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Molecular Phylogenetic Study of Anemone pendulisepala (Ranunculaceae) (태백바람꽃(Anemone pendulisepala, Ranunculaceae)의 분자계통학적 검토)

  • Lee, Chang Shook;Lee, Nam Sook;Yeau, Sung Hee
    • Korean Journal of Plant Taxonomy
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    • v.36 no.4
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    • pp.263-277
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    • 2006
  • Anemone pendulisepala, recently described as a new species, is distributed in sympatry with A. reflexa, A. amurensis, and A. raddeana at Mt. taebeark and Mt. Baekdu. Anemone pendulisepala was previously proposed to be a hybrid species between A. reflexa and A. amurensis becaue it displavs overlapping features with them in involucre shape, petiole length, sepal apex and xylem shape, To verify the taxonomic status and to examine the hybridity of A. pendulisepala, sequences of ITS region of nuclear ribosomal DNA and the psba-trnH, rps16 and trnLF region of cpDNA from 36 accessions of 5 taxa including outgroup were analyzed. In maximum parsimony tree based on ITS sequences, A. pendulisepala had the same sequences of A. reflexa and was clustered with monophyletic A. amurensis, and then A. raddeana. Anemone pendulisepala was distinguished from the other taxa by having four base insertion in rps16 region, two species-specific bases and insertion in trnLF region. In the phylogenetic trees of combined cpDNA, A. pendulisepala showed monophyly with the bootstrap 100%. Anemone pendulisepala exhibited no polymorphism and shared no sequences with putative parental or related taxa examined in this study. Molecular data suggest that A. pendulisepala should be a distinct species, and no evidence of the hybridization was detectcd.

Photoluminescence Properties of CaNb2O6:RE3+ (RE = Dy, Eu, Dy/Eu) Phosphors (CaNb2O6:RE3+ (RE = Dy, Eu, Dy/Eu) 형광체의 발광 특성)

  • Cho, Hyungchel;Cho, Shinho
    • Korean Journal of Materials Research
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    • v.27 no.6
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    • pp.339-344
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    • 2017
  • A series of $CaNb_2O_6:Dy^{3+}$, $CaNb_2O_6$:$Eu^{3+}$ and $CaNb_2O_6:Dy^{3+}$, $Eu^{3+}$ phosphors were prepared by solid-state reaction process. The effects of activator ions on the structural, morphological and optical properties of the phosphor particles were investigated. XRD patterns showed that all the phosphors had an orthorhombic system with a main (131) diffraction peak. For the $Dy^{3+}$-doped $CaNb_2O_6$ phosphor powders, the excitation spectra consisted of one broad band centered at 267 nm in the range of 210-310 nm and three weak peaks; the main emission band showed an intense yellow band at 575 nm that corresponded to the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transition of $Dy^{3+}$ ions. For the $Eu^{3+}$-doped $CaNb_2O_6$ phosphor, the emission spectra under ultraviolet excitation at 263 nm exhibited one strong reddish-orange band centered at 612 nm and four weak bands at 536, 593, 650, and 705 nm. For the $Dy^{3+}$ and $Eu^{3+}$-codoped $CaNb_2O_6$ phosphor powders, blue and yellow emission bands due to the $^4F_{9/2}{\rightarrow}^6H_{15/2}$ and $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transitions of $Dy^{3+}$ ions and a main reddish-orange emission line at 612 nm resulting from the $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$ ions were observed. As the concentration of $Eu^{3+}$ ions increased from 1 mol% to 10 mol%, the intensities of the emissions due to $Dy^{3+}$ ions rapidly decreased, while those of the emission bands originating from the $Eu^{3+}$ ions gradually increased, reached maxima at 10 mol%, and then slightly decreased at 15 mol% of $Eu^{3+}$. These results indicate that white light emission can be achieved by modulating the concentrations of the $Eu^{3+}$ ions incorporated into the $Dy^{3+}$-doped $CaNb_2O_6$ host lattice.

Crystallographic Studies of Dehydrated $Ag^{+}\;and\;K^{+}$ Exchanged Zeolite A Reacted with Alkali Metal Vapor

  • Yang Kim;Mi Suk Jeong;Karl Seff
    • Bulletin of the Korean Chemical Society
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    • v.14 no.5
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    • pp.603-610
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    • 1993
  • The crystal structure of dehydrated $Ag_{5.6}K_{6.4}-A$, zeolite A ion-exchanged with $K^+\;and\;Ag^+$ as indicated and dehydrated at 360$^{\circ}$C, has been determined by single-crystal X-ray diffraction techniques. Also determined were the structures of the products of the reactions of this zeolite with 0.1 Torr of Cs vapor at 250$^{\circ}$C for 48 h and 72 h, and with 0.1 Torr of Rb vapor at 250$^{\circ}$C for 24 h. The structures were solved and refined in the cubic space group Pm3m at 21(l)$^{\circ}$C (a= 12.255(l) ${\AA}$ , 12.367(l) ${\AA}$, 12.350(l) ${\AA}$, and 12.263(l) ${\AA}$, respectively). Dehydrated $Ag_{5.6}K_{6.4}$-A was refined to the final error indices $R_1= 0.044\;and\;R_2=0.037$ with 202 reflections for which I>3${\sigma}$(I). The crystal structures of the reaction products were refined to $R_1=0.087\;and\;R_2= 0.089$ with 157 reflections, $R_1=0.080\;and\;R_2= 0.087$ with 161 reflections, and $R_1= 0.071\;and\;R_2=0.061$ with 88 reflections, respectively. In the structure of $Ag_{5.6}K_{6.4}-A,\;K^+$ ions block all 8-oxygen rings, and one reduced Ag atom is found per sodalite cavity. Also, ca. 4.6 $Ag^+ ions\;and\;3.4 K^+ ions$ are found at 6-ring sites in the large cavity. The crystal structures of the reaction products show that all $K^+$ and $Ag^+$ ions have been reduced, and that all K^+$ atoms have left the zeolite. Cs or Rb species are found at three different crystallographic sites: 3.0 $Cs^+\;or\;3.0Rb^+$ ions per unit cell occupy 8-ring centers, ca. 8.0 $Cs^+ ions\;or\;5.7 Rb^+$ ions, are found on threefold axes opposite 6-rings deep in the large cavity, and ca. 2.5 $Cs^+\;or\;2.3 Rb^+ ions are found on threefold axes in the sodalite unit. Also, 1 $Rb^+$ ion lies opposite a 4-ring. Silver atoms, corresponding to 75% or 40% occupancy of hexasilver clusters stabilized by coordination to $Cs^+\;or\;Rb^+$ ions, are found at the centers of the large cavities. In the crystal structures of dehydrated Ag_{5.6}K_{6.4}-A$ reacted with Cs vapor, excess Cs atoms are absorbed and these form (locally) cationic clusters such as $(Cs_4)3^+\;and\;(Cs_6)4^+$.

Sorption Characteristics of Cs on Weathered Biotite (흑운모 풍화에 따른 Cs 이온의 흡착 특성)

  • Kim, Ji-Yeon;Kim, Yeongkyoo
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.3
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    • pp.255-263
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    • 2015
  • To investigate the effect of the weathering process of biotite on Cs sorption, sorption experiment of Cs with $10^{-3}M$ solution was carried out on the biotite reacted at different reaction times at pH 2 and 4, and 1 M solutions of Na, K, Ca, Mg, Rb, and Cs. Peak changes were observed for some samples by XRD, indicating that new mineral phase formed by biotite weathering. Among several factors, cations in solutions have the most significant influence on the mineralogical changes. The samples reacted with Na showed the most outstanding change with increasing peak width and appearance of $12{\AA}$ peak and $14{\AA}$ peak. This new peaks indicate the formation of hydrobiotite and vermiculite. The new peaks had stronger peak intensity for the sample reacted at pH 4 than that at pH 2, probably due to the fast dissolution of small particles and edges and resultant decrease in the formation of expandable layers. The biotite reacted at Mg solution showed small intensity at $14{\AA}$. Based on XRD results, the degree of biotite weathering was in the order of Na, Mg, and Ca. The samples reacted with K, Rb, Cs solutions did not show noticeable mineralogical changes caused by weathering. The amount of sorbed Cs on weathered biotite showed close relationship with the degree of weathering indicated by XRD. At both pH 2 and 4, the biotite reacted with Na solution showed the highest Cs sorption, and those with Mg and Ca solutions showed the next highest ones. The sorbed amounts of Cs on the bitote reacted with K, Rb, Cs solutions were relatively low. This indicates that at the Cs concentration ($10^{-3}M$) which we used for this experiment and which was much higher than the maximum Cs concentration sorbed on the frayed edge site, expandable layer plays more important role than frayed edge. In the cases of K, Rb, and Cs solutions, Cs sorption was decreased because K is the same cations as the one in the interlayer or the sorption of Rb and Cs on the frayed edge prevents the formation of expandable layers.

Adaptive Error Detection Using Causal Block Boundary Matching in Block-Coded Video (블록기반 부호화 비디오에서 인과적 블록 경계정합을 이용한 적응적 오류 검출)

  • 주용수;김태식;김남철
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.8C
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    • pp.1125-1132
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    • 2004
  • In this Paper, we Propose an effective boundary matching based error detection algorithm using causal neighbor blocks to improve video quality degraded from channel error in block-coded video. The proposed algorithm first calculates boundary mismatch powers between a current block and each of its causal neighbor blocks. It then decides that a current block should be normal if all the mismatch powers are less than an adaptive threshold, which is adaptively determined using the statistics of the two adjacent blocks. In some experiments under the environment of 16bi1s burst error at bit error rates (BERs) of 10$^{-3}$ -10$^{-4}$ , it is shown that the proposed algorithm yields the improvements of maximum 20% in error detection rate and of maximum 3.5㏈ in PSNR of concealed kames, compared with Zeng's error detection algorithm.

A Study of Wildlife Roadkill in Joongang Highway (우리나라 야생동물의 도로치사에 관한 연구 -중앙고속도로의 동물치사 사례를 중심으로-)

  • Lee, Sang-Don;Cho, H.S.;Kim, J.G.
    • Journal of Environmental Impact Assessment
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    • v.13 no.1
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    • pp.21-31
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    • 2004
  • Construction of highway would influence wildlife habitat being fragmented and deteriorated. It is inevitable to observe the death of animals that are killed by vehicles. Nonetheless the cause and status of animal roadkill have not been studied, and this study first attempted to analyze the roadkill in major highway in Korea. We collected 860 individuals of dead animals in Joongang Highway during 1996-2003. Among them Korean hare(Lepus sinensis) was totaled in 165 individuals(19.2%) with the highest figure; Korean racoon dog(Nyctereutes procyonoides) was 146(17.0%); Korean squirrel(Sciurus vulgaris) 56(6.5%); Korean roe deer(Capreolus capreolus) 26(3.0%). Domestic animals was totaled in 232 individuals(27.0%); domestic dog(Canis familiairis) 25, and domestic cat(Catus felis) 207. This study also categorized habitat as mountain-mountain, mountain-plain, mountain-river, plain-plain, plain-river, river-river in each side of the road. Habitat of mountain-plain was the heightest with 296(38.9%) individuals followed by mountain-mountain with 263(34.6%). This indicates that wild animals associated with mountain habitat was most influenced by the construction of roads. This study implied that we should mitigate the roadkill by designing artificial construction such as eco-bridge, fences along the sideway, and boxes under the highway, underdrain structure, etc. The monitoring and cause of habitat fragmentation with GIS approach should be followed to reduce the roadkill.

Operating System level Dynamic Power Management for Robot (로봇을 위한 운영체제 수준의 동적 전력 관리)

  • Choi Seungmin;Chae Sooik
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.42 no.5 s.335
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    • pp.63-72
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    • 2005
  • This paper describes a new approach for the operating system level power management to reduce the energy consumed in the IO devices in a robot platform, which provides various functions such as navigation, multimedia application, and wireless communication. The policy proposed in the paper, which was named the Energy-Aware Job Schedule (EAJS), rearranges the jobs scattered so that the idle periods of the devices are clustered into a time period and the devices are shut down during their idle period. The EAJS selects a schedule that consumes the minimum energyamong the schedules that satisfy the buffer and time constraints. Note that the burst job execution needs a larger memory buffer and causes a longer time delay from generating the job request until to finishing it. A prototype of the EAJS is implemented on the Linux kernel that manages the robot system. The experiment results show that a maximum $44\%$ power saving on a DSP and a wireless LAN card can be obtained with the EAJS.

Synthesizing and Assessing Fire-Resistant Geopolymer from Rejected Fly Ash

  • An, Eung-Mo;Cho, Young-Hoon;Chon, Chul-Min;Lee, Dong-Gyu;Lee, Sujeong
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.253-263
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    • 2015
  • Ordinary Portland cement is a widely favored construction material because of its good strength and durability and its reasonable price; however, spalling behaviour during fire exposure can be a serious risk that can lead to strength degradation or collapse of a building. Geopolymers, which can be synthesized by mixing aluminosilicate source materials such as metakaolin and fly ash, and alkali activators, are resistant to fire. Because the chemical composition of geopolymers controls the properties of the geopolyers, geopolymers with various Si:Al ratios were synthesized and evaluated as fire resistant construction materials. Rejected fly ash generated from a power plant was quantitatively analyzed and mixed with alkali activators to produce geopolymers having Si:Al ratios of 1.5, 2.0, and 3.5. Compressive strength of the geopolymers was measured at 28 days before and after heating at $900^{\circ}C$. Geopolymers having an Si:Al ratio of 1.5 presented the best fire resistance, with a 44% increase of strength from 29 MPa to 41 MPa after heating. This material also showed the least expansion-shrinkage characteristics. Geopolymer mortar developed no spalling and presented more than a 2 h fire resistance rating at $1,050^{\circ}C$ during the fire testing, with a cold side temperature of $74^{\circ}C$. Geopolymers have high potential as a fire resistant construction material in terms of their increased strength after exposure to fire.

Reflection Characteristics of Vortical Slit Caisson Breakwater (종 SLIT형 케이슨 방파제의 반사특성)

  • 이종인;조지훈
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.13 no.4
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    • pp.263-272
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    • 2001
  • Recently, some attempts to construct slit caisson-type breakwaters are made in Korea. Since slit caisson-type breakwaters are suitable for relatively deep sea areas, a lot of theoretical and experimental researches have been performed. In this study, the reflection characteristics of vertical slit caisson breakwaters are investigated based on the measured data in two-dimensional hydraulic model tests with irregular waves. The experiments were conducted for various cases; variation of porosity of perforated-wall, width of wave chamber, number of slits for single-and double-chamber, respectively. It is found that in the case when the wave steepness (H/L$_{s}$ ) is small, the reflection coefficients are large. The existing researches have shown that the wave reflection is minimized when the nondimensional width of wave chamber B/L is about 0.2~0.25 for the regular waves. However, for the irregular waves the reflection is lowest when $B/L_2$, is 0.13~0.15. For a same porosity condition, the wave dissipation is stronger as the width of s1it is larger. The double-chamber caisson is superior to single- chamber caisson in the wave dissipating effects.

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Protective Effects of Silymarin against the Toxicity of Bisphenol A (BPA) on Boar Sperm Quality

  • Jang, Hyun-Young;Kong, Hong-Sik;Choi, Byoung-Yang;Shin, Jong-Suh;Cheong, Hee-Tae;Kim, Jong-Tack;Park, In-Chul;Park, Choon-Keun;Yang, Boo-Keun
    • Journal of Embryo Transfer
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    • v.26 no.4
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    • pp.257-263
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    • 2011
  • BPA, a diphenyl compound containing groups, that make it structurally similar to synthetic estrogen and is considered as one of the major endocrine disruptors. Silymarin has extensively been used to prevent and/or alleviate some human disease, especially for the treatment of adverse liver conditions. It has an antioxidative efficacy and cancer preventive efficacy. Therefore, we examined the hypothesis that silymarin can inhibit BPA-induced toxicity in boar sperm duing in vitro storage. Sperm characteristics (motility, viability, membrane integrity and mitochondrion activity) in semen exposed to BPA (10~200 uM) were sharply lowered, while it increase in a dose and time dependent manner due to silymarin addition (50~200 uM) into semen extender in the presence of BPA (100 uM). All of the evaluated characteristics were gradually improved in the groups that were treated with silymarin (50~200 uM) in the presence of BPA (100 uM) in comparison to BPA 100 uM alone group, irrespective of incubation periods (3 and 6 h). These results demonstrate that silymarin can ameliorate the toxicity of BPA on boar sperm characteristics during in vitro storage, suggesting that silymarin indirectly act as an antioxidant.