• Title/Summary/Keyword: H2 absorption

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The Effect of Temperature on Corrosion of Absorption Refrigeration Systems Using LiBr-$H_2O$ Working Fluids (LiBr-$H_2O$계 흡수식냉동기의 부식에 미치는 온도의 영향)

  • 임우조;정기철;윤병두;강성수
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2001.11a
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    • pp.92-97
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    • 2001
  • This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using LiBr-$H_2O$ working fluids. In the fresh water and 62 %lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(Cl220T-OL) and Ni-Al bronze was carried out. And Polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: As the experimental temperature increase, the change of corrosion rate of Ni-Al bronze become duller than SS 400 and Cu in 62 % lithium bromide solution. Open circuit potential of SS 400 is less noble than that of Cu and Ni-Al bronze in fresh water, but that becomes noble than Cu and Ni-Al bronze in 62 % lithium bromide solution. The corrosion sensitivity of Ni-Al bronze was controlled than that of Cu and SS 400 in 62% LiBr solution.

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Assessment of intestinal permeability of EGCG by piperine using Caco-2 cell monolayer system

  • Hwang, Se-hee;Lee, Jin-hee;Kim, Dae-kyong
    • Journal of Applied Biological Chemistry
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    • v.63 no.1
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    • pp.35-41
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    • 2020
  • (-)-epigallocatechin-3-gallate (EGGG), a flavonoid found in green tea, is known to have low bioavailability. In this study, we determine whether piperine, a natural bioenhancer, can increase the absorption rate of EGCG. Using a Caco-2 cell monolayer, permeability experiments were performed in Hanks' balanced salt solution (HBSS) and EGCG stability was adjusted to pH 6.5 and pH 5.5 by ascorbic acid treatment. When HBSS was adjusted to pH 6.5, EGCG remained at 94.78% for up to 2 h and remained at 86.04% after 4 h and the net efflux decreased compared to the control. As a result, uptake was significantly increased in the piperine co-administered group compared to the EGCG-alone group, showing that piperine increased the permeability of EGCG in the Caco-2 cell monolayer. These results suggest that piperine inhibits EGCG glucuronidation and efflux, allowing for greater absorption of EGCG.

Hydrogen Desorption and Absorption Properties of MgH2, LiBH4, and MgH2 + LiBH4 Composite

  • Park, Hye Ryoung;Song, Myoung Youp
    • Korean Journal of Metals and Materials
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    • v.50 no.12
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    • pp.955-959
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    • 2012
  • To increase the hydrogen storage capacity of Mg-based materials, a sample with a composition of 69.7 wt% $MgH_2$ + 30.3 wt% $LiBH_4$ was prepared by planetary ball milling under hydrogen. The absorption and desorption properties of unmilled $MgH_2$, unmilled $LiBH_4$, and 69.7 wt% $MgH_2$ + 30.3 wt% $LiBH_4$ were examined. At 648 K the unmilled $MgH_2$ desorbed 5.70 wt% for 60 min. The unmilled $LiBH_4$ desorbed 6.40 wt% H for 780 min at 673 K. The 69.7 wt% $MgH_2$ + 30.3 wt% $LiBH_4$ sample desorbed 3.10 wt% H for 50 min, and 3.32 wt% H for 300 min at 623 K at the second cycle.

Optimization of Parameters for Simultaneous Multielemental Analysis by Atomic Absorption Spectrometry (원자흡수분광법에 의한 다원소 동시분석시 조건의 최적화)

  • Kim, Hyo Jin;Kang, Jong Seong
    • Analytical Science and Technology
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    • v.6 no.4
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    • pp.359-362
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    • 1993
  • To find compromise experimental conditions that will allow a group of elements to be run on flame atomic absorption spectrometer without changing the burner height or gas flow rates, measurements were carried out. The optimum absorbance for simultaneous analysis of ten elements was observed at high flow rate of air-$C_2H_2$ as fuel and at 2mm of burner height. At the condition, 73% of mean relative absorbance were achieved.

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A Study on CO2 Removal by Chemical Absorption Using Structured Packing (규칙충전물을 적용한 화학흡수법에 의한 이산화탄소 제거에 관한 연구)

  • K?m, Jae-Hong;K?m, Hyoung-Ho;Kim, Jang-ho
    • Clean Technology
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    • v.9 no.1
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    • pp.43-48
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    • 2003
  • As a result of study on factor affecting absorption efficiency using the structured packing, Mellapak N. 250Y for the chemical absorption of $CO_2$ that cause global warming due to development of industry, it is shown that Mellapak N. 250Y has lower pressure drop and superior efficiency of mass transfer than 25mm Pall ring. Also, in the absorption process, it produces high efficiency in the increase of load and concentration of absorption liquid and produces low efficiency in the increase of temperature. In the effect of overall mass transfer coefficient for 15% MEA on the temperature variation of absorbent, when absorbent temperature for 15% MEA varied as 25, 50, $80^{\circ}C$, overall mass transfer coefficients were shown as 0.83, 1.00, $0.90kmol/m^3-h-kPa$.

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Pressure Drop and Refrigerant-Entrainment Characteristics of the Eliminators used in Absorption Chillers (흡수식 냉동기용 엘리미네이터의 압력손실 및 액적유입 특성)

  • 정시영;류진상;이상수;이정주
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.2
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    • pp.109-115
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    • 2003
  • The performance of two vertical-blade eliminators (V1, V2) and two horizontal-blade ones (H1, H2) for absorption chillers were tested in terms of pressure drop and refrigerant entrainment. The test was carried out using a wind tunnel with a cross section of 300 mm$\times$300 mm. The pressure drop of four eliminators tested was found to be in the rage of 1.0~2.7mm $H_2O$ at the face velocity of 2m/s. In the refrigerant entrainment test the vertical-blade eliminators showed much better performance than the horizontal-blade ones. The horizontal-blade eliminators showed satisfactory results at the air velocity of 2m/s but exceeded the limit value at 3 m/s. Since the cooling capacity of a machine is lowered by about 2.5% at the pressure drop of 1 m $H_2O$, more researches are required to reduce the pressure drop in the eliminator.

Heat and mass transfer characteristics in a vertical absorber (수직형 흡수기내 열 및 물질 전달 특성)

  • 서정훈;조금남;최기봉
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.6
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    • pp.835-845
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    • 1999
  • The objective of the present study was to investigate heat and mass transfer characteristics in a vertical falling film type absorber using LiBr-$H_2O$ solution with 6owt%. The experimental apparatus consisted of an absorber with inner diameter of 17.2 mm and length of 1150mm, a generator, an evaporator/condenser, a solution tank, a sampling trap etc. The parameters were solution temperature of 45 and $50^{\circ}C$, coolant temperature of 30 and $35^{\circ}C$, and film Reynolds numbers from 50 to 150. Pressure drop in the absorber increased as solution and coolant temperatures decreased. Pressure drop in the absorber increased up to the film Reynolds number of 90, and then decreased at the further increase of the Reynolds number above 90. The maximum absorption mass flux observed at the film Reynolds number of 90. Absorption mass flukes increased as coolant temperature decreased. Absorption mass fluxes and heat transfer coefficients under subcooled condition were larger than those under superheated condition. Heat transfer coefficients were affected by solution temperature more than coolant temperature. The maximum absorption effectiveness under the subcooled condition was 23% for coolant temperature of $30^{\circ}C$ and 31% for coolant temperature of $35^{\circ}C$ under the present experimental conditions.

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Mechanistic Studies of Ketoprofen Absorption in Perfused Rat Intestine Model (관류 랫드 장관모델에서의 케토프로펜의 흡수기전 연구)

  • Kim, Mi-Jeong;Lane, Majella E.
    • Journal of Pharmaceutical Investigation
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    • v.37 no.2
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    • pp.73-78
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    • 2007
  • The aim of this study was to investigate the absorption properties of ketoprofen. The in-situ perfusion model has advantages over in vitro models as it provides intact lymphatic and blood flow circulation. The absorption properties of six different concentrations of ketoprofen have been studied in single pass in-situ rat intestine model. $^{14}C-PEG$ 4000 was used as a permeability marker and the possibility of an energy dependent contribution to ketoprofen absorption was also Investigated using the metabolic inhibitor sodium azide. Three different concentrations of sodium azide were studied to examine its effect on absorption of ketoprofen from the rat intestine. The findings of this study suggest that mono-carboxylic type drugs like ketoprofen cause permeability changes in the intestine. This is shown by the increase in absorption of $^{14}C-PEG$ 4000 as the concentration of ketoprofen is increased. However, the trend for ketoprofen permeability is to decrease over the concentration ranges. It was observed that the Papp values for ketoprofen with sodium azide shows a trend towards reduction in the amount of ketoprofen absorbed from the rat intestine which was significantly different (p<0.05) from that of ketoprofen with sodium azide 3.0mM. This indicates that sodium azide has an affect on the absorption of ketoprofen. The pH of all the perfusion solutions was altered to ${\sim}pH\;6.7$ by the buffering capacity of the small intestine secretions. The results suggest that mechanisms other than passive diffusion may be involved in ketoprofen absorption. This would be consistent with the involvement of active transport or saturatable processes in the absorption of drugs containing monocarboxylic acid group, as has been previously suggested from in vitro data.

Hydrogen Absorption by Crystalline Semiconductors: Si(100), (110) and (111)

  • Jeong, Min-Bok;Jo, Sam-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.383-383
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    • 2010
  • Gas-phase hydrogen atoms create a variety of chemical and physical phenomena on Si surfaces: adsorption, abstraction of pre-adsorbed H, Si etching, Si amorphization, and penetration into the bulk lattice. Thermal desorption/evolution analyses exhibited three distinct peaks, including one from the crystalline bulk. It was previously found that thermal-energy gaseous H(g) atoms penetrate into the Si(100) crystalline bulk within a narrow substrate temperature window(centered at ~460K) and remain trapped in the bulk lattice before evolving out at a temperature as high as ~900K. Developing and sustaining atomic-scale surface roughness, by H-induced silicon etching, is a prerequisite for H absorption and determines the $T_s$ windows. Issues on the H(g) absorption to be further clarified are: (1) the role of the detailed atomic surface structure, together with other experimental conditions, (2) the particular physical lattice sites occupied by, and (3) the chemical nature of, absorbed H(g) atoms. This work has investigated and compared the thermal H(g) atom absorptivity of Si(100), Si(111) and Si(110) samples in detail by using the temperature programmed desorption mass spectrometry (TPD-MS). Due to the differences in the atomic structures of, and in the facility of creating atom-scale etch pits on, Si(100), (100) and (110) surfaces, the H-absorption efficiency was found to be larger in the order of Si(100) > Si(111) > Si(110) with a relative ratio of 1 : 0.22 : 0.045. This intriguing result was interpreted in terms of the atomic-scale surface roughening and kinetic competition among H(g) adsorption, H(a)-by-H(g) abstraction, $SiH_3(a)$-by-H(g) etching, and H(g) penetraion into the crystalline silicon bulk.

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