 표면의 물성과 광학적 성능을 개선하기 위하여 3-glycidoxypropyltrimethoxysilane(GPTS), methyltrimethoxysilane(MTMS) 및 tetraethyl orthosilicate(TEOS)의 몰 비를 변화시켜 유-무기 하이브리드 재료로 사용하였다. Sol-gel 공정에 의한 flow코팅하여, $140^{\circ}C$에서 4시간 경화하였다. 코팅 렌즈는 투과율, 부착력, 연필경도, 내마모성, 내온수성 및 내약품성을 평가하였고 GPTS, MTMS 및 TEOS의 몰 비가 각각 1:1:2일 때 가장 우수한 것으로 나타났다.

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$TiB_2$ 코팅의 접착력 향상을 위한 AlSl H13 steel의 질화처리 (Adhesion Improvements of $TiB_2$ Coatings on Nitrided AlSl H13 Steel)

  • 박보환;정동하;김훈;이정중
    • 한국표면공학회지
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    • 제38권2호
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    • pp.79-82
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    • 2005
  • This study investigated the effect of nitriding on the hardness and adhesion properties of $TiB_2$ coatings. Inductively coupled plasma (ICP) was used for both nitriding and deposition. By applying ICP, H13 steel was nitrided at a high rate of $50\;{\mu}m/hr$. After nitriding, a Fe4N compound layer or a diffusion layer was formed according to the hydrogen/nitrogen ratio. Both layers could improve the load-bearing capacity of the substrate by increasing the substrate hardness. The adhesion of the $TiB_2$ coatings increased to $\~30N$ after nitriding, but the hardness of the coating was lowered to 20-30 GPa. However, the adhesion of the $TiB_2$ coatings with a high hardness (>60 GPa) could not be improved substantially by nitriding due to the large difference in hardness between the coating and the substrate. The grain size of the $TiB_2$ coating was larger on the nitrided substrates, resulting in a decrease in the hardness of the coating.

멤브레인형 LNG 운반선용 고강도 워시프라이머 개발 (Development of Newly Formulated High-strength Wash Primer for Membrane LNG Carrier)

  • 송은하;이성균;정몽규;백광기
    • 대한조선학회 특별논문집
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    • 대한조선학회 2007년도 특별논문집
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    • pp.48-56
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    • 2007
  • Wash primer was applied to cargo tank of Membrane-LNG Carrier (M-LNGC) for corrosion resistance and high bond-strength with the mastic. However, a lack of bond-strength verification at high thickness wash primer coating resulted in strict coating thickness control. Therefore wash primer was controlled below DFT(Dry Film Thickness) $30{\mu}m$. In order to develop the wash primer satisfying GTT (GAZ TRANSPORTAION TECHNIGAZ) standard even at high thickness, we evaluated coating properties such as wash primer/mastic bond-strength, corrosion resistance, as well as workability for the newly formulated wash primer materials. The newly formulated wash primer had high bonding-strength to mastic even at high thickness and had proper corrosion resistance and workability suitable to yard condition.

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Planarization of flexible tape substrate by solution coating process

  • Kang, Boo-Min;Ko, Rock-Kil;Kim, Dong-Hyuk;Ha, Dong-Woo;Park, Seong-Soo
    • 한국초전도ㆍ저온공학회논문지
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    • 제13권4호
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    • pp.18-21
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    • 2011
  • In this work, the yttrium oxide($Y_2O_3$) thin films as the buffer layer were prepared by the simple solution coating and reel-to-reel process on an unpolished metal tape substrate. The $Y_2O_3$ thin films were successfully synthesized by the hydrolysis of yttrium acetate. We have studied the improvement of surface roughness with the concentration of solution(0.1 M, 0.4 M, M) and the number of coatings. The planarization by solution coating process is simple in comparison with the existing polishing process, and it is eco-friendly, and has the benefits of low cost process. The thickness of $Y_2O_3$ films was increased with the $Y_2O_3$ concentration in the solution, and the surface became smoother with the number of coating cycles. Using this process, we have achieved 1.2 nm RMS roughness from a starting roughness of over 31 nm on 25 ${\mu}m^2$ area.