• 제목/요약/키워드: H-NMR spectroscopy

검색결과 628건 처리시간 0.045초

Production of Useful Chemicals from Sunflower Oil by Microorganisms

  • El-Sharkawy, Saleh Hassan
    • Natural Product Sciences
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    • 제1권1호
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    • pp.10-16
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    • 1995
  • A number of microorganisms have been screened for growth on sunflower oil as a sale carbon source for production of useful chemicals. Rhizopus stolonifer NRRL 1478 was found to transform the lipid contents of sunflower oil into dodecyl ${\beta}$-D-glucopyranoside and dodecanedioic acid in 15 and 25% yield respectively. The produced compounds were isolated and purified by column chromatography and its chemical identity were established using MS, IR, $^1H\;and\;^{13}C\;NMR$ spectroscopy.

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One Pot Synthesis of Bioactive Novel Cyanopyridones

  • Khokhani, Kamlesh;Khatri, Taslimahemad;Patel, Praful
    • 대한화학회지
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    • 제57권4호
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    • pp.476-482
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    • 2013
  • Cyanopyridone was prepared by the condensation of cyanoacetamide, substituted arylaldehydes and malononitrile in presence of pipyridine. The structure of the synthesized compound CP 1-20 was assigned on the basis of elemental analysis, IR, $^1H$-NMR and mass spectroscopy. These compounds were also screened for antimicrobial activity. The Minimum Inhibitory Concentration (MIC) of all the synthesized compounds was compared with standard drugs.

Investigation of Photoluminescence Properties for Dibenzosiloles and Tetrabenzospirosilole

  • 장승현
    • 통합자연과학논문집
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    • 제3권2호
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    • pp.107-111
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    • 2010
  • Silicon-containing ${\pi}$-conjugated compounds, especially silacyclopentadienes (siloles), have emerged as a new class of electroactive materials with good electron transport properties in OLEDs. 9,9'-spiro-9-silabifluorene compound as well as its starting material 2,2'-dibromobiphenyl have been synthesized with higher yields. Spirosilabifluorene is expected to be an efficient host material for the blue-light emitting diodes. 9,9'-spiro-9-silabifluorene, 1,1-dichloro-1-silafluorene, and 1,1-dimethyl-1-silafluorene were characterized by $^1H$-NMR, UV/Vis and photoluminescence spectroscopy.

Anion Receptors with 2-Imidazolidone Molecular Scaffold

  • Kim, Hyung-Il;Kang, Jong-Min
    • Bulletin of the Korean Chemical Society
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    • 제28권9호
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    • pp.1531-1534
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    • 2007
  • Anion receptor based on 2-imidazolidone molecular scaffold has been synthesized. Anion binding studies carried out using 1H NMR and UV?vis spectroscopy revealed that this receptor 6 displays selectivity for the for the oxyanions such as acetate and dihydrogenphosphate ions and the affinity for the anions simply reflects the basicity of anions.

Potentilla속 식물의 성분연구 -3, 3', 4-tri-O-methylellagic acid의 분리 및 동정- (Components of Potentilla Species -Isolation and Identification of 3, 3', 4-tri-O-methylellagic acid-)

  • 김학성
    • 약학회지
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    • 제33권6호
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    • pp.377-379
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    • 1989
  • The methylated compound of ellagic acid was isolated from Potentilla chinensis (Rosaceae). The isolated compound was 3, 3', 4-tri-O-methylellagic acid, [2, 3, 7-trimethoxy-8-hydroxy[1] benzopyrano-[5, 4, 3, cde][1] benzopyran-5, 10-dione], $C_{17}H_{12}O_8$, m.p. $293-295^{\circ}C$. The isolation of trimethylellagic acid was conducted by the column chromatography and the identification of the compound was carried out by the methods of IR, NMR and MS spectroscopy.

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Pentiptycene Diacetylene의 합성 (Synthesis of Pentiptycenediacetylene)

  • 한정민;권형준
    • 통합자연과학논문집
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    • 제2권2호
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    • pp.69-72
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    • 2009
  • Pentiptycenediacetylene is very useful precursor materials for the synthesis of conducting polymer materials. The incorporation of rigid three-dimensional pentiptycene moieties into conjugated polymer backbones would offer several design advantages. They prevent ${\pi}$-stacking of the polymer backbones and thereby maintain high fluorescence quantum yields and spectroscopic stability in thin films. The pentiptycenediactylene was synthesized and characterized by 1H- and 13C-NMR spectroscopy.

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Lewis Acid Catalysis of Coumarin and 5,7-Dimethoxycoumarin Photodimerization

  • Shim, Sang-Chul;Kim, Eun-Il;Lee, Ki-Taek
    • Bulletin of the Korean Chemical Society
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    • 제8권3호
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    • pp.140-144
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    • 1987
  • The effect of Lewis acids on spectroscopic properties and photodimerization of coumarin and 5,7-dimethoxycoumarin was investigated. Quantum yields of coumarin photodimerization increase in the presence of $BF_3{\cdot}OEt_2$ but those of 5,7-dimethoxycoumarin decrease. The spectroscopic properties of the coumarin-$BF_3{\cdot}OEt_2$ and 5,7-dimethoxycoumarin-$BF_3{\cdot}OEt_2$ complexes were studied by UV, IR, $^1H$ NMR and fluorescence spectroscopy.

Synthesis of Calix[4]arenes in AAAB or AABB Type Substitution at Upper Rim

  • 노광현;권경미;김종은
    • Bulletin of the Korean Chemical Society
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    • 제17권6호
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    • pp.525-528
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    • 1996
  • Seven cali[4]arenes, having two different substituents in AAAB or AABB pattern at the upper rim of calix were synthesized by fragmentation condensation reaction of p-substituted phenol trimer (AAA) with 2,6-bishydroxymethylated 4-substituted phenol (B) or that of dimer (AA) with 2,2'-bishydroxymethylated dimer (BB). An equimolar mixture of the coupling components (trimer and monomer or dimer and dimer) was refluxed in dioxane in the presence of TiCl4to afford calix[4]arene 6 and 7 in 15-38% yield. The structure of calix[4]arenes was confirmed by elemental analysis and the 1H/13C NMR spectroscopy.