• Title/Summary/Keyword: HA coating

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Development of High Functional Coating Agents for Pulp Mold (IV) - Manufacture of higher functional and biodegradable coating agents - (펄프몰드용 새로운 고기능 코팅제 제조기술개발(제4보) - 고기능 생분해성 코팅제 제조 -)

  • Kang Jin-Ha;Lim Hyun-A;Park Seong-Cheol
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.1 s.113
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    • pp.45-53
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    • 2006
  • This study was carried out to produce high functional and biodegradable coating agents for pulp mold by evaluating various kinds of biodegradable polymers. Five kinds of biodegradable polymers were used. In addition, the mixture of the carboxymethylated starch and biodegradable polymers(${\kappa}$-carrageenan, chitosan) were used for mixed coating agents. Physical properties of coated paperboards were evaluated. Conclusions obtained were as follows. 4% ${\kappa}$-carrageenan and 5% chitosan showed higher water and oil resistance. 10% sodium alginate, 4% corn zein and 15% polycaprolactone showed high water resistance while no improvement was found on oil resistance. The optimum mixture ratios for the mixed coating agents were 90:10(carboxymethylated starch : ${\kappa}$-carrageenan) and 50:50(carboxymethylated starch : chitosan). Since these mixed coating agents have excellent biodegradability with higher water and oil resistance, these can be used for the environmental-friendly coating agents.

The Effect of a Latex and Ash Percent on the Surface Resistance of Coated Paper (코팅컬러의 라텍스와 회분이 코팅지의 표면강도에 미치는 영향에 관한 연구)

  • Jeon, Su-Kyoung;Han, Sam-Hwa;Ha, Young-Baeck;Youn, Jong-Tae
    • Journal of the Korean Graphic Arts Communication Society
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    • v.22 no.1
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    • pp.19-28
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    • 2004
  • A piece of coating color or base paper picked during printing is called coating pick. Loosely bonded materials of coating color or broken piece of fiber could be adhered to the blanket or would be mixed with ink during printing. Because the coating pick can make troubles in printing press such as piling, hickey and collecting, the coating pick of a paper has been one of the most serious problems in printing. In this paper, two influential factors to the coating pick in the printing, those are latex content and ash content of the coating color, are studied. The surface resistance of coating paper is directly proportional to the latex content, otherwise inversely proportional to the ash content. We propose a different way to evaluate the picking and used a homemade pick test device.

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Concentration of Urinary Hippuric Acid in Toluene-Exposed Workers According to the Specific Characteristic of Work

  • Kwon, Se-Young;Na, Young-Ak;Kim, Sang-Rak
    • Korean Journal of Clinical Laboratory Science
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    • v.44 no.1
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    • pp.17-23
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    • 2012
  • This study is assessed the urinary hippuric acid (HA) concentration in toluene-exposed workers. Toluene is widely used in the coating, printing, painting and petroleum industries. We analyzed the hippuric acid level of toluene-exposed workers (males: 198, females: 63) from 2008 to 2010 and examined the relationship between hippuric acid and the characteristics of their work. The measurements of the urinary hippuric acid were confirmed by high-performance liquid chromatography. Among the subjects, males had on average more work experience than females (males: 9.17 years, females: 4.45 years), but females showed a higher hippuric acid concentration levels than males (males: 0.26 g/L, females: 0.75 g/L). The mean of the HA concentration according to the age group was 0.19 g/L in 30's, 0.30 g/L in 40's, 0.54 g/L in 50's, 1.36 g/L in 60's. Those in their 60's had the highest concentration. The mean of HA concentration according to the type of work was 0.70 g/L for the coating, 0.52 g/L for the painting, and 0.16 g/L for the printing industries, revealing that the workers in the coating industry had the highest concentration. By the highest order, the mean of HA concentration by working period was as follows; less than 5 years, ${\leq}5\;years{\sim}<10\;years$. The factors that influence the HA concentration are not only how long one is exposed to toluene but also the type of work, worker's age, and their gender.

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Development of Higher Functional Coating Agents for Pulp Mold (III) Manufacture of starch derivatives for coating - (펄프몰드용 새로운 고기능 코팅제 제조기술개발(제3보) -코팅용 전분유도체 제조-)

  • Kang Jin Ha;Lim Hyun A
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.4 s.107
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    • pp.49-59
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    • 2004
  • This study was carried out to obtain the basic data for producing higher functional coating agents for pulp mold by evaluating various kinds of starch derivatives. At that time, four kinds of starch derivatives were manufactured for making coating agents respectively. Physical properties of coated paperboards were tested. Conclusions obtained from this results were as follows. The water and oil resistance of hydroxypropylated, cyanoethylated and carboxymethy­lated starch were high when degree of molar substitution(DS) of propylene oxide, acrylonitrile and sodium monochloroacetate were 0.18, 0.07 and 0.009, respectively. Also, the those of crosslinked starch were high when degree of crosslinking of epichlorohydrin was 0.02. Consequently, $8\%$ solution of carboxymethylated starch made with DS 0.009 of monochloroacetate was the best among coating agents from starch derivatives men­tioned above.

Processing and Microstructure of Alumina Coated with $Al_2O_3$/SiC Nanocomposite

  • Ha, Jung-Soo;Kim, C-S.;D-S. Cheong
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.19-22
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    • 1997
  • The surface modificaion of alumina by $Al_2$O$_3$/SiC nanocomposite coating was studied in terms of processing and microstructure. A powder slurry of 5 vol% SiC composition was dipcoated onto presintered alumina bodies and pressurelessly sintered at 1$700^{\circ}C$ for 2 h in $N_2$. The used of organic binder and plasticizer in the slurry preparation, and the control of the density of presintered alumina body were found to be necessary to avoid cracking and warping during processing. The nanocomposite coating well bonded to the alumina body with thickness about 110 ${\mu}{\textrm}{m}$. The average grain size of coating (2 ${\mu}{\textrm}{m}$) was much finer than that of alumina body (13 ${\mu}{\textrm}{m}$). Fracture surface observations revealed mostly transgranular fracture for the coating, whereas intergranular fracture for the alumina body. Some pores (about 6%) were observed in the coating layer, although the alumina body showed fully dense microstructure.

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Properties and Biodegradability of Polylactide for Paper Coating Application - $Poly(_{L} -lactide)\;and\;Poly(_{D}-lactide)$ Blend -

  • Lim Hyun A;Kang Jin Ha
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.5 s.108
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    • pp.53-61
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    • 2004
  • [ $Poly(_{D}-ldactide)\;(_{D}-PLA)$ ] was synthesized to have low molecular weight for miscible blends with a high molecular $poly(_{L}-lactide)\;(_{L} -PLA)$. The blends were prepared by dissolving the two components of $_{L}-PLA\;and\;_{D}-PLA\;(w/w)$ in chloroform (l00/0, 90/10, 70/30, 50/50, 30/70, 0/100). The miscibility of these miscible blends was characterized by gel-permeation chromatography (GPC), differential scanning calorimetry (DSC), and the selective degradability by enzymes (proteinase K, subtilisin and $\alpha$-chymotrypsin). The coating efficiency of PLA blends onto paper was determined and the degrading activity cellulases by on these blends. The miscibility, coating efficiency and enzymatic degradability of these blends were decreased according to increasing of $_{D}-PLA$ blending part. Such results were attributed to the extent of coating application of PLA, with better miscibility (compatibility), coating efficiency and degradability due to a higher $_{L}-PLA$ content.

Synthesis and Charcterization of UV-curable Polyurethane Acrylates Coating Composition for PVC Tiles (PVC 바닥상재용 광경화형 폴리우레탄 아크릴 수지의 합성 및 특성고찰)

  • Zhao, Hong;Ha, Jin-Wook
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.80-83
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    • 2009
  • Application of UV curing technique for poly vinyl chloride (PVC) floor tiles coating has improved the quality of PVC floor. Various formulations including acrylated oligomers based on a polyurethane were blended with reactive monomers, photoinitiators and other additives. The used oligomers are commercial aliphatic urethane acrylates. Thin films were prepared on PVC tiles by bar coating with different formulations using UV radiation. The coating resins were characterized by FTIR. The properties of UV-cured films such as gloss grade and adhesion were examined. The properties of UV-cured films dependent on the influence of composition and processing conditions was studied. The investigation was conducted to achieve an optimal domain of composition and desired coating effect.

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Flow Analysis of the Spin Coating Machine

  • Ha, Man-Yeong;Kang, Dong-Hoon;Jeong, Bong-Kyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1147-1150
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    • 2003
  • When a braun tube becomes wider, one of the major problems to be experienced is the non-uniform coating along the four diagonal directions on its surface. This non-uniformity in the coating thickness has a deep relation with the fluid flow on the surface of a braun tube. In order to control the fluid flow properly, we install the plate to block fluid flow at the corner of a braun tube. In the present study, we investigate the effects of the geometry of plate to control the fluid flow and coating uniformity and determine the optimal shape of plate to improve the quality of coating uniformity.

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Hydrophobic Self-assembled monolayers(SAMs) coating for enhanced micromolding (Micromolding 기술의 성능 향상을 위한 소수성 SAM coating)

  • Park, Sang-Ha;Pak, Jung-Ho;Moon, Sung;Park, Jong-Oh
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1887-1889
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    • 2001
  • 금속 재질의 MEMS 구조물의 모양을 폴리머에 전사하는 micromolding 과정에서 금속 구조물과 폴리머 사이를 분리 (demolding)시킬 때 금속 구조물과 폴리머 기판 사이에 분리를 방해하는 응착 (Adhesion) 문제가 발생한다. 이러한 응착 문제를 줄이고자 표면 에너지가 낮은 Self-Assembled Monolayer(SAM) coating을 금속(Ni) 표면에 시도하였다. SAM coating 막의 형성 여부와 응착력 (Adhesion force) 값을 구하기 위해 각각 XPS(X-ray photoelectron spectroscopy)와 AFM(Atomic force microscopy)을 이용하여 측정하였고 측정 결과 Ni 표면에 SAM이 형성되었음을 XPS로부터 알 수 있었고 SAM coating된 Ni 시편에서 더 낮은 응착력값을 보여 주었다.

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Convergence study of mechanical properties and biocompatability of Ti Gr4 surface coated with HA using plasma spray for ossoeintegration (골융합 촉진을 위한 Ti Gr4의 HA 코팅에 대한 물리적 특성과 생체안정성에 대한 융합적 연구)

  • Hwang, Gab-Woon
    • Journal of the Korea Convergence Society
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    • v.12 no.12
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    • pp.145-151
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    • 2021
  • This study aimed to investigate the efficient conduct of HA coating on Ti Gr4 for the practical use of medical device. Ti Gr4 alloy specimens measuring 𝜱 25mm × 1mm were sprayed with hydroxyapatite using thermal spray according to ASTM F1185-88. The surface was evaluated at #120, #400, #1,000 sandpaper and barrel finishing. Each coating properties was analyzed using SEM, UTS 20,000psi cap. and in vitro cytotoxicity. Surface morphology consists of well molten particles with very little resolidified or unmolten areas. The average Ca/P ratio is 1.74 which is in good agreement with theoretical value of 1.67. The average roughness Ra is very representative of roughness of specimen. The coatings are dense and well adhered to the substrate. The average bond strength was 61.74 MPa with a standard deviation of 4.06 which indicates fairly reliable results for ASTM 633 type tests. Variations in results from jig design, epoxy used, crosshead speeds etc. in vitro cytotoxicity result had a Grade 3. The results of the study are expected to be helpful in osseointegration and plasma-spray HA coated Ti Gr4 are more satisfactory in HA coating thickness elevation which is preferable to any other system.